MATERIAL SAFETY DATA SHEET PAGE 1 OF X - Germiphene

MATERIAL SAFETY DATA SHEETProduct name:Last revised date:Print date:PEDI-PURGE23-Dec-1021-Jul-111. SUBSTANCE AND SUPPLIER IDENTIFICATIONPRODUCT NAME:Pedi-PurgeMANUFACTURER:ADDRESS:PHONE: 519-759-7100FAX: 519-759-1625Germiphene Corporation1379 Colborne Street East, Brantford,Ontario N3T 5M1, CanadaEMERGENCY PHONE: CANUTEC 613-996-6666PRODUCT USE:Disinfectant for use in SPA foot bath & bath lines.2. COMPOSITION / INFORMATION ON INGREDIENTSINGREDIENT: N,N-Didecyl-N,N-dimethylammonium chlorideCAS No 7173-51-5 % wt 9.22HAZARDOUS: YesINGREDIENT: N-Alkyl(C12-16)-N,N-dimethyl-N-benzylammonium chlorideCAS No 8001-54-5 % wt 6.14HAZARDOUS: YesINGREDIENT: N,N-Dimethyl-1-octylamine-N-oxideCAS No 2605-78-9 % wt 8.0HAZARDOUS: YesINGREDIENT: Ethylenediaminetetraacetic acid, trisodium saltCAS No 150-38-9 % wt 3.0HAZARDOUS: YesINGREDIENT: Sodium HydroxideCAS No 1310-73-2 % wt 1.35HAZARDOUS: Yes3. HAZARD IDENTIFICATIONPRIMARY ROUTES OF ENTRY: Skin contact, inhalation, eye contact.EFFECTS OF OVEREXPOSURE: Based on information available for similar products, it isanticipated that direct contact will produce severe eyeand skin irritation and/or burns and possible irreversibledamage. Solvent vapors or mists of product can produceirritation of the mucous membranes. Ingestion can produceimmediate burning pain in the mouth, throat and abdomen;severe swelling of the larynx; skeletal muscle paralysisaffecting the ability to breath; circulatory shock; and/orconvulsions.OVEREXPOSURE MAY AGGRAVATE EXISTING CONDITIONS: No effects indicated.Germiphene Corporation Page 1 of 7

MATERIAL SAFETY DATA SHEETProduct name:Last revised date:Print date:PEDI-PURGE23-Dec-1021-Jul-118. EXPOSURE CONTROLS / PERSONAL PROTECTIONENGINEERING CONTROLS:RESPIRATORY PROTECTION:PROTECTIVE GLOVES:EYE PROTECTION:In processes where mists or vapors may be generated,proper ventilation must be provided in accordance withgood ventilation practices.In processes where mists or vapors may be generated, aNIOSH/MSHA jointly approved respirator is advised inthe absence of proper environmental controls.Rubber or neoprene, to prevent skin contact.Wear chemical splash goggles if there is a potentialfor eye contact. Use safety glasses with side shieldsif there is no potential for eye contact.OTHER PROTECTIVE EQUIPMENT: Eye wash; safety shower; protective clothing (longsleeves, coveralls or other, as appropriate), toprevent skin contact.9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE:Clear,colourless to light yellow or pale straw colored liquidODOUR:Varies with fragrance added (if any)PHYSICAL STATE: LiquidPH: 6.0-8.0BOILING POINT: Not knownMELTING POINT: Not knownFREEZING POINT: Not knownSPECIFIC GRAVITY: 0.98-1.08 g/mlEVAPORATION RATE: Not knownSOLUBILITY IN WATER: SolubleVISCOSITY:Not knownFLASH POINT:Not known10. STABILITY AND REACTIVITYSTABILITY: StableCONDITIONS TO AVOID: None known.INCOMPATIBILITY (MATERIAL TO AVOID): Strong oxidizing or reducing agents.HAZARDOUS DECOMPOSITION PRODUCTS OR BY-PRODUCTS: Thermal decomposition may producetoxic vapors/fumes of hydrogenchloride, amines and otherorganic materials, and oxides ofcarbon and nitrogen.Germiphene Corporation Page 3 of 7

MATERIAL SAFETY DATA SHEETProduct name:Last revised date:Print date:PEDI-PURGE23-Dec-1021-Jul-1111. TOXICOLOGICAL INFORMATIONNo toxicity information is available for this product. The information providedbelow is for closely related products:ACUTE Oral RAT LD50 1650 mg/kgDermal rabbit LD50 1870 mg/kgEye irritation rabbit, severeSkin irritation rabbit, severeSkin corrosivity (DOT method), corrosive12. ECOLOGICAL INFORMATIONN/Av13. DISPOSAL CONSIDERATIONSWASTE DISPOSAL METHOD:According to state, federal, provincial, and localregulations. Incineration is the preferred method.CONTAINER DISPOSAL:Triple rinse (or equivalent). Then offer for recycling orreconditioning, or puncture and dispose of in a sanitarylandfill, or incineration, or, if allowed by state and localauthorities, by burning. If burned, stay out of smoke.14. TRANSPORT INFORMATIONTRANSPORT HAZARD CLASS: N/Av15. REGULATORY INFORMATIONUSA FEDERAL LEVEL REGULATIONS:TOXIC SUBSTANCES CONTROL ACT (TSCA INVENTORY) STATUS:All components in this product are listed on the US EPA TSCA 8(b) inventoryTSCA Section 12(b) Export NotificationComponents present in this product which, if exported, could require either annualor one-time reporting under this regulation are as follows:Typical MaximumChemical Name CAS Number ConcentrationNone knownUS EPA Regulation on Pesticides:This is an EPA registered pesticide (EPA Registration No. 47371-129). Thismaterial can only be used commercially in the EPA registered application(s)noted on the product label.Germiphene Corporation Page 4 of 7

MATERIAL SAFETY DATA SHEETProduct name:Last revised date:Print date:PEDI-PURGE23-Dec-1021-Jul-11CERCLA (Comprehensive Environmental Response, Compensation and Liability Act of1980 requires notification of the National Response Center(Telephone 800-424-8802) in the event of a release of quantities of thefollowing hazardous materials contained in this product, if the release isequal to or greater than the Reportable Quantities (RQs) listed in40 CFR 302.4:Typical MaximumChemical Name CAS Number ConcentrationNone knownSARA Title III, Sections 302/304 (Superfund Amendments and Reauthorization act of1986) - This act requires emergency planning, including agency notification, forpossible release of the following components of this material, based upon theThreshold Planning Quantities (TPQs) and release Reportable Quantities (RQs)listed for the Components in 40 CFR 355:Typical MaximumChemical Name CAS Number ConcentrationNone knownSARA Title III Sections 311/312 - This act requires reporting under the CommunityRight-to-Know provisions due to the inclusion of the following components of thismaterial in one or more of the five hazard categories listed in 40 CFR 370:Hazard *)Chemical Name CAS Number CategoriesN,N-Didecyl-N,N-dimethylammonium chloride 7173-51-5 AN-Alkyl(C12-16)-N,N-dimethyl-N-benzylammonium 68424-85-1 AchlorideN,N-Dimethyl-1-octylamine-N-oxide 2605-78-9 AEthanol 64-17-5 F*) The five hazard categories are as follows: F=FIRE HAZARD; S= SUDDEN RELEASE OFPRESSURE; R=REACTIVE; A=IMMEDIATE (ACUTE) HEALTH HAZARD; C=DELAYED (CHRONIC)HEALTH HAZARDSARA Title III Section 313 - This act requires submission of annual reports off thereleases of the following components of this material if the threshold reportingquantities as listed in 40 CFR 372, are met or exceeded:Typical MaximumChemical Name CAS Number ConcentrationNone knownSTATE RIGHT-TO-KNOW REGULATIONS:Germiphene Corporation Page 5 of 7

MATERIAL SAFETY DATA SHEETProduct name:Last revised date:Print date:PEDI-PURGE23-Dec-1021-Jul-11CALIFORNIA PROPOSITION 65 - Components present in this material which the State ofCalifornia has found to cause cancer, birth defects or other reproductive harmare as follows:AS A CANCER HAZARDTypical MaximumChemical Name CAS Number ConcentrationNone knownAcetaldehyde 75-07-0 300 ppbBenzene 71-43-2 15 ppmBenzyl chloride 100-44-7 30 ppmN-Nitrosodimethylamine 62-75-9 160 ppbPropylene oxide 75-56-9 3 ppmAS A REPRODUCTIVE HAZARDTypical MaximumChemical Name CAS Number ConcentrationBenzene 71-43-2 15 ppmToluene 108-88-3 15 ppmMASSACHUSETTS Right-to-Know - The following components of this material are includedin the Massachusetts Substance List and are present at or above reportablelevels:Typical MaximumChemical Name CAS Number ConcentrationAcetaldehyde 75-07-0 300 ppbBenzene 71-43-2 15 ppmBenzyl chloride 100-44-7 30 ppmSodium Hydroxide 1310-73-2 1.35 %Hydrogen peroxide 7722-84-1 30 ppmPropylene oxide 75-56-9 3 ppmMICHIGAN Critical Materials - The following components of this material are includedin the Michigan Critical Materials List:Typical MaximumChemical Name CAS Number ConcentrationNone knownNEW JERSEY Right-to-Know - The following components of this material are included inthe New Jersey Hazardous Substance List and are present at or above reportablelevels:Typical MaximumChemical Name CAS Number ConcentrationN,N-Didecyl-N,N-dimethylammonium chloride 7173-51-5 9.70%N-Alkyl(C12-16)-N,N-dimethyl-N-benzylammonium 68424-85-1 6.47%chlorideSodium Hydroxide 1310-73-2 1.35 %PENNSYLVANIA Right-to-Know - The following components of this material are includedGermiphene Corporation Page 6 of 7

MATERIAL SAFETY DATA SHEETProduct name:Last revised date:Print date:PEDI-PURGE23-Dec-1021-Jul-11in the Pennsylvania Hazardous Substance List and are present at or abovereportable levels:Typical MaximumChemical Name CAS Number ConcentrationSodium Hydroxide 1310-73-2 1.35 %16. OTHER INFORMATIONPREPARED BY:Germiphene Technical DepartmentDisclaimerNo representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, orof any nature are made with respect to the product or information contained in this Material Safety Data Sheet. Allinformation contained herein is presented in good faith and is believed to be appropriate and accurate. However, neitherthe above named supplier, nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completenessof the information contained herein. Final determination of suitability of any material is the sole responsibility ofthe user. All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist. The buyer or user assumes all risksassociated with the use, misuse or disposal of this product. The buyer or user is responsible to comply with allfederal, state, provincial, or local regulations concerning the use, misuse, or disposal of these products.Germiphene Corporation Page 7 of 7