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ION-EXCHANGE RESINS<br />
An <strong>ion</strong>-<strong>exchange</strong> <strong>resin</strong> is an insoluble matrix<br />
in the form of small (1–2 mm diameter)<br />
beads, usually white or yellowish, fabricated<br />
from an organic polymer substrate. The<br />
material has highly developed structure of<br />
pores on the surface which are sites where<br />
<strong>ion</strong>s are easily trapped and released. The<br />
trapping of <strong>ion</strong>s takes place only with<br />
simultaneous releasing of other <strong>ion</strong>s, thus<br />
the process is called <strong>ion</strong>-<strong>exchange</strong>.<br />
Depending on the applicat<strong>ion</strong>, there are<br />
different types of <strong>ion</strong>-<strong>exchange</strong> <strong>resin</strong><br />
available. As beads they are widely used in<br />
different separat<strong>ion</strong>, purificat<strong>ion</strong>, and<br />
decontaminat<strong>ion</strong> processes. The most<br />
common examples are water softening and<br />
water purificat<strong>ion</strong>.<br />
Water softening<br />
In this applicat<strong>ion</strong>, <strong>ion</strong>-<strong>exchange</strong> <strong>resin</strong>s are used to replace the magnesium and calcium<br />
<strong>ion</strong>s found in hard water with sodium <strong>ion</strong>s. When the <strong>resin</strong> is fresh, it contains sodium <strong>ion</strong>s<br />
at its active sites. When in contact with a solut<strong>ion</strong> containing magnesium and calcium <strong>ion</strong>s<br />
(but a low concentrat<strong>ion</strong> of sodium <strong>ion</strong>s), the magnesium and calcium <strong>ion</strong>s preferentially<br />
migrate out of solut<strong>ion</strong> to the active sites on the <strong>resin</strong>, being replaced in solut<strong>ion</strong> by sodium<br />
<strong>ion</strong>s. This process reaches equilibrium with a much lower concentrat<strong>ion</strong> of magnesium and<br />
calcium <strong>ion</strong>s in solut<strong>ion</strong> than was started with.<br />
The <strong>resin</strong> can be recharged by washing it with a solut<strong>ion</strong> containing a high concentrat<strong>ion</strong> of<br />
sodium <strong>ion</strong>s (e.g. it has large amounts of common salt (NaCl) dissolved in it). The calcium<br />
and magnesium <strong>ion</strong>s migrate off the <strong>resin</strong>, being replaced by sodium <strong>ion</strong>s from the solut<strong>ion</strong><br />
until a new equilibrium is reached.<br />
Water purificat<strong>ion</strong><br />
In this applicat<strong>ion</strong>, <strong>ion</strong>-<strong>exchange</strong> <strong>resin</strong>s are used to remove poisonous (e.g. copper) and<br />
heavy metal (e.g. lead or cadmium) <strong>ion</strong>s from solut<strong>ion</strong>, replacing them with more innocuous<br />
<strong>ion</strong>s, such as sodium and potassium.<br />
Few <strong>ion</strong>-<strong>exchange</strong> <strong>resin</strong>s remove chlorine or organic contaminants from water - this is<br />
usually done by using an activated charcoal filter mixed in with the <strong>resin</strong>. There are some<br />
<strong>ion</strong>-<strong>exchange</strong> <strong>resin</strong>s that do remove organic <strong>ion</strong>s, such as MIEX (magnetic <strong>ion</strong>-<strong>exchange</strong>)<br />
<strong>resin</strong>s. Domestic water purificat<strong>ion</strong> <strong>resin</strong> is not usually recharged - the <strong>resin</strong> is discarded<br />
when it can no longer be used.<br />
g:\homepage - 2010\dateien sar\<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong>.doc<br />
27.04.11<br />
<strong>Tedimex</strong> GmbH · Hittfelder-Kirchweg 21 · D-21220 Seevetal<br />
phone: +49 4105 598 62 10 · fax +49 4105 598 62 20 · sales@tedimex.de · www.tedimex.de
MB 400<br />
MB 400 <strong>resin</strong> is a ready for use mixture of powdered cat<strong>ion</strong> and an<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong>s. This<br />
<strong>resin</strong> is designed to be applied to pre-coat filters to demineralise and filter liquids to a high<br />
degree of purity.<br />
MB 400 <strong>resin</strong> is the ideal choice for the treatment of neutral or slightly alkaline condensates<br />
and offers the following advantages:<br />
• Total absence of unpleasant smell,<br />
• Highly efficient filtrat<strong>ion</strong>,<br />
• Cycles usually longer, resulting in less <strong>resin</strong> consumpt<strong>ion</strong>,<br />
• Reduct<strong>ion</strong> in the volume of spent <strong>resin</strong> sludge to be destroyed or stored.<br />
MB 400 <strong>resin</strong> is prepared from <strong>resin</strong>s which have been nearly 100% regenerated with a<br />
high-purity reagent.<br />
Typical Properties<br />
These properties are typical but do not constitute specificat<strong>ion</strong>s !<br />
Cat<strong>ion</strong> component 75% dry weight<br />
An<strong>ion</strong> component 25% dry weight<br />
Ionic form as shipped H + /OH -<br />
Cat<strong>ion</strong>ic <strong>exchange</strong> capacity 4,8 meq/g of dry <strong>resin</strong> (minimum)<br />
An<strong>ion</strong>ic <strong>exchange</strong> capacity 3,5 meq/g of dry <strong>resin</strong> (minimum)<br />
Moisture content 52 to 57% (approximate)<br />
Purity<br />
Convers<strong>ion</strong> H + > 98% OH - > 94%<br />
Iron < 50 ppm of dry matter<br />
Copper < 50 ppm of dry matter<br />
Aluminium < 50 ppm of dry matter<br />
Heavy metals (as Lead) < 10 ppm of dry matter<br />
Typical Condit<strong>ion</strong>s of Use<br />
Quantity 0,7 to 1 kg/m 2 of filter area<br />
Filtrat<strong>ion</strong> rate 5 to 10 m/h, usually about 8 m/h, i.e, 8 m 3 /m 2 /h of filter area<br />
Temperature 60 to 100°C (100°C in a thermal power stat<strong>ion</strong>)<br />
Pressure drop Pressure drop due to the micro-<strong>resin</strong> is very low (no<br />
turbidity in the supernatant) usually 0,05 to 0,1 bar<br />
(excluding the pressure drop due to the filter) at the<br />
Precoat replacement<br />
beginning of the cycle<br />
Pressure drop: 1,5 to 1,8 bar or conductivity: 1µS/cm or<br />
effluent = influent or <strong>ion</strong>ic leakage<br />
We reserve the right to change specificat<strong>ion</strong>s without further notice !<br />
g:\homepage - 2010\dateien sar\<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong>.doc<br />
27.04.11<br />
<strong>Tedimex</strong> GmbH · Hittfelder-Kirchweg 21 · D-21220 Seevetal<br />
phone: +49 4105 598 62 10 · fax +49 4105 598 62 20 · sales@tedimex.de · www.tedimex.de
MB 20<br />
AMBERLITE MB20 is an <strong>ion</strong>ically equilibrated mixed bed <strong>resin</strong>. Ready for use, it is a mixture<br />
of a strongly acidic cat<strong>ion</strong> <strong>exchange</strong>r with a strongly basic type 1 an<strong>ion</strong> <strong>exchange</strong>r.<br />
AMBERLITE MB20 has been developed for the product<strong>ion</strong> of high purity water. It can be<br />
used for all applicat<strong>ion</strong>s requiring totally demineralised water, free of silica and of carbon<br />
dioxide.<br />
PROPERTIES<br />
Composit<strong>ion</strong> in volume *1<br />
Cat<strong>ion</strong> component : 38 to 44 %<br />
An<strong>ion</strong> component : 56 to 62 %<br />
Ionic form as shipped H + / 0H -<br />
Bulk density *1<br />
665 to 740 g/l<br />
Chemical stability Insoluble in water, dilute solut<strong>ion</strong> of<br />
acids and bases or common solvents<br />
*1 = Contractual value<br />
Test methods are available on request.<br />
SUGGESTED OPERATING CONDITIONS<br />
Maximum operating temperature 60°C<br />
Minimum bed depth 700 mm<br />
Service flow rate 20 to 40 BV/h *2<br />
Regenerants Cat<strong>ion</strong> component : HCl or H2S04<br />
An<strong>ion</strong> component : NaOH<br />
*2 = 1 BV (bed volume) = 1m³ solut<strong>ion</strong> per m³ <strong>resin</strong><br />
We reserve the right to change specificat<strong>ion</strong>s without further notice !<br />
g:\homepage - 2010\dateien sar\<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong>.doc<br />
27.04.11<br />
<strong>Tedimex</strong> GmbH · Hittfelder-Kirchweg 21 · D-21220 Seevetal<br />
phone: +49 4105 598 62 10 · fax +49 4105 598 62 20 · sales@tedimex.de · www.tedimex.de
AMBERJET 1200 Na<br />
AMBERJET 1200 Na is a uniform particle size, high quality, strong acid cat<strong>ion</strong> <strong>exchange</strong>r<br />
designed for use in all water treatment applicat<strong>ion</strong>s: softening as well as demineralisat<strong>ion</strong>.<br />
The uniformity and mean particle size of AMBERJET 1200 Na has been optimised for<br />
use in industrial equipment. In H + cycle, it can be used in mixed bed applicat<strong>ion</strong>s paired with<br />
AMBERJET 4200 CL.<br />
AMBERJET 1200 Na can be directly substituted for convent<strong>ion</strong>al gel cat<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong><br />
in new equipment and in rebeds of existing installat<strong>ion</strong>s.<br />
PROPERTIES<br />
Matrix Styrene divinylbenzene copolymer<br />
Funct<strong>ion</strong>al groups SO3<br />
Physical form Insoluble, amber beads<br />
Ionic form as shipped Na +<br />
<strong>exchange</strong> capacity * > 2,0 eq /l (Na + form)<br />
Moisture holding capacity * 43 to 47 % (Na + form)<br />
Shipping weight 850 g/L<br />
Specific gravity 1,26 to 1,30 (Na + form)<br />
Uniformity coefficient * < 1,2<br />
Harmonic mean size 620 ± 50 pm<br />
Fines content * < 0,300 mm : 0.1 % max<br />
Coarse beads > 0,850 mm : 10 % max<br />
Maximum reversible swelling Na + → H + : 10 %<br />
* = Contractual value Test methods are available on request.<br />
SUGGESTED OPERATING CONDITIONS<br />
Minimum bed depth 800 mm<br />
Service flow rate 5 to 50 BV/h **<br />
Maximum service velocity 60 m/h<br />
Regenerant NaCl HCl H2S04<br />
Level 50 - 240 40 - 150 40 - 200<br />
Concentrat<strong>ion</strong> 10 4 - 10 1 - 8<br />
Flow rate 2 - 8 2 - 5 2 - 20<br />
Minimum contact time 20 minutes<br />
Slow rinse 2 BV at regenerat<strong>ion</strong> flow rate<br />
Fast rinse 1 to 3 BV at service flow rate<br />
** 1 BV (Bed Volume) = 1 m3 solut<strong>ion</strong> per m3 <strong>resin</strong><br />
We reserve the right to change specificat<strong>ion</strong>s without further notice !<br />
g:\homepage - 2010\dateien sar\<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong>.doc<br />
27.04.11<br />
<strong>Tedimex</strong> GmbH · Hittfelder-Kirchweg 21 · D-21220 Seevetal<br />
phone: +49 4105 598 62 10 · fax +49 4105 598 62 20 · sales@tedimex.de · www.tedimex.de
AMBERJET 4200 CL<br />
AMBERJET 4200 CL is a uniform particle size, gelular, high quality, strong base type 1<br />
an<strong>ion</strong> <strong>exchange</strong>r designed for use in all general demineralizat<strong>ion</strong> systems. The uniformity<br />
and mean particle size of AMBERJET 4200 CL have been optimized for use in industrial<br />
equipment including mixed beds, when paired with AMBERJET 1200 H, AMBERJET 1200<br />
Na or AMBERJET 1500 H.<br />
AMBERJET 4200 CL can be directly substituted for convent<strong>ion</strong>al gel an<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong><br />
in new equipment and in rebeds of existing installat<strong>ion</strong>s.<br />
PROPERTIES<br />
Matrix Styrene divinylbenzene copolymer<br />
Funct<strong>ion</strong>al Groups Type 1 quaternary amine<br />
Physical Form Insoluble, light amber beads<br />
Ionic Form as Shipped Chloride<br />
Total Exchange Capacity 1.30 meq/ml minimum (C1 - form)<br />
Moisture Holding Capacity 49 to 55% (C1 - form)<br />
Shipping Weight 42 lbs/ft³<br />
Harmonic mean size 0.60 to 0.80 mm<br />
Uniformity Coefficient 1.25 maximum<br />
Maximum Reversible Swelling Cl - → OH - : approximately 20 %<br />
Test methods are available on request.<br />
SUGGESTED OPERATING CONDITIONS<br />
pH Range 0 - 14<br />
Maximum Operating Temperature 140 °F (OH - form) / 170 °F (C1 - form)<br />
Minimum Bed Depth 24 inches<br />
Service Flow Rate 1 to 6 gpm/ft³<br />
Maximum Service Velocity 25 gpm/ft 2<br />
Regenerant (100% basis) NaOH<br />
Maximum Regenerat<strong>ion</strong> Temperature 120 °F maximum<br />
Flow Rate 0.25 - 1 gpm/ft³<br />
Concentrat<strong>ion</strong> 2 - 5 %<br />
Level 3 - 10 lbs/ft³<br />
Minimum Contact Time 20 minutes<br />
Slow Rinse 15 gal/ft³ at regenerat<strong>ion</strong> flow rate<br />
Fast Rinse 25 to 50 gal/ft³ at service flow rate<br />
We reserve the right to change specificat<strong>ion</strong>s without further notice !<br />
g:\homepage - 2010\dateien sar\<strong>ion</strong> <strong>exchange</strong> <strong>resin</strong>.doc<br />
27.04.11<br />
<strong>Tedimex</strong> GmbH · Hittfelder-Kirchweg 21 · D-21220 Seevetal<br />
phone: +49 4105 598 62 10 · fax +49 4105 598 62 20 · sales@tedimex.de · www.tedimex.de