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Heat Transfer-1 (color)

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– <strong>Heat</strong> <strong>Transfer</strong> via Free Electrons:<br />

This second conduction heat transfer mechanism is observed<br />

primarily in metallic solids. The concentration of free electrons<br />

varies considerably for metallic alloys and is very low for nonmetals.<br />

The previous statement implies that the ability of solids<br />

to conduct heat via this mechanism varies directly with the free<br />

electron concentration (pure metals conduct heat the best). This<br />

conduction mechanism also relies on the existence of a<br />

temperature gradient.<br />

• Theoretical Treatment of <strong>Heat</strong> <strong>Transfer</strong> by Conduction<br />

A quantitative expression relating the rate of heat transfer, the<br />

temperature gradient and the nature of the conducting medium<br />

is attributed to Fourier (1822)<br />

q x dT<br />

= − k temperature<br />

A dx gradient along x<br />

<strong>Heat</strong> flux= heat thermal<br />

flow rate per unit conductivity<br />

area in direction x of material<br />

A: area normal to<br />

heat flow

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