U-09Fl Resin MSDS - On-Hand Adhesives, Inc.

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HENKEL LOCTITE CORPORATION 1001 TROUT BROOK CROSSING 06/09/03ROCKY HILL, CONNECTICUT 06067EMERGENCY PHONE: (860) 571-5100MATERIAL SAFETY DATA SHEET Page 02 of 08Product Name:Loctite(R) Hysol(R) U-09FL Urethane Adhesive ResinItem No.: 293703. HAZARDS IDENTIFICATION (continued)reversable. Chemical or hypersensitive pneumonitiswith flu-like symptoms (e.g., fever, chills) hasalso been reported.Chronic inhalation: As a result of previousrepeated overexposures or a single large dosecertain individuals develop isocyanatesensitization (chemical asthma) which will causethem to react to a later exposure to isocyanate atlevels well below the TLV. These symptoms, whichcan include chest tightness, wheezing, cough,shortness of breath or asthma attack, could beimmediate or delayed (up to several hours afterexposure). Similar to many non-specific asthmaticresponses, there are reports that once sensitizedan individual can experience these symptoms uponexposure to dust, cold air, or other irritants.This increased lung sensitivity can persist forweeks and in severe cases for several years.Overexposure to isocyanates has also been reportedto cause lung damage (including decrease in lungfunction) which may be permanent. Sensitizationcan either be temporary or permanent.Acute skin contact: Dicyclohexylmethane-4,4'-diisocyanate is a primary skin irritant. Itreacts with protein and moisture and can causeirritation. Symptoms of skin irritation include:redness, swelling, rash, scaling and blistering.Dicyclohexylmethane-4,4'-diisocyanate is also apotent sensitizer. Experience indicates thatdirect contact is the route of exposure mostlikely to cause sensitization. Once sensitized,an individual may react even to airborne levelsbelow the TLV with the following symptoms:itching and tingling or the earlobes and neck,rash, hives, swelling of the arms and legs orother symptoms common to allergic dermatitis.These symptoms may be immediate or delayed.Chronic skin contact: Prolonged contact can causereddening, swelling, rash, scaling, blistering andin some cases, skin sensitization. Individuals whohave skin sensitization can develop these symptomsfrom contact with liquid or vapor. Animal testshave indicated that respiratory sensitization canresult from skin contact with dicyclohexylmethane-4,4'-diisocyanate.
HENKEL LOCTITE CORPORATION 1001 TROUT BROOK CROSSING 06/09/03ROCKY HILL, CONNECTICUT 06067EMERGENCY PHONE: (860) 571-5100MATERIAL SAFETY DATA SHEET Page 03 of 08Product Name:Loctite(R) Hysol(R) U-09FL Urethane Adhesive ResinItem No.: 293703. HAZARDS IDENTIFICATION (continued)Acute eye contact: Liquid, vapors and mist areirritating and can cause tearing, reddening andswelling of the eyes possibly accompanied bystinging sensation.Primary Routes of Entry:Signs and Symptomsof Exposure:Existing ConditionsAggravated by Exposure:Acute ingestion: Irritation and corrosive actioncan occur in the mouth, stomach tissue anddigestive tract. Symptoms can include sore throat,abdominal pain, nausea, vomiting and diarrhea.Skin contact, inhalation of vapors and mist,eye contact.Eye, skin, and respiratory irritation. Allergicskin or respiratory reaction.Asthma, other respiratory disorders ( bronchitis,emphysema, bronchial hyperreactivity), skinallergies, eczema.Literature ReferencedCarcinogenIngredients Target Organ and Other Health Effects NTP IARC OSHAPolyurethane prepolymer No Data NO NO NODicyclohexylmethane-4,4'-diisocyanate ALG IRR RES NO NO NO-------------------------------------------------------------------------------AbbreviationsALG AllergenRES RespiratoryIRR Irritant4. FIRST AID MEASURESIngestion:Inhalation:Skin Contact:Do not induce vomiting. Give one to two cups ofmilk or water to drink. Do not give anything bymouth to an unconscious person. Consult aphysician.Move to an area free from risk of further exposureAdminister oxygen or artificial respiration asneeded. Obtain medical attention. Asthmatic-typesymptoms may develop and may be immediate ordelayed up to several hours. Consult a physician.Remove contaminated clothing. Wash affected skinthoroughly with soap and water. Wash contaminatedclothing thoroughly before reuse. For severeexposures, get under safety shower after removing
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U-09Fl Resin MSDS - On-Hand Adhesives, Inc.

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