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Material Safety Data Sheet - Bello Zon Chlorit 7

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<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

according to Regulation (EC) No 1907/2006<br />

<strong>Bello</strong> <strong>Zon</strong> <strong>Chlorit</strong> 7,5%_1026422-1027595-950136-950137<br />

ProMinent Dosiertechnik GmbH<br />

Print date: 04.06.2012 Product code: 1000093<br />

Page 1 of 6<br />

SECTION 1: Identification of the substance/mixture and of the company/undertaking<br />

1.1. Product identifier<br />

<strong>Bello</strong> <strong>Zon</strong> <strong>Chlorit</strong> 7,5%_1026422-1027595-950136-950137<br />

Further trade names<br />

:1026422; 1027595; 950136; 950137<br />

Abbreviation:<br />

CAS No:<br />

EC No:<br />

<strong>Bello</strong><strong>Zon</strong> <strong>Chlorit</strong> 7,5 %<br />

7758-19-2<br />

231-836-6<br />

1.2. Relevant identified uses of the substance or mixture and uses advised against<br />

1.3. Details of the supplier of the safety data sheet<br />

Company name:<br />

Street:<br />

Place:<br />

Post-office box:<br />

ProMinent Dosiertechnik GmbH<br />

Im Schuhmachergewann 5-11<br />

DE-69123 Heidelberg<br />

101760<br />

DE-69007 Heidelberg<br />

Telephone: 0049/6221 842 (0) Telefax:0049/6221 842 (445)<br />

e-mail: sicherheitsdatenblaetter@prominent.de<br />

Contact person: Sabine Baumann<br />

Telephone: +49(0)6221 842-720<br />

e-mail: s.baumann@prominent.de<br />

Internet:<br />

Responsible Department:<br />

1.4. Emergency telephone:<br />

SECTION 2: Hazards identification<br />

2.1. Classification of the substance or mixture<br />

www.prominent.com<br />

Gefahrstoffmanagement/Operational management of Hazardous Substances<br />

REACh Compliance<br />

Giftnotruf Berlin +49 (0)30 - 19240<br />

Indications of danger : Harmful, Dangerous for the environment<br />

R-phrases:<br />

Harmful if swallowed.<br />

Contact with acids liberates very toxic gas.<br />

Risk of serious damage to eyes.<br />

Very toxic to aquatic organisms.<br />

GHS classification<br />

Hazard categories:<br />

Respiratory/skin sensitization: Skin Sens. 1<br />

Hazardous to the aquatic environment: Aquatic Acute 3<br />

Hazard Statements:<br />

Toxic in contact with skin.<br />

Harmful if swallowed.<br />

Causes severe skin burns and eye damage.<br />

2.2. Label elements<br />

Hazardous components which must be listed on the label<br />

Sodium <strong>Chlorit</strong>e<br />

Signal word: Danger<br />

Pictograms: GHS05-GHS07<br />

Revision no.: 1,22 IRL - EN<br />

Revision date: 04.06.2012


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

according to Regulation (EC) No 1907/2006<br />

<strong>Bello</strong> <strong>Zon</strong> <strong>Chlorit</strong> 7,5%_1026422-1027595-950136-950137<br />

ProMinent Dosiertechnik GmbH<br />

Print date: 04.06.2012 Product code: 1000093<br />

Page 2 of 6<br />

Hazard statements<br />

H311 Toxic in contact with skin.<br />

H302 Harmful if swallowed.<br />

H314 Causes severe skin burns and eye damage.<br />

Precautionary statements<br />

P280 Wear protective gloves/protective clothing/eye protection/face protection.<br />

P262 Do not get in eyes, on skin, or on clothing.<br />

Special labelling of certain mixtures<br />

For use in industrial installations only.<br />

SECTION 3: Composition/information on ingredients<br />

3.2. Mixtures<br />

Chemical characterization<br />

SODIUM CHLORITE 7,5%<br />

Sum formula: NaClO2<br />

Molecular weight: 90,41<br />

Hazardous components<br />

EC No Chemical name<br />

CAS No<br />

Classification<br />

Index No<br />

GHS classification<br />

REACH No<br />

231-836-6<br />

7758-19-2<br />

01-2119529240-51<br />

Sodium <strong>Chlorit</strong>e<br />

Xn, Xi, N R22-32-41-50<br />

Full text of R- and H-phrases: see section 16.<br />

SECTION 4: First aid measures<br />

4.1. Description of first aid measures<br />

Ox. Liq. 2, Acute Tox. 3, Skin Corr. 1, Eye Dam. 1, Aquatic Acute 1; H272 H301 H314<br />

H318 H400<br />

After contact with skin<br />

Take off immediately all contaminated clothing. Wash thoroughly (shower or bath).<br />

After contact with eyes<br />

If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at<br />

least 5 minutes. Subsequently consult an ophthalmologist.<br />

After ingestion<br />

If swallowed, immediately drink: Water. Do not induce vomiting. Medical advice absolutely required!<br />

SECTION 5: Firefighting measures<br />

5.1. Extinguishing media<br />

Suitable extinguishing media<br />

Water. Foam.<br />

Revision no.: 1,22 IRL - EN<br />

Revision date: 04.06.2012<br />

Quantity<br />

5 - 10 %


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

according to Regulation (EC) No 1907/2006<br />

<strong>Bello</strong> <strong>Zon</strong> <strong>Chlorit</strong> 7,5%_1026422-1027595-950136-950137<br />

ProMinent Dosiertechnik GmbH<br />

Print date: 04.06.2012 Product code: 1000093<br />

Page 3 of 6<br />

Extinguishing media which must not be used for safety reasons<br />

Carbon dioxide (CO2).<br />

5.3. Advice for firefighters<br />

In case of fire: Wear self-contained breathing apparatus.<br />

SECTION 6: Accidental release measures<br />

6.1. Personal precautions, protective equipment and emergency procedures<br />

Avoid contact with skin.<br />

6.2. Environmental precautions<br />

Do not empty into drains or the aquatic environment.<br />

6.3. Methods and material for containment and cleaning up<br />

Suitable material for diluting or neutralizing: Water.<br />

6.4. Reference to other sections<br />

Treat the assimilated material according to the section on waste disposal.<br />

SECTION 7: Handling and storage<br />

7.1. Precautions for safe handling<br />

Advice on protection against fire and explosion<br />

To clean the floor and all object contaminated by this material, use: Water. Flooring, walls and other<br />

surfaces in the hazard area must be cleaned regularly. keep wet with: Water. do not mix with: acid.<br />

Further information on handling<br />

Keep away from: acid. Reducing agents.<br />

7.2. Conditions for safe storage, including any incompatibilities<br />

Advice on storage compatibility<br />

Keep away from: acid. Reducing agents.<br />

SECTION 8: Exposure controls/personal protection<br />

8.1. Control parameters<br />

8.2. Exposure controls<br />

Protective and hygiene measures<br />

Keep away from food, drink and animal feeding stuffs.<br />

Hand protection<br />

Hand protection: Suitable material: NBR (Nitrile rubber). Butyl rubber. Unsuitable materials: NR<br />

(Natural rubber (Caoutchouc), Natural latex).<br />

Eye protection<br />

Tightly sealed safety glasses.<br />

SECTION 9: Physical and chemical properties<br />

9.1. Information on basic physical and chemical properties<br />

Physical state:<br />

Colour:<br />

liquid<br />

colourless<br />

Test method<br />

Revision no.: 1,22 IRL - EN<br />

Revision date: 04.06.2012


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

according to Regulation (EC) No 1907/2006<br />

<strong>Bello</strong> <strong>Zon</strong> <strong>Chlorit</strong> 7,5%_1026422-1027595-950136-950137<br />

ProMinent Dosiertechnik GmbH<br />

Print date: 04.06.2012 Product code: 1000093<br />

Page 4 of 6<br />

pH-Value (at 20 °C): 12<br />

Changes in the physical state<br />

Boiling point:<br />

Flash point:<br />

Explosive properties<br />

No data available<br />

No data available<br />

No data available<br />

Oxidizing properties<br />

brandfördernd<br />

Density (at 20 °C): 1,06 g/cm³<br />

Water solubility: highly soluble.<br />

Flow time:<br />

SECTION 10: Stability and reactivity<br />

10.1. Reactivity<br />

Do not mix with acids.<br />

10.3. Possibility of hazardous reactions<br />

Do not mix with acids.<br />

10.4. Conditions to avoid<br />

In dry state: Risk of selfignition.<br />

10.5. Incompatible materials<br />

Violent reaction with: Reducing agents.<br />

Formation of potentially explosive mixtures with: Acid. Releases:<br />

10.6. Hazardous decomposition products<br />

Formation of potentially explosive mixtures with: Acid. Releases:<br />

SECTION 11: Toxicological information<br />

11.1. Information on toxicological effects<br />

Acute toxicity<br />

LD50: 1019mg/kg, Rat.<br />

CAS No<br />

Chemical name<br />

No data available<br />

Exposure routes Method Dose Species<br />

Source<br />

7758-19-2 Sodium <strong>Chlorit</strong>e<br />

oral<br />

ATE 100 mg/kg<br />

Irritation and corrosivity<br />

Irritant effect on the skin: species: Rabbit. method: OECD 404 Evaluation: Not an irritant.<br />

Irritant effect on the eye: species: Rabbit. Method: OECD 405 Evaluation: strong irritant.<br />

SECTION 12: Ecological information<br />

12.1. Toxicity<br />

aquatoxicity Acute fish toxicity LC50: >500mg/L Brachydanio rerio<br />

Further information<br />

Product may not be released into water without pre-treatment.<br />

SECTION 13: Disposal considerations<br />

13.1. Waste treatment methods<br />

Revision no.: 1,22 IRL - EN<br />

Revision date: 04.06.2012


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

according to Regulation (EC) No 1907/2006<br />

<strong>Bello</strong> <strong>Zon</strong> <strong>Chlorit</strong> 7,5%_1026422-1027595-950136-950137<br />

ProMinent Dosiertechnik GmbH<br />

Print date: 04.06.2012 Product code: 1000093<br />

Page 5 of 6<br />

Waste disposal number of waste from residues/unused products<br />

060704 WASTES FROM INORGANIC CHEMICAL PROCESSES; wastes from the MFSU of halogens and<br />

halogen chemical processes; solutions and acids, for example contact acid<br />

Classified as hazardous waste.<br />

Waste disposal number of used product<br />

060704 WASTES FROM INORGANIC CHEMICAL PROCESSES; wastes from the MFSU of halogens and<br />

halogen chemical processes; solutions and acids, for example contact acid<br />

Classified as hazardous waste.<br />

Waste disposal number of contaminated packaging<br />

060704 WASTES FROM INORGANIC CHEMICAL PROCESSES; wastes from the MFSU of halogens and<br />

halogen chemical processes; solutions and acids, for example contact acid<br />

Classified as hazardous waste.<br />

SECTION 14: Transport information<br />

Land transport (ADR/RID)<br />

14.1. UN number:<br />

14.2. UN proper shipping name:<br />

14.3. Transport hazard class(es):<br />

14.4. Packing group:<br />

Hazard label:<br />

1908<br />

Classification code: C9<br />

Limited quantity: LQ22<br />

Hazard No:<br />

80<br />

Other applicable information (land transport)<br />

: 521<br />

: 2<br />

Inland waterways transport<br />

14.1. UN number:<br />

14.3. Transport hazard class(es):<br />

14.4. Packing group:<br />

Hazard label: 8<br />

Classification code:<br />

Marine transport<br />

14.1. UN number:<br />

14.2. UN proper shipping name:<br />

14.3. Transport hazard class(es):<br />

14.4. Packing group:<br />

Hazard label:<br />

CHLORITE SOLUTION<br />

8<br />

II<br />

8<br />

1908<br />

8<br />

II<br />

C9<br />

1908<br />

<strong>Chlorit</strong>e Solution<br />

8/UN 1908 PG.II<br />

II<br />

8<br />

Revision no.: 1,22 IRL - EN<br />

Revision date: 04.06.2012


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

according to Regulation (EC) No 1907/2006<br />

<strong>Bello</strong> <strong>Zon</strong> <strong>Chlorit</strong> 7,5%_1026422-1027595-950136-950137<br />

ProMinent Dosiertechnik GmbH<br />

Print date: 04.06.2012 Product code: 1000093<br />

Page 6 of 6<br />

Air transport<br />

UN/ID number:<br />

14.2. UN proper shipping name:<br />

14.3. Transport hazard class(es):<br />

14.4. Packing group:<br />

Hazard label:<br />

Other applicable information<br />

EmS 8-06; MFAB 741<br />

SECTION 15: Regulatory information<br />

1908<br />

<strong>Chlorit</strong>e Solution<br />

8 UN 1908 PG.II/Drill 8L<br />

II<br />

8<br />

15.1. <strong>Safety</strong>, health and environmental regulations/legislation specific for the substance or mixture<br />

National regulatory information<br />

Water contaminating class (D):<br />

SECTION 16: Other information<br />

2 - water contaminating<br />

Full text of R-phrases referred to under sections 2 and 3<br />

22 Harmful if swallowed.<br />

32 Contact with acids liberates very toxic gas.<br />

41 Risk of serious damage to eyes.<br />

50 Very toxic to aquatic organisms.<br />

Full text of H-Statements referred to under sections 2 and 3<br />

H272 May intensify fire; oxidiser.<br />

H301 Toxic if swallowed.<br />

H302 Harmful if swallowed.<br />

H311 Toxic in contact with skin.<br />

H314 Causes severe skin burns and eye damage.<br />

H318 Causes serious eye damage.<br />

H400 Very toxic to aquatic life.<br />

Further Information<br />

The receiver of our product is singulary responsible for adhering to existing laws and regulations.<br />

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety<br />

data sheet.)<br />

Revision no.: 1,22 IRL - EN<br />

Revision date: 04.06.2012

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