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Petroleum System Identification and Clarification, E.A. Mancini

Petroleum System Identification and Clarification, E.A. Mancini

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<strong>Petroleum</strong> <strong>System</strong><strong>Identification</strong> <strong>and</strong>CharacterizationE. A. <strong>Mancini</strong>


Overview‣ Objective‣ Introduction‣ Potential Source Rocks‣ Smackover Source Rocks‣ <strong>Petroleum</strong> <strong>System</strong>s‣ Conclusions


Objective‣ To provide information on the organic <strong>and</strong>thermal maturation characteristics ofpotential source rocks in the onshoreinterior salt basins of the northern Gulf ofMexico.


Introduction


Gulf Coast Interior Salt Basins


<strong>System</strong>SeriesStageGroupFormationMississippiAlabamaMemberOligoceneRupelianVicksburg(see text for formations)StratigraphyPaleogeneUpper CretaceousPaleoceneEocenePriabonianBartonianLutetianYpresianSel<strong>and</strong>ianDanianMaastrichtianCampanianSantonianConiacianJacksonClaiborneWilcoxMidwaySelmaTuronianTuscaloosaCenomanianMoodys Branch FormationCockfield FormationCook Mountain FormationKosciusko S<strong>and</strong>"lower Lisbon"Zilpha ShaleWinona Fm.Tallahatta Fm. Tallahatta Fm.WilcoxHatchetigbee FormationTuscahoma FormationNanafalia FormationNaheola Formation"Jackson Gas Rock" Porters Creek Clay(Cane River)undifferentiatedMidway undiff.Yazoo Clay(see text for formations)Eutaw FormationUpper Tuscaloosa FormationMarine ShaleLower Tuscaloosa FormationMoodys BranchGosport S<strong>and</strong>"upper Lisbon""middle Lisbon"(see textfor members)(see textfor members)Tombigbee S<strong>and</strong>CretaceousAlbianWashita-FredericksburgundifferentiatedDantzler FormationAndrew FormationPaluxy FormationLower CretaceousAptianBarremianHauterivianBerriasianTithonianCottonValleyMooringsport FormationFerry Lake AnhydriteRodessa FormationJames Limestone/Pine Isl<strong>and</strong> ShaleSligo Formation/Hosston FormationSchuler FormationDorcheatShongalooJurassicUpperJurassicMiddleJurassicKimmeridgianOxfordianCallovianBathonianBajocianHaynesville FormationSmackover FormationNorphlet FormationLouann SaltBuckner Anhydrite"Brown Dense"Pine Hill AnhydriteAalenianWerner AnhydriteTriassicLwr. JurassicHettangian?Rhaetian?Eagle Mills Formation


SequenceStratigraphy


North Louisiana Salt Basin


Mississippi Interior Salt Basin


Conecuh <strong>and</strong> Manila Sub-basinsbasins


Potential Source Rocks‣ Upper Jurassic (Oxfordian, Tithonian)‣ Lower Cretaceous (Albian)‣ Upper Cretaceous (Cenomanian,Turonian)


UpperCretaceousTuscaloosaMarineShaleBelden & Blake Wall 3-9 well5270.5 ft


LowerCretaceousPine Isl<strong>and</strong>ShaleWavel<strong>and</strong> Gas Unit No. 1 well15679 ft.


Upper JurassicSmackover SourceRocks


Smackover Condensed Section


UpperJurassicSmackoverLimeMudstoneL & N Railroad well15535 ft


Smackover Source Rocks‣ Lower <strong>and</strong> Middle Lime Mudstone Beds• Average of 0.81% TOC• High Range of 8.42 to 9.30% TOC• Microbial Kerogen Type• Range of Ro of 0.55 to 4.0%


Thermal MaturationKEROGEN TYPEKEROGEN ALTERATIONMARINECONTINENTALDEPOSITIONAL ENVIRONMENT


Hydrocarbon/Organic Carbon vs Depth


Oil <strong>and</strong> Gas-Condensate Chemical Composition


Oil <strong>and</strong> Gas-Condensate Comparisons


Oil to GasConversion


Oil <strong>and</strong> Gas-CondensateGroups


Oil vsSource RockComparison


St<strong>and</strong>ard Chromatogram


Smackover ChromatogramLake Como Field, Jasper Co, Mi.


Hosston ChromatogramFree State Field, Jones Co, Mi.


Hydrocarbon Gas ChromatogramsLower CretaceousHosston oil from FreeState Field, Jones County,Mississippi.Smackover oil from LakeComo Field, JasperCounty, Mississippi.


Washita ChromatogramMain Pass 253 Field, OCS


Biomarkers HistogramOil from Smackover reservoirTerpanesOil from Washitareservoir


Biomarkers HistogramOil from Smackover reservoirSteranesOil from Washitareservoir


<strong>Petroleum</strong> <strong>System</strong>s


North Louisiana SaltBasinCross SectionsLocation


NNorth Louisiana Salt Basin CrossSectionSVE: 22X


NThermal Maturation Cross Section NLSBSVE: 32X


Burial History Profile NLSB, Sabine Uplift


Thermal Maturation History Profile NLSB, SabineUplift


Hydrocarbon Expulsion Plot NLSB, Sabine Uplift


NNorth Louisiana Salt Basin Cross SectionSVE: 29X


NThermal Maturation Cross Section NLSBSVE: 32X


Burial History Profile NLSB Updip


Thermal Maturation History Profile NLSB Updip


Hydrocarbon Expulsion Plot NLSB Updip


Thermal Maturation History Profile NLSB Downdip


Hydrocarbon Expulsion Plot NLSB Downdip


NNorth Louisiana Salt Basin Cross SectionSVE: 30X


NThermal Maturation Cross Section NLSBSVE: 33X


North Louisiana Salt Basin Cross SectionWEVE: 22X


Thermal Maturation Cross Section NLSBWEVE: 16X


Burial History Profile NLSB, Monroe Uplift


Thermal Maturation History Profile NLSB,Monroe Uplift


Hydrocarbon Expulsion Plot NLSB, Monroe Uplift


Mississippi Interior Salt BasinCross SectionsLocation


NMississippi Interior Salt Basin Cross SectionSVE: 16X


Thermal Maturation Cross Section MISBNSVE: 16X


Burial History Profile MISB Updip


Thermal Maturation History ProfileMISB Updip


Hydrocarbon Expulsion Plot MISB Updip


Burial History Profile MISB Downdip


Thermal Maturation History ProfileMISB Downdip


Hydrocarbon Expulsion Plot MISB Downdip


Smackover-Sourced Sourced Hydrocarbon MigrationPathways in MISB


Pattern of Migration within SouthMississippi Salt BasinEvans, 1987


Patterns of Migration in NorthLouisiana Salt BasinSassen, 1990


Event Chart for Smackover <strong>Petroleum</strong><strong>System</strong> in the North Louisiana <strong>and</strong>Mississippi Interior Salt Basins


Manila <strong>and</strong> Conecuh SubbasinsCross SectionsLocation


NManila <strong>and</strong> Conecuh Subbasins Cross SectionSVE: 24X


NThermal Maturation Cross SectionManila <strong>and</strong> Conecuh SubbasinsSVE: 23X


Burial History Profile Manila Subbasin102520112 BURIAL HIST0JKPalNFmUndiffDepth Subsurface (feet)500010000SelmaEutawTuscaloosaMarine ShaleLower TuscaloosaLower CretaceousPaluxyMooringsportFerry LakeRodessaPine Isl<strong>and</strong>Sligo/HosstonCotton ValleyHaynesvilleBucknerSmackoverNorphletLouann Salt15000200150100500t = 0Age (my)


Thermal Maturation History ProfileManila Subbasin


Hydrocarbon Expulsion PlotManila Subbasin102520112 EXPULSION300JKPalNHQCumulative Hydrocarbon / TOC (mg/g TOC)2001000200150100500in-situOilin-situGasin-situResidueexpelledOilexpelledGasAge (my)


NManila <strong>and</strong> Conecuh Subbasins Cross SectionSVE: 20X


Thermal Maturation Cross SectionManila <strong>and</strong> Conecuh SubbasinsNSVE: 21X


Burial History Profile Conecuh Subbasin0105320007 BURIAL HISTJ K Pal NFmUndiffDepth Subsurface (feet)500010000SelmaEutawTuscaloosaMarine TuscaloosaLowerTuscaloosaLower CretaceousPaluxyMooringsportRodessaPine Isl<strong>and</strong>Sligo/HosstonCotton Valley15000HaynesvilleBuckerSmackoverNorphlet16000200 150 100 50 0Age (my)t = 0


Thermal Maturation History ProfileConecuh Subbasin


Hydrocarbon Expulsion PlotConecuh Subbasin103520008 EXPULSION400JKPalNHQCumulative Hydrocarbon / TOC (mg/g TOC)3002001000200150100500in-situOilin-situGasin-situResidueexpelledOilexpelledGasAge (my)


Event Chart for Smackover <strong>Petroleum</strong><strong>System</strong> in the Manila <strong>and</strong> ConecuhSubbasins


<strong>Petroleum</strong> <strong>System</strong>Characterization Summary‣ Initiation of the generation of crude oil inthe Early to Late Cretaceous <strong>and</strong>continuing into the Cenozoic‣ Commencement of hydrocarbon expulsionin the Early to Late Cretaceous <strong>and</strong>continuing into the Cenozoic‣ Peak hydrocarbon expulsion in the lateEarly to Late Cretaceous


Conclusions‣ Upper Jurassic Smackover lime mudstonebeds served as an effective regionalpetroleum source rock‣ Upper Cretaceous Tuscaloosa Marineshale beds served as a local source rock‣ Upper most Jurassic <strong>and</strong> LowerCretaceous beds were possible sourcerocks

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