Bio San - Swisher Hygiene

Material Safety Data SheetIssuing date 11-Oct-2011 Revision Date 28-Nov-2011 Version 11. PRODUCT AND COMPANY IDENTIFICATIONProduct nameProduct codeReference number(s)UN/ID NoRecommended UseEPA Registration NumberSwisher Bio San42088-142088-5UN1791Sanitizer550-197-72802DistributorSwisher Hygiene Inc.4725 Piedmont Row Drive,Suite 400,Charlotte, NC 28210Chemical Emergency PhoneNumberCompany Emergency PhoneNumber800-424-9300 (Chemtrec)800-444-4138Appearance Clear Liquid2. HAZARDS IDENTIFICATIONEmergency OverviewCauses severe irritation to eyes, skin, and mucous membranes.Physical state liquid.Odor Pungent, ChlorinePotential Health EffectsAcute toxicityEyesSkinInhalationIngestionChronic EffectsAggravated Medical ConditionsEnvironmental hazardSevere irritation and burningReddening, eczemaBronchial irritation, cough, difficulty breathingIrritation of membranes of the mouth, throat, and stomach pain and possible ulcerationNo known effect based on information suppliedNone known.See Section 12 for additional Ecological Information3. COMPOSITION/INFORMATION ON INGREDIENTSThis product is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)._____________________________________________________________________________________________Page 1 / 7

42088-1 - Swisher Bio San Revision Date 28-Nov-2011_____________________________________________________________________________________________Chemical NameSodium hypochloriteCAS-No7681-52-9Weight %10-154. FIRST AID MEASURESEye contactSkin contactInhalationIngestionNotes to physicianFlush eyes with cool water for 15-30 minutes and get immediate medical attention.Flush with water. Remove contaminated clothing and do not re-wear until washed. Ifirritation persists, see a physician.Move to fresh air If irritation persists, see a physicianDrink water or milk. DO NOT INDUCE VOMITING. DO NOT USE BAKING SODA ORACIDIC ANTIDOTES. Get medical attention immediately.Treat symptomatically5. FIRE-FIGHTING MEASURESFlammable PropertiesFlash pointSuitable Extinguishing MediaExplosion DataSensitivity to Mechanical ImpactSensitivity to Static DischargeSpecific hazards arising from thechemicalProtective Equipment andPrecautions for FirefightersNot flammableN/ADry chemical Water spray Alcohol-resistant foamnonenoneCan be decomposed by heat or acid. Chlorine gas is a strong fire promoter.As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gearNFPAHMISHealth Hazard 0Health Hazard 2Flammability 0Flammability 0Stability 0Physical Hazard 1Physical and chemicalhazards -Personal protection -6. ACCIDENTAL RELEASE MEASURESPersonal precautionsEnvironmental precautionsMethods for ContainmentMethods for cleaning upEnsure adequate ventilationTry to prevent the material from entering drains or water coursesStop leak. Reduce spilled material with bisulfites or ferrous salt solutions (some heat willresult). Keep solution alkaline to neutral. Dilute with large quantities of water.Pick up and transfer to properly labeled containers7. HANDLING AND STORAGEAdvice on safe handlingKEEP OUT OF REACH OF CHILDREN CAUTION Keep container tightly closed when notin use Wash hands before eating._____________________________________________________________________________________________Page 2 / 7

42088-1 - Swisher Bio San Revision Date 28-Nov-2011_____________________________________________________________________________________________Technical measures/StorageconditionsStore in vented, closed, clean, non-corrosive containers in a cool, dry place away from heatand adjacent chemicals.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONExposure GuidelinesReview Section 3 & 4 for Exposure Guidelines.Engineering MeasuresShowersEyewash stationsVentilation systemsPersonal Protective Equipment Institutional EnvironmentEye/Face ProtectionSafety glasses are suggested when using this product in heavy use and institutionalenvironments.Consumer Environments Care should be taken to avoid Eye contact.Skin and body protection Rubber glovesRespiratory protection Unnecessary in open institutional enviroment.Hygiene measuresPractice good personal hygiene. Wash after handling.Personal Protective Equipment Industrial EnvironmentEye/Face ProtectionSplash-proof chemical goggles or face shield.Skin and body protection Impervious rubber, alkali-proof protecetive gloves Impervious rubber boots & apron.Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approvedrespiratory protection should be worn. Positive-pressure supplied air respirators may berequired for high airborne contaminant concentrations. Respiratory protection must beprovided in accordance with current local regulations.Hygiene measuresPractice good personal hygiene. Wash after handling. Shower at end of work periodPractice good personal hygiene. Wash after handling9. PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical propertiesPhysical stateliquidAppearanceClear LiquidColorPale yellow/greenPropertyValuespH11.5-12.5Melting/freezing pointFreezing PointBoiling point/boiling range 210 °FFlash PointEvaporation rateFlammability (solid, gas)Flammability Limits in Airupper flammability limitlower flammability limitExplosion LimitsupperlowerVapor pressureVapor densitySpecific Gravity 1.15Water solubilityNDOdorOdor ThresholdRemarks MethodsNo information availableNo information availableNo information availableNo information availableNo information availableNo information availableNo information availableNo information availableNo information availableNo information availableNo information availableNo information availablePungent ChlorineNo information available_____________________________________________________________________________________________Page 3 / 7

42088-1 - Swisher Bio San Revision Date 28-Nov-2011_____________________________________________________________________________________________Solubility in other solventsNo information availablePartition coefficient: n-octanol/waterNo information availableAutoignition temperatureNo information availableDecomposition temperatureNo information availableViscosity, kinematicNo information availableViscosity, dynamicExplosive propertiesNo information availableOxidizing PropertiesNo information available9.2 Other informationSoftening pointMolecular WeightVOC Content(%)Density VALUEBulk Density VALUENo information availableNo information availableNo information availableNo information availableNo information available10. STABILITY AND REACTIVITYStabilityunstableIncompatible products Acids Ammonia Urea Nickel Copper Oxidizable material TinConditions to AvoidNone known based on information suppliedHazardous Decomposition Products Hypochlorous Acid (HOCl) Chlorine Hydrochloric Acid (HCl)Hazardous PolymerizationHazardous polymerization does not occur11. TOXICOLOGICAL INFORMATIONAcute toxicityProduct InformationIrritation to mucous membranes. Very little hazard from properly stored solution.Chemical Name LD50 Oral LD50 Dermal LC50 InhalationSodium hypochlorite 8200 mg/kg ( Rat ) 10000 mg/kg ( Rabbit )Chronic toxicityChemical Name ACGIH IARC NTP OSHASodium hypochlorite Group 3Target Organ EffectsNone known.12. ECOLOGICAL INFORMATIONEcotoxicityThe environmental impact of this product has not been fully investigatedChemical Name Toxicity to algae Toxicity to fish Toxicity tomicroorganismsToxicity to daphnia andother aquatic invertebrates_____________________________________________________________________________________________Page 4 / 7

42088-1 - Swisher Bio San Revision Date 28-Nov-2011_____________________________________________________________________________________________Sodium hypochlorite0.095: 24 h Skeletonemacostatum mg/L EC500.03 - 0.19: 96 hOncorhynchus mykiss mg/LLC50 semi-static 0.05 -0.771: 96 h Oncorhynchusmykiss mg/L LC50flow-through 0.06 - 0.11: 96h Pimephales promelasmg/L LC50 flow-through 0.18- 0.22: 96 h Oncorhynchusmykiss mg/L LC50 static0.28 - 1: 96 h Lepomismacrochirus mg/L LC50flow-through 0.4 - 0.8: 96 hLepomis macrochirus mg/LLC50 static 4.5 - 7.6: 96 hPimephales promelas mg/LLC50 static0.033 - 0.044: 48 h Daphniamagna mg/L EC50 Static2.1: 96 h Daphnia magnamg/L EC5013. DISPOSAL CONSIDERATIONSWaste Disposal MethodsContaminated packagingNeutralized, diluted material may be flushed to sewerDo not re-use empty containers14. TRANSPORT INFORMATIONNoteUN1791, Hypochlorite solution, 8, PG IIIDotRegulatedProper shipping nameUN1791, Hypochlorite solution, 8, PG IIIHazard class 8UN/ID NoUN1791Packing GroupIIITDGMEXICAOICAO/IATAIMDG / IMORIDADR/RIDADNInternational InventoriesTSCADSLNDSLEINECSNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulated15. REGULATORY INFORMATIONTSCACompliesCompliesComplies_____________________________________________________________________________________________Page 5 / 7

42088-1 - Swisher Bio San Revision Date 28-Nov-2011_____________________________________________________________________________________________ELINCS-ENCSCompliesIECSCCompliesKECLCompliesPICCSCompliesAICSCompliesTSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListEINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical SubstancesENCS - Japan Existing and New Chemical SubstancesIECSC - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical SubstancesPICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical SubstancesU.S. Federal RegulationsSARA 313SARA TITLE III (EPCRA) NOTIFICATION: Does not contain chemicals subject to the reporting requirements of Section 302, 304,or 313 of Title III of the Superfund Amendments andReauthorization Act of 1986.COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT (CERCLA) NOTIFICATION:Sodium HypochloriteFor more information, consult 40 CFR parts 302, 355, 370, 372, and 40 CFR part 68.SARA 311/312 Hazard CategoriesAcute Health HazardChronic Health HazardFire HazardSudden Release of Pressure HazardReactive HazardnononononoClean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42).Chemical NameCWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousQuantitiesSubstancesSodium hypochlorite 100 lb XCERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material.Chemical Name Hazardous Substances RQs Extremely Hazardous SubstancesRQsRQSodium hypochlorite 100 lb RQ 100 lb final RQ RQ 45.4 kg finalRQU.S. State RegulationsCalifornia Proposition 65This product does not contain any Proposition 65 chemicals.U.S. State Right-to-Know Regulations_____________________________________________________________________________________________Page 6 / 7

42088-1 - Swisher Bio SanRevision Date 28-Nov-2011_____________________________________________________________________________________________International RegulationsCanadaThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) andthe MSDS contains all the information required by the CPR.16. OTHER INFORMATIONPrepared BySwisher Hygiene Inc.4725 Piedmont Row DriveSuite 400Charlotte, NC 28210Issuing date11-Oct-2011Revision Date28-Nov-2011Revision NoteNo information availableDisclaimerThe information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. Theinformation given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered as a warranty or quality specification. The information relates only to the specific material designated and may not bevalid for such material used in combination with any other material or in any process, unless specified in the textEnd of Material Safety Data Sheet_____________________________________________________________________________________________Page 7 / 7