Safety Data Sheet - Marineware

DRSafety Data Sheetaccording to 1907/2006/EC, Article 31Page 1/7Printing date 23.04.2010 Revision: 13.08.2009* 1 Identification of substance/mixture and of the company/undertaking· Product details:· Trade name: Ampreg F230 Resin· Application of the substance / the preparation Epoxy resin· Manufacturer/Supplier:GURIT (UK) LTDST. CROSS BUSINESS PARKNEWPORT I.O.W.PO30 5WUUNITED KINGDOMFor SDS information contact simon.rhodes@gurit.com TEL.: +44 (0) 1983 828000FAX : +44 (0) 1983 828100OUT OF HOURS EMERGENCY.: +44 (0) 2392 241208· Informing department: Product safety department.· Emergency information: Contact as above* 2 Hazards identification· Hazard designation:Xi IrritantN Dangerous for the environment· Information pertaining to particular dangers for man and environmentThe product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.R 36/38 Irritating to eyes and skin.R 43 May cause sensitisation by skin contact.R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.Contains epoxy constituents. See information supplied by the manufacturer.· Classification systemThe classification is in line with current EC lists. It is expanded, however, by information fromtechnical literature and by information furnished by supplier companies.* 3 Composition/information on ingredients· Chemical characterization· Description: Mixture of the substances listed below with harmless additions.· Dangerous components:CAS: 25068-38-6NLP: 500-033-5CAS: 28064-14-4bisphenol-A-(epichlorhydrin) epoxy resin (number averagemolecular weight ≤ 700)Xi, N; R 36/38-43-51/53Diglicidylether of Bisphenol-FXi, N; R 36/38-43-51/53C12/C14 AlkylglycidyletherXi; R 38-43CAS: 68609-97-2EINECS: 271-846-8· Additional information For the wording of the listed risk phrases refer to section 16.50-100%2.5-10%2.5-10%GB(Contd. on page 2)PDF created with FinePrint pdfFactory trial version http://www.pdffactory.com

DRSafety Data Sheetaccording to 1907/2006/EC, Article 31Page 2/7Printing date 23.04.2010 Revision: 13.08.2009Trade name: Ampreg F230 Resin(Contd. of page 1)* 4 First aid measures· After inhalationSupply fresh air and call for doctor for safety reasons.In case of unconsciousness bring patient into stable side position for transport.· After skin contact Instantly wash with water and soap and rinse thoroughly.· After eye contactRinse opened eye for several minutes under running water. If symptoms persist, consult doctor.· After swallowingA person vomiting while lying on their back should be turned onto their side.Administer medicinal carbonRinse out mouth and then drink plenty of water.* 5 Fire fighting measures· Suitable extinguishing agentsWater hazeFoamFire-extinguishing powderCarbon dioxide· For safety reasons unsuitable extinguishing agents Water with a full water jet.· Special hazards caused by the material, its products of combustion or resulting gases:Formation of toxic gases is possible during heating or in case of fire.· Protective equipment:Wear full protective suit.Wear self-contained breathing apparatus.· Additional informationCollect contaminated fire fighting water separately. It must not enter drains.* 6 Accidental release measures· Person-related safety precautions:Wear protective equipment. Keep unprotected persons away.· Measures for environmental protection:Inform respective authorities in case product reaches water or sewage system.Do not allow to enter drainage system, surface or ground water.· Measures for cleaning/collecting:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Ensure adequate ventilation.* 7 Handling and storage· Handling· Information for safe handling:Keep away from heat and direct sunlight.Keep containers tightly sealed.Ensure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.· Information about protection against explosions and fires: No special measures required.· Storage· Requirements to be met by storerooms and containers: Store in cool location.· Information about storage in one common storage facility: Not required.(Contd. on page 3)GBPDF created with FinePrint pdfFactory trial version http://www.pdffactory.com

DRSafety Data Sheetaccording to 1907/2006/EC, Article 31Page 3/7Printing date 23.04.2010 Revision: 13.08.2009Trade name: Ampreg F230 Resin· Further information about storage conditions:Keep container tightly sealed.Store in cool, dry conditions in well sealed containers.Protect from heat and direct sunlight.(Contd. of page 2)* 8 Exposure controls and personal protection· Additional information about design of technical systems: No further data; see item 7.· Components with limit values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have tobe monitored at the workplace.· Additional information: The lists that were valid during the compilation were used as basis.· Personal protective equipment· General protective and hygienic measuresKeep away from foodstuffs, beverages and food.Take off immediately all contaminated clothingWash hands during breaks and at the end of the work.Avoid contact with the eyes and skin.· Breathing equipment: Use breathing protection in case of insufficient ventilation.· Protection of hands:Protective gloves.The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Selection of the glove material on consideration of the penetration times, rates of diffusion andthe degradation· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on furthermarks of quality and varies from manufacturer to manufacturer. As the product is a preparation ofseveral substances, the resistance of the glove material can not be calculated in advance andhas therefore to be checked prior to the application.· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.· For the permanent contact of a maximum of 15 minutes gloves made of the followingmaterials are suitable:Nitrile rubber, NBR· As protection from splashes gloves made of the following materials are suitable:Nitrile rubber, NBR· Eye protection:Tightly sealed safety glasses.· Body protection: Protective work clothing.GB(Contd. on page 4)PDF created with FinePrint pdfFactory trial version http://www.pdffactory.com

DRSafety Data Sheetaccording to 1907/2006/EC, Article 31Page 4/7Printing date 23.04.2010 Revision: 13.08.2009Trade name: Ampreg F230 Resin(Contd. of page 3)* 9 Physical and chemical properties:· General InformationForm:Colour:Odour:LiquidWhitishWeak, characteristic· Change in conditionMelting point/Melting range: Not determinedBoiling point/Boiling range: Not determined· Flash point: 101°C· Ignition temperature: 460°C· Self-inflammability: Product is not selfigniting.· Danger of explosion: Product is not explosive.· Vapour pressure at 20°C: 0.1 hPa· Density Not determined· Solubility in / Miscibility withWater:· Solvent content:Organic solvents: 0.5 %Water: 0.0 %Solids content: 1.7 %Not miscible or difficult to mix* 10 Stability and reactivity· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.· Materials to be avoided:· Dangerous reactionsReacts with alcohols, amines, aqueous acids and alkalisDevelops readily flammable gases / fumes· Dangerous products of decomposition: Danger of toxic pyrolysis products11 Toxicological information· Acute toxicity:· LD/LC50 values that are relevant for classification:25068-38-6 bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight£ 700)Oral LD50 10000 mg/kg (rat)Dermal LD50 2000 mg/kg (rat)· Primary irritant effect:· on the skin: Irritant to skin and mucous membranes.· on the eye: Irritant effect.· Sensitization: Sensitization possible by skin contact.· Additional toxicological information:The product shows the following dangers according to the calculation method of the General ECClassification Guidelines for Preparations as issued in the latest version:(Contd. on page 5)GBPDF created with FinePrint pdfFactory trial version http://www.pdffactory.com

DRSafety Data Sheetaccording to 1907/2006/EC, Article 31Page 5/7Printing date 23.04.2010 Revision: 13.08.2009Trade name: Ampreg F230 ResinIrritant· Sensitisation May cause sensitisation by skin contact.(Contd. of page 4)* 12 Ecological information:· Additional ecological information:· General notes:Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.Do not allow product to reach ground water, water bodies or sewage system.* 13 Disposal considerations· Product:· RecommendationMust not be disposed of together with household garbage. Do not allow product to reach sewagesystem.· European waste catalogue08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE(MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS),ADHESIVES, SEALANTS AND PRINTING INKS08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products)08 04 09 waste adhesives and sealants containing organic solvents or other dangeroussubstances· Uncleaned packagings:· Recommendation:Packagings that cannot be cleaned are to be disposed of in the same manner as the product.* 14 Transport information· Land transport ADR/RID (cross-border)· ADR/RID Class: 9 Miscellaneous dangerous substances and articles.· Kemler Number: 90· UN-Number: 3082· Packaging group: III· Label 9· Special marking: Symbol (fish and tree)· Designation of goods: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S. (bisphenol-A-(epichlorhydrin) epoxy resin (number averagemolecular weight ≤ 700))· Maritime transport IMDG:· IMDG Class: 9(Contd. on page 6)GBPDF created with FinePrint pdfFactory trial version http://www.pdffactory.com

DRSafety Data Sheetaccording to 1907/2006/EC, Article 31Page 6/7Printing date 23.04.2010 Revision: 13.08.2009Trade name: Ampreg F230 Resin(Contd. of page 5)· UN Number: 3082· Label 9· Packaging group: III· EMS Number: FA,SF· Marine pollutant: YesSymbol (fish and tree)· Correct technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(bisphenol-A-(epichlorhydrin) epoxy resin (number average molecularweight ≤ 700))· Air transport ICAO-TI and IATA-DGR:· ICAO/IATA Class: 9· UN/ID Number: 3082· Label 9· Special marking: Symbol (fish and tree)· Packaging group: III· Correct technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(bisphenol-A-(epichlorhydrin) epoxy resin (number average molecularweight ≤ 700))* 15 Regulatory information· Designation according to EC guidelines:The product has been classified and labelled in accordance with EC Directives / Ordinance onHazardous Materials (GefStoffV)· Code letter and hazard designation of product:Xi IrritantN Dangerous for the environment· Hazard-determining components of labelling:bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)Diglicidylether of Bisphenol-FC12/C14 Alkylglycidylether· Risk phrases:36/38 Irritating to eyes and skin.43 May cause sensitisation by skin contact.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.· Safety phrases:23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by themanufacturer).24 Avoid contact with skin.26 In case of contact with eyes, rinse immediately with plenty of water and seek medicaladvice.28 After contact with skin, wash immediately with plenty of water.37/39 Wear suitable gloves and eye/face protection.57 Use appropriate container to avoid environmental contamination.(Contd. on page 7)GBPDF created with FinePrint pdfFactory trial version http://www.pdffactory.com

DRSafety Data Sheetaccording to 1907/2006/EC, Article 31Page 7/7Printing date 23.04.2010 Revision: 13.08.2009Trade name: Ampreg F230 Resin· Special designation of certain preparations:Contains epoxy constituents. See information supplied by the manufacturer.· National regulations· Technical instructions (air):Class Share in %NK 0.5(Contd. of page 6)· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.* 16 Other information:These data are based on our present knowledge. However, they shall not constitute a guaranteefor any specific product features and shall not establish a legally valid contractual relationship.· Relevant R-phrases36/38 Irritating to eyes and skin.38 Irritating to skin.43 May cause sensitisation by skin contact.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.· Department issuing data specification sheet: Health, Safety & Environmental department.· Contact: SIMON RHODES· * Data compared to the previous version altered.GBPDF created with FinePrint pdfFactory trial version http://www.pdffactory.com