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AED Batteries MSDS

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Product Safety Data SheetSDX 01 Lithium /Sulphur (Sulfer) Dioxide Cells Simplified Advice Code(<strong>Batteries</strong>)10/05/01 G1. Identification of the Substance or Preparation and CompanyProduct Lithium/Sulphur (Sulfer) Dioxide Cells (<strong>Batteries</strong>)(Li –SO 2 )Company Saft LtdRiver DriveSouth ShieldsTyne & WearNE33 2TRTel. No. 0191 456 1451Fax No. 0191 456 63832. Composition & Information on IngredientsEach cell consists of a hermetically sealed metallic container containing a number ofchemicals and materials of construction of which the following could potentially behazardous upon release.Ingredient Content CAS No. CHIP ClassificationLithium (Li) 2.5 – 3.0% 7439-93-2 F; R14/15C; R34R14/15,R21,R22, R35,R41, R43S2, S8, S45Acetonitrile(CH 3 CN)8.3 – 8.8% 75-05-8 F; R11, R14/15,R21, R22,S2, S8, S24,S26, S36, S37,S45Sulphur Dioxide(SO 2 )25 – 30% 7446-09-5 R22, R36/37,R41,S2, S8, S22,S24, S26, S36,S37, S45Lithium Bromide 2.0 – 2.5% NONE KNOWNCarbon (C n ) 6.5 – 7.0% NONE KNOWN3. Hazards IdentificationDo not short circuit, recharge, puncture, incinerate, crush, immerse, force dischargeor expose to temperatures above the temperature range of the battery. The cell hasa vent, which upon severe mechanical, electrical or thermal abuse will open andallow some of the chemicals listed above to escape.


4. First Aid MeasuresInhalationSkin ContactEye ContactIngestionFurther TreatmentRemove from exposure, rest and keep warm. In severecases obtain medical attention.Wash off skin thoroughly with water. Remove contaminatedclothing and wash before reuse. In severe cases obtainmedical attention.Irrigate thoroughly with water for at least 15 minutes. Obtainmedical attention.Wash out mouth thoroughly with water and give plenty ofwater to drink. Obtain medical attention.All cases of eye contamination, persistent skin irritation andcasualties who have swallowed this substance or beenaffected by breathing its vapours should be seen by aDoctor.5. Fire Fighting MeasuresIf cells are directly involved in a fire, DO NOT USE WATER, SAND, CO 2 , DRYPOWDER OR SODA ASH EXTINGUISHERS. A Lith-X (graphite base) fireextinguisher or material is the only recommended extinguishing media for firesinvolving lithium metal or some types ofcell. If a fire is in an adjacent area, and cellsare packed in their original containers, the fire can be fought based on fuelingmaterial, e.g. paper and plastic products. Avoid fume inhalation.Extinguishing MediaLith-X (graphite based) or other metal (Class D) powder fireextinguisher.6. Accidental Release MeasuresDo not breath vapours or touch liquid with bare hands. If the skin has come intocontact with the electrolyte it should be washed thoroughly with water. Graphitepowder should be used to absorb the exudation, seal leaking battery and graphitepowder in plastic bag and dispose of as Special Waste.7. Handling and StorageHandling Do not short circuit or expose to temperatures above thetemperature rating of battery. Do not recharge, overdischarge,force discharge, immerse puncture or crush.Storage Store in a cool place but prevent condensation on cells andbatteries. Elevated temperatures can result in shortenedbattery life and degrade performance. Do not store batteriesin high humidity environments for long periods.


8. Exposure Controls & Personal ProtectionOccupational Exposure 8hr TWA10min TWAStandardRespiratoryProtectionIn all fire situations, use self-contained breathingapparatus.HandProtectionIn the event of leakage wear gloves.EyeProtectionSafety glasses are recommended during handlingOtherIn the event of leakage, wear chemical apron.9. Physical and Chemical PropertiesAppearance Cylindrical shapeOdour If leaking, gives off a pungent corrosive odour.pH Not applicableFlash Point Not applicable unless individual components exposedFlammability Not applicable unless individual components exposedRelative Density Not applicable unless individual components exposedSolubility (Water) Not applicable unless individual components exposedSolubility (Other) Not applicable unless individual components exposed10. Stability and ReactivityProduct is stable under conditions described in Section 7.Hazardous reactions Flammable when in contact with moisture.Hazardous decomposition reactions Toxic fumes.11. Toxicological InformationSigns & None, unless battery ruptures. In the event of exposure to internalSymptoms contents, corrosive fumes will be very irritating to skin, eyes andmucous membranes. Overexposure can cause symptoms of nonfibroticlung injury and membrane irritation.Inhalation Lung irritant.Skin Contact Skin irritantEye Contact Eye irritant.IngestionMedicalConditionsGenerallyAggravatedby ExposureTissue damage to throat and gastro/respiratory tact if swallowed.In the event of exposure to internal contents, eczema, skin allergies,lung injuries, asthma and other respiratory disorders may occur.


12. Ecological InformationMammalian effectsEco-toxicityBioaccumulation potentialEnvironmental fateNone known if used/disposed of correctly.None known if used/disposed of correctly.None known if used/disposed of correctly.None known if used/disposed of correctly.13. Disposal ConsiderationsDO NOT INCINERATE or subject cells to temperature’s in excess of 100 o C. Suchabuse can result in loss of seal, leakage, and/or cell explosion. Dispose of inaccordance with appropriate local regulations.14. Transport InformationLabel for Conveyance Cargo Aircraft Only, Class 9 Miscellaneous DangerousGoods, UN Identification Number.UN NumberUN3090Shipping Name Lithium <strong>Batteries</strong>Hazard Classification Class 9 (Miscellaneous)Packing group IIIMDG Code 9033CASEmS No. 4.1-06Marine Pollutant NoADR ClassClass9,515. Regulatory InformationRisk Phrases Lithium R14/15Acetonitrile (CH 3 CN)Sulphur Dioxide (SO 2 )R21R22R35R41R42/43R11R14/15R21R22R22R36/37R41Reacts violently with water,liberating extremely flammablegases.Harmful in contact with skin.Harmful if swallowed.Causes burns.Risk of serious damage to eye.May cause sensitization byinhalation and skin contact.Highly flammable.Reacts violently with water,liberating extremely flammablegases.Harmful in contact with skin.Harmful if swallowed.Harmful if swallowed.Irritating to respiratory system.Risk of serious damage to eye.


Safety Phrases Lithium S2S8S45Keep out of reach of childrenKeep away from moistureIn case of incident, seek medicalattention.Acetonitrile (CH 3 CN)Sulphur Dioxide (SO 2 )S2S8S24S26S36S37S45S2S8S22S24S26S36S37S45Keep out of reach of children.Keep away from moisture.Avoid contact with skin.In case of contact with eyes,rinse immediately with plenty ofwater.Wear suitable protective clothing.Wear suitable gloves.In case of incident, seek medicalattention.Keep out of reach of children.Keep away from moisture.Do not breathe dust.Avoid contact with skin.In case of contact with eyes,rinse immediately with plenty ofwater.Wear suitable protective clothing.Wear suitable gloves.In case of incident, seek medicalattention.UK RegulatoryReferencesClassified under CHIP16. Other InformationThis information has been compiled from sources considered to be dependable andis, to the best of our knowledge and belief accurate and reliable as of the datecompiled. However, no representation, warranty (either expressed or implied ) orguarantee is made to the accuracy, reliability or completeness of the informationcontained herein.This information relates to the specific materials designated and may not be valid forsuch material used in combination with any other materials or in any process. It is theuser’s responsibility to satisfy himself as to the suitability and completeness of thisinformation for his particular use.Saft does not accept liability for any loss or damage that may occur, whether direct,indirect, incidental or consequential, from the use of this information. Saft does notoffer warranty against patent infringement.

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