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Heavy Fuel Oil Components9.7. Use of Heavy Fuel Oil as a Fuel – Industrial9.7.1. Exposure ScenarioSection 1 Exposure Scenario Title Heavy Fuel OilTitleUse as a FuelUse DescriptorSector(s) of Use 3Process Categories 1, 2, 3, 8a, 8b, 16Further information on the mapping and allocation ofPROC codes is contained in Table 9.1Environmental Release Categories 7Specific Environmental Release Category ESVOC SpERC 7.12a.v1Processes, tasks, activities coveredCovers the use as a fuel (or fuel additives and additive components) within closed or containedsystems, including incidental exposures during activities associated with its transfer, use, equipmentmaintenance and handling of waste.Assessment MethodSee Section 3.Section 2 Operational conditions and risk management measuresSection 2.1 Control of worker exposureProduct characteristicsPhysical form of product LiquidVapour pressure (kPa) Liquid, vapour pressure
Heavy Fuel Oil Components(closed systems). + CS137Product sampling.CS502 Bulk closedunloading + OC9 OutdoorCS8 Drum/batch transfersCS 117 Operation of solidsfiltering equipmentor other system to avoid exposure E8. Avoid carrying out activitiesinvolving exposure for more than 1 hour OC27. Provide a good standardof controlled ventilation (10 to 15 air changes per hour) E40. Wearchemically resistant gloves (tested to EN374) in combination with ‘basic’employee training PPE16.Transfer via enclosed lines E52. Avoid carrying out activities involvingexposure for more than 4 hours OC28. Wear chemically resistant gloves(tested to EN374) in combination with ‘basic’ employee training PPE16.Ensure material transfers are under containment or extract ventilationE66. , or (G9): Provide a good standard of general ventilation (not lessthan 3 to 5 air changes per hour) E11.Avoid carrying out activities involving exposure for more than 1 hourOC27. Wear chemically resistant gloves (tested to EN374) in combinationwith ‘basic’ employee training PPE16.Provide a good standard of general ventilation (not less than 3 to 5 airchanges per hour) E11. Avoid carrying out activities involving exposurefor more than 4 hours OC28. Wear chemically resistant gloves (tested toEN374) in combination with ‘basic’ employee training PPE16.CS85 Bulk product storage. Store substance within a closed system E84. Provide a good standard ofgeneral ventilation (not less than 3 to 5 air changes per hour) E11. Avoidcarrying out activities involving exposure for more than 4 hours OC28.Wear chemically resistant gloves (tested to EN374) in combination with‘basic’ employee training PPE16.GEST_12I Use as a fuel.CS 107 (closed system)CS39 Equipment cleaningand maintenanceWear chemically resistant gloves (tested to EN374) in combination with‘basic’ employee training PPE16.Drain down and flush system prior to equipment break-in or maintenanceE55. Wear chemically resistant gloves (tested to EN374) in combinationwith specific activity training PPE17. Retain drain downs in sealed storagepending disposal or for subsequent recycle ENVT4.Additional information on the basis for the allocation of the identified OCs and RMMs iscontained in Appendices 2 to 3Section 2.2 Control of environmental exposureProduct characteristicsSubstance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a].Amounts usedFraction of <strong>EU</strong> tonnage used in region 0.1Regional use tonnage (tonnes/year) 1.1e7Fraction of Regional tonnage used locally1.4e-1Annual site tonnage (tonnes/year) 1.5e6Maximum daily site tonnage (kg/day) 5.0e6Frequency and duration of useContinuous release [FD2].Emission days (days/year) 300Environmental factors not influenced by risk managementLocal freshwater dilution factor 10Local marine water dilution factor 100Other given operational conditions affecting environmental exposureRelease fraction to air from process (initial release prior to RMM)7.0e-4Release fraction to wastewater from process (initial release prior to 4.4e-7RMM)Release fraction to soil from process (initial release prior to RMM) 0Technical conditions and measures at process level (source) to prevent releaseCommon practices vary across sites thus conservative process release estimates used [TCS1].Technical onsite conditions and measures to reduce or limit discharges, air emissions andreleases to soil2010-08-10 CSR 141
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Page 48 and 49: Heavy Fuel Oil Components10. RISK C
Page 50 and 51: Heavy Fuel Oil ComponentsREFERENCES
Page 52 and 53: Heavy Fuel Oil ComponentsStreet, Lo
Page 54 and 55: Heavy Fuel Oil ComponentsUT 84108,
Page 56 and 57: Heavy Fuel Oil ComponentsARCO (1992
Page 58 and 59: Heavy Fuel Oil ComponentsReport dat
Page 60 and 61: Heavy Fuel Oil ComponentsCONCAWE (2
Page 62 and 63: Heavy Fuel Oil ComponentsKachholz,
Page 64 and 65: Heavy Fuel Oil Componentsand Health
Page 66 and 67: Heavy Fuel Oil ComponentsCrude oil
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Page 70 and 71: Heavy Fuel Oil Components 7.15 Sta
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Page 76 and 77: Heavy Fuel Oil ComponentsAnthracene
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Page 82 and 83: Heavy Fuel Oil Components2010-08-10
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Industrial: SU3 SU8SU9 Ind
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ES5-W3 Professional: SU22
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Heavy Fuel Oil ComponentsExposures
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Heavy Fuel Oil Components2010-08-10
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Industrial: S
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Industrial: S
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ES5-W3 Professional:
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Heavy Fuel Oil Components concerne
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Heavy Fuel Oil ComponentsRCR Water,
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Executive SummaryIn order to comply
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1.0 IntroductionREACH requires that
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PolyAr = poly-aromatics consisting
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Figure 1. Half-life predictions for
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Figure 3. Half-life predictions for
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4-methyldodecane 13 12.2 3.3 6.72,6
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dimethylcyclohexanehexylcyclohexane
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Figure 8. BioHCwin (Y-axis) vs. exp
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Figure 10. BioHCwin (Y-axis) vs. ex
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Figure 19. Half-life predictions fo
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4.0 Bioaccumulation Assessment of P
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where POC and DOC are the particula
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10000100010010nP Dietary BCFnP Aque
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Hydrocarbon C BMFBCF(Arnot)DietaryB
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4.3 Mono-Naphthenic hydrocarbonsThe
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Figure 31. Experimentally derived f
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2-isopropyldecalin13 0.02 2694 3893
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Hydrocarbon C BMFBCFArnotDietaryBCF
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100001000100101MonoaromaticsBvB05 1
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4.7 Naphthenic Mono-AromaticsRegres
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carp. Bold blue entries represent B
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100001000100101DiArBvB05 10 15 20 2
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100000100001000DAH Dietary BCFDAH A
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hexahydropyrene4,5,9,10-tetrahydrop
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10000010000100010010PArBvB110 15 20
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Hydrocarbon C BMFArnotBCFDietaryBCF
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100001000100PAr Dietary BCFPAr Aque
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pyrene 0.17 0.74 0.62Table 21. Trop
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Hydrocarbon metabolites have been b
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2,6-dimethyldecane 11 10 No2,2,4,6,
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a -EMBSI 2009d; b -EMBSI 2009e; c -
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EMBSI (2001a). Fish, dietary bioacc
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EMBSI (2009n). CONCAWE Product Comp
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Yakata N, Sudo Y, Tadokoro H. (2006
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iP 9 2-Methyloctane CC(C)CCCCCCiP 9
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iP 17 3-Methylhexadecane CCCCCCCCCC
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MN 11 1-Methylbutylcyclohexane C1CC
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MN 21 n-Hexadecylcyclopentane CCCCC
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DN 13 2,4,5-Trimethyldecalin C1CC(C
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PN 14 Hydro-Phenanthrene C1CCC2CCC3
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MAr 6 Benzene c1ccccc1MAr 7 Toluene
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MAr 18 1-benzyl4,8dimethyldecane c1
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NMAr 17 n-Octylindan c1ccc2CC(CCCCC
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NMAr 25NMAr 25 isoheptyl-bicylohexy
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DAr 12 2,5-Dimethylnaphthalene Cc1c
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naphthaleneDAr 23 4-2,6dimethyldecy
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NDAr 20iso-Hexyltetrahydrophenanthr
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PAr 16 2,4-Dimethylanthracene Cc1cc
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PAr 21Methyl2-naphthyl-1-naphthalen
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PAr 24 iso-Butylperylene CC(C)Cc2cc
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Appendix 2. Description of BCF calc
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infinite number of structures inclu
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1.2.1.4. Acute aquatic toxicity mod
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method, the LLNA value was accepted
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ioaccumulative than the parent mole
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parent PAH (McCoy et al. 1979; Niko
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Name C# LogKow L(E)C50 Primary Bioa
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REFERENCESBondy GS, Armstrong CL, D
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Kachholz T, Rehm H. (1977). Degrada
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products in surface waters by rever
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CONTENTSSectionPage1 INTRODUCTION .
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1-1SECTION 11 INTRODUCTIONRefined p
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1-3ReferencesRedman A, Parkerton T,
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3-1SECTION 33 SUMMARY OF COMPOSITIO
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11-1SECTION 1111 SUMMARY OF COMPOSI
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