SAFETY DATA SHEET Phosphoric Acid 75%

Phosphoric Acid 75% Page 1 of 8SAFETY DATA SHEETPhosphoric Acid 75%SECTION 1: Identification of the substance/mixture and of thecompany/undertakingDate issued 12.11.20121.1. Product identifierProduct name Phosphoric Acid 75%Synonyms Fosforsyre 75%REACH Reg No 01-2119485924-24CAS no. 7664-38-2EC no. 231-633-21.2. Relevant identified uses of the substance or mixture and uses advised againstUse of the substance/preparation1.3. Details of the supplier of the safety data sheetDistributorCompany nameOffice addressFertilizer production. Surface treatment of metals / rust removal. pH regulation.Water treatment. Cleaning of process equipment for food production.Acinor ASTitangt. 13, NO-1630 Gamle FredrikstadPostal address Titangaten 13Postcode 1630CityGamle FredrikstadCountryNorwayTel 69384082Fax 69384084E-mailpost@acinor.noWebsitehttp://www.acinor.noEnterprise no.NO 984 648 324 MVAContact personRolf Egil de Flon1.4. Emergency telephone numberEmergency telephone Toxic Information:22 59 13 00SECTION 2: Hazards identification2.1. Classification of the substance or mixtureClassification according to67/548/EEC or 1999/45/ECClassification according toRegulation (EC) No 1272/2008[CLP/GHS]Substance / mixture hazardousproperties2.2. Label elementsHazard Pictograms (CLP)C; R34Skin Corr 1B; H314;Causes severe skin burns and eye damage.

Phosphoric Acid 75% Page 2 of 8Composition on the label Orthophosphoric acid ...%: 70 - 85 %Signal wordDangerHazard statementsH314 Causes Severe skin burns and eye damage.Precautionary statementsP305 + P351 + P338 IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing.P223 Keep away from any possible contact with water, because of violentreaction and possible flash fire.P280 Wear protective gloves/protective clothing/eye protection/face protection.P101 If medical advice is needed, have product container or label at hand.P273 Avoid release to the environment.2.3. Other hazardsPBT / vPvBPBT/vPvB assessment has not been performed.SECTION 3: Composition/information on ingredients3.1. SubstancesComponent name Identification Classification ContentsOrthophosphoric acid ...% CAS no.: 7664-38-2EC no.: 231-633-2Index no.: 015-011-00-6Synonyms: Orthophosphoric acidWater CAS no.: 7732-18-5EC no.: 231-791-2Component commentsC; R34Skin Corr. 1B; H314See section 16 for explanation of H- and R-phrases listed above.SECTION 4: First aid measures4.1. Description of first aid measuresGeneralIf in doubt, seek medical advice.InhalationSkin contactEye contactIngestion70 - 85 %15 - 30 %Fresh air and rest. Rinse nose and mouth with water. Get medical attention ifany discomfort continues. For breathing difficulties oxygen may be necessary.Remove contaminated clothing. Flush skin thoroughly with water. Important toremove the substance from the skin immediately. Get medical attention.Chemical burns must be treated by a physician. Wash contaminated clothesbefor reuse.Promptly rinse eyes with plenty of water (tempered at 20-30°C) for at least15 minutes. Remove contact lenses and open eyes wide apart. Immediatelyconsult a doctor. Transport to physician. Keep on flushing during transport.DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Drink a few glassesof water or milk. Do not give victim anything to drink if he is unconscious.Immediately consult a doctor. Transport to hospital. Bring the safety datasheet.4.2. Most important symptoms and effects, both acute and delayedInformation for health personnel Treat Symptomatically.Acute symptoms and effectsDelayed symptoms and effectsCorrosive. Forms blisters and can cause ulceration.Corrosive to the eyes, danger of vision impairment / blindness, burning nose,chemical burns to the skin.Causes burns if swallowed. Causes burning sensation in the mouth, throatand esophagus. May cause serious permanent damage.Inhalation: May cause chemical burns to the respiratory tract.Langvarig eller gjentatt påvirkning kan gi varige skader.4.3. Indication of any immediate medical attention and special treatment neededOther InformationSplashes in the eyes and ingestion of more than an insignificant amountrequires immediate medical attention. Chemical burns of the skin must betreated as burns.

Phosphoric Acid 75% Page 3 of 8SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing mediaImproper extinguishing mediaDry-powder, carbon dioxide (CO2), water mist, foam.Do not use water jet.5.2. Special hazards arising from the substance or mixtureFire and explosion hazardsThe product is not classified as flammable.Hazardous combustion products Oxides of phosphorous (POx). Phosphoric acid mist.5.3. Advice for firefightersPersonal protective equipmentOther InformationUse fresh air equipment when the product is involved in fire. In case ofevacuation, an approved protection mask should be used. See also section 8.Containers close to fire should be removed immediately or cooled with water.Spill water from fire fighting may be strongly caustic. Extinguishing water mustnot be discharged into drains.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresPersonal precautions Use protective equipment as referred to in section 8.Provide adequate ventilation. Avoid inhalation of spray mist and contact withskin and eyes.6.2. Environmental precautionsEnvironmental precautionsDo not allow to enter into sewer, water system or soil.6.3. Methods and material for containment and cleaning upMethods for cleaning6.4. Reference to other sectionsOther instructions See also sections 8 and 13.SECTION 7: Handling and storage7.1. Precautions for safe handlingHandlingAbsorb in vermiculite, dry sand or earth and place into containers. Collect ina suitable container and dispose as hazardous waste according to section 13.Use protective equipment as referred to in section 8. Provide adequateventilation.Avoid inhalation of vapours/spray and contact with skin and eyes. Avoid directcontact. Never pour water into acid/base. Dilute by slowly pouring the productinto water while stirring. Be aware of the risk of exotermic reactions.Immediately change contaminated clothes.Protective MeasuresAdvice on general occupationalhygiene7.2. Conditions for safe storage, including any incompatibilitiesStorageHints on storage assembly7.3. Specific end use(s)Specific use(s) See section 1.2.Wash hands at the end of each work shift and before eating, smoking andusing the toilet. Do not eat, drink or smoke during work.Store in a tightly closed container in a cool, well-ventilated room, protectedfrom direct sunlight. Store in a dry place. Corrosive storage.Keep away from: Bases.SECTION 8: Exposure controls/personal protection8.1. Control parametersExposure limit valuesComponent name Identification Value YearPhosphoric acid CAS no.: 7664-38-2 8 h.: 1 mg/m3 2007

Phosphoric Acid 75% Page 4 of 88.2. Exposure controlsOccupational exposure controlsRespiratory protectionRespiratory protectionHand protectionHand protectionSuitable gloves typeBreakthrough timeEye / face protectionEye protectionSkin protectionSkin protection (other than of thehands)Additional skin protection measuresOther InformationOther InformationEC no.: 231-633-2Index no.: 015-011-00-6Provide adequate ventilation. Personal protection equipment should be chosenaccording to the CEN standards and in discussion with the supplier of thepersonal protective equipment.In case of inadequate ventilation or risk of inhalation of vapours, use suitablerespiratory equipment with combination filter (type B2/P2).Use chemical resistant gloves.Polyvinyl chloride (PVC). Neoprene. Nitrile. Rubber (natural, latex). Butylrubber.Penetration time is not known. The recommended material of gloves isrecommended after a study of the single components in the product.Use approved safety goggles or face shield.Wear appropriate clothing to prevent any possibility of skin contact.Wash promptly if skin becomes wet or contaminated. Promptly remove anyclothing that becomes wet or contaminated.Eye wash facilities and emergency shower should be available when handlingthis product. The listed protective equipment is a recommendation. A riskassessment of the actual risk may lead to other requirements.SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical stateViscous liquid.ColourColourless.OdourNo characteristic odour.Comments, Odour limitNot known.pH (as supplied) Value: < 1Comments, pH (as supplied) Concentrated solution.Comments, Melting point / melting Not known.rangeBoiling point / boiling range Value: 140 °CComments, Flash pointNot known.Comments, Evaporation rate Not known.Flammability (solid, gas)Not known.Comments, Explosion limitNot known.Comments, Vapour pressure Not known.Comments, Vapour densityNot known.Specific gravityValue: 1,63 g/cm³Comments, Specific gravityValid for density.Solubility in waterSoluble.Comments, Partition coefficient: n- Not known.octanol / waterComments, SpontaneousNot known.combustabilityComments, DecompositionNot known.temperature

Phosphoric Acid 75% Page 5 of 8Comments, ViscosityPhysical hazardsExplosive propertiesOxidising propertiesNot known.Not known.Not known.9.2. Other informationOther physical and chemical propertiesPhysical and chemical properties Freezing point: -15°C.SECTION 10: Stability and reactivity10.1. ReactivityReactivity Reactive with the materials listed in Section 10.5.10.2. Chemical stabilityStability10.3. Possibility of hazardous reactionsPossibility of hazardous reactions10.4. Conditions to avoidConditions to avoidStable under normal temperature conditions and recommended use.Arise in contact with incompatible materials (section 10.5) and inappropriateconditions (section 10.4).Do not add water directly to the product. It may cause a violent reaction.Generates heat upon contact with water.10.5. Incompatible materialsMaterials to avoidBases, alkalis (organic). Bases, alkalis (inorganic).10.6. Hazardous decomposition productsHazardous decomposition products None under normal conditions. See also section 5.2.SECTION 11: Toxicological information11.1. Information on toxicological effectsToxicological Information:LD50 oralLD50 dermalValue: 1530 mg/kgTest animal species: RatComments: (25%)Value: 2740 mg/kgTest animal species: RabbitOther information regarding health hazardsGeneralThis substance is corrosive.Potential acute effectsInhalationSkin contactEye contactIngestionDelay / RepeatingSensitisationCarcinogenic, Mutagenic or ReprotoxicCarcinogenicityVapours are corrosive. After 24-36 hours, injured persons may developserious shortness of breath and lung oedema.Corrosive. Prolonged contact causes serious tissue damage. Cause blistersand burns.Corrosive. Immediate first aid is necessary. Risk of serious damage to eyes.Risk of permanent corneal damage, loss of sight and blindness.Causes burns if swallowed. Causes burning sensation in the mouth, throatand esophagus. May cause serious permanent damage. Risk of perforation ofthe stomach if there has been swallowed large amounts.None of the substances mentioned in section 3 is considered to havesensitizing effects according to current labelling rules.None of the substances mentioned in section 3 is considered as carcinogenicaccording to current labelling rules.

Phosphoric Acid 75% Page 6 of 8MutagenicityTeratogenic propertiesReproductive toxicitySECTION 12: Ecological information12.1. ToxicityEcotoxicityNone of the substances mentioned in section 3 are considered to havemutagenic or pro-mutagenic effects.None of the substances mentioned in section 3 are considered to cause harmto the unborn child.None of the substances mentioned in section 3 are considered to havegenotoxic effects.The product is not classified as dangerous for the environment. The productmay affect the acidity (pH-factor) in water with risk of harmful effects toaquatic organisms. Evalute the necessity of neutralization.12.2. Persistence and degradabilityPersistence and degradability The product contains inorganic compounds that are not biodegradable.12.3. Bioaccumulative potentialBioaccumulative potentialProduct is not expected to be bioaccumulative.12.4. Mobility in soilMobilityThe product is miscible with water. May spread in water systems.12.5. Results of PBT and vPvB assessmentPBT assessment resultsPBT assessment has not been performed.vPvB evaluation resultsvPvB assessment has not been performed.12.6. Other adverse effectsOther adverse effects / RemarksSECTION 13: Disposal considerations13.1. Waste treatment methodsSpecify the appropriate methods ofdisposalProduct classified as hazardouswasteEWC waste codeNORSASAcids cause decreased pH values in the water. A low pH value harmsaquatic organisms. Do not allow to enter into sewer, water system or soil.Disposed of as hazardous waste by approved contractor. The waste code(EWC-Code) is intented as a guide. The code must be chosen by the user,if the use differs from the one mentioned above.YesEWC: *06 01 04 phosphoricand phosphorous acid7131 Acids, inorganic.SECTION 14: Transport information14.1. UN numberADR 1805RID 1805IMDG 1805ICAO/IATA 180514.2. UN proper shipping nameADRPHOSPHORIC ACID, SOLUTIONRIDPHOSPHORIC ACID, SOLUTIONIMDGPHOSPHORIC ACID SOLUTIONICAO/IATAPHOSPHORIC ACID, SOLUTION14.3. Transport hazard class(es)ADR 8Hazard no. 80RID 8IMDG 8

Phosphoric Acid 75% Page 7 of 8ICAO/IATA 814.4. Packing groupADRRIDIMDGICAO/IATAIIIIIIIIIIII14.5. Environmental hazardsIMDG Marine pollutantNo14.6. Special precautions for userADR Other applicable information Classification code: C1EmSF-A, S-B14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeOther applicable information.Other applicable information. Not relevant.SECTION 15: Regulatory informationEC no. 231-633-215.1. Safety, health and environmental regulations/legislation specific for thesubstance or mixtureReferences (laws/regulations)Norwegian regulation on classification and labeling of dangerous chemicals.Valid from June 21, 2010.Regulation on classification, labeling and packaging of substances andmixtures (CLP) dated 16.06.2012.Commission Regulation (EU) No 453/2010 amending Regulation (EC) No1907/2006 of the European Parliament and of the Council on the Registration,Evaluation, Authorisation and Restriction of Chemicals (REACH), Annex IISafety Data Sheets.Administrative norms for pollution of the atmosphere, the latest edition, fromNorwegian labour inspection authorityNorwegian regulations on waste, no. 930/2004, from Minestry of theEnvironment.Dangerous Goods regulationsThe Safety Data Sheet is based on information provided by the producer.Declaration no. 9394115.2. Chemical safety assessmentChemical safety assessment hasbeen carried outNoSECTION 16: Other informationSupplier's notesClassification according toRegulation (EC) No 1272/2008[CLP/GHS]List of relevant R phrases (underheadings 2 and 3).List of relevant H-phrases (Section2 and 3).Abbreviations and acronyms usedSources of key data used tocompile the safety data sheetThe information contained in this SDS must be made available to all thosewho handle the product.Skin Corr 1B; H314;R34 Causes burns.H314 Causes Severe skin burns and eye damage.PBT: Persistent, Bioaccumulative and ToxicvPvB: very Persistent and very BioaccumulativeVersion: 4 from supplier, dated: 16.12.2012.

Phosphoric Acid 75% Page 8 of 8Information which has been added,deleted or revisedChecking quality of informationResponsible for safety data sheetPrepared byNew Safety Data Sheet.This SDS is quality controlled by National Institute of Technology in Norway,certified according to the Quality Management System requirements specifiedin ISO 9001:2008.Acinor ASNational Institute of Technology as, Norway v/ Camilla M. Ormset