SAFETY DATA SHEET Phosphoric Acid 75%

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Phosphoric Acid 75% Page 2 of 8Composition on the label Orthophosphoric acid ...%: 70 - 85 %Signal wordDangerHazard statementsH314 Causes Severe skin burns and eye damage.Precautionary statementsP305 + P351 + P338 IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing.P223 Keep away from any possible contact with water, because of violentreaction and possible flash fire.P280 Wear protective gloves/protective clothing/eye protection/face protection.P101 If medical advice is needed, have product container or label at hand.P273 Avoid release to the environment.2.3. Other hazardsPBT / vPvBPBT/vPvB assessment has not been performed.SECTION 3: Composition/information on ingredients3.1. SubstancesComponent name Identification Classification ContentsOrthophosphoric acid ...% CAS no.: 7664-38-2EC no.: 231-633-2Index no.: 015-011-00-6Synonyms: Orthophosphoric acidWater CAS no.: 7732-18-5EC no.: 231-791-2Component commentsC; R34Skin Corr. 1B; H314See section 16 for explanation of H- and R-phrases listed above.SECTION 4: First aid measures4.1. Description of first aid measuresGeneralIf in doubt, seek medical advice.InhalationSkin contactEye contactIngestion70 - 85 %15 - 30 %Fresh air and rest. Rinse nose and mouth with water. Get medical attention ifany discomfort continues. For breathing difficulties oxygen may be necessary.Remove contaminated clothing. Flush skin thoroughly with water. Important toremove the substance from the skin immediately. Get medical attention.Chemical burns must be treated by a physician. Wash contaminated clothesbefor reuse.Promptly rinse eyes with plenty of water (tempered at 20-30°C) for at least15 minutes. Remove contact lenses and open eyes wide apart. Immediatelyconsult a doctor. Transport to physician. Keep on flushing during transport.DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Drink a few glassesof water or milk. Do not give victim anything to drink if he is unconscious.Immediately consult a doctor. Transport to hospital. Bring the safety datasheet.4.2. Most important symptoms and effects, both acute and delayedInformation for health personnel Treat Symptomatically.Acute symptoms and effectsDelayed symptoms and effectsCorrosive. Forms blisters and can cause ulceration.Corrosive to the eyes, danger of vision impairment / blindness, burning nose,chemical burns to the skin.Causes burns if swallowed. Causes burning sensation in the mouth, throatand esophagus. May cause serious permanent damage.Inhalation: May cause chemical burns to the respiratory tract.Langvarig eller gjentatt påvirkning kan gi varige skader.4.3. Indication of any immediate medical attention and special treatment neededOther InformationSplashes in the eyes and ingestion of more than an insignificant amountrequires immediate medical attention. Chemical burns of the skin must betreated as burns.
Phosphoric Acid 75% Page 3 of 8SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing mediaImproper extinguishing mediaDry-powder, carbon dioxide (CO2), water mist, foam.Do not use water jet.5.2. Special hazards arising from the substance or mixtureFire and explosion hazardsThe product is not classified as flammable.Hazardous combustion products Oxides of phosphorous (POx). Phosphoric acid mist.5.3. Advice for firefightersPersonal protective equipmentOther InformationUse fresh air equipment when the product is involved in fire. In case ofevacuation, an approved protection mask should be used. See also section 8.Containers close to fire should be removed immediately or cooled with water.Spill water from fire fighting may be strongly caustic. Extinguishing water mustnot be discharged into drains.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresPersonal precautions Use protective equipment as referred to in section 8.Provide adequate ventilation. Avoid inhalation of spray mist and contact withskin and eyes.6.2. Environmental precautionsEnvironmental precautionsDo not allow to enter into sewer, water system or soil.6.3. Methods and material for containment and cleaning upMethods for cleaning6.4. Reference to other sectionsOther instructions See also sections 8 and 13.SECTION 7: Handling and storage7.1. Precautions for safe handlingHandlingAbsorb in vermiculite, dry sand or earth and place into containers. Collect ina suitable container and dispose as hazardous waste according to section 13.Use protective equipment as referred to in section 8. Provide adequateventilation.Avoid inhalation of vapours/spray and contact with skin and eyes. Avoid directcontact. Never pour water into acid/base. Dilute by slowly pouring the productinto water while stirring. Be aware of the risk of exotermic reactions.Immediately change contaminated clothes.Protective MeasuresAdvice on general occupationalhygiene7.2. Conditions for safe storage, including any incompatibilitiesStorageHints on storage assembly7.3. Specific end use(s)Specific use(s) See section 1.2.Wash hands at the end of each work shift and before eating, smoking andusing the toilet. Do not eat, drink or smoke during work.Store in a tightly closed container in a cool, well-ventilated room, protectedfrom direct sunlight. Store in a dry place. Corrosive storage.Keep away from: Bases.SECTION 8: Exposure controls/personal protection8.1. Control parametersExposure limit valuesComponent name Identification Value YearPhosphoric acid CAS no.: 7664-38-2 8 h.: 1 mg/m3 2007
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SAFETY DATA SHEET Phosphoric Acid 75%

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