TREMproof 201/60 R Black MSDS - Tremco Sealants

Material Safety Data SheetTREMPROOF 201/60 - RVersion 5.0 Print Date 06/19/2014REVISION DATE: 06/18/2014SECTION 6 - ACCIDENTAL RELEASE MEASURESUse appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.SECTION 7 - HANDLING AND STORAGEPrevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed whennot in use. Precautions also apply to emptied containers. Change soiled work clothes frequently. Clean handsthoroughly after handling. Do not smoke, weld, generate sparks, or use flame near container. To preventgeneration of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignitionsources including pilot lights, non-explosion proof motors and electrical equipment until vapors dissipate. Storeunder dry warehouse conditions away from heat and all ignition sources.SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONPersonal protection equipmentRespiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved respirator whenairborne contaminant level(s) are expected to exceed exposure limitsindicated on the MSDS. Select positive pressure supplied air respirator(TC19C or equivalent) for isocyanates.Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel toreduce exposure.Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or faceshield to prevent eye contact. Do not wear contact lenses. Do not touch eyeswith contaminated body parts or materials. Have eye washing facilities readilyavailable.Skin and body protection : Prevent contact with shoes and clothing.Protective measures : Use professional judgment in the selection, care, and use.Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosedareas.Use local exhaust when the general ventilation is inadequate.Exposure LimitsChemical Name CAS Number Regulation Limit FormCalcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.(Limestone)OSHA PEL: 15 mg/m3 Total dust.ACGIH TWA: 3 mg/m3 Respirable particles.ACGIH TWA: 10 mg/m3 Inhalable particles.OSHA TWA: 15 mg/m3 Total dust.OSHA TWA: 5 mg/m3 Respirable fraction.Calcium oxide 1305-78-8 ACGIH TWA: 2 mg/m3OSHA PEL: 5 mg/m3OSHA TWA: 15 mg/m3 Total dust.OSHA TWA: 5 mg/m3 Respirable fraction.3/7 859509 805

Material Safety Data SheetTREMPROOF 201/60 - RVersion 5.0 Print Date 06/19/2014REVISION DATE: 06/18/2014Chemical Name CAS Number Regulation Limit FormCarbon Black 1333-86-4 ACGIH TWA: 3.5 mg/m3OSHA PEL: 3.5 mg/m3OSHA TWA: 15 mg/m3 Total dust.OSHA TWA: 5 mg/m3 Respirable fraction.Stoddard solvent (MineralSpirits)Hydrotreated heavynaphthenic distillate8052-41-3 ACGIH TWA: 100 ppmOSHA PEL: 2,900 mg/m364742-52-5 OSHA PEL: 2,000 mg/m3OSHA PEL: 5 mg/m3 Mist.ACGIH TWA: 5 mg/m3 Inhalable fraction.2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppmACGIH STEL: 0.02 ppm1,2,4-Trimethylbenzene 95-63-6 ACGIH TWA: 25 ppmSECTION 9 - PHYSICAL AND CHEMICAL PROPERTIESForm: LiquidColor: Black / BrownOdor: SolventpH: Not available.Vapour pressure: Not available.Vapor density: Heavier than airMelting point/range: Not available.Freezing point: Not available.Boiling point/range: Not available.Water solubility: NegligibleSpecific Gravity : 1.2% Volatile Weight : 7 %SECTION 10 - REACTIVITY / STABILITYSubstances to avoidStabilityHazardous polymerization: Strong acids.Strong bases.Amines.Water or moisture.Alcohols.: Material is stable under normal storage, handling, and use.: Will not occur under normal conditions.SECTION 11 - TOXICOLOGICAL INFORMATION2,4-Toluene diisocyanate, CAS-No.: 584-84-9Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat )4/7 859509 805

Material Safety Data SheetTREMPROOF 201/60 - RVersion 5.0 Print Date 06/19/2014REVISION DATE: 06/18/2014Acute inhalation toxicity (LC-50) 14 mg/l for 4 h ( Rat ) 10 mg/l for 4 h ( Mouse ) 13 mg/l for 4h ( Guinea pig ) 11 mg/l for 4 h ( Rabbit )SECTION 12 - ECOLOGICAL INFORMATIONNo Data AvailableSECTION 13 - DISPOSAL CONSIDERATIONSDisposal Method : Subject to hazardous waste treatment, storage, and disposal requirements underRCRA. Recycle or incinerate waste at EPA approved facility or dispose of incompliance with federal, state and local regulations.SECTION 14 - TRANSPORTATION / SHIPPING DATACFR / DOT:Not RegulatedTDG:Not RegulatedIMDG:Not RegulatedSECTION 15 - REGULATORY INFORMATIONNorth American Inventories:This product or its components are listed on, or exempt from the Canadian Domestic Substances List.All components are listed or exempt from the TSCA inventory.This product or its components are listed on, or exempt from the Canadian Domestic Substances List.U.S. Federal Regulations:SARA 313 Components : 2,4-Toluene diisocyanate 584-84-9SARA 311/312 Hazards : Acute Health HazardChronic Health HazardFire HazardOSHA Hazardous Components :Aromatic process oil 64741-62-4Calcium Carbonate (Limestone) 1317-65-3Calcium oxide 1305-78-85/7 859509 805

Material Safety Data SheetTREMPROOF 201/60 - RVersion 5.0 Print Date 06/19/2014REVISION DATE: 06/18/2014Carbon Black 1333-86-4Stoddard solvent (Mineral Spirits) 8052-41-3Hydrotreated heavy naphthenic distillate 64742-52-52,4-Toluene diisocyanate 584-84-91,2,4-Trimethylbenzene 95-63-6OSHA Status: Consideredhazardous based on thefollowing criteria:: IrritantSensitizerCarcinogenOSHA Flammability : IIIARegulatory VOC (less water andexempt solvent): 82 g/lVOC Method 310 : 6.75 %Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:Carbon Black 1333-86-4Hydrotreated heavy naphthenic distillate 64742-52-5U.S. State Regulations:MASS RTK Components : Calcium Carbonate (Limestone) 1317-65-3Calcium oxide 1305-78-8Carbon Black 1333-86-4Stoddard solvent (Mineral Spirits) 8052-41-32,4-Toluene diisocyanate 584-84-9Penn RTK Components : Aromatic process oil 64741-62-4Polyurethane Polymer NJ TSRN# 51721300-5024PCalcium Carbonate (Limestone) 1317-65-3Calcium oxide 1305-78-8Carbon Black 1333-86-4Stoddard solvent (Mineral Spirits) 8052-41-32,4-Toluene diisocyanate 584-84-9NJ RTK Components : Aromatic process oil 64741-62-4Polyurethane Polymer NJ TSRN# 51721300-5024PCalcium Carbonate (Limestone) 1317-65-3Calcium oxide 1305-78-8Carbon Black 1333-86-4Stoddard solvent (Mineral Spirits) 8052-41-3Hydrotreated heavy naphthenic distillate 64742-52-5Components under California Proposition 65:WARNING! Contains chemicals known to the State of California to cause cancer, birth defects and/or otherreproductive harm6/7 859509 805

Material Safety Data SheetTREMPROOF 201/60 - RVersion 5.0 Print Date 06/19/2014REVISION DATE: 06/18/2014SECTION 16 - OTHER INFORMATIONHMIS Rating :Health 2 0 = MinimumFlammability 21 = SlightReactivity 02 = ModeratePPE3 = Serious4 = SevereFurther information:For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for theconsideration of the user, subject to their own investigation of compliance with applicable regulations, includingthe safe use of the product under every foreseeable condition.Prepared by: Rich MikolLegendACGIH - American Conference of Governmental HygienistsCERCLA - Comprehensive Environmental Response, Compensation, andLiability ActDOT - Department of TransportationDSL - Domestic Substance ListEPA - Environmental Protection AgencyHMIS - Hazardous Materials Information SystemIARC - International Agency for Research on CancerMSHA - Mine Safety Health AdministrationNDSL - Non-Domestic Substance ListNIOSH - National Institute for Occupational Safety and HealthNTP - National Toxicology ProgramOSHA - Occupational Safety and Health AdministrationPEL - Permissible Exposure LimitRCRA - Resource Conservation and Recovery ActRTK - Right To KnowSARA - Superfund Amendments and Reauthorization ActSTEL - Short Term Exposure LimitTLV - Threshold Limit ValueTSCA - Toxic Substances Control ActTWA - Time Weighted AverageV - VolumeVOC - Volatile Organic CompoundWHMIS - Workplace Hazardous Materials InformationSystem7/7 859509 805