Heat Transfer-1 (color)
Heat Transfer-1 (color)
Heat Transfer-1 (color)
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Kinetic Theory of Gases:<br />
assumes ideal gas behavior.<br />
Chapman-Erskog Theory:<br />
accounts for pairwise interactions<br />
based on the Lennard-Jones potential.<br />
T: absolute temperature<br />
m: molecular mass<br />
M: molar mass<br />
d: molecular diameter<br />
k b: Boltzmann constant<br />
Ω k, σ: related to Lennard-Jones potential<br />
k =<br />
k =<br />
1<br />
3 / 2 d 2<br />
1.9891 ⋅10 −4<br />
Ω k 2<br />
k<br />
3<br />
T<br />
b<br />
m<br />
T<br />
M<br />
see viscosity<br />
section for<br />
discussion on Ω k<br />
Chapman-Erskog theory accounts better than the Kinetic<br />
Theory for the temperature dependence of interactions.