ABFIGURE 4 A. Schematic of a planar oriented aggregate of crystalline entities, as often found inbiaxially deformed films. B. Structure of a planar assembly of perfect, extended-chain polymercrystals. 432.1 Classical Lamination TheoryUniaxially oriented polymer foils, such as drawn tapes or even single-crystal layers,can typically be regarded as transversely isotropic materials, characterized by fiveindependent elastic constants, having a high stiffness in the longitudinal direction anda low isotropic modulus in the plane transverse to the longitudinal direction. The offaxisstiffness and strength of laminates from these foils is then described, respectively,by classical lamination theory, and anisotropic failure rules, such as the Tsai-Hillcriterion. 59In classical lamination theory, it is assumed that a laminate is in a plane stress state,reducing the number of relevant elastic constants for a single foil to four: thelongitudinal modulus, E l , the transverse modulus, E t , the shear modulus, G lt , and thePoisson’s ratio, υ lt . It can be shown through an appropriate coordinate transformationof the compliance tensor, that in uniaxial deformation, the off-axis Young’s modulus,E θ , of a single foil varies with θ, the angle between the loading direction and thelongitudinal axis as:E ⎛4⎛ E ⎞l2 2 E ⎞θ l 4= cos θ 2νltcos θsin θ sin θE ⎜+ ⎜ − ⎟+lGlt E ⎟⎝ ⎝ ⎠t ⎠−1(1)When the longitudinal and transverse modulus, E l and E t , and the Poisson’s ratio υ lt-18-
(often assumed to be equal to that of the isotropic material) are known, the shearmodulus, G lt , can be calculated from E 45 , the off-axis stiffness determined in a tensiletest at θ = 45 °, as:G ⎛ltEl E ⎞l= ⎜4 −( 1−2νlt ) − ⎟El⎝ E45Et⎠−1(2)Similarly, the anisotropic failure criterion of Tsai-Hill allows calculation of the offaxisstrength, σ θ , from the longitudinal, transverse and shear strength (respectively, σ l ,σ t , and τ lt ) as:( − )2 2 2⎛cos θ cos θ sin θ 4 2 2cos θ cos θ sin θ ⎞σθ= + +2 2 2⎜ σl σt τ ⎟⎝lt⎠Here, the shear strength,. τ lt , can be determined from the off-axis tensile strength, σ 10 ,−1(3)measured at an angle θ = 10 °, as: 60 10τlt= σ sin(10 ° )cos(10 ° )(4)The influence of the elastic constants on the anisotropic behavior of a single foil isdepicted in Figure 5. Obviously, the longitudinal and transverse modulus determine,respectively, the upper and lower limit of the foil stiffness. However, from Figure 5, itcan be seen that the off-axis stiffness of the foil strongly depends on the shearmodulus, G lt .-19-
- Page 3: Diss. ETH No. 17603Ultra-high-perfo
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TABLE 1 Young’s modulus, E, and t
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s12A-A0.50.1B-B17BAABs2BA13A-A0.1B-
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ABextruder20 mmFIGURE 4 A. Schemati
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and planar foils were tested in ten
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s11 3 10 33 120s2504540353013 1729
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f1-s11 2 4 913f2-s2A6560555045401 3
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4.4 Air-gap ExtrusionIn view of the
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A100B1001010W ratio / T ratio (-)10
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ABCDFIGURE 11 A. Photographs of as-
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A70B1.2601.0500.8E (GPa)40302010σ
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Finally, the mechanical characteris
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6 References and Notes1. Kwolek, S.
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1 IntroductionIt was already discus
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2 ExperimentalMaterials. The polyme
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3 Results and Discussion3.1 Foil Ex
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3.2 Heat TreatmentAs already demons
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Expectedly, the Young’s modulus o
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the experimentally observed angular
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5 References1. Aoki, H. ; Onogi, Y.
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1 IntroductionCellulose is the main
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2 ExperimentalMaterials. The nutrie
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A0.5 mmBCFIGURE 1 Bacterial cellulo
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Finally, the test-angle dependence
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5 References1. Meyer, K. H. ; Lotma
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1 ConclusionsThe results presented
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10,0001,000σ (MPa/(g/cm 3 ))100101
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1.4 Final ConclusionIn the literatu
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precursor fibers, which, however, a
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3 References1. Gordon, J. E. Proc.
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Group for great unforgettable teamw