Super Vulcaseal - Bostik Philippines Inc.

Material Safety Data SheetNotes to physicianMain symptomsTreatment5. FIRE FIGHTING MEASURESSkin rashes, alkali burns, and dry skin; eye irritation, respiratoryirritationTreat symptomatically.Fire & Explosion HazardsExtinguishing mediaSensitivity to mechanicalimpactSensitivity to static dischargeHazardous combustionproductsFire fightingequipment/instructionHighly flammable. Vapour may travel a considerable distance tosource of ignition and flash back. Avoid all ignition sources, openflames, pilot lights, furnaces, etc.In case of fire, use foam, dry chemicals/powder, carbon dioxide(CO2), or water spray.None knownElectrical equipment and switches producing sparks may causefire or explosion hazardCombustion of this product may produce toxic fumes.Heating can cause expansion or decomposition leading to violentrupture of containers. Remove containers from fire sources. Incase of exposure to decomposition, wear full protective clothingand self-contained breathing apparatus.6. ACCIDENTAL RELEASE MEASURESPersonal precautionsEnvironmental precautionsClean-up procedureWear personal protective equipment to avoid skin and eyecontact. Avoid inhalation of vapors, wear suitable face mask orbreathing apparatus.Do not allow material to contaminate ground water system. Donot flush into surface water or sewer systemRemove spill with clean rag or paper towel. In case of large spills,shut-off all possible sources of ignition, increase ventilation.Collect and seal in properly labeled containers for disposal.Clean contaminated equipments with suitable solventimmediately after use. Dispose of according to local regulations.7. HANDLING & STORAGEHandlingAvoid skin and eye contact and inhalation of vapors.StorageStore in a cool, dry, well ventilated areas away from directsunlight, and sources of heat and ignition.This material is classified as Dangerous Goods, Flammable, and must be stored and used accordingto relevant regulations8. EXPOSURE CONTROLS/PERSONAL PROTECTIONTWASTELCarcinogenMaterialNoticesppm mg/m3 ppm mg/m3 CategoryToluene 100 377 150 565 - -TWA- the time weighted average airborne concentration over an eight-hour working day, for a five dayworking week over an entire working lifeMSDS CODE: MSDS_SVSMSDSRevision #: 001 Revision Date: 01-JAN-2009 Page 2 of 4

Material Safety Data SheetSTEL (Short Term Exposure Limit)- the average airborne concentrationover a 15minute period which should not be exceeded at any time during a normal eight-hour work-dayThese exposure standards are guides to be used in the control f occupational health hazards. Allatmospheric contamination should be kept too as low a level as is workable. These exposurestandards should not be used as fine dividing lines between safe and dangerous concentrations ofchemicals. They are not measures of relative toxicity.If the directions for use on the product label are followed, exposure of individuals using the productshould not exceed above standard. The standard was created for workers who are routinely,potentially exposed during manufacture of product.Biological Limit Values: As per the “National Model Regulations for the Control of WorkplaceHazardous Substances [NOHSC:1005 (1994)]”, the ingredients in this material do not have a biologicalLimit Allocated.For detailed information see “Guidelines for Health Surveillance [NOHSC:7039(1995)]”Engineering Measures: Ensure ventilation is adequate to maintain air concentrations below ExposureStandards. Use only in well ventilated areas. Use with local exhaust ventilation or while wearing dustmasks. Keep Containers closed when not in use.Personal protection equipment: OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES,DUST MASK.Wear overalls, chemical goggles and impervious gloves. Use only under adequate ventilation. In caseof inhalation risks, wear organic vapour/particulate respirator. Available information suggests thatgloves made from nitrile rubber should be suitable for intermittent contact. However, due to variationsin glove construction and local conditions, the user should make a final assessment. Always washhands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and otherprotective equipment before storing or re-using.9. PHYSICAL AND CHEMICAL PROPERTIESAppearanceFormThick pasteColourGrey/ Beige/ Green/ RedOdoraromatic solventWater SolubilityInsolubleViscosity650,000- 1,200,000 cpsSpecific Gravity 1.10 + 0.01Flash Point 10ºC10. STABILITY AND REACTIVITYStabilityConditions to avoidMaterials to avoidThermal decompositionHazardous reactionsStable under recommended storage conditionsElevated temperature and sources of ignitionOxidizing agentsThis product is thermally stable. Decomposition may produceoxides of carbon and nitrogen, smoke and other toxic fumes.Data not established11. TOXICOLOGICAL INFORMATIONToxicological dataInhalationThis product may cause irritation to mucous membranes andMSDS CODE: MSDS_SVSMSDSRevision #: 001 Revision Date: 01-JAN-2009 Page 3 of 4

Material Safety Data SheetSkin contactEye ContactIngestionLong term effectsAcute toxicity/ Chronic toxicityrespiratory tract, dizziness, headaches and nausea. Inhalation ofhigh concentration may cause central nervous systemdepression, leading to loss of coordination and impairedjudgment. Prolonged exposure may cause unconsciousnessIrritant to skin; Prolonged or repeated skin contact may causeallergic contact dermatitisVapor may cause eye irritationSwallowing can result to nausea, vomiting, and irritation to thegastrointestinal tract. May cause lung damage if swallowed.No information availableNo LD50 Data available for the product. HoweverTolueneOral LD50 (rat): 636 mg/kgDermal LD50 (rabbit): 14,100 uL/kg12. ECOLOGICAL INFORMATIONEcotoxicological InformationToluene:Toxic to aquatic organisms. Avoid contaminating waterways.13. DISPOSAL CONSIDERATIONWaste disposalWaste materials should be disposed of according to state andlocal regulations.14. TRANSPORT INFORMATIONProper Shipping NameTransport Labels RequiredPackaging/ ContainerSealant containing Flammable LiquidsFlammable MaterialTin containers15. REGULATORY INFORMATIONClassificationOSHA: Hazardous by definition of Hazard CommunicationStandardFlammable Liquid16. OTHER INFORMATIONDisclaimerInformation in this MSDS has been compiled based from publiclyavailable sources. Materials herein may present unknownhazards and caution concerning use of this product must beobserved. Bostik Phils., Inc. makes no warranty about theaccuracy of the data herein and assumes no liability for the useof such data. It is the responsibility of the user to comply with allapplicable state and local laws and regulations.MSDS CODE: MSDS_SVSMSDSRevision #: 001 Revision Date: 01-JAN-2009 Page 4 of 4