Multi-Tube Pack MSDS Number: VS60338-01 Issue Date: March 5 ...

MATERIAL SAFETY DATA SHEET Page 1 of 5Product Group: Multi-Tube PackCHEMICAL PRODUCT AND COMPANY IDENTIFICATION - SECTION 1MSDS Number: VS60338-01Issue Date: March 5, 1998Supersedes : New IssueERCO No.: R6-1251Company Identification:Becton Dickinson VACUTAINER SystemsA Division of Becton Dickinson and Company1 Becton DriveFranklin Lakes, NJ 07417-1885FOR CHEMICAL EMERGENCY, SPILL LEAK, FIRE, EXPOSURE, OR ACCIDENT:In the continental U.S., call Chemtrec: 1-800-424-9300For additional non-emergency information, call: 1-800-631-0174Product Name: Three VACUTAINER ® Brand Tubes - One serum tube, one containing potassium oxalateand sodium fluoride, and one containing sodium heparin.Reorder Number: 366402 (Contains three tubes - 366430, 369735, 367722)Synonym(s): N/AChemical Family: Inorganic salts.Chemical Formula: Tube 367722: 2(COOK)H 2 O + Na F.COMPOSITION/ INFORMATION ON INGREDIENTS - SECTION 2Chemical Name CAS Number Exposure Limits Weight (mg)Tube 367722Sodium fluoride 7681-49-4 NA 7.5 mgPotassium oxalate 6487-48-5 NA 6.0 mgTube 369735Sodium Heparin 9041-08-1 NA .1 mLsTube 366430No Hazardous IngredientsHEALTH EFFECTS SUMMARY - SECTION 3The following information summarizes human experience and results of scientific investigations reviewed byhealth professionals for hazard evaluation of and development of Precautionary Measures and OccupationalControl Procedures recommended in this document.Tube 367722:Primary Route of Entry: Dermal contact, eye contact, inhalation, and ingestion.Medical Conditions Which Might be Aggravated: None expected.Acute Exposure Effects:1. Skin: Extremely irritating, corrosive, and may cause burns.2. Eyes: Severe irritation or burns.3. Inhalation: Is harmful and may be fatal. Nausea, vomiting, and severe irritation to mucousmembranes and respiratory system.

MATERIAL SAFETY DATA SHEET Page 2 of 5Product Group: Multi-Tube Pack4. Ingestion: Toxic. May be fatal. Headache, nausea, vomiting, gastrointestinal irritation andconvulsions. May have caustic effect on mouth, esophagus, and stomach. Solubleoxalates can cause kidney damage.Repeated Exposure Effects:1. Skin: None identified.2. Inhalation: Increased bone density, calcium deposits in ligaments, mottled tooth enamel.3. Ingestion: Increased bone density, calcium deposits in ligaments, mottled tooth enamel.Tube 369735:Acute Exposure Effects:1. Skin: None identified.2. Eyes: None identified.3. Inhalation: May cause nosebleeds.4. Ingestion: None identified.Repeated Exposure Effects:1. Skin: None identified.2. Inhalation: May cause nosebleeds.3. Ingestion: None identified.EMERGENCY AND FIRST AID PROCEDURES - SECTION 4Tubes 367722 and 369735:Skin:Eyes:Inhalation:Ingestion:Flush with plenty of water for at least 15 minutes while removing contaminated clothing.Flush eyes with plenty of water for at least 15 minutes.Remove to fresh air. Give artificial respiration ONLY if breathing has stopped.Seek medical attention IMMEDIATELY. Do NOT induce vomiting. Give victim 1 glass ofwater, milk, or milk of magnesia to dilute.FIRE PROTECTION INFORMATION - SECTION 5Flash Point: N/A Method: N/AAutoignition Temperature: N/A Method: N/ACombustibility: N/A Method: N/AExtinguishing Media: Use extinguishing media appropriate for surrounding fire.Special Fire Fighting Procedures: Firefighters should wear a self-contained breathing apparatus withfull facepiece operating in positive pressure mode.ACCIDENTAL RELEASE MEASURES - SECTION 6Avoid overexposure. Spill should be contained with inert material and gathered into a suitable retaining area.Use water spray to reduce vapors. Take up with sand or other inert non-combustible material. Wash sitethoroughly with water.HANDLING AND STORAGE PROCEDURES - SECTION 7Tube 367722:Follow routine safe handling procedures. Avoid generating dust. Material must be handled with adequateventilation. Keep container tightly closed. Do not store in glass. Keep away from strong acids. Store in a

MATERIAL SAFETY DATA SHEET Page 3 of 5Product Group: Multi-Tube Packcool, dry area, out of direct sunlight. Store in secure poison area. Sodium fluoride reacts with acids to formhydrogen fluoride, which is highly corrosive and poisonous -- Keep away from strong acids.Tube 369735:Product is hygroscopic. It should be stored in dark-colored glass or metal containers in a cool, dry place.OCCUPATIONAL CONTROL PROCEDURES - SECTION 8Eye Protection: Use safety goggles.Skin Protection: Uniform, apron, and rubber gloves.Respiratory Protection: Self-contained breathing apparatus, dust mask, extraction hood, and fumecupboard cubicle.Ventilation: Use general or local exhaust ventilation to meet TLV requirements.Airborne Exposure Limits: TLVaprons.Other Protective Equipment: Eye bath, safety shower,PHYSICAL PROPERTIES - SECTION 9Tubes 367722 and 369735:Appearance: White crystals/powderOdor: Odorless.Vapor Pressure (@20°C mm Hg): N/A Viscosity @ 40°C (centistokes): N/ASpecific Gravity @ 25/25°C: N/A Solubility in Water (wt. %): N/ASolubility in Other Solvents: N/ANote: These physical data are typical values based on material tested but may vary from sample to sample.Typical values should not be construed as a guaranteed analysis of any specific lot or as specifications forthe product.REACTIVITY DATA - SECTION 10Tube 367722:Reactivity: StableIncompatibility: Strong acids, strong oxidizing agents, and glass.Hazardous Decomposition Products: Hydrogen fluoride, carbon monoxide, carbon dioxide.Hazardous Polymerization: Will not occur.Tube 369735:Reactivity: StableIncompatibility: None identified.Hazardous Decomposition Products: None identified.Hazardous Polymerization: Will not occur.TOXICOLOGY INFORMATION - SECTION 11Tube 367722:Acute Eye Effects: May cause irritation. Acute Skin Effects: May cause irritation.Inhalation Toxicity: May be fatal.Ingestion Toxicity: Toxic. May be fatal.Exposure Limits: Not established.Teratogenicity: Not established.Reproductive Toxicity: Not established.Mutagenicity: Not established.

MATERIAL SAFETY DATA SHEET Page 4 of 5Product Group: Multi-Tube PackSynergistic Products: Not established. Sensitization to Product: Not established.Carcinogenicity: Contains more than 0.1% by weight of a material listed as a potential carcinogen by:NTP No IARC No OSHA NoOther Chronic Effects: Increased bone density, calcium deposits in ligaments, and mottled tooth enamel.Signs and Symptoms of Overexposure: Skin irritation.Medical Conditions Generally Aggravated by Overexposure: None identified.Tube 369735:Acute Eye Effects: None identified.Acute Skin Effects:None identified.Inhalation Toxicity: May cause nosebleeds. Ingestion Toxicity:None identified.Exposure Limits: Not established.Teratogenicity: Not established.Reproductive Toxicity: Not established.Mutagenicity: Not established.Synergistic Products: Not established. Sensitization to Product: Not established.Carcinogenicity: Contains more than 0.1% by weight of a material listed as a potential carcinogen by:NTP No IARC No OSHA NoOther Chronic Effects: None identified.Signs and Symptoms of Overexposure: None identified.Medical Conditions Generally Aggravated by Overexposure: None identified.ECOLOGICAL INFORMATION - SECTION 12No data is available on the adverse effects of this material on the environment. Neither COD nor BOD dataare available.DISPOSAL CONSIDERATIONS - SECTION 13Disposal should be done in accordance with local, state and federal regulations.TRANSPORTATION INFORMATION - SECTION 14Please note: The information contained in this section applies to the transport of full case cartons only.D.O.T.Proper Shipping Name: Toxic solids, organic n.o.s. (contains Sodium Fluoride and Potassium Oxalate)Hazard Class/I.D. No./Packing Group: 6.1, UN2811, Ltd. Qty., PG IIILabel: None RequiredI.M.O.Proper Shipping Name: Toxic solids, organic n.o.s. (contains Sodium Fluoride and Potassium Oxalate)Hazard Class/I.D. No./Packing Group: 6.1, UN2811, Ltd. Qty., PG IIILabel: ToxicI.C.A.O./I.A.T.A.Proper Shipping Name: Toxic solids, organic n.o.s. (contains Sodium Fluoride and Potassium Oxalate)Hazard Class/I.D. No./Packing Group: 6.1, UN2811, Ltd. Qty., PG IIILabel: Excepted QuantitiesREGULATORY INFORMATION - SECTION 15

MATERIAL SAFETY DATA SHEET Page 5 of 5Product Group: Multi-Tube PackTSCA Inventory: YesReportable Quantity (RQ) Under US EPA CERCLA Regulations: 1000 lbs.SARA Hazard Notification Hazard Categories Under Criteria of SARA Title III Rules(40 CFR Part 370): NoneSection 313 Toxic Chemical(s): NoneHazardous Chemical(s) Under OSHA Hazard Communication Standard: NoneOTHER INFORMATION - SECTION 16Label Information:POISON DANGERCauses burns. Keep away from strong acids. May be fatal if swallowed or inhaled. Do not get in eyes, onskin, or on clothing. Avoid breathing dust. Keep in tightly closed container. Use with adequate ventilation.Wash thoroughly after handling.Hazard Ratings:NFPAHMISFire -- 0 Health -- 3Health -- 3 Flammability -- 0Reactivity -- 1 Reactivity -- 1Specific Hazard -- 3Information Contact:Becton Dickinson VACUTAINER SystemsA Division of Becton Dickinson and Company1 Becton DriveFranklin Lakes, NJ 07417-1885To the best of our knowledge, the information contained herein is accurate. However, neither BectonDickinson and Company nor any of its subsidiaries assumes any liability whatsoever for the accuracy orcompleteness of the information contained herein. Final determination of suitability of any material is the soleresponsibility of the user. All materials may present unknown hazards and should be used with caution.Although certain hazards are described herein, we cannot guarantee that these are the only hazards thatexist.