4 th International Conference on <strong>Tribology</strong> in <strong>Manufacturing</strong> <strong>Processes</strong> - ICTMP 2010while the mineral oil does not [87]. Differential Thermal Analysis (DTA) proves that thechlorinated paraffin oil as well as P1 reacts chemically with the punch material, PMHSS, at elevated temperature implying that it is likely that a thin boundary film isestablished on the punch. The poor performance <strong>of</strong> the polymer coating is to beexpected due to the small punch clearance (10-15 μm) and the fact that this semi-solidfilm lubricant has difficult access to the clearance area between punch and die.Figure 16 : Maximum punch stem friction stress during backstroke as a function <strong>of</strong>stroke number. Curve legends refer to lubricants listed in Table 3.7 CONCLUSIONSThe increased focus on environmental issues in industrial production as well as on externalenvironment has resulted in important developments <strong>of</strong> new, environmentally benignlubricants for metal forming. As regards cold forging new, single bath lubricant systemsdepositing a double layer <strong>of</strong> an inorganic salt and a wax on the slug surface have proven veryefficient in substituting phosphate coating and soap lubrication. In warm and hot forging theblack lubricants have been abandoned by many industries now using white lubricants oneither polymer base, carvone base or liquid glass base. The huge amount <strong>of</strong> lubricantconsumption in rolling has promoted the application <strong>of</strong> water based emulsions, whichlubricate almost as well as the oil based and have better cooling efficiency.In sheet metal forming pre-lubrication at the rolling mill with polymer coating is replacing inprocesslubrication with mineral oils. Regarding more severe sheet forming <strong>of</strong> materials26
Green lubricants for metal formingprone to galling a number <strong>of</strong> lubricant manufacturers have developed promising alternativesto chlorinated paraffin oils, such as mineral oils with Ca-, S- and P-additives and vegetableoils with fatty acid esters.8 ACKNOWLEDGEMENTSThe authors gratefully acknowledge contributions and assistance by T. Altan, Ohio StateUniv., A. Azushima, Yokohama Nat. Univ., D. Brans, Rhenus Lub., L. Dubart, Univ. deValenciennes et du Hainaut Cambrésis, P. Groche, Techn. Univ. <strong>of</strong> Darmstadt, J. Holzand P. Zwez, ZWEZ-Chemie, H. Ike, RIKEN, I. Ishibashi, Sumico Lubricants, K.Kitamura, Nagoya Inst. <strong>of</strong> Techn., F. Klocke, Aachen Univ., K. Kuzman, Univ.Ljubljana, M. Merklein, Univ. <strong>of</strong> Erlangen-Nuremberg, M. Morishita, Toyota MotorCorp., G. Ngaile, North Carolina State Univ., K.P. Rao, City Univ. <strong>of</strong> Hongkong, E.Suvanto, Pinifer, M. Yoshida, Nihon Parkerizing.9 REFERENCES[1] European Parliament, Council, REACH, EC Regulation No 1907/2006 <strong>of</strong> theEuropean Parliament and <strong>of</strong> the Council, 2006[2] http://www.env.go.jp/en/laws/policy/basic/index.html[3] http://www.env.go.jp/en/laws/recycle/01.pdf[4] http://www.cdc.gov/niosh/98-102.html[5] ICFG Doc. 10/95, “Lubrication Aspects in Cold Forging <strong>of</strong> Aluminium andAluminium Alloys”, The International Cold Forging Group, 1995. Publ. in WIRE 1(1996) 1-12 (supplement <strong>of</strong> WIRE)[6] ICFG Doc. 8/91, “Lubrication Aspects in Cold Forging <strong>of</strong> Carbon Steels and LowAlloy Steels”, The International Cold Forging Group, 1991[7] N. Bay, “The State <strong>of</strong> the Art in Cold Forging Lubrication”, J. <strong>of</strong> Matls Process.Techn. 46 (1994) 19-40[8] M. Yoshida, Y., Imai, H., Yamaguchi, S., Nagata, Nihon Parkerizing, TechnicalReport No. 15, (2003)[9] T. Nakamura, I., Ishibashi, “Environmentally Friendly Lubrication System forForging”, English translation <strong>of</strong> Report from JSTP’s Sub-Committee on Process-<strong>Tribology</strong> (2004)[10] M. Morishita, “<strong>Tribology</strong> in <strong>Manufacturing</strong> <strong>Processes</strong> <strong>of</strong> Automobiles at Toyota”,In Azushima, A. (Edtr.): Proceed. 3rd Int. Conf. on <strong>Tribology</strong> in <strong>Manufacturing</strong><strong>Processes</strong>, ICTMP3, Yokohama, Japan, Oct. 2007, 1-9[11] H. Ike, “Report on Metal Forming <strong>Tribology</strong> Research in Japan with SpecialFocus on Environmental Aspects”, In: Bay, N. (Edtr.): Proceed. Int. Conf. on<strong>Tribology</strong> in Manuf. Process., ICTMP2, Nyborg, Denmark, June 2004, 29-3827