CAMD_2015_Annual_Report
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Centre for Advanced Macromolecular Design<br />
<strong>2015</strong> <strong>Annual</strong> <strong>Report</strong><br />
Never Stand Still<br />
Centre for Advanced Macromolecular Design
Mission Statement<br />
The Centre for Advanced Macromolecular<br />
Design (<strong>CAMD</strong>) is a research centre in the<br />
School of Chemical Engineering at the<br />
University of New South Wales that is<br />
dedicated to the synthesis and application of<br />
polymers/polymeric nano-objects using a wide<br />
range of modern polymerization techniques.<br />
A significant portion of <strong>CAMD</strong>’s activities are<br />
directed towards general and specific<br />
applications in the areas of advanced materials,<br />
as well as polymers for energy, sustainability<br />
and health/bio applications.
Objectives<br />
To continue to be recognised as a world leader<br />
in macromolecular chemistry and employ<br />
macromolecular science to address problems in<br />
the areas of advanced materials, energy,<br />
sustainability and human health<br />
To further the fundamental understanding of<br />
polymerization processes for the optimization<br />
of synthetic polymer protocols<br />
To produce high quality research leading to<br />
publications in high impact journals<br />
To attract and train outstanding PhD students<br />
To provide a work environment that encourages<br />
high quality research<br />
To attract high quality industry partners and<br />
help solve important problems<br />
To work at the interface of nanotechnology and<br />
polymer science
Steering<br />
Committee<br />
Prof Mark Hoffman (Presiding Dean)<br />
Dean of Engineering<br />
Prof Martina Stenzel (co-Director)<br />
School of Chemistry<br />
Prof Per Zetterlund (co-Director)<br />
School of Chemical Engineering<br />
Prof Scott Kable<br />
School of Chemistry (HoS)<br />
Prof Vicki Chen<br />
School of Chemical Engineering (HoS)<br />
Prof Peter Steinberg<br />
School of Biological, Earth &<br />
Environmental Sciences<br />
Centre for Marine Bio-Innovation<br />
Sydney Institute of Marine Science<br />
(Director)<br />
Prof Peter Lovibond<br />
Senior Associate Dean (Faculty of<br />
Science)<br />
Mr Eh Hau Pan (Laboratory Manager)<br />
School of Chemical Engineering
Directors<br />
<strong>Report</strong><br />
The Centre for Advanced<br />
Macromolecular Design (<strong>CAMD</strong>)<br />
focuses on the synthesis of polymers<br />
for advanced applications. This broad<br />
research field encompasses the<br />
development of new polymerization<br />
techniques to create<br />
polymers/polymeric nano-objects for<br />
applications mainly in the areas of<br />
advanced materials, health and<br />
energy/environment.<br />
The year <strong>2015</strong> was another successful<br />
year for <strong>CAMD</strong> in terms of research<br />
output. The centre has been highly<br />
productive, publishing 56 papers or<br />
book chapters in leading international<br />
journals, including high impact<br />
publications such as papers in<br />
Chemical Reviews and JACS. <strong>CAMD</strong><br />
also hosted numerous visitors<br />
throughout the year, including several<br />
internationally renowned researchers<br />
who gave presentations as part of the<br />
<strong>CAMD</strong> lecture program. Strong<br />
international links are also reflected in<br />
a range of publications with<br />
collaborators from around the world.<br />
<strong>CAMD</strong> researchers were active in<br />
attending conferences and giving<br />
seminars, including a one day<br />
workshop entitled Polymer Research<br />
in NWS Symposium organized by<br />
<strong>CAMD</strong> researchers at UNSW in<br />
November <strong>2015</strong>.<br />
The year 2014 witnessed significant<br />
change in terms of personnel. Dr<br />
Stuart Thickett took up a position at<br />
the University of Tasmania. Dr Peter<br />
Roth left <strong>CAMD</strong> for a position at the<br />
University of Surrey in the UK. Our<br />
longstanding Centre Manager, Dr<br />
Istvan Jacenyik, accepted a position at<br />
Macquarie University. We thank them<br />
for their hard work at <strong>CAMD</strong> and wish<br />
all of them well in their future<br />
endeavours. Several new staff also<br />
joined <strong>CAMD</strong> – Dr Damia Mawad was<br />
appointed Lecturer at the School of<br />
Materials Science and Engineering<br />
(Faculty of Science) at UNSW, and<br />
joined <strong>CAMD</strong> shortly thereafter. Her<br />
research is mainly concerned with<br />
polymeric biomaterials applied in<br />
tissue engineering and drug delivery.<br />
Dr Robert Chapman arrived at <strong>CAMD</strong><br />
as a Vice Chancellor’s Postdoctoral<br />
Research Fellow to work mainly on the<br />
development of macromolecular<br />
therapeutics able to control cell<br />
behaviour through clustering of cell<br />
receptor proteins.<br />
In closing, we would like to thank all<br />
the members of <strong>CAMD</strong> for their hard<br />
work, and we also gratefully<br />
acknowledge the ongoing support<br />
from the School of Chemical<br />
Engineering and the School of<br />
Chemistry.<br />
Prof Martina Stenzel<br />
Prof Per Zetterlund<br />
Directors
Centre for Advanced<br />
Macromolecular Design<br />
Staff
Professor Martina Stenzel<br />
Dr.rer.nat.(PhD) (1999)<br />
Polymer Chemistry<br />
University of Stuttgart, Germany<br />
Martina Stenzel studied chemistry at<br />
the University of Bayreuth, Germany,<br />
before completing her PhD in 1999 at<br />
the Institute of Applied<br />
Macromolecular Chemistry, University<br />
of Stuttgart, Germany. She then<br />
moved to UNSW, Australia, as a<br />
postdoctoral fellow, sponsored by<br />
DAAD and was later employed as<br />
lecturer at UNSW. She is now a full<br />
Professor and Co-director of the<br />
Centre for Advanced Macromolecular<br />
Design (<strong>CAMD</strong>), a UNSW research<br />
Centre dedicated to the synthesis and<br />
application of polymers.<br />
Her research interest is focused on the<br />
synthesis of functional polymers with<br />
complex architectures such as<br />
glycopolymers and other polymers for<br />
biomedical applications, especially<br />
polymers with in-built metal<br />
complexes for the delivery of<br />
metal-based anti-cancer drugs.<br />
The aim is to create nanoparticles for<br />
the treatment of cancer. One focal<br />
point is the formation of hybrid<br />
materials from biopolymers such as<br />
polysaccharides and proteins with<br />
synthetic polymers. Martina has<br />
published more than 200 peer<br />
reviewed papers, mainly on RAFT<br />
polymerization and biomedical<br />
applications. Martina currently serves<br />
on eight editorial advisory boards in<br />
the area of polymer science and<br />
biomaterials and is a scientific editor of<br />
RSC Materials Horizons.<br />
She is a member of the ARC College of<br />
experts and a member of the national<br />
committee for chemistry of the<br />
Australian Academy of Science.<br />
Martina has received several awards<br />
for her work including the 2011 Le<br />
Fèvre Memorial Prize and the 2013<br />
NSW Science and Engineering award -<br />
Excellence in Engineering.
Professor Per Zetterlund<br />
PhD 1998<br />
Polymer Chemistry<br />
University of Leeds, UK<br />
Per Zetterlund graduated from The<br />
Royal Institute of Technology in<br />
Stockholm (Sweden) in 1994, obtained<br />
his Ph.D. at Leeds University (UK) in<br />
1998, and subsequently conducted<br />
postdoctoral research at Griffith<br />
University (Brisbane, Australia).<br />
In 1999, he became Assistant<br />
Professor at Osaka City University<br />
(Japan) in the group of Prof. Yamada,<br />
and moved to Kobe University (Japan)<br />
in 2003 to join the team of Prof.<br />
Okubo, where he was promoted to<br />
Associate Prof in 2005. Since 2009,<br />
he is working at The Centre for<br />
Advanced Macromolecular Design<br />
(<strong>CAMD</strong>) at The University of New<br />
South Wales (Sydney, Australia),<br />
where he is currently full Professor<br />
and co-Director of the Centre.<br />
hybrid polymeric materials with a<br />
variety of applications ranging from<br />
materials science to nanomedicine.<br />
Important aspects of his research<br />
include the use of environmentally<br />
friendly carbon dioxide in polymer<br />
(nanoparticle) synthesis, as well as<br />
experimental/theoretical studies of<br />
polymerization in nanoreactors. He<br />
has to date published ~150<br />
peer-reviewed papers, and currently<br />
serves on the editorial boards of the<br />
journals Macromolecular Theory and<br />
Simulations and Polymer Chemistry.<br />
Prof Zetterlund’s research is concerned<br />
with the synthesis of polymer,<br />
polymeric nanoparticles, as well as
Associate Professor Cyrille Boyer<br />
PhD (2006)<br />
Polymer Chemistry<br />
University of Montpellier II, France<br />
Cyrille Boyer received his PhD in<br />
polymer chemistry from the University<br />
of Montpellier II in 2006. In 2010, he<br />
was appointed as a lecturer and he<br />
received an Australian Research<br />
Council Fellow (APD-ARC). In 2012,<br />
Cyrille was promoted Senior Lecturer<br />
at the School of Chemical Engineering<br />
and he was awarded an Australian<br />
Research Council Future Fellowship.<br />
cover the preparation of hybrid<br />
organic-inorganic nanoparticles for<br />
imaging & drug delivery and the use<br />
of photoinduced living polymerization<br />
(photopolymerization).<br />
Cyrille serves on the editorial boards of<br />
Polymer Chemistry and European<br />
Polymer Journal.<br />
He received several awards, including<br />
the Scopus Young Researcher of the<br />
Year Award 2012, UNSW Research<br />
Excellence Award and was listed as<br />
finalist of NSW innovation award in<br />
2014. In 2013, Cyrille was promoted to<br />
Associate Professor.<br />
Cyrille has published over 135 research<br />
articles, 19 conference papers, 5<br />
granted patents and 2 provisional<br />
patents, which have garnered over<br />
5200 citations (his H-index is 43).<br />
Cyrille’s research interests mainly
Associate Professor Frank Lucien<br />
PhD (1997)<br />
Chemical Engineering, UNSW<br />
Frank Lucien received his PhD in<br />
Chemical Engineering in 1997 from<br />
the University of New South Wales.<br />
His doctoral research was concerned<br />
with solubility enhancement of solids<br />
in supercritical CO 2 .<br />
polymeric nanoparticles (with Prof. Per<br />
Zetterlund). He has published over 80<br />
scientific papers, including 4 book<br />
chapters and 1 patent.<br />
He carried out postdoctoral research at<br />
F. Hoffmann-La Roche (Basel,<br />
Switzerland) and continued work on<br />
high pressure processes involving CO 2 .<br />
He was appointed as a lecturer in the<br />
School of Chemical Engineering &<br />
Industrial Chemistry at UNSW in<br />
1997.<br />
His early work involved the use of<br />
CO 2 -expanded liquids as reaction<br />
media, focusing on catalytic<br />
hydrogenation and catalytic chain<br />
transfer polymerization. He was<br />
promoted to A/Prof. in 2009 and is<br />
currently conducting research on<br />
radical polymerization in CO 2 -induced<br />
emulsions for the synthesis of
Dr Anthony Granville - Lecturer<br />
PhD (2004)<br />
Polymer Chemistry<br />
University of Akron, USA<br />
Anthony Granville graduated from<br />
Stevens Institute of Technology (New<br />
Jersey, USA) with a degree in<br />
chemistry before going on to the<br />
University of Akron (Ohio, USA) and<br />
completing his PhD in polymer<br />
chemistry.<br />
Upon completing postdoctoral work in<br />
<strong>CAMD</strong>, he was appointed as an<br />
Academic Fellow to the School of<br />
Chemical Engineering at UNSW<br />
before being converted to a full-time<br />
lecturer at the school.<br />
their capabilities as osteoblast<br />
promoters, and new surface<br />
polymerisations from these constructs<br />
using UV irradiation.<br />
Tony is secretary of the RACI NSW<br />
POLY group as well as on several<br />
academic boards at UNSW.<br />
Tony’s current research interests deals<br />
with the investigating novel synthetic<br />
molecules capable of undergoing the<br />
mussel-inspired self-polymerisation<br />
process as well as their applications to<br />
health, water purification, and energy.<br />
This work has led to investigations into<br />
the radiolabelling of nanocapsules of<br />
these materials (in the form of an<br />
AINSE grant at ANSTO), investigating
Dr Peter Roth - Research Fellow<br />
PhD (2009)<br />
Chemistry<br />
University of Mainz, Germany<br />
Peter Roth studied chemistry at the<br />
University of Mainz (Germany), the<br />
University of Massachusetts (USA),<br />
and Seoul National University (South<br />
Korea), obtaining his PhD in 2009 in<br />
the group of Patrick Theato (Mainz).<br />
His PhD work focused on the end<br />
group modification of RAFT-made<br />
(co)polymers using activated esters<br />
and functional thiosulfonates.<br />
After obtaining a pre-diploma in<br />
Psychology in 2010 from the<br />
University of Mainz, he did<br />
postdoctoral research at the University<br />
of New South Wales, Sydney, working<br />
with Profs Tom Davis and Andrew<br />
Lowe on the self-assembly of<br />
homopolymers into vesicles from<br />
2010–2012.<br />
His group’s research focused on novel<br />
smart materials responding to<br />
(multiple) external stimuli such as<br />
temperature (including rare aqueous<br />
UCST systems), presence of specific<br />
chemical analytes, pH, and mechanical<br />
agitation; the use and development of<br />
efficient post-polymerization<br />
modification reactions; and the use of<br />
multicomponent reactions in the<br />
design and preparation of novel<br />
multifunctional materials.<br />
He received an ARC DECRA on the<br />
development of novel stimulus<br />
responsive polymers in 2012 and was<br />
promoted to Research Fellow in 2013.
Dr Stuart Thickett - Research Fellow<br />
PhD (2008)<br />
Chemistry<br />
University of Sydney<br />
Stuart Thickett received his BSc (Hons)<br />
from The University of Sydney in<br />
2004 and completed his PhD with<br />
Professor Robert Gilbert at The<br />
University of Sydney in 2008.<br />
He has since held post-doctoral<br />
positions at The University of Toronto,<br />
Canada (with Professor Mitchell<br />
Winnik) and The University of Sydney<br />
(with Associate Professor Chiara Neto).<br />
He is interested in the underlying<br />
kinetic and mechanistic phenomena<br />
that govern such systems, with the<br />
goal of using this knowledge to create<br />
new materials with specific properties<br />
and attributes.<br />
In 2012 he was awarded a<br />
Vice-Chancellor's Post-Doctoral<br />
Fellowship to join the School of<br />
Chemical Engineering at UNSW. His<br />
work focuses on the physical<br />
chemistry of soft matter, specifically<br />
polymers, colloids, nanoparticles and<br />
thin films.
Dr Pu Xiao - Research Fellow<br />
PhD (2009)<br />
Polymer Chemistry and Physics<br />
Wuhan University, China<br />
Dr. Pu Xiao obtained his Bachelor’s<br />
degree (2004) in Chemistry and PhD<br />
(2009) in Polymer at Wuhan<br />
University (China).<br />
He started his academic career as a<br />
Scientific Associate at the University of<br />
Applied Sciences and Arts<br />
Northwestern Switzerland (FHNW,<br />
Switzerland) from 2009. In 2012, he<br />
moved to the Institute of Materials<br />
Science of Mulhouse (IS2M, CNRS,<br />
France) and worked as a Post-doctoral<br />
Fellow.<br />
nanodiamond/polymer hybrid<br />
nanomarials as drug delivery systems).<br />
He has published >65 peer-reviewed<br />
papers, most of which are concerned<br />
with novel photoinitiating systems of<br />
polymerization.<br />
Since 2014, he has been working as a<br />
Research Fellow (ARC DECRA) in Prof<br />
Stenzel’s group at <strong>CAMD</strong> at UNSW.<br />
His research interests are focused on<br />
the fabrication of polymeric materials<br />
in a green environment such as mild<br />
visible light and nanomaterials for<br />
environmental or biomedical<br />
applications (e.g.
Dr Hongxu Lu - DECRA research<br />
fellow<br />
PhD (2009)<br />
Biomaterials<br />
University of Tsukuba, Japan<br />
Hongxu Lu obtained his BSc and MSc<br />
degrees from Ocean University of<br />
China in 1998 and 2006,<br />
respectively. He completed his PhD in<br />
Materials Science and Engineering<br />
(Biomaterials) in 2009 from the joint<br />
PhD program of University of Tsukuba<br />
and National Institute for Materials<br />
Science of Japan (NIMS). From 2009<br />
to 2012, he worked as a postdoc<br />
researcher in the same lab of his PhD<br />
study at NIMS under the supervision<br />
of Prof. Guoping Chen.<br />
medicine and investigation of<br />
cell-biomaterials interactions. Dr. Lu<br />
was awarded with the Young<br />
Investigator Award from Japanese<br />
Society for Regenerative Medicine<br />
(Japan, 2012) and the Young Scientist<br />
Award from International Symposium<br />
of Materials on Regenerative<br />
Medicine (Taiwan, 2010). He has<br />
published more than 50 peer reviewed<br />
journal papers with more than 600<br />
citations. His current H-index is 13.<br />
Since 2012, he has been working at<br />
UNSW mentored by Prof. Martina<br />
Stenzel. In <strong>2015</strong>, Dr. Hongxu Lu was<br />
awarded an ARC DECRA Research<br />
Fellowship. His research focuses on the<br />
development of nano drug carriers and<br />
novel 2D and 3D cellular models for<br />
the evaluation of nano drug carriers.<br />
He is also interested in the<br />
development of 3D scaffolds for tissue<br />
engineering and regenerative
Dr Damia Mawad<br />
Lecturer<br />
PhD (2007)<br />
Biomedical Engineering<br />
University of New South Wales<br />
Australia<br />
Damia Mawad received her PhD in<br />
Biomedical Engineering in 2007 from<br />
University of New South Wales. She<br />
started her academic career as a<br />
post-doctoral fellow in University of<br />
Lyon, France. From 2008 to 2012,<br />
she was a Research Fellow at the<br />
Intelligent Polymer Research Institute<br />
(IPRI), University of Wollongong. She<br />
was then awarded IN 2013 a Marie<br />
Curie International Incoming<br />
Fellowship hosted by Imperial College<br />
London, UK. In August <strong>2015</strong>, she has<br />
been appointed a lecturer at the<br />
School of Materials Science and<br />
Engineering, UNSW.<br />
Her research interests are in polymeric<br />
biomaterials applied in tissue<br />
engineering and drug delivery. One of<br />
her main investigations is<br />
development of electroactive and<br />
conductive scaffolds for biomedical<br />
applications with emphasis on the<br />
material chemistry and design<br />
strategies that transition from a<br />
monomer to a polymer to 3D<br />
construct. Examples include conductive<br />
porous hydrogels that induce cell<br />
attachment, proliferation and<br />
differentiation and conductive<br />
bioadhesives with micropatterned<br />
surfaces for cell alignment and<br />
photoadhesion to tissue. Recent<br />
research interests include control of<br />
the conduction anisotropy in<br />
conjugated polymers to better match<br />
the hierarchical organization and<br />
sophisticated architectures found in<br />
biological tissues.
Dr Robert Chapman<br />
Vice-Chancellor research fellow<br />
PhD (2013)<br />
Chemistry<br />
University of Sydney<br />
Australia<br />
Robert Chapman completed a BE<br />
(Hons I) in Industrial Chemistry at<br />
UNSW in 2007 and a PhD in<br />
Chemistry at the University of Sydney<br />
in 2013, where he studied the<br />
synthesis and self-assembly of cyclic<br />
peptide - polymer conjugates under<br />
Prof. Sebastien Perrier. He<br />
subsequently worked as a research<br />
associate in the lab of Prof. Molly<br />
Stevens at Imperial College London<br />
(2013-15) on the development of<br />
nanomaterial based biosensors for<br />
diagnosis of disease at point of care,<br />
and on polymer scaffolds for tissue<br />
engineering. In 2016 he returned to<br />
UNSW as a Vice Chancellor’s<br />
Postdoctoral Research Fellow.<br />
Robert’s research focuses on the<br />
development of macromolecular<br />
therapeutics able to control cell<br />
behaviour through clustering of cell<br />
receptor proteins. Through the<br />
development of combinatorial<br />
approaches to polymer synthesis he is<br />
investigating the effect that polymer<br />
architecture and rigidity has on<br />
biological activity.
Dr Istvan Jacenyik - Centre Manager<br />
DPharm (2009)<br />
Semmelweis University, Hungary<br />
Eh Hau Pan - Technical Officer<br />
BE - Industrial Chemistry (2006)<br />
UNSW<br />
Research Associates:<br />
Dr Florent Jasinski<br />
Dr ChangKui Fu<br />
Dr Antoine Tardy<br />
Dr Jiangtao Xu<br />
Postgraduates:<br />
Nik Nik Mohd Adnan<br />
Sri Agustina<br />
Rhiannon Batchelor<br />
Kash Bhullar<br />
Teddy Chang<br />
Fan Chen (Charles)<br />
Nathaniel Corrigan<br />
Alice Du<br />
Ka Wai Fan<br />
Noor Hadzuin Nik Hadzir (Awin)<br />
Fumi Ishizuka<br />
Yanyan Jiang<br />
Kenward Jung<br />
Yee Yee Khine<br />
Haiwang Lai<br />
Mingxia Lu (Mia)<br />
Russul Mamdooh<br />
Diep Nguyen<br />
Thuy Khanh Nguyen<br />
Janina Miriam Noy<br />
Susan Oliver<br />
Alberto Piloni<br />
Narasinga Rao Hanumanth Rao<br />
Sivaprakash Shanmugam (Siva)<br />
Jiaying Su (Amanda)<br />
Victoria Teo<br />
Haiqiao Wang<br />
Chin Ken Wong (Ken)<br />
Jonathan Yeow<br />
Yujian Zhai<br />
Jiacheng Zhao<br />
New PhD Students (<strong>2015</strong>)<br />
Nathaniel Corrigan<br />
Yee Yee Khine<br />
Haiwang Lai<br />
Russul Mamdooh<br />
Janina Miriam Noy<br />
Susan Oliver<br />
Alberto Piloni<br />
Haiqiao Wang
PhD Completions:<br />
Yan Jin (Joey)<br />
Surface Modification of Optical Fibers<br />
and Waveguides for Creating<br />
Localized Surface Plasmon Resonance<br />
Biosensors (Dr Anthony Granville)<br />
Siming Dong (Sam)<br />
Radical Polymerizations in Dispersed<br />
Systems (Prof Per Zetterlund)<br />
Yicheng Zhu (Mike)<br />
Thermoresponsive Polymers with<br />
Aqueous LCST and/or UCST through<br />
Postpolymerization Modification<br />
(Dr Peter Roth)<br />
Visitors:<br />
Bandit Thong-On<br />
Neomy Zaquen<br />
Kilian Wuest<br />
Ann-Katrin Friedrich<br />
Jonas Kolsch<br />
Timos Hees<br />
Masayoshi Tokuda<br />
Dr Kazuaki Taguchi<br />
A/Prof. Jianbo Qu
Collaborators<br />
UNSW<br />
Prof Rose Amal (Chemical<br />
Engineering)<br />
Prof Robert Burford (Chemical<br />
Engineering)<br />
Dr Nicolas Barraud (BABS)<br />
Dr Rita Henderson (Water Research)<br />
Prof Naresh Kumar (Chemistry)<br />
Dr Megan Lord (GSBmE)<br />
Dr Penny Martens (GSBmE)<br />
Prof David Morris (St George Hospital)<br />
Dr Yun Hau Ng (Chemical Engineering)<br />
Prof Laura Poole-Warren (GSBmE)<br />
Dr Robert Taylor (Mech & Man Eng)<br />
Dr Renee Whan (Biomedical Imaging)<br />
Prof John Whitelock (GSBmE)<br />
A/Prof Jia-Lin Yang (Prince of Wales)<br />
Prof Melissa Knothe-Tate (Biomedical<br />
Engineering)<br />
Domestic<br />
Prof Paul de Souza (Ingham Institute)<br />
A/Prof Brian Hawkett (University of<br />
Sydney)<br />
Dr Kristopher Thurecht (UQ)<br />
Prof Gunther Andersson (Flinders<br />
University)<br />
International<br />
Dr Fawaz Aldabbagh (Ireland, Galway)<br />
Prof Christopher Barner-Kowollik (KIT,<br />
Germany)<br />
Prof Laurent Billon (Pau, France)<br />
Prof B. Boutevin (Montpellier II,<br />
France)<br />
Prof Jerome Claverie (Montréal,<br />
Canada)<br />
Dr Ghislain David (Montpellier II,<br />
France)<br />
Prof Filip Du Prez (Ghent, Belgium)<br />
Prof Laurent Fontaine (Mans, France)<br />
Prof David Haddleton (Warwick, UK)<br />
A/Prof Atsushi Kajiwara (Nara Uni.,<br />
Japan)<br />
Dr Sophie Laurent (Mons, Belgium)<br />
Prof H.-U. Moritz, (Hamburg,<br />
Germany)<br />
Prof Rachel O’Reilly (Warwick, UK)<br />
A/Prof Nicolay Tsarevsky (Sthn<br />
Methodist, USA)<br />
Prof Philipp Vana (Göttingen,<br />
Germany)<br />
Prof Tanja Weil (Ulm, Germany)<br />
A/ Prof Hideto Minami (Kobe, Japan)<br />
Prof Sebastien Perrier (Warwick, UK)<br />
Dr Michael Gottschalt (Jena, Germany)<br />
Prof Stephan Förster (Bayreuth,<br />
Germany)<br />
A/ Prof Emily Pentzer (Case Western<br />
Reserve University, USA)<br />
A/Prof Lacey McNally (University of<br />
Louisville)<br />
Prof Jingquan Liu (Qiandao University,<br />
China)<br />
Prof. Lei Tao (Tsinghua University,<br />
China)<br />
Dr Simon Harrisson (Universite´ Paul<br />
Sabatier Toulouse, France)<br />
Industrial<br />
Henkel (Ireland)<br />
Nubian Water Systems (Australia)<br />
Nuplex Industries (Australia)<br />
Novogen (Australia)
Polymer Sunthesis
Polymer<br />
Synthesis<br />
<strong>CAMD</strong> continues to make significant<br />
contributions in advanced polymer<br />
synthesis. Most efforts are centred on<br />
RAFT polymerization, a controlled/living<br />
radical polymerization technique<br />
investigated to great length at <strong>CAMD</strong> over<br />
the last decade. Current research aims<br />
both at improving the scope of RAFT as<br />
method and at exploiting its inherent<br />
advantages for state-of the art design of<br />
advanced macromolecules. Whereas<br />
conventional RAFT polymerization is<br />
sensitive to oxygen impurity and may not<br />
be controlled through external stimuli, a<br />
recent development of photoinduced<br />
RAFT polymerization eliminates these<br />
shortcomings while offering<br />
polymerization control over conjugated<br />
and unconjugated monomers. This<br />
method employs trace amounts of a<br />
photoredox catalyst which allows<br />
polymerizations to be reversibly stopped<br />
and continued by way of a visible light<br />
trigger. Taking advantage of the controlled<br />
nature of RAFT polymerization and its<br />
ability to produce well-defined A-B<br />
diblock copolymers, well-defined<br />
nanoparticles can be produced in onestep<br />
RAFT dispersion polymerisation. In this<br />
technique, a soluble macro-RAFT agent is<br />
used to polymerize a second monomer in<br />
a selective solvent that causes<br />
self-assembly of the growing second block<br />
giving access to distinct morphologies<br />
depending on recipe and reaction time.<br />
Recent research at <strong>CAMD</strong> has widened<br />
the scope of this technique, successfully<br />
applying it to a variety of functional<br />
monomers which has allowed, for<br />
example, simple preparation of gold<br />
nanoparticle-functional microparticles.<br />
nanoreactors may be exploited in tandem<br />
with template polymerization has led to a<br />
biomimetic approach based on template<br />
polymerization involving nucleobase<br />
containing vinyl monomers in a<br />
segregated environment achieved via<br />
self-assembly of template diblock<br />
copolymers. A further synthetic technique<br />
applied and progressed at <strong>CAMD</strong> is<br />
postpolymerization modification, the<br />
chemical transformation of reactive,<br />
pre-made (co)polymers. This method takes<br />
advantage of the high compatibility of the<br />
RAFT process with functional chemical<br />
groups. Using a variety of reactive<br />
precursors, we can introduce virtually any<br />
chemical functional group into a<br />
polymeric material, including groups that<br />
may not be compatible with the<br />
polymerization procedure. This gives<br />
access to a very wide range of functional<br />
materials with tuneable properties— see<br />
also Advanced Materials section.<br />
Control over polymer microstructure is<br />
also being explored at the fundamental<br />
level using the combined approach of (i)<br />
biomimetic template radical<br />
polymerization and (ii) polymerization in<br />
nanoreactors in the form of<br />
submicron-sized micelles or droplets. The<br />
realization that the concept of
Advanced Materials
Advanced<br />
Materials<br />
A number of projects deal with synthesis<br />
of advanced materials, e.g. stimulus<br />
responsive, “smart” polymers and<br />
nanocomposite materials. “Smart”<br />
polymers exhibit drastic changes of their<br />
physical properties in response to external<br />
stimuli such as temperature, light, certain<br />
gases, mechanical agitation, pH changes<br />
and specific chemical substances, and<br />
these materials offer great potential for<br />
applications in separation science, sensing<br />
and detection, and microfluidics. At<br />
<strong>CAMD</strong>, we aim to develop novel smart<br />
polymers, understand and improve their<br />
behaviour. Another area of research is<br />
surface modification of polymeric optical<br />
fibres for chemo- and biosensor<br />
technology, which involves generation of<br />
gold coated surfaces as a platform for<br />
various polymerisation and surface<br />
binding techniques.<br />
The material graphene was discovered in<br />
2004 (Noble Prize awarded in 2010) – it<br />
is the strongest material ever measured,<br />
and this is accompanied by a range of<br />
other extraordinary physical properties<br />
such as high thermal conductivity and<br />
high electrical conductivity. Graphene is<br />
seen as the material of the future, with the<br />
potential to revolutionize a wide range of<br />
industries from electronics to healthcare,<br />
and there is currently immense worldwide<br />
research activity in this area. At <strong>CAMD</strong>,<br />
we are interested in preparing novel<br />
polymeric nanocomposite materials with<br />
superior physical properties using<br />
graphene and graphene oxide.<br />
polymers, and do not form homogeneous<br />
polymer composites. We specifically<br />
address these issues by employing various<br />
techniques involving (controlled/living)<br />
radical polymerization in aqueous<br />
dispersed systems for synthesis of<br />
polymer/graphene nanocomposite<br />
materials. The key in our approach is to<br />
exploit the amphiphilic properties of<br />
graphene oxide – it can behave as a<br />
surfactant in aqueous emulsions of oil<br />
(vinyl monomer) under suitable conditions.<br />
We thus conduct various types of<br />
dispersed phase polymerizations<br />
(emulsion, miniemulsion) using graphene<br />
oxide as surfactant, thereby accessing a<br />
novel route to graphene/polymer<br />
nanocomposite materials.<br />
Fig. 2. TEM image and schematic illustration<br />
of hollow polymeric nanoparticle coated with<br />
graphene oxide nanosheets.<br />
The addition of graphene as a component<br />
of polymer nanocomposites results in<br />
superior material properties over the more<br />
common fillers such as carbon black. In<br />
order to fulfil the potential of such<br />
nanocomposites, a high degree of<br />
dispersion of graphene as individual<br />
two-dimensional sheets in the polymer<br />
matrix is essential. However, both pristine<br />
graphene and graphene oxide are<br />
incompatible with most hydrophobic
Energy &<br />
Environment
Energy &<br />
Environment<br />
A number of active research themes are<br />
focused on energy/environment, including<br />
projects as diverse as development of<br />
environmentally friendly aqueous<br />
coatings, micropatterned surfaces or the<br />
efficient collection of water directly from<br />
the atmosphere, hybrid inorganic/organic<br />
nanomaterials for hydrogen storage,<br />
synthesis of various types of emulsions<br />
using carbon dioxide, and environmentally<br />
friendly synthesis of polybenzimidazoles<br />
for use in the in the energy storage and<br />
transfer realms.<br />
Hydrogen could be the ultimate energy<br />
carrier enabling energy security and<br />
global sustainability in this 21st century. In<br />
the sun, hydrogen releases the energy<br />
that sustains life on Earth, while hydrogen<br />
bonded to carbon provides us with the<br />
so-called fossil fuels that have powered<br />
our industrial revolution. Unfortunately, a<br />
heavy reliance on finite resources and the<br />
adverse effects of fossil fuels on global<br />
climate are now threatening further<br />
development. In its purest form hydrogen<br />
has high energy content, and therefore<br />
hydrogen has naturally emerged as the<br />
only possible synthetic energy carrier with<br />
sufficient versatility to replace oil.<br />
However, the effective storage of<br />
hydrogen in a compact manner remains<br />
the central difficulty for its widespread<br />
use. Efforts over the last decades have<br />
targeted a range of materials capable of<br />
storing hydrogen with high density in the<br />
form of a hydride, e.g. MgH2, but the<br />
realization of successful strategies to<br />
control and balance competitive<br />
thermodynamics/kinetics requirements<br />
for the effective storage of hydrogen<br />
remains unanswered. The aim of this<br />
project is to develop a method for the<br />
facile production of MgH2 nanoparticles<br />
and their assembly into a tertiary<br />
structure providing remarkable stability to<br />
the magnesium nanoparticles against<br />
agglomeration and sintering.<br />
Fig. 3. Self-assembly of magnesium<br />
nanoparticles in polymer structures and<br />
SEM/TEM micrograph showing the self<br />
assembly in fibre structure<br />
Mussels and other bivalves excrete a<br />
natural polymeric adhesive shown to be<br />
water insoluble, tough, and nontoxic. This<br />
material can be synthetically<br />
manufactured using dopamine as the<br />
monomeric material in a rather simple,<br />
weakly basic, aqueous solution. The<br />
dopamine compound will cyclise to form<br />
an indole intermediate before crosslinking<br />
to form the desired polymer. When a<br />
substrate is immersed in the aqueous<br />
solutions system, the polydopamine will<br />
form a homogeneous coating on the<br />
substrate surface. This paves the way for<br />
simple, benign coatings of a controlled<br />
thickness to be used for drug delivery,<br />
surface modification, and metal binding<br />
for electronic applications. The<br />
universality of this approach is being<br />
investigated with a focus on<br />
polybenzimidazoles, which are renowned<br />
for their high temperature properties as<br />
well as their ability to be used as proton<br />
exchange membranes when doped with<br />
acids.
Polymers<br />
for Health
Polymers<br />
for Health<br />
The area of biomedical engineering has a<br />
strong need for new polymers to be able<br />
to finetune the interface between<br />
synthetic materials and the biological<br />
environment. RAFT (reversible<br />
addition-fragmentation chain transfer)<br />
polymerization is an excellent tool to<br />
address this need.<br />
Polymers can be synthesized to suit<br />
different applications and <strong>CAMD</strong><br />
researchers are active in the area of<br />
synthesis of nanoparticles for drug<br />
delivery to grafting of polymers from<br />
various surfaces to adjust their<br />
biocompatibility. In particular the area of<br />
drug delivery and imaging of<br />
nanoparticles is one of the main themes at<br />
<strong>CAMD</strong>. Self-assembled aggregates such<br />
as micelles, rod-like micelles and vesicles<br />
are proposed as drug carriers due to their<br />
hydrophobic interior, while size and shape<br />
is easily controlled by the underlying<br />
polymer. The nature of the block<br />
copolymer can be adjusted to solve a<br />
range of drug delivery problems. This<br />
includes traditional anti-cancer drugs, but<br />
also other, more challenging bioactive<br />
molecules such as DNA, heparin, peptides<br />
and metal-based drugs. The central<br />
questions are how can we design suitable<br />
polymers to encapsulate the drug and<br />
how does the polymer affect the<br />
properties of the nanoparticle?<br />
Next to self-assembled block copolymers<br />
<strong>CAMD</strong> researchers are focussing on<br />
coating of inorganic nanoparticles such as<br />
gold nanoparticles or nanodiamonds to<br />
generate drug carriers that have added<br />
features such as they can be imaged or<br />
they can be used in hypothermia. On the<br />
quest for suitable drug delivery carriers for<br />
various drugs we developed a synthetic<br />
tool kit to achieve the best possible<br />
cellular uptake. We are interested in<br />
stabilizing the micelles by crosslinking,<br />
which often leads to better cell uptake. In<br />
addition, by replacing the more tradition<br />
PEG shell of micelles by other polymers<br />
such as polymers with a zwitterionic<br />
structure, we can create drug carriers that<br />
are not only nontoxic, but also show very<br />
high uptake efficiency.<br />
<strong>CAMD</strong> researchers are inspired by<br />
Nature’s building blocks such as sugars,<br />
proteins and polysaccharides. Synthetic<br />
routes are developed to create drug<br />
carriers that combine the tailored<br />
properties of synthetic polymers with the<br />
bioactivity of natural products. Drug<br />
carriers coated with albumin or sugars<br />
show high bioactivity, while at the same<br />
time the synthesis of these carriers can be<br />
very simple.<br />
In vitro<br />
In vivo<br />
Fig. 4. Preparation of self-assembled<br />
core-shell nanoparticles for the delivery of<br />
drugs into cancer cells, and the subsequent<br />
study of the movement of these nanoparticles<br />
in multicellular cancer models and in vivo.
Research<br />
Grants <strong>2015</strong><br />
•MREII grant for FT-IR system, $110,894<br />
(Granville/Zetterlund/Stenzel/Boyer/Luci<br />
en)<br />
•Emerging anode materials for li-s<br />
batteries - ba14017, Gentle, Ian; Wang,<br />
Da-wei; Aguez-Zinsou, Kondo-Francois;<br />
Boyer, Cyrille. (BAOSTEEL-AUSTRALIA<br />
Joint research & development centre<br />
shared grant); $250,000<br />
•Beamtime application at Australian<br />
Synchrotron, including travel grant<br />
(Zetterlund)<br />
•Internal equipment grant from Chem Eng<br />
to purchase new GPC system (about 60k)<br />
– (Boyer)<br />
•Expanding quartz crystal microbalance<br />
(QCM) capabilities for solid-liquid<br />
interfaces ($5.6 K) (Granville)
Publications<br />
in <strong>2015</strong><br />
pH-, thermo- and electrolyte-responsive polymer<br />
gels derived from a well-defined,<br />
RAFT-synthesized, poly<br />
(2-vinyl-4,4-dimethylazlactone) homopolymer via<br />
one-pot post-polymerization modification<br />
European Polymer Journal (<strong>2015</strong>), 62, 204–213<br />
Y. Pei, O. R. Sugita, J. Y. Quek, P. J. Roth, A. B. Lowe<br />
Nanoparticles Based on Star Polymers as<br />
Theranostic Vectors: Endosomal-Triggered Drug<br />
Release Combined with MRI Sensitivity<br />
Advanced Healthcare Materials (<strong>2015</strong>), 4, 148–156<br />
Y. Li, H. T. T. Duong, S. Laurent, A. MacMillan, R. M.<br />
Whan, L. Vander Elst, R. N. Muller, J. Hu, A. Lowe ,<br />
C. Boyer, T. P. Davis<br />
Simultaneous ROMP and Titania Sol-Gel<br />
Reactions and a New Approach to Nanodispersed<br />
Organic/Inorganic Hybrid Materials<br />
Journal of Materials Chemistry C (<strong>2015</strong>), 3,<br />
693–702. J. A. van Hensbergen, M. Liu, R. P.<br />
Burford, A. B. Lowe<br />
Thiol-reactive Functional Poly(meth)acrylates:<br />
Multicomponent Monomer Synthesis, RAFT<br />
(Co)polymerization and Highly Efficient<br />
Thiol–para-Fluoro Postpolymerization<br />
Modification<br />
Polymer Chemistry (<strong>2015</strong>), 6, 436–447<br />
J.-M. Noy, M. Koldevitz, P. J. Roth<br />
RAFT Dispersion Polymerization in Nonpolar<br />
Media: Polymerization of 3 Phenylpropyl<br />
Methacrylate in n Tetradecane with Poly(stearyl<br />
methacrylate) Homopolymers as Macro Chain<br />
Transfer Agents<br />
Macromolecules (<strong>2015</strong>), 18 (1), 236-244<br />
Y. Pei, L. Thurairajah, O. R. Sugita, A. B. Lowe<br />
Graphene Oxide (GO) Nanosheets as Oil-in-Water<br />
Emulsion Stabilizers: Influence of Oil Phase<br />
Polarity<br />
Journal of Colloid and Interface Science (<strong>2015</strong>),<br />
442, 67–74<br />
S. C. Thickett, P. B. Zetterlund<br />
Multicomponent Isocyanide-based Synthesis of<br />
Reactive Styrenic and (Meth)acrylic Monomers<br />
and their RAFT (Co)polymerization<br />
Polymer Chemistry (<strong>2015</strong>) ,6, 44-54<br />
S. Schmidt, M. Koldevitz, J.-M. Noy, P. J. Roth<br />
ROMP Synthesis of Novel Thermo, pH and Salt<br />
Responsive (Co)Polymers Containing the<br />
Morpholino Functional Group<br />
Journal of Polymer Science, Part A: Polymer<br />
Chemistry (<strong>2015</strong>), 53, 50-58<br />
J. A. van Hensbergen, S. Ganda, P. J. Roth, R. P.<br />
Burford, A. B. Lowe<br />
RAFT-prepared α-Difunctional<br />
Poly(2-vinyl-4,4-dimethylazlactone)s and their<br />
Derivatives: Synthesis and Effect of End Groups on<br />
Inverse Aqueous Temperature Solubility<br />
Polymer Chemistry (<strong>2015</strong>) ,6, 118-127<br />
J. Y. Quek, X. Liu, T. P. Davis, P. J. Roth, A. B. Lowe<br />
Surface modification of polydopamine coated<br />
particles via glycopolymer brush synthesis for<br />
protein binding and FLIM testing<br />
Polymer Chemistry (<strong>2015</strong>) ,6, 2504–2511<br />
S. P. Le-Masurier, H. T. T. Duong, C. Boyer, A. M.<br />
Granville<br />
Biocompatible Glycopolymer Nanocapsules via<br />
Inverse Miniemulsion Periphery RAFT<br />
Polymerization for the Delivery of Gemcitabine<br />
Biomacromolecules (<strong>2015</strong>), 16 (7), 2144–2156<br />
R. H. Utama, Y. Jiang, P. B. Zetterlund, M. H. Stenzel<br />
RAFT Polymerization in Supercritical Carbon<br />
Dioxide Based on an Induced Precipitation<br />
Approach: Synthesis of 2-Ethoxyethyl<br />
methacrylate/Acrylamide Block Copolymers<br />
Journal of Polymer Science, Part A: Polymer<br />
Chemistry (<strong>2015</strong>), 53, 2351–2356<br />
G. Hawkins, P. B. Zetterlund, F. Aldabbagh<br />
An Innovative Approach to Implementation of<br />
Organotellurium-Mediated Radical Polymerization<br />
(TERP) in Emulsion Polymerization<br />
Macromolecules (<strong>2015</strong>), 48 (13), 4312–4318<br />
Y. Sugihara, S. Yamago, P. B. Zetterlund<br />
Polymerization Induced Self-Assembly: Tuning of<br />
Nano-Object Morphology by Use of CO2<br />
Polymer Chemistry (<strong>2015</strong>), 6, 2249 - 2254<br />
S. Dong, W. Zhao, F. P. Lucien, S. Perrier, and P. B.<br />
Zetterlund<br />
Factors Influencing the Preparation of Hollow<br />
Polymer-Graphene Oxide Nanocapsules via<br />
Pickering Miniemulsion Polymerization<br />
Polymer (<strong>2015</strong>), 63, 1-9<br />
G. H. Teo, Y. H. Ng, P. B. Zetterlund, S. C. Thickett<br />
Online SAXS Analysis of Shell Formation during<br />
Nanocapsule Synthesis via Inverse Miniemulsion<br />
Periphery RAFT Polymerization (IMEPP)<br />
Macromolecular Rapid Communications (<strong>2015</strong>), 36,<br />
1267-1271. R. H. Utama, M. Dulle, S. Förster, M. H.<br />
Stenzel, P. B. Zetterlund<br />
Controlled/Living Radical Polymerization in<br />
Dispersed Systems: An Update<br />
Chemical Reviews (<strong>2015</strong>), 115 (18),9745-9800<br />
Per B. Zetterlund, Stuart C. Thickett, Sébastien<br />
Perrier, Elodie Bourgeat-Lami, Muriel Lansalot
Publications<br />
in <strong>2015</strong><br />
Synthesis of Crosslinked Polymeric Nanocapsules<br />
using Catanionic Vesicle Templates Stabilized by<br />
Compressed CO2<br />
Soft Matter (<strong>2015</strong>), 11, 8613-8620<br />
S. Dong, P. T. Spicer, F. P. Lucien, P. B. Zetterlund<br />
Visible-Light-Regulated Controlled/Living Radical<br />
Polymerization in Miniemulsion<br />
ACS Macro Letters (<strong>2015</strong>), 4 (10), 1139–1143,<br />
K. Jung, J. Xu, P. B. Zetterlund, C. Boyer<br />
Surface Modification of Polydivinylbenzene<br />
Microspheres with a Fluorinated Glycopolymer<br />
using Thiol-Halogen Click Chemistry<br />
Macro-Glycoligands – Methods and Protocols<br />
(<strong>2015</strong>), Chapter 10, 123-135<br />
Song, Wentao; Granville, Anthony M<br />
Copolymerization of an indazole ligand into the<br />
self-polymerization of dopamine for enhanced<br />
binding with metal ions<br />
Journal of Materials Chemistry B (<strong>2015</strong>), 3, 7457 –<br />
7465. Fan, Ka Wai; Roberts, Justine J.; Martens,<br />
Penny J.; Stenzel, Martina H.; Granville, Anthony M<br />
RAFT Inverse Miniemulsion Periphery<br />
Polymerization in Binary Solvent Mixtures for<br />
Synthesis of Nanocapsules<br />
European Polymer Journal (<strong>2015</strong>), 73, 324-334<br />
F. Ishizuka, R. H. Utama, S. Kim, M. H. Stenzel, and<br />
P. B. Zetterlund<br />
Micropatterned Surfaces for Atmospheric Water<br />
Condensation via Controlled Radical<br />
Polymerization and Thin Film Dewetting<br />
ACS Applied Materials and Interfaces (<strong>2015</strong>), 7<br />
(38), 21562–21570. Ian Wong,Guo Hui Teo, Chiara<br />
Neto, and Stuart C. Thickett<br />
Macromolecular and Inorganic Nanomaterials<br />
Scaffolds for Carbon Monoxide Delivery: Recent<br />
Developments and Future Trends<br />
ACS Biomaterials Science and Engineering (<strong>2015</strong>), 1<br />
(10), 895–913. Nguyen, Diep; Boyer, Cyrille<br />
Polymerization-Induced Self-Assembly Using<br />
Visible Light Mediated Photoinduced Electron<br />
Transfer-Reversible Addition-Fragmentation Chain<br />
Transfer Polymerization<br />
ACS Macro Letters (<strong>2015</strong>), 4(9), 984-990<br />
Yeow, Jonathan; Xu, Jiangtao; Boyer, Cyrille<br />
Organic Electron Donor-Acceptor Photoredox<br />
Catalysts: Enhanced Catalytic Efficiency toward<br />
Controlled Radical Polymerization<br />
ACS Macro Letters (<strong>2015</strong>), 4(9), 926-932.<br />
Xu, Jiangtao; Shanmugam, Sivaprakash; Boyer,<br />
Cyrille<br />
CO-Releasing Polymers Exert Antimicrobial<br />
Activity<br />
Biomacromolecules (<strong>2015</strong>), 16(9), 2776-2786.<br />
Nguyen, Diep; Nguyen, Thuy-Khanh; Rice, Scott A.;<br />
Boyer, Cyrille<br />
Stereo-, Temporal and Chemical Control through<br />
Photoactivation of Living Radical Polymerization:<br />
Synthesis of Block and Gradient Copolymers<br />
Journal of the American Chemical Society (<strong>2015</strong>),<br />
137(31), 9988-9999.<br />
Shanmugam, Sivaprakash; Boyer, Cyrille<br />
Exploiting Metalloporphyrins for Selective Living<br />
Radical Polymerization Tunable over Visible<br />
Wavelengths<br />
Journal of the American Chemical Society (<strong>2015</strong>),<br />
137(28), 9174-9185. Shanmugam, Sivaprakash; Xu,<br />
Jiangtao; Boyer, Cyrille<br />
Multi-responsive polymers<br />
European Polymer Journal (<strong>2015</strong>), 69, 438-440<br />
Boyer, Cyrille; Hoogenboom, Richard<br />
Inhalable curcumin formulations: Micronization<br />
and bioassay<br />
Chemical Engineering Journal (<strong>2015</strong>), 279,<br />
799-808. Kurniawansyah, Firman; Duong, Hien T.<br />
T.; Luu, Thai Danh; Mammucari, Raffaella; Vittorio,<br />
Orazio; Boyer, Cyrille; Foster, Neil.<br />
Catalyst-free visible light-induced RAFT<br />
photopolymerization<br />
ACS Symposium Series (<strong>2015</strong>), volume 1187,<br />
chapter13, 247-267. Xu, Jiangtao; Shanmugam,<br />
Sivaprakash; Corrigan, Nathaniel Alan; Boyer,<br />
Cyrille<br />
Visible Light Photocatalytic Thiol-Ene Reaction: An<br />
Elegant Approach for Fast Polymer<br />
Postfunctionalization and Step-Growth<br />
Polymerization<br />
Macromolecules (<strong>2015</strong>), 48(3), 520-529<br />
Xu, Jiangtao; Boyer, Cyrille<br />
The use of nanoparticles to deliver nitric oxide to<br />
hepatic stellate cells for treating liver fibrosis and<br />
portal hypertension<br />
Small <strong>2015</strong>, 11(19), 2291-2304<br />
Duong, Hien T. T.; Dong, Zhixia; Su, Lin; Boyer,<br />
Cyrille; George, Jacob; Davis, Thomas P.; Wang,<br />
Jianhua
Publications<br />
in <strong>2015</strong><br />
Nanoparticles Based on Star Polymers as<br />
Theranostic Vectors: Endosomal-Triggered Drug<br />
Release Combined with MRI Sensitivity<br />
Advanced Healthcare Materials (<strong>2015</strong>), 4(1),<br />
148-156. Li, Yang; Duong, Hien T. T.; Laurent,<br />
Sophie; MacMillan, Alexandre; Whan, Renee<br />
Megan; Vander Elst, Luce; Muller, Robert N.; Hu,<br />
Jinming; Lowe, Andrew; Boyer, Cyrille<br />
Utilizing the electron transfer mechanism of<br />
chlorophyll a under light for controlled radical<br />
polymerization<br />
Chemical Science (<strong>2015</strong>), 6(2), 1341-1349.<br />
Shanmugam, Sivaprakash; Xu, Jiangtao; Boyer,<br />
Cyrille<br />
Organo- photocatalysts for photoinduced electron<br />
transfer-reversible addition-fragmentation chain<br />
transfer (PET-RAFT) polymerization<br />
Polymer Chemistry (<strong>2015</strong>), 6(31), 5615-5624<br />
Xu, Jiangtao; Shanmugam, Sivaprakash; Duong,<br />
Hien T.; Boyer, Cyrille<br />
Carbohydrate-Specific Uptake of Fucosylated<br />
Polymeric Micelles by Different Cancer Cell Lines<br />
Biomacromolecules (<strong>2015</strong>), 16 (7), 1948-1957.<br />
K. Babiuch, A. Dag, J. Zhao, H. Lu, M. H. Stenzel<br />
Incorporating ruthenium into advanced drug<br />
delivery carriers-an innovative generation of<br />
chemotherapeutics<br />
Journal of Chemical Technology and Biotechnology<br />
(<strong>2015</strong>), 90, 1177-1195.<br />
B. M. Blunden, M. H. Stenzel<br />
Correlation between Molecular Weight and Branch<br />
Structure of Glycopolymers Stars and Their<br />
Binding to Lectins<br />
Macromolecules (<strong>2015</strong>), 48, 346-357.<br />
Y. Chen, M. S. Lord, A. Piloni, M. H. Stenzel<br />
Polymer-Albumin Conjugate for the Facilitated<br />
Delivery of Macromolecular Platinum Drugs<br />
Macromolecule Rapid Communications (<strong>2015</strong>),<br />
36(10), 890-897<br />
A. Dag, Y. Jiang, K. J. Abd Karim, G. Hart-Smith, W.<br />
Scarano, M. H. Stenzel<br />
Controlling the morphology of glyco-nanoparticles<br />
in water using block copolymer mixtures: the effect<br />
on cellular uptake<br />
Polymer Chemistry (<strong>2015</strong>), 6, 7812-7820<br />
A. Dag, H. Lu, M. H. Stenzel<br />
Origami with ABC Triblock Terpolymers Based on<br />
Glycopolymers: Creation of Virus-Like<br />
Morphologies<br />
ACS Macro Letters (<strong>2015</strong>), 4, 579-583<br />
A. Dag, J. Zhao, M. H. Stenzel<br />
Core-Cross-Linking Accelerates Antitumor<br />
Activities of Paclitaxel-Conjugate Micelles to<br />
Prostate Multicellular Tumor Spheroids: A<br />
Comparison of 2D and 3D Models<br />
Biomacromolecules (<strong>2015</strong>), 16, 1470-1479<br />
A. W. Du, H. Lu, M. H. Stenzel<br />
In Vivo Evaluation of Folate Decorated<br />
Cross-Linked Micelles for the Delivery of Platinum<br />
Anticancer Drugs<br />
Biomacromolecules (<strong>2015</strong>), 16, 515-523.<br />
J. Eliezar, W. Scarano, N. R. B. Boase, K. J. Thurecht,<br />
M. H. Stenzel<br />
An Oligonucleotide Transfection Vector Based on<br />
HSA and PDMAEMA Conjugation: Effect of<br />
Polymer Molecular Weight on Cell Proliferation<br />
and on Multicellular Tumor Spheroids<br />
Macromolecule Bioscience (<strong>2015</strong>), 15, 965-978.<br />
Y. Jiang, C. K. Wong, M. H. Stenzel<br />
Dual-Responsive pH and Temperature Sensitive<br />
Nanoparticles Based on Methacrylic Acid and<br />
Di(ethylene glycol) Methyl Ether Methacrylate for<br />
the Triggered Release of Drugs<br />
Macromolecule Bioscience (<strong>2015</strong>), 15, 1091-1104<br />
Y. Y. Khine, Y. Jiang, A. Dag, H. Lu, M. H. Stenzel<br />
Enhanced transcellular penetration and drug<br />
delivery by crosslinked polymeric micelles into<br />
pancreatic multicellular tumor spheroids<br />
Biomaterial Science (<strong>2015</strong>), 3, 1085-1095<br />
H. Lu, R. H. Utama, U. Kitiyotsawat, K. Babiuch, Y.<br />
Jiang, M. H. Stenzel<br />
Albumin nanoparticles increase the anticancer<br />
efficacy of albendazole in ovarian cancer xenograft<br />
model<br />
Journal of Nanobiotechnology (<strong>2015</strong>), 13-25<br />
L. Noorani, M. Stenzel, R. Liang, M. H.<br />
Pourgholami, D. L. Morris<br />
Glycopolymer Self-Assemblies with Gold(I)<br />
Cornplexed to the Core as a Delivery System for<br />
Auranofin<br />
Macromolecules (<strong>2015</strong>), 48, 1065-1076<br />
S. Pearson, H. Lu, M. H. Stenzel<br />
Light-responsive azobenzene-based glycopolymer<br />
micelles for targeted drug delivery to melanoma<br />
cells<br />
European Polymer Journal (<strong>2015</strong>), 69, 616-627.<br />
S. Pearson, D. Vitucci, Y. Y. Khine, A. Dag, H. Lu, M.<br />
Save, L. Billon, M. H. Stenzel
Publications<br />
in <strong>2015</strong><br />
Dual-drug delivery of curcumin and platinum drugs<br />
in polymeric micelles enhances the synergistic<br />
effects: a double act for the treatment of<br />
multidrug-resistant cancer<br />
Biomaterials Science (<strong>2015</strong>), 3, 163-174.<br />
W. Scarano, P. de Souza, M. H. Stenzel<br />
N-Vinylcarbazole as Versatile Photoinaddimer of<br />
Photopolymerization under Household UV LED<br />
Bulb (392 nm)<br />
Macromolecular Rapid Communications (<strong>2015</strong>), 36,<br />
1675-1680. P. Xiao, J. Lalevee, J. Zhao, M. H.<br />
Stenzel<br />
A new role of curcumin: as a multicolor<br />
photoinitiator for polymer fabrication under<br />
household UV to red LED bulbs<br />
Polymer Chemistry (<strong>2015</strong>), 6, 5053-5061.<br />
J. Zhao, J. Lalevee, H. Lu, R. MacQueen, S. H. Kable,<br />
T. W. Schmidt, M. H. Stenzel, P. Xiao<br />
Prepared from Thermoresponsive Fluorescent<br />
Protein-Polymer Bioconjugates: Capture of and<br />
<strong>Report</strong> on Drug and Protein Payloads<br />
Angewandte Chemie International Edition (<strong>2015</strong>),<br />
54, 5317-5322. C. K. Wong, A. J. Laos, A. H.<br />
Soeriyadi, J. Wiedenmann, P. M. G. Curmi, J. J.<br />
Gooding, C. P. Marquis, M. H. Stenzel, P. Thordarson<br />
Iron oxide nanoparticle-mediated hyperthermia<br />
stimulates dispersal in bacterial biofilms and<br />
enhances antibiotic efficacy<br />
Nature scientific reports (<strong>2015</strong>), 5, Article number:<br />
18385. T.-K. Nguyen, H. TT Duong, R.<br />
Selvanayagam, C. Boyer, N. Barraud
Highlights, Awards<br />
& Other Activities<br />
Awards:<br />
Cyrille Boyer; <strong>2015</strong> Malcolm McIntosh<br />
Prize for Physical Scientist of the Year -<br />
one of the six Prime Minister's Science<br />
Prizes.<br />
Cyrille Boyer; Australian academy of<br />
Science prize - Le Fèvre prize<br />
Siva Shanmugam; Pacifichem <strong>2015</strong> poster<br />
competition winner<br />
Yanyan Jiang; RACI Polymer Division<br />
O’Donnell award<br />
<strong>CAMD</strong> seminar series:<br />
Prof. Dr. Robert Luxenhofer, University of<br />
Wuerzburg, Germany<br />
Prof. Dr. Philipp Vana,<br />
Georg-August-University Göttingen,<br />
Germany<br />
Dr. James Oliver, Colorado School of<br />
Mines, USA<br />
High impact papers:<br />
Utilizing the electron transfer mechanism<br />
of chlorophyll a under light for controlled<br />
radical polymerization<br />
Chemical Science (<strong>2015</strong>), 6(2), 1341-1349.<br />
Shanmugam, Sivaprakash; Xu, Jiangtao;<br />
Boyer, Cyrille<br />
Controlled/Living Radical Polymerization<br />
in Dispersed Systems: An Update<br />
Chemical Reviews, <strong>2015</strong>,115 (18),<br />
9745-9800<br />
Per B. Zetterlund, Stuart C. Thickett,<br />
Sébastien Perrier, Elodie Bourgeat-Lami,<br />
Muriel Lansalot<br />
Exploiting Metalloporphyrins for<br />
Selective Living Radical Polymerization<br />
Tunable over Visible Wavelengths<br />
Journal of the American Chemical Society<br />
(<strong>2015</strong>), 137(28), 9174-9185<br />
Shanmugam, Sivaprakash; Xu, Jiangtao;<br />
Boyer, Cyrille<br />
Stereo-, Temporal and Chemical Control<br />
through Photoactivation of Living Radical<br />
Polymerization: Synthesis of Block and<br />
Gradient Copolymers<br />
Journal of the American Chemical Society<br />
(<strong>2015</strong>), 137(31), 9988-9999.<br />
Shanmugam, Sivaprakash; Boyer, Cyrille
Highlights, Awards<br />
& Other Activities<br />
Recognition and Services:<br />
Cyrille Boyer selected as one of the 100<br />
Innovators by Knowledge of Nation<br />
Per Zetterlund appearing as Expert<br />
Witness (topic: coatings) in hearing in<br />
Melbourne in April<br />
Cyrille Boyer nominated as High-end<br />
Foreign Experts by Chinese Government<br />
and invited professorship in China at<br />
Qingdao University, Shandong, China<br />
Cyrille Boyer - invited professorship in<br />
France (Ecole Nationale Superieur de<br />
Chimie de Montpellier, University of<br />
Montpellier)<br />
Editorial Publications:<br />
Cyrille Boyer - Guest editor role: Special<br />
issue on Stimuli Responsive Polymers<br />
published by European Polymer Journal<br />
Cyrille Boyer - Associate Editor for RSC<br />
Advanced since August <strong>2015</strong><br />
Martina Stenzel - Associate editor for<br />
Beilstein Journal of Nanotechnology<br />
Martina Stenzel - Publication committee<br />
of Materials Research Society<br />
Per Zetterlund co-organizing symposium<br />
entitled “Radical Polymerization Kinetics<br />
and Process Modelling” at Pacifichem in<br />
Dec 15 (Hawaii)<br />
Per Zetterlund / Anthony Granville – 1<br />
day Polymer Research in NSW<br />
symposium (UNSW)<br />
Martina Stenzel - Short film on UNSW<br />
TV<br />
Martina Stenzel - Postgraduate<br />
coordinator in the school of chemistry
Highlights, Awards<br />
& Other Activities<br />
Invited keynote presentations:<br />
Cyrille Boyer; invited by Chinese<br />
Government as International Expert in<br />
<strong>2015</strong> (Lecture tour in China - Fudan,<br />
Shanghai Univeristy, Qiangdao University,<br />
Shanghai Jiao Tong, Beijing Institute of<br />
Technology, Beijing University of Chemical<br />
Technology, Soochow University)<br />
Martina Stenzel; Polymer Pacific<br />
Conference, 8th to 12th December <strong>2015</strong>,<br />
Hawaii, US<br />
Seminars by <strong>CAMD</strong> researchers:<br />
Per Zetterlund; Kobe University (Japan)<br />
Per Zetterlund; Osaka City University<br />
(Japan)<br />
Cyrille Boyer; invited lectures at Polymer<br />
Advanced Technology <strong>2015</strong> (June <strong>2015</strong>,<br />
Hangzhou, China)<br />
Cyrille Boyer; invited lectures at American<br />
Chemical Society National Conference in<br />
<strong>2015</strong><br />
Cyrille Boyer; invited lecture at PACIFIC<br />
CHEM in <strong>2015</strong> (Hawaii, USA)<br />
Cyrille Boyer; invited lecture at Fusion<br />
conference in <strong>2015</strong> (Ascott, UK)<br />
Cyrille Boyer; invited lecture at<br />
APNGM15, Sept <strong>2015</strong>, Budapest, Hungry<br />
Martina Stenzel; invited lectures at<br />
Congress of European Polymer Federation<br />
(June <strong>2015</strong>, Dresden, Germany)<br />
Martina Stenzel; invited lectures at<br />
Functional Polymeric Materials, August<br />
<strong>2015</strong>, (August <strong>2015</strong>, Ascot, UK )<br />
Martina Stenzel; invited lectures at ACS<br />
meeting Polymers in Medicine<br />
(September <strong>2015</strong>, US)<br />
Martina Stenzel; invited lectures at<br />
NanoDDS (September <strong>2015</strong>, US)<br />
Martina Stenzel; 24th <strong>Annual</strong> Meeting of<br />
the Australian Society of Biomaterials and<br />
Tissue Engineering, 7 - 10 April <strong>2015</strong>,<br />
Sydney, Australia<br />
Martina Stenzel; 35th Australian Polymer<br />
Symposium, 12th – 15th July <strong>2015</strong>, Gold<br />
Coast, Australia