874717 COSHH Datasheet (PDF) - Travis Perkins

1.IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OFTHE COMPANY/UNDERTAKINGIdentification of the substance/preparationProduct name or Trade name :Sikadur®-31 CF Normal/Rapid Part ASafety Data SheetConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)Use of the substance/preparationCompany/undertaking identification:Chemical product for construction and industryManufacturer/DistributorTelephone no.: 01707 394444Fax no. : 01707 329129e-mail address of personresponsible for this SDSEmergency telephone number:::Sika LimitedWatchmead Welwyn Garden CityHertfordshire. AL7 1BQUnited KingdomEHS@uk.sika.com+44 (0)1707 363899 (available during office hours).2.HAZARDS IDENTIFICATIONThe product is classified as dangerous according to Directive 1999/45/EC and its amendments.ClassificationHuman health hazardsEnvironmental hazardsAdditional warning phrases:::Xi; R36/38R43R52/53Irritating to eyes and skin. May cause sensitisation by skin contact.Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.: Contains epoxy constituents. See information supplied by the manufacturer.See section 11 for more detailed information on health effects and symptoms.3.COMPOSITION/INFORMATION ON INGREDIENTSChemical family/Characteristics:Filled and modified epoxy resinIngredient name CAS number % EC number Classificationreaction product: bisphenol A-(epichlorhydrin)epoxy resin (number average molecular weight

Sikadur®-31 CF Normal/Rapid Part A 13.07.2010 5/613.DISPOSAL CONSIDERATIONS15 01 10* packaging containing residues of or contaminated by dangeroussubstances14.TRANSPORT INFORMATIONInternational transport regulationsADRNot regulated.IMDGNot regulated.Marine pollutantIATANot regulated.:No15.REGULATORY INFORMATIONEU regulationsClassification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC(including amendments) and take into account the intended product use.Hazard symbol or symbolsContainsRisk phrases:::XiIrritantreaction product: bisphenol A-(epichlorhydrin) epoxy resin (number averagemolecular weight

Sikadur®-31 CF Normal/Rapid Part A 13.07.2010 6/616.OTHER INFORMATIONFull text of classificationsreferred to in sections 2 and3Full text of classificationsreferred to in sections 2 and3::R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.Xi - IrritantN - Dangerous for the environmentHistoryDate of printing: 13.07.2010.Date of issue : 13.07.2010.Date of previous issue : No previous validation.Indicates information that has changed from previously issued version.Notice to readerThe information contained in this Safety Data Sheet corresponds to our level of knowledge at the time ofpublication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consultthe product data sheet prior to any use and processing.Date of issue : 13.07.2010.MSDS no. : 1142216/6

Sikadur®-31 CF normal Part B 13.07.2010 3/67.HANDLING AND STORAGEHandlingStoragePackaging materialsRecommended::Put on appropriate personal protective equipment (see section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist.Keep in the original container or an approved alternative made from a compatiblematerial, kept tightly closed when not in use. Empty containers retain product residueand can be hazardous.Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatiblematerials (see section 10) and food and drink. Keep container tightly closed andsealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination.: Use original container.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONExposure limit valuesIngredient nameNo exposure limit value known.Occupational exposure limitsRecommended monitoringproceduresExposure controlsOccupational exposurecontrolsHygiene measures :Respiratory protection :Hand protectionEye protectionSkin protectionEnvironmental exposurecontrols:If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.: Good general ventilation should be sufficient to control worker exposure to airbornecontaminants. If this product contains ingredients with exposure limits, use processenclosures, local exhaust ventilation or other engineering controls to keep workerexposure below any recommended or statutory limits.:::Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing.No special measures required.Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary. Recommended: Butyl rubber/nitrile rubber gloves.Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts.Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialist beforehandling this product. Recommended: Use barrier skin cream.: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.Date of issue : 13.07.2010.MSDS no. : 1142223/6

Sikadur®-31 CF normal Part B 13.07.2010 4/69.PHYSICAL AND CHEMICAL PROPERTIESGeneral informationAppearanceFormColourOdour:::Paste.Dark grey.Amine-like.Important health, safety and environmental informationpH: 11.4 [Conc. (% w/w): 50%]Flash point: Closed cup: >101°C (>213.8°F)Density: ~1.94 g/cm 3 [20°C (68°F)]10.STABILITY AND REACTIVITYStabilityConditions to avoidMaterials to avoid :Hazardous decompositionproducts:::The product is stable.No specific data.No specific data.Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.11.TOXICOLOGICAL INFORMATIONPotential acute health effectsInhalationIngestionSkin contactEye contactChronic effects :: May cause irritation.:Irritating to mouth, throat and stomach.: Irritating to skin. May cause sensitisation by skin contact.:Irritating to eyes.Once sensitized, a severe allergic reaction may occur when subsequently exposed tovery low levels.12.ECOLOGICAL INFORMATIONEnvironmental effects: Avoid contact of spilt material and runoff with soil and surface waterways. Do notempty into drains; dispose of this material and its container in a safe way.13.DISPOSAL CONSIDERATIONSMethods of disposalEuropean waste catalogue(EWC)::The generation of waste should be avoided or minimised wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable productsvia a licensed waste disposal contractor. Disposal of this product, solutions and anyby-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authorityrequirements. Avoid dispersal of spilt material and runoff and contact with soil,waterways, drains and sewers.08 04 09* waste adhesives and sealants containing organic solvents or otherdangerous substancesPackaging: Completely emptied packaging or practically empty packaging containing dried/curedresidues, once relieved of all pressure can be disposed of as non-hazardous waste.Packaging may still contain hazardous residues and disposal should undertaken by alicensed waste contractor.Any disposal practice must be in compliance with local and national laws andregulations.Date of issue : 13.07.2010.MSDS no. : 1142224/6

Sikadur®-31 CF normal Part B 13.07.2010 5/613.DISPOSAL CONSIDERATIONS15 01 10* packaging containing residues of or contaminated by dangeroussubstances14.TRANSPORT INFORMATIONInternational transport regulationsADRNot regulated.IMDGNot regulated.Marine pollutantIATANot regulated.:No15.REGULATORY INFORMATIONEU regulationsClassification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC(including amendments) and take into account the intended product use.Hazard symbol or symbolsContainsRisk phrases:::XiIrritant3-aminomethyl-3,5,5-trimethylcyclohexylamine3,6-diazaoctanethylenediaminR36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.Safety phrasesNational regulations:S24- Avoid contact with skin.S37- Wear suitable gloves.VOC content (EU) : VOC (w/w): 8.12%Regulatory informationGuidance Publications:Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP4)Control of Substances Hazardous to Health Regulations 2002 (COSHH) (asamended)Health & Safety at Work Act 1974The Environmental Protection (Duty of Care) Regulations 1991Hazardous waste regulations 2005The Carriage of Dangerous Goods and Use of Transportable Pressure EquipmentRegulations 2007: Approved Code of Practice - Management of Health and Safety at Work, HSEGeneral Approved Code of Practice to COSHH Regulations, HSE.16.OTHER INFORMATIONFull text of classificationsreferred to in sections 2 and3:R21- Harmful in contact with skin.R22- Harmful if swallowed.R20/22- Harmful by inhalation and if swallowed.R21/22- Harmful in contact with skin and if swallowed.R34- Causes burns.R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theDate of issue : 13.07.2010.MSDS no. : 1142225/6

Sikadur®-31 CF normal Part B 13.07.2010 6/616.OTHER INFORMATIONFull text of classificationsreferred to in sections 2 and3:aquatic environment.C - CorrosiveXn - HarmfulXi - IrritantHistoryDate of printing13.07.2010.Date of issue : 13.07.2010.Date of previous issue : No previous validation.Notice to reader:Indicates information that has changed from previously issued version.The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time ofpublication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consultthe product data sheet prior to any use and processing.Date of issue : 13.07.2010.MSDS no. : 1142226/6