<strong>Stone</strong> Decay 7ing the difficult challenge <strong>of</strong> long-term evaluation <strong>of</strong> stone treatments(Simon and Lind 1999; Favaro et al. 2006; Favaro et al. 2007).The development and application <strong>of</strong> the drilling resistance measurementsystem (DRMS), also known as the drilling force measurementsystem (DFMS), has provided an extremely useful and minimally destructivemethod for evaluating the condition <strong>of</strong> stone and the performance<strong>of</strong> treatments for stone (Lotzmann and Sasse 1999; Leroux et al. 2000;Delgado Rodrigues, Ferreira Pinto, and Rodrigues da Costa 2002;Pamplona et al. 2008). The system uses a portable drill and ceramic drillbit with a sensor to measure the force needed to advance the drill bit agiven distance. In principle, the DFMS can determine depth <strong>of</strong> deteriorationand the penetration depth <strong>of</strong> consolidants, in situ, with a minimum<strong>of</strong> destruction (a 3 mm hole).Ground-penetrating radar is increasingly used in archaeologicalprospecting, and it is natural that its use should be extended to historicbuildings (Finzi, Massa, and Morero 1992). It has seen wider applicationrecently by a number <strong>of</strong> researchers (Binda et al. 2003; Binda, Lualdi, andSaisi 2007; Huneau et al. 2008; Palieraki et al. 2008). The method is usefulin detecting flaws, voids, moisture, metal straps, and the thickness <strong>of</strong>stone masonry.Infrared thermography has been used by a wide range <strong>of</strong>researchers (Moropoulou, Avdelidis, and Theoulakis 2003; Grinzato et al.2004; Tavukçuoglu et al. 2005) to study moisture in stone. To provideuseful results, a thermal contrast, such as solar heating or deliberate heatingby infrared lamps, is <strong>of</strong>ten needed to identify the different surfacetemperatures related to differences in moisture content. This method isknown as photothermal radiometry and has been developed to detectdelaminations and voids (Madrid, C<strong>of</strong>fman, and Ginell 1993; Candoré etal. 2008). Most building materials have significant thermal inertia, andpractitioners using thermography on a casual basis will not necessarilyfind useful temperature contrasts.One interesting way to look into a stone’s subsurface for smallsurface detachments is to use the sensitivity <strong>of</strong> laser holography interferometryin combination with varying sound vibrations from a loudspeakerto map detached segments <strong>of</strong> wall paintings or stone surfaces(Castellini et al. 2003; Gulker, Hinsch, and El Jarad 2004; Keene andChiang 2009).A range <strong>of</strong> field evaluation methods has proven useful for quantifyingwater uptake and surface coherence, including the sponge andScotch tape tests (Urzï and De Leo 2001; Vergès-Belmin and Laboure2007; Vandevoorde et al. 2009).Laboratory-Based MethodsSo far, we have considered minimally destructive techniques. It is,<strong>of</strong> course, possible in some instances to remove samples for analysis inthe laboratory. These will <strong>of</strong>ten consist <strong>of</strong> core samples, which are slicedparallel to the original surface. The slices may be examined using the normaltechniques for characterizing stone, such as polarized light microscopy,scanning electron microscopy combined with energy- dispersive
8 Chapter 1spectroscopy, hygric tests, and biaxial flexural strength measurements(Mamillan 1991; Snethlage, Wendler, and Sattler 1991; Bläuer Böhm2004). Surface hardness measurements may be useful, and the salt content<strong>of</strong> the slices may also be determined (Bläuer Böhm 2005).The European Commission (EC) projects COMPASS andDESALINATION have developed a simple test for salt content basedon the hygroscopic moisture content (HMC) (Gonçalves and DelgadoRodrigues 2006; Gonçalves, Delgado Rodrigues, and Abreu 2006;Nasraoui, Nowik, and Lubelli 2009). Kaminski (2008) has proposed analternative gravimetric system and makes some constructive criticisms<strong>of</strong> common aspects <strong>of</strong> the diagnosis and analysis <strong>of</strong> moisture and salts,including misleading readings from moisture meters based on electricalresistance or dialetric properties, dry drill powders showing lower thanexpected results, and salt solution–conditioned chambers not providingconsistent conditions for HMC measurements.Jacobs, Sevens, and Kunnen (1995) proposed the use <strong>of</strong> computerizedX-ray tomography (CT) to gain further insight into the internalstructure <strong>of</strong> stone and the changes that occur during the deterioration <strong>of</strong>building materials. Procedures were developed to bring the resolutiondown to grain-size level (about 100 microns or less). Mossotti andCastanier (1990) used CT scanning to show that for Salem limestone,capillary water reached the surface except under windy conditions, whenthe air/water interface moved into the stone. In the past decade, resolution<strong>of</strong> the CT method has advanced significantly (Bugani et al. 2008;Cnudde et al. 2009; Ruiz de Argandoña et al. 2009); however, it is stilldifficult to see treatments and salts inside pores owing to the lack <strong>of</strong>contrast and the small amount <strong>of</strong> material scanned. A promising way toovercome the limitations <strong>of</strong> x-ray CT is the use <strong>of</strong> high-speed neutrontomography (synchrotron radiation) for in situ dynamic analysis <strong>of</strong> wetting/drying,moisture transport, salt development, or the curing and evaluation<strong>of</strong> protective coatings and consolidants within a porous stone(Vlassenbroeck et al. 2007; Cnudde et al. 2008).The linear variable differential transformer (LVDT; also knownas a linear velocity displacement transducer) has also proven to be animportant lab tool in the quantitative evaluation <strong>of</strong> the thermal andhygric response <strong>of</strong> building materials to wetting and humidity cycles,measuring expansion and contraction behavior on a micron scale(Martin, Röller, and Stöckhert 1999; Lombardo, Doehne, and Simon2004; Poupeleer et al. 2006).Nuclear magnetic resonance (NMR) imaging (also known asMRI) <strong>of</strong> building materials has advanced rapidly in the last fifteen years.This method allows the measurement <strong>of</strong> hydrogen and sodium ions insolutions present inside porous materials and has provided an importantnew dimension for understanding the behavior <strong>of</strong> moisture in buildingmaterials, especially at the millimeter to centimeter scale (Pel, Kopinga,and Brocken 1996; Pel, Huinink, and Kopinga 2002; Rijniers et al. 2004;Huinink et al. 2006; Gonçalves, Pel, and Delgado Rodrigues 2009). Forexample, when a stone has finer pores than an overlying plaster, NMR
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References 91Charola, A. E. 1995. W
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References 97Facaoaru, I., and C. L
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References 101Historia. http://www.
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References 103Poland, ed. J. W. Luk
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References 119Paradise, T. R. 2002.
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Index 155hexafluoropropene-vinylide
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Index 157research needed on, 55-56w
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About the AuthorsEric Doehne holds