vanish 750ec - Nulandis

MATERIAL SAFETY DATA SHEETDSCL (Pictograms) DSCL (Classification) Protective ClothingR22- Harmful if swallowed.R38- Irritating to skin. Possible risk of harm tothe unborn child.Conforms to 93/112/EC and ISO 11014-1VANISH 750EC1. Identification of the substance/preparation and of the company/undertakingProduct name : VANISH 750EC SupplierManufacturerSynonyms: Fungicide: PLAASKEM (Pty) Ltd.14 Field Road,LILIANTON: PLAASKEM (Pty) Ltd.14 Field Road,LILIANTONEmergency telephone number : 011-823-8000 (o/h); 0800 147 112 (a/h)2. Composition / information on ingredientsSubstance/Preparation : PreparationChemical name*TridemorphCAS No.81412-43-3%85-87SymbolXnR-PhrasesR22, R38* Occupational Exposure Limit(s), if available, are listed in section 83. Hazards identificationPhysical/chemical hazardsHuman health hazards: Not applicable.: Harmful if swallowed.Irritating to skin.4. First-aid measuresFirst-Aid measuresInhalationIngestionSkin ContactEye ContactEffects and symptomsInhalationIngestionSkin ContactAggravating conditions: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, giveoxygen. Get medical attention.: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything bymouth to an unconscious person. If large quantities of this material are swallowed, call aphysician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with anemollient.Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes beforereuse. Get medical attention.: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plentyof water for at least 15 minutes. WARM water MUST be used. Get medical attention.: Slightly hazardous in case of inhalation.: Slightly hazardous in case of ingestion.: Hazardous in case of skin contact (irritant). Slightly hazardous in case of skin contact (sensitizer).Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.: Repeated or prolonged exposure is not known to aggravate medical condition.5. Fire-fighting measuresExtinguishing MediaSuitableSpecial fire-fighting procedures: Not applicable.: Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and fullturnout gear.Date of issue : 2009/10/01 Version 2.00 Page: 1/3

VANISH 750EC6. Accidental release measuresPersonal precautionsEnvironmental Precautionsand Clean-up Methods: Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient;consult a specialist BEFORE handling this product.: Absorb with an inert material and put the spilled material in an appropriate waste disposal.7. Handling and storageHandlingStoragePackaging materialsRecommended use: Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with skin. Wear suitable protectiveclothing. If ingested, seek medical advice immediately and show the container or the label.: Keep container tightly closed. Keep container in a cool, well-ventilated area.: Use original container.8. Exposure controls/personal protectionEngineering measuresHygiene measuresOccupational Exposure LimitsIngredient NameTridemorph Tech: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vaporsbelow their respective threshold limit value.: Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,using lavatory, and at the end of day.:Occupational Exposure LimitsNot available.Personal protective equipmentRespiratory systemSkin and bodyHandsEyes: Wear appropriate respirator when ventilation is inadequate.: Lab coat.: Gloves.: Safety glasses.9. Physical and chemical propertiesPhysical stateColorOdorBoiling PointMelting PointDensitySolubilityOctanol/water partition coefficientpHFlash pointExplosive properties: Liquid.: Light.: Amine like.: The lowest known value is 200°C (392°F) (Trade Secret).: May start to solidify at 10°C (50°F) based on data for: Trade Secret.: The only known value is 1.02 g/cm 3 (Trade Secret).: Easily soluble in methanol, diethyl ether.Partially soluble in n-octanol.Very slightly soluble in hot water.Insoluble in cold water.: The product is more soluble in oil.: Neutral.: Not applicable.: Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.10.Stability and reactivityStabilityMaterials to avoid: The product is stable.: Slightly reactive to reactive with oxidizing agents.11. Toxicological informationLocal effectsSkin irritationSensitizationAcute toxicityChronic toxicity: Hazardous in case of skin contact (irritant).: Slightly hazardous in case of skin contact (sensitizer).: Acute oral toxicity (LD50): 584 mg/kg [Male Rat], 271 mg/kg [Female Rat].Acute dermal toxicity (LD50): 2710 mg/kg [Male], 2330 mg/kg [Female].Inhalation LC50: (4h) 4.5 mg/l (air).: Repeated or prolonged exposure is not known to aggravate medical condition.Date of issue : 2009/10/01 Version 2.00 Page: 2/3

VANISH 750EC12. Ecological informationEcotoxicity : Not available.13. Disposal considerationsMethods of disposal; Waste ofresidues; Contaminated packaging: Waste must be disposed of in accordance with federal, state and local environmental control regulations.14. Transport informationInternational transport regulationsUN numberLand - Road/RailwayProper shipping nameADR/RID ClassPacking GroupSeaProper shipping nameIMDG ClassPacking GroupAirProper shipping nameUN/ID NumberIATA-DGR ClassInland waterwaysProper shipping nameADNR ClassificationUN/NA (Europe) ADNRPacking Group: Not regulated.: -: -:: -: -:: -: Not regulated.: -: -: -: Not regulated.:15. Regulatory informationEU RegulationsHazard symbol(s) :ClassificationRisk PhrasesSafety PhrasesContains: Harmful: R22- Harmful if swallowed.R38- Irritating to skin.: S2- Keep out of the reach of children.S46- If swallowed, seek medical advice immediately and show this container or label.: - Tridemorph Tech16. Other informationHISTORYDate of printingDate of issueDate of Previous IssueVersionPrepared by:: 2009/10/01: 2006/08/01.: 2.00:Notice to ReaderTo the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiariesassumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be usedwith caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.2009/10/01 2.00 Page: 3/3