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The oil spill model OILTRANS and its application to the Celtic Sea ...

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1234567891011121314151617181920212223242526272829303132333435363738394041424344454647484950515253545556575859606162636465U U 0. 035U(15)acurrentwindwhere U a is <strong>the</strong> advective velocity of <strong>the</strong> <strong>oil</strong> slick (m/s). By <strong>model</strong>ling <strong>the</strong> <strong>oil</strong> <strong>spill</strong> as a large numberof discrete lagrangian particles in an XY planar reference frame at <strong>the</strong> water surface such that (x t ,y t )represents <strong>the</strong> location of a particle at time-step t, <strong>the</strong> location of that particle at time-step t+1 due <strong>to</strong>advective <strong>and</strong> diffusive transport processes will be (x t+1 ,y t+1 ) where:x t+1 = x t + u a (x t ,y t ) Δt + Δx diffy t+1 = y t + v a (x t ,y t ) Δt + Δy diffwhere u a (x t ,y t ) <strong>and</strong> v a (x t ,y t ) are <strong>the</strong> u <strong>and</strong> v components of <strong>the</strong> interpolated advective velocity U a atlocation x,y in <strong>the</strong> X <strong>and</strong> Y directions respectively (m/s), Δt is <strong>the</strong> time-step interval (s), Δx diff <strong>and</strong>Δy diff are <strong>the</strong> diffusive displacements of <strong>the</strong> particle in <strong>the</strong> X <strong>and</strong> Y directions respectively due <strong>to</strong>r<strong>and</strong>om process. Based on <strong>the</strong> work by Al Rabeh et al. (1989) <strong>the</strong> values of Δx diff <strong>and</strong> Δy diff can becalculated as:1Δx diff = [ R]12D hcos θ0t(17)1Δy diff = [ R]12D hsin θwhere0t1[R] 0is a r<strong>and</strong>om number uniformly distributed between 0 <strong>and</strong> 1, D h is <strong>the</strong> horizontaldiffusion coefficient (m 2 /s) <strong>and</strong> is user-definable, <strong>and</strong> θ is <strong>the</strong> directional angle assumed <strong>to</strong> beuniformly distributed between 0 <strong>and</strong> 2 (ie. θ = 2 [R ).2.2.3. EvaporationEvaporation is <strong>the</strong> primary wea<strong>the</strong>ring process involved in <strong>the</strong> natural removal of <strong>oil</strong> from <strong>the</strong> seasurface, with <strong>the</strong> rate of evaporation being determined by <strong>the</strong> <strong>oil</strong> properties <strong>and</strong> increasing due <strong>to</strong><strong>the</strong> spreading of <strong>the</strong> <strong>oil</strong>, seawater temperature <strong>and</strong> wind speed (CONCAWE, 1983). <strong>The</strong>evaporation process in <strong>OILTRANS</strong> is <strong>model</strong>led using <strong>the</strong> pseudo-component approach adopted byJones (1997) where <strong>the</strong> <strong>oil</strong> is approximated as an ideal mixture of a small number of components.Each component is characterised by a mole fraction <strong>and</strong> vapour pressure. <strong>The</strong> <strong>to</strong>tal evaporation ratefor <strong>the</strong> <strong>oil</strong> is <strong>the</strong> sum of <strong>the</strong> evaporation rates of each component, i, which is expressed as:dVdtKiA( t)PVi i (ti (18)RTi)Where A is <strong>the</strong> area of <strong>the</strong> <strong>oil</strong> slick (m 2 ), at time t, R is <strong>the</strong> gas constant, T is <strong>the</strong> <strong>oil</strong> temperature,assumed equal <strong>to</strong> <strong>the</strong> water temperature ( o K), K i is <strong>the</strong> mass transfer coefficient, expressed afterMackay <strong>and</strong> Matsugu (1973) as:1] 0(16)

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