24.11.2016 Views

CAMD_2015_Annual_Report

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

Centre for Advanced Macromolecular Design<br />

<strong>2015</strong> <strong>Annual</strong> <strong>Report</strong><br />

Never Stand Still<br />

Centre for Advanced Macromolecular Design


Mission Statement<br />

The Centre for Advanced Macromolecular<br />

Design (<strong>CAMD</strong>) is a research centre in the<br />

School of Chemical Engineering at the<br />

University of New South Wales that is<br />

dedicated to the synthesis and application of<br />

polymers/polymeric nano-objects using a wide<br />

range of modern polymerization techniques.<br />

A significant portion of <strong>CAMD</strong>’s activities are<br />

directed towards general and specific<br />

applications in the areas of advanced materials,<br />

as well as polymers for energy, sustainability<br />

and health/bio applications.


Objectives<br />

To continue to be recognised as a world leader<br />

in macromolecular chemistry and employ<br />

macromolecular science to address problems in<br />

the areas of advanced materials, energy,<br />

sustainability and human health<br />

To further the fundamental understanding of<br />

polymerization processes for the optimization<br />

of synthetic polymer protocols<br />

To produce high quality research leading to<br />

publications in high impact journals<br />

To attract and train outstanding PhD students<br />

To provide a work environment that encourages<br />

high quality research<br />

To attract high quality industry partners and<br />

help solve important problems<br />

To work at the interface of nanotechnology and<br />

polymer science


Steering<br />

Committee<br />

Prof Mark Hoffman (Presiding Dean)<br />

Dean of Engineering<br />

Prof Martina Stenzel (co-Director)<br />

School of Chemistry<br />

Prof Per Zetterlund (co-Director)<br />

School of Chemical Engineering<br />

Prof Scott Kable<br />

School of Chemistry (HoS)<br />

Prof Vicki Chen<br />

School of Chemical Engineering (HoS)<br />

Prof Peter Steinberg<br />

School of Biological, Earth &<br />

Environmental Sciences<br />

Centre for Marine Bio-Innovation<br />

Sydney Institute of Marine Science<br />

(Director)<br />

Prof Peter Lovibond<br />

Senior Associate Dean (Faculty of<br />

Science)<br />

Mr Eh Hau Pan (Laboratory Manager)<br />

School of Chemical Engineering


Directors<br />

<strong>Report</strong><br />

The Centre for Advanced<br />

Macromolecular Design (<strong>CAMD</strong>)<br />

focuses on the synthesis of polymers<br />

for advanced applications. This broad<br />

research field encompasses the<br />

development of new polymerization<br />

techniques to create<br />

polymers/polymeric nano-objects for<br />

applications mainly in the areas of<br />

advanced materials, health and<br />

energy/environment.<br />

The year <strong>2015</strong> was another successful<br />

year for <strong>CAMD</strong> in terms of research<br />

output. The centre has been highly<br />

productive, publishing 56 papers or<br />

book chapters in leading international<br />

journals, including high impact<br />

publications such as papers in<br />

Chemical Reviews and JACS. <strong>CAMD</strong><br />

also hosted numerous visitors<br />

throughout the year, including several<br />

internationally renowned researchers<br />

who gave presentations as part of the<br />

<strong>CAMD</strong> lecture program. Strong<br />

international links are also reflected in<br />

a range of publications with<br />

collaborators from around the world.<br />

<strong>CAMD</strong> researchers were active in<br />

attending conferences and giving<br />

seminars, including a one day<br />

workshop entitled Polymer Research<br />

in NWS Symposium organized by<br />

<strong>CAMD</strong> researchers at UNSW in<br />

November <strong>2015</strong>.<br />

The year 2014 witnessed significant<br />

change in terms of personnel. Dr<br />

Stuart Thickett took up a position at<br />

the University of Tasmania. Dr Peter<br />

Roth left <strong>CAMD</strong> for a position at the<br />

University of Surrey in the UK. Our<br />

longstanding Centre Manager, Dr<br />

Istvan Jacenyik, accepted a position at<br />

Macquarie University. We thank them<br />

for their hard work at <strong>CAMD</strong> and wish<br />

all of them well in their future<br />

endeavours. Several new staff also<br />

joined <strong>CAMD</strong> – Dr Damia Mawad was<br />

appointed Lecturer at the School of<br />

Materials Science and Engineering<br />

(Faculty of Science) at UNSW, and<br />

joined <strong>CAMD</strong> shortly thereafter. Her<br />

research is mainly concerned with<br />

polymeric biomaterials applied in<br />

tissue engineering and drug delivery.<br />

Dr Robert Chapman arrived at <strong>CAMD</strong><br />

as a Vice Chancellor’s Postdoctoral<br />

Research Fellow to work mainly on the<br />

development of macromolecular<br />

therapeutics able to control cell<br />

behaviour through clustering of cell<br />

receptor proteins.<br />

In closing, we would like to thank all<br />

the members of <strong>CAMD</strong> for their hard<br />

work, and we also gratefully<br />

acknowledge the ongoing support<br />

from the School of Chemical<br />

Engineering and the School of<br />

Chemistry.<br />

Prof Martina Stenzel<br />

Prof Per Zetterlund<br />

Directors


Centre for Advanced<br />

Macromolecular Design<br />

Staff


Professor Martina Stenzel<br />

Dr.rer.nat.(PhD) (1999)<br />

Polymer Chemistry<br />

University of Stuttgart, Germany<br />

Martina Stenzel studied chemistry at<br />

the University of Bayreuth, Germany,<br />

before completing her PhD in 1999 at<br />

the Institute of Applied<br />

Macromolecular Chemistry, University<br />

of Stuttgart, Germany. She then<br />

moved to UNSW, Australia, as a<br />

postdoctoral fellow, sponsored by<br />

DAAD and was later employed as<br />

lecturer at UNSW. She is now a full<br />

Professor and Co-director of the<br />

Centre for Advanced Macromolecular<br />

Design (<strong>CAMD</strong>), a UNSW research<br />

Centre dedicated to the synthesis and<br />

application of polymers.<br />

Her research interest is focused on the<br />

synthesis of functional polymers with<br />

complex architectures such as<br />

glycopolymers and other polymers for<br />

biomedical applications, especially<br />

polymers with in-built metal<br />

complexes for the delivery of<br />

metal-based anti-cancer drugs.<br />

The aim is to create nanoparticles for<br />

the treatment of cancer. One focal<br />

point is the formation of hybrid<br />

materials from biopolymers such as<br />

polysaccharides and proteins with<br />

synthetic polymers. Martina has<br />

published more than 200 peer<br />

reviewed papers, mainly on RAFT<br />

polymerization and biomedical<br />

applications. Martina currently serves<br />

on eight editorial advisory boards in<br />

the area of polymer science and<br />

biomaterials and is a scientific editor of<br />

RSC Materials Horizons.<br />

She is a member of the ARC College of<br />

experts and a member of the national<br />

committee for chemistry of the<br />

Australian Academy of Science.<br />

Martina has received several awards<br />

for her work including the 2011 Le<br />

Fèvre Memorial Prize and the 2013<br />

NSW Science and Engineering award -<br />

Excellence in Engineering.


Professor Per Zetterlund<br />

PhD 1998<br />

Polymer Chemistry<br />

University of Leeds, UK<br />

Per Zetterlund graduated from The<br />

Royal Institute of Technology in<br />

Stockholm (Sweden) in 1994, obtained<br />

his Ph.D. at Leeds University (UK) in<br />

1998, and subsequently conducted<br />

postdoctoral research at Griffith<br />

University (Brisbane, Australia).<br />

In 1999, he became Assistant<br />

Professor at Osaka City University<br />

(Japan) in the group of Prof. Yamada,<br />

and moved to Kobe University (Japan)<br />

in 2003 to join the team of Prof.<br />

Okubo, where he was promoted to<br />

Associate Prof in 2005. Since 2009,<br />

he is working at The Centre for<br />

Advanced Macromolecular Design<br />

(<strong>CAMD</strong>) at The University of New<br />

South Wales (Sydney, Australia),<br />

where he is currently full Professor<br />

and co-Director of the Centre.<br />

hybrid polymeric materials with a<br />

variety of applications ranging from<br />

materials science to nanomedicine.<br />

Important aspects of his research<br />

include the use of environmentally<br />

friendly carbon dioxide in polymer<br />

(nanoparticle) synthesis, as well as<br />

experimental/theoretical studies of<br />

polymerization in nanoreactors. He<br />

has to date published ~150<br />

peer-reviewed papers, and currently<br />

serves on the editorial boards of the<br />

journals Macromolecular Theory and<br />

Simulations and Polymer Chemistry.<br />

Prof Zetterlund’s research is concerned<br />

with the synthesis of polymer,<br />

polymeric nanoparticles, as well as


Associate Professor Cyrille Boyer<br />

PhD (2006)<br />

Polymer Chemistry<br />

University of Montpellier II, France<br />

Cyrille Boyer received his PhD in<br />

polymer chemistry from the University<br />

of Montpellier II in 2006. In 2010, he<br />

was appointed as a lecturer and he<br />

received an Australian Research<br />

Council Fellow (APD-ARC). In 2012,<br />

Cyrille was promoted Senior Lecturer<br />

at the School of Chemical Engineering<br />

and he was awarded an Australian<br />

Research Council Future Fellowship.<br />

cover the preparation of hybrid<br />

organic-inorganic nanoparticles for<br />

imaging & drug delivery and the use<br />

of photoinduced living polymerization<br />

(photopolymerization).<br />

Cyrille serves on the editorial boards of<br />

Polymer Chemistry and European<br />

Polymer Journal.<br />

He received several awards, including<br />

the Scopus Young Researcher of the<br />

Year Award 2012, UNSW Research<br />

Excellence Award and was listed as<br />

finalist of NSW innovation award in<br />

2014. In 2013, Cyrille was promoted to<br />

Associate Professor.<br />

Cyrille has published over 135 research<br />

articles, 19 conference papers, 5<br />

granted patents and 2 provisional<br />

patents, which have garnered over<br />

5200 citations (his H-index is 43).<br />

Cyrille’s research interests mainly


Associate Professor Frank Lucien<br />

PhD (1997)<br />

Chemical Engineering, UNSW<br />

Frank Lucien received his PhD in<br />

Chemical Engineering in 1997 from<br />

the University of New South Wales.<br />

His doctoral research was concerned<br />

with solubility enhancement of solids<br />

in supercritical CO 2 .<br />

polymeric nanoparticles (with Prof. Per<br />

Zetterlund). He has published over 80<br />

scientific papers, including 4 book<br />

chapters and 1 patent.<br />

He carried out postdoctoral research at<br />

F. Hoffmann-La Roche (Basel,<br />

Switzerland) and continued work on<br />

high pressure processes involving CO 2 .<br />

He was appointed as a lecturer in the<br />

School of Chemical Engineering &<br />

Industrial Chemistry at UNSW in<br />

1997.<br />

His early work involved the use of<br />

CO 2 -expanded liquids as reaction<br />

media, focusing on catalytic<br />

hydrogenation and catalytic chain<br />

transfer polymerization. He was<br />

promoted to A/Prof. in 2009 and is<br />

currently conducting research on<br />

radical polymerization in CO 2 -induced<br />

emulsions for the synthesis of


Dr Anthony Granville - Lecturer<br />

PhD (2004)<br />

Polymer Chemistry<br />

University of Akron, USA<br />

Anthony Granville graduated from<br />

Stevens Institute of Technology (New<br />

Jersey, USA) with a degree in<br />

chemistry before going on to the<br />

University of Akron (Ohio, USA) and<br />

completing his PhD in polymer<br />

chemistry.<br />

Upon completing postdoctoral work in<br />

<strong>CAMD</strong>, he was appointed as an<br />

Academic Fellow to the School of<br />

Chemical Engineering at UNSW<br />

before being converted to a full-time<br />

lecturer at the school.<br />

their capabilities as osteoblast<br />

promoters, and new surface<br />

polymerisations from these constructs<br />

using UV irradiation.<br />

Tony is secretary of the RACI NSW<br />

POLY group as well as on several<br />

academic boards at UNSW.<br />

Tony’s current research interests deals<br />

with the investigating novel synthetic<br />

molecules capable of undergoing the<br />

mussel-inspired self-polymerisation<br />

process as well as their applications to<br />

health, water purification, and energy.<br />

This work has led to investigations into<br />

the radiolabelling of nanocapsules of<br />

these materials (in the form of an<br />

AINSE grant at ANSTO), investigating


Dr Peter Roth - Research Fellow<br />

PhD (2009)<br />

Chemistry<br />

University of Mainz, Germany<br />

Peter Roth studied chemistry at the<br />

University of Mainz (Germany), the<br />

University of Massachusetts (USA),<br />

and Seoul National University (South<br />

Korea), obtaining his PhD in 2009 in<br />

the group of Patrick Theato (Mainz).<br />

His PhD work focused on the end<br />

group modification of RAFT-made<br />

(co)polymers using activated esters<br />

and functional thiosulfonates.<br />

After obtaining a pre-diploma in<br />

Psychology in 2010 from the<br />

University of Mainz, he did<br />

postdoctoral research at the University<br />

of New South Wales, Sydney, working<br />

with Profs Tom Davis and Andrew<br />

Lowe on the self-assembly of<br />

homopolymers into vesicles from<br />

2010–2012.<br />

His group’s research focused on novel<br />

smart materials responding to<br />

(multiple) external stimuli such as<br />

temperature (including rare aqueous<br />

UCST systems), presence of specific<br />

chemical analytes, pH, and mechanical<br />

agitation; the use and development of<br />

efficient post-polymerization<br />

modification reactions; and the use of<br />

multicomponent reactions in the<br />

design and preparation of novel<br />

multifunctional materials.<br />

He received an ARC DECRA on the<br />

development of novel stimulus<br />

responsive polymers in 2012 and was<br />

promoted to Research Fellow in 2013.


Dr Stuart Thickett - Research Fellow<br />

PhD (2008)<br />

Chemistry<br />

University of Sydney<br />

Stuart Thickett received his BSc (Hons)<br />

from The University of Sydney in<br />

2004 and completed his PhD with<br />

Professor Robert Gilbert at The<br />

University of Sydney in 2008.<br />

He has since held post-doctoral<br />

positions at The University of Toronto,<br />

Canada (with Professor Mitchell<br />

Winnik) and The University of Sydney<br />

(with Associate Professor Chiara Neto).<br />

He is interested in the underlying<br />

kinetic and mechanistic phenomena<br />

that govern such systems, with the<br />

goal of using this knowledge to create<br />

new materials with specific properties<br />

and attributes.<br />

In 2012 he was awarded a<br />

Vice-Chancellor's Post-Doctoral<br />

Fellowship to join the School of<br />

Chemical Engineering at UNSW. His<br />

work focuses on the physical<br />

chemistry of soft matter, specifically<br />

polymers, colloids, nanoparticles and<br />

thin films.


Dr Pu Xiao - Research Fellow<br />

PhD (2009)<br />

Polymer Chemistry and Physics<br />

Wuhan University, China<br />

Dr. Pu Xiao obtained his Bachelor’s<br />

degree (2004) in Chemistry and PhD<br />

(2009) in Polymer at Wuhan<br />

University (China).<br />

He started his academic career as a<br />

Scientific Associate at the University of<br />

Applied Sciences and Arts<br />

Northwestern Switzerland (FHNW,<br />

Switzerland) from 2009. In 2012, he<br />

moved to the Institute of Materials<br />

Science of Mulhouse (IS2M, CNRS,<br />

France) and worked as a Post-doctoral<br />

Fellow.<br />

nanodiamond/polymer hybrid<br />

nanomarials as drug delivery systems).<br />

He has published >65 peer-reviewed<br />

papers, most of which are concerned<br />

with novel photoinitiating systems of<br />

polymerization.<br />

Since 2014, he has been working as a<br />

Research Fellow (ARC DECRA) in Prof<br />

Stenzel’s group at <strong>CAMD</strong> at UNSW.<br />

His research interests are focused on<br />

the fabrication of polymeric materials<br />

in a green environment such as mild<br />

visible light and nanomaterials for<br />

environmental or biomedical<br />

applications (e.g.


Dr Hongxu Lu - DECRA research<br />

fellow<br />

PhD (2009)<br />

Biomaterials<br />

University of Tsukuba, Japan<br />

Hongxu Lu obtained his BSc and MSc<br />

degrees from Ocean University of<br />

China in 1998 and 2006,<br />

respectively. He completed his PhD in<br />

Materials Science and Engineering<br />

(Biomaterials) in 2009 from the joint<br />

PhD program of University of Tsukuba<br />

and National Institute for Materials<br />

Science of Japan (NIMS). From 2009<br />

to 2012, he worked as a postdoc<br />

researcher in the same lab of his PhD<br />

study at NIMS under the supervision<br />

of Prof. Guoping Chen.<br />

medicine and investigation of<br />

cell-biomaterials interactions. Dr. Lu<br />

was awarded with the Young<br />

Investigator Award from Japanese<br />

Society for Regenerative Medicine<br />

(Japan, 2012) and the Young Scientist<br />

Award from International Symposium<br />

of Materials on Regenerative<br />

Medicine (Taiwan, 2010). He has<br />

published more than 50 peer reviewed<br />

journal papers with more than 600<br />

citations. His current H-index is 13.<br />

Since 2012, he has been working at<br />

UNSW mentored by Prof. Martina<br />

Stenzel. In <strong>2015</strong>, Dr. Hongxu Lu was<br />

awarded an ARC DECRA Research<br />

Fellowship. His research focuses on the<br />

development of nano drug carriers and<br />

novel 2D and 3D cellular models for<br />

the evaluation of nano drug carriers.<br />

He is also interested in the<br />

development of 3D scaffolds for tissue<br />

engineering and regenerative


Dr Damia Mawad<br />

Lecturer<br />

PhD (2007)<br />

Biomedical Engineering<br />

University of New South Wales<br />

Australia<br />

Damia Mawad received her PhD in<br />

Biomedical Engineering in 2007 from<br />

University of New South Wales. She<br />

started her academic career as a<br />

post-doctoral fellow in University of<br />

Lyon, France. From 2008 to 2012,<br />

she was a Research Fellow at the<br />

Intelligent Polymer Research Institute<br />

(IPRI), University of Wollongong. She<br />

was then awarded IN 2013 a Marie<br />

Curie International Incoming<br />

Fellowship hosted by Imperial College<br />

London, UK. In August <strong>2015</strong>, she has<br />

been appointed a lecturer at the<br />

School of Materials Science and<br />

Engineering, UNSW.<br />

Her research interests are in polymeric<br />

biomaterials applied in tissue<br />

engineering and drug delivery. One of<br />

her main investigations is<br />

development of electroactive and<br />

conductive scaffolds for biomedical<br />

applications with emphasis on the<br />

material chemistry and design<br />

strategies that transition from a<br />

monomer to a polymer to 3D<br />

construct. Examples include conductive<br />

porous hydrogels that induce cell<br />

attachment, proliferation and<br />

differentiation and conductive<br />

bioadhesives with micropatterned<br />

surfaces for cell alignment and<br />

photoadhesion to tissue. Recent<br />

research interests include control of<br />

the conduction anisotropy in<br />

conjugated polymers to better match<br />

the hierarchical organization and<br />

sophisticated architectures found in<br />

biological tissues.


Dr Robert Chapman<br />

Vice-Chancellor research fellow<br />

PhD (2013)<br />

Chemistry<br />

University of Sydney<br />

Australia<br />

Robert Chapman completed a BE<br />

(Hons I) in Industrial Chemistry at<br />

UNSW in 2007 and a PhD in<br />

Chemistry at the University of Sydney<br />

in 2013, where he studied the<br />

synthesis and self-assembly of cyclic<br />

peptide - polymer conjugates under<br />

Prof. Sebastien Perrier. He<br />

subsequently worked as a research<br />

associate in the lab of Prof. Molly<br />

Stevens at Imperial College London<br />

(2013-15) on the development of<br />

nanomaterial based biosensors for<br />

diagnosis of disease at point of care,<br />

and on polymer scaffolds for tissue<br />

engineering. In 2016 he returned to<br />

UNSW as a Vice Chancellor’s<br />

Postdoctoral Research Fellow.<br />

Robert’s research focuses on the<br />

development of macromolecular<br />

therapeutics able to control cell<br />

behaviour through clustering of cell<br />

receptor proteins. Through the<br />

development of combinatorial<br />

approaches to polymer synthesis he is<br />

investigating the effect that polymer<br />

architecture and rigidity has on<br />

biological activity.


Dr Istvan Jacenyik - Centre Manager<br />

DPharm (2009)<br />

Semmelweis University, Hungary<br />

Eh Hau Pan - Technical Officer<br />

BE - Industrial Chemistry (2006)<br />

UNSW<br />

Research Associates:<br />

Dr Florent Jasinski<br />

Dr ChangKui Fu<br />

Dr Antoine Tardy<br />

Dr Jiangtao Xu<br />

Postgraduates:<br />

Nik Nik Mohd Adnan<br />

Sri Agustina<br />

Rhiannon Batchelor<br />

Kash Bhullar<br />

Teddy Chang<br />

Fan Chen (Charles)<br />

Nathaniel Corrigan<br />

Alice Du<br />

Ka Wai Fan<br />

Noor Hadzuin Nik Hadzir (Awin)<br />

Fumi Ishizuka<br />

Yanyan Jiang<br />

Kenward Jung<br />

Yee Yee Khine<br />

Haiwang Lai<br />

Mingxia Lu (Mia)<br />

Russul Mamdooh<br />

Diep Nguyen<br />

Thuy Khanh Nguyen<br />

Janina Miriam Noy<br />

Susan Oliver<br />

Alberto Piloni<br />

Narasinga Rao Hanumanth Rao<br />

Sivaprakash Shanmugam (Siva)<br />

Jiaying Su (Amanda)<br />

Victoria Teo<br />

Haiqiao Wang<br />

Chin Ken Wong (Ken)<br />

Jonathan Yeow<br />

Yujian Zhai<br />

Jiacheng Zhao<br />

New PhD Students (<strong>2015</strong>)<br />

Nathaniel Corrigan<br />

Yee Yee Khine<br />

Haiwang Lai<br />

Russul Mamdooh<br />

Janina Miriam Noy<br />

Susan Oliver<br />

Alberto Piloni<br />

Haiqiao Wang


PhD Completions:<br />

Yan Jin (Joey)<br />

Surface Modification of Optical Fibers<br />

and Waveguides for Creating<br />

Localized Surface Plasmon Resonance<br />

Biosensors (Dr Anthony Granville)<br />

Siming Dong (Sam)<br />

Radical Polymerizations in Dispersed<br />

Systems (Prof Per Zetterlund)<br />

Yicheng Zhu (Mike)<br />

Thermoresponsive Polymers with<br />

Aqueous LCST and/or UCST through<br />

Postpolymerization Modification<br />

(Dr Peter Roth)<br />

Visitors:<br />

Bandit Thong-On<br />

Neomy Zaquen<br />

Kilian Wuest<br />

Ann-Katrin Friedrich<br />

Jonas Kolsch<br />

Timos Hees<br />

Masayoshi Tokuda<br />

Dr Kazuaki Taguchi<br />

A/Prof. Jianbo Qu


Collaborators<br />

UNSW<br />

Prof Rose Amal (Chemical<br />

Engineering)<br />

Prof Robert Burford (Chemical<br />

Engineering)<br />

Dr Nicolas Barraud (BABS)<br />

Dr Rita Henderson (Water Research)<br />

Prof Naresh Kumar (Chemistry)<br />

Dr Megan Lord (GSBmE)<br />

Dr Penny Martens (GSBmE)<br />

Prof David Morris (St George Hospital)<br />

Dr Yun Hau Ng (Chemical Engineering)<br />

Prof Laura Poole-Warren (GSBmE)<br />

Dr Robert Taylor (Mech & Man Eng)<br />

Dr Renee Whan (Biomedical Imaging)<br />

Prof John Whitelock (GSBmE)<br />

A/Prof Jia-Lin Yang (Prince of Wales)<br />

Prof Melissa Knothe-Tate (Biomedical<br />

Engineering)<br />

Domestic<br />

Prof Paul de Souza (Ingham Institute)<br />

A/Prof Brian Hawkett (University of<br />

Sydney)<br />

Dr Kristopher Thurecht (UQ)<br />

Prof Gunther Andersson (Flinders<br />

University)<br />

International<br />

Dr Fawaz Aldabbagh (Ireland, Galway)<br />

Prof Christopher Barner-Kowollik (KIT,<br />

Germany)<br />

Prof Laurent Billon (Pau, France)<br />

Prof B. Boutevin (Montpellier II,<br />

France)<br />

Prof Jerome Claverie (Montréal,<br />

Canada)<br />

Dr Ghislain David (Montpellier II,<br />

France)<br />

Prof Filip Du Prez (Ghent, Belgium)<br />

Prof Laurent Fontaine (Mans, France)<br />

Prof David Haddleton (Warwick, UK)<br />

A/Prof Atsushi Kajiwara (Nara Uni.,<br />

Japan)<br />

Dr Sophie Laurent (Mons, Belgium)<br />

Prof H.-U. Moritz, (Hamburg,<br />

Germany)<br />

Prof Rachel O’Reilly (Warwick, UK)<br />

A/Prof Nicolay Tsarevsky (Sthn<br />

Methodist, USA)<br />

Prof Philipp Vana (Göttingen,<br />

Germany)<br />

Prof Tanja Weil (Ulm, Germany)<br />

A/ Prof Hideto Minami (Kobe, Japan)<br />

Prof Sebastien Perrier (Warwick, UK)<br />

Dr Michael Gottschalt (Jena, Germany)<br />

Prof Stephan Förster (Bayreuth,<br />

Germany)<br />

A/ Prof Emily Pentzer (Case Western<br />

Reserve University, USA)<br />

A/Prof Lacey McNally (University of<br />

Louisville)<br />

Prof Jingquan Liu (Qiandao University,<br />

China)<br />

Prof. Lei Tao (Tsinghua University,<br />

China)<br />

Dr Simon Harrisson (Universite´ Paul<br />

Sabatier Toulouse, France)<br />

Industrial<br />

Henkel (Ireland)<br />

Nubian Water Systems (Australia)<br />

Nuplex Industries (Australia)<br />

Novogen (Australia)


Polymer Sunthesis


Polymer<br />

Synthesis<br />

<strong>CAMD</strong> continues to make significant<br />

contributions in advanced polymer<br />

synthesis. Most efforts are centred on<br />

RAFT polymerization, a controlled/living<br />

radical polymerization technique<br />

investigated to great length at <strong>CAMD</strong> over<br />

the last decade. Current research aims<br />

both at improving the scope of RAFT as<br />

method and at exploiting its inherent<br />

advantages for state-of the art design of<br />

advanced macromolecules. Whereas<br />

conventional RAFT polymerization is<br />

sensitive to oxygen impurity and may not<br />

be controlled through external stimuli, a<br />

recent development of photoinduced<br />

RAFT polymerization eliminates these<br />

shortcomings while offering<br />

polymerization control over conjugated<br />

and unconjugated monomers. This<br />

method employs trace amounts of a<br />

photoredox catalyst which allows<br />

polymerizations to be reversibly stopped<br />

and continued by way of a visible light<br />

trigger. Taking advantage of the controlled<br />

nature of RAFT polymerization and its<br />

ability to produce well-defined A-B<br />

diblock copolymers, well-defined<br />

nanoparticles can be produced in onestep<br />

RAFT dispersion polymerisation. In this<br />

technique, a soluble macro-RAFT agent is<br />

used to polymerize a second monomer in<br />

a selective solvent that causes<br />

self-assembly of the growing second block<br />

giving access to distinct morphologies<br />

depending on recipe and reaction time.<br />

Recent research at <strong>CAMD</strong> has widened<br />

the scope of this technique, successfully<br />

applying it to a variety of functional<br />

monomers which has allowed, for<br />

example, simple preparation of gold<br />

nanoparticle-functional microparticles.<br />

nanoreactors may be exploited in tandem<br />

with template polymerization has led to a<br />

biomimetic approach based on template<br />

polymerization involving nucleobase<br />

containing vinyl monomers in a<br />

segregated environment achieved via<br />

self-assembly of template diblock<br />

copolymers. A further synthetic technique<br />

applied and progressed at <strong>CAMD</strong> is<br />

postpolymerization modification, the<br />

chemical transformation of reactive,<br />

pre-made (co)polymers. This method takes<br />

advantage of the high compatibility of the<br />

RAFT process with functional chemical<br />

groups. Using a variety of reactive<br />

precursors, we can introduce virtually any<br />

chemical functional group into a<br />

polymeric material, including groups that<br />

may not be compatible with the<br />

polymerization procedure. This gives<br />

access to a very wide range of functional<br />

materials with tuneable properties— see<br />

also Advanced Materials section.<br />

Control over polymer microstructure is<br />

also being explored at the fundamental<br />

level using the combined approach of (i)<br />

biomimetic template radical<br />

polymerization and (ii) polymerization in<br />

nanoreactors in the form of<br />

submicron-sized micelles or droplets. The<br />

realization that the concept of


Advanced Materials


Advanced<br />

Materials<br />

A number of projects deal with synthesis<br />

of advanced materials, e.g. stimulus<br />

responsive, “smart” polymers and<br />

nanocomposite materials. “Smart”<br />

polymers exhibit drastic changes of their<br />

physical properties in response to external<br />

stimuli such as temperature, light, certain<br />

gases, mechanical agitation, pH changes<br />

and specific chemical substances, and<br />

these materials offer great potential for<br />

applications in separation science, sensing<br />

and detection, and microfluidics. At<br />

<strong>CAMD</strong>, we aim to develop novel smart<br />

polymers, understand and improve their<br />

behaviour. Another area of research is<br />

surface modification of polymeric optical<br />

fibres for chemo- and biosensor<br />

technology, which involves generation of<br />

gold coated surfaces as a platform for<br />

various polymerisation and surface<br />

binding techniques.<br />

The material graphene was discovered in<br />

2004 (Noble Prize awarded in 2010) – it<br />

is the strongest material ever measured,<br />

and this is accompanied by a range of<br />

other extraordinary physical properties<br />

such as high thermal conductivity and<br />

high electrical conductivity. Graphene is<br />

seen as the material of the future, with the<br />

potential to revolutionize a wide range of<br />

industries from electronics to healthcare,<br />

and there is currently immense worldwide<br />

research activity in this area. At <strong>CAMD</strong>,<br />

we are interested in preparing novel<br />

polymeric nanocomposite materials with<br />

superior physical properties using<br />

graphene and graphene oxide.<br />

polymers, and do not form homogeneous<br />

polymer composites. We specifically<br />

address these issues by employing various<br />

techniques involving (controlled/living)<br />

radical polymerization in aqueous<br />

dispersed systems for synthesis of<br />

polymer/graphene nanocomposite<br />

materials. The key in our approach is to<br />

exploit the amphiphilic properties of<br />

graphene oxide – it can behave as a<br />

surfactant in aqueous emulsions of oil<br />

(vinyl monomer) under suitable conditions.<br />

We thus conduct various types of<br />

dispersed phase polymerizations<br />

(emulsion, miniemulsion) using graphene<br />

oxide as surfactant, thereby accessing a<br />

novel route to graphene/polymer<br />

nanocomposite materials.<br />

Fig. 2. TEM image and schematic illustration<br />

of hollow polymeric nanoparticle coated with<br />

graphene oxide nanosheets.<br />

The addition of graphene as a component<br />

of polymer nanocomposites results in<br />

superior material properties over the more<br />

common fillers such as carbon black. In<br />

order to fulfil the potential of such<br />

nanocomposites, a high degree of<br />

dispersion of graphene as individual<br />

two-dimensional sheets in the polymer<br />

matrix is essential. However, both pristine<br />

graphene and graphene oxide are<br />

incompatible with most hydrophobic


Energy &<br />

Environment


Energy &<br />

Environment<br />

A number of active research themes are<br />

focused on energy/environment, including<br />

projects as diverse as development of<br />

environmentally friendly aqueous<br />

coatings, micropatterned surfaces or the<br />

efficient collection of water directly from<br />

the atmosphere, hybrid inorganic/organic<br />

nanomaterials for hydrogen storage,<br />

synthesis of various types of emulsions<br />

using carbon dioxide, and environmentally<br />

friendly synthesis of polybenzimidazoles<br />

for use in the in the energy storage and<br />

transfer realms.<br />

Hydrogen could be the ultimate energy<br />

carrier enabling energy security and<br />

global sustainability in this 21st century. In<br />

the sun, hydrogen releases the energy<br />

that sustains life on Earth, while hydrogen<br />

bonded to carbon provides us with the<br />

so-called fossil fuels that have powered<br />

our industrial revolution. Unfortunately, a<br />

heavy reliance on finite resources and the<br />

adverse effects of fossil fuels on global<br />

climate are now threatening further<br />

development. In its purest form hydrogen<br />

has high energy content, and therefore<br />

hydrogen has naturally emerged as the<br />

only possible synthetic energy carrier with<br />

sufficient versatility to replace oil.<br />

However, the effective storage of<br />

hydrogen in a compact manner remains<br />

the central difficulty for its widespread<br />

use. Efforts over the last decades have<br />

targeted a range of materials capable of<br />

storing hydrogen with high density in the<br />

form of a hydride, e.g. MgH2, but the<br />

realization of successful strategies to<br />

control and balance competitive<br />

thermodynamics/kinetics requirements<br />

for the effective storage of hydrogen<br />

remains unanswered. The aim of this<br />

project is to develop a method for the<br />

facile production of MgH2 nanoparticles<br />

and their assembly into a tertiary<br />

structure providing remarkable stability to<br />

the magnesium nanoparticles against<br />

agglomeration and sintering.<br />

Fig. 3. Self-assembly of magnesium<br />

nanoparticles in polymer structures and<br />

SEM/TEM micrograph showing the self<br />

assembly in fibre structure<br />

Mussels and other bivalves excrete a<br />

natural polymeric adhesive shown to be<br />

water insoluble, tough, and nontoxic. This<br />

material can be synthetically<br />

manufactured using dopamine as the<br />

monomeric material in a rather simple,<br />

weakly basic, aqueous solution. The<br />

dopamine compound will cyclise to form<br />

an indole intermediate before crosslinking<br />

to form the desired polymer. When a<br />

substrate is immersed in the aqueous<br />

solutions system, the polydopamine will<br />

form a homogeneous coating on the<br />

substrate surface. This paves the way for<br />

simple, benign coatings of a controlled<br />

thickness to be used for drug delivery,<br />

surface modification, and metal binding<br />

for electronic applications. The<br />

universality of this approach is being<br />

investigated with a focus on<br />

polybenzimidazoles, which are renowned<br />

for their high temperature properties as<br />

well as their ability to be used as proton<br />

exchange membranes when doped with<br />

acids.


Polymers<br />

for Health


Polymers<br />

for Health<br />

The area of biomedical engineering has a<br />

strong need for new polymers to be able<br />

to finetune the interface between<br />

synthetic materials and the biological<br />

environment. RAFT (reversible<br />

addition-fragmentation chain transfer)<br />

polymerization is an excellent tool to<br />

address this need.<br />

Polymers can be synthesized to suit<br />

different applications and <strong>CAMD</strong><br />

researchers are active in the area of<br />

synthesis of nanoparticles for drug<br />

delivery to grafting of polymers from<br />

various surfaces to adjust their<br />

biocompatibility. In particular the area of<br />

drug delivery and imaging of<br />

nanoparticles is one of the main themes at<br />

<strong>CAMD</strong>. Self-assembled aggregates such<br />

as micelles, rod-like micelles and vesicles<br />

are proposed as drug carriers due to their<br />

hydrophobic interior, while size and shape<br />

is easily controlled by the underlying<br />

polymer. The nature of the block<br />

copolymer can be adjusted to solve a<br />

range of drug delivery problems. This<br />

includes traditional anti-cancer drugs, but<br />

also other, more challenging bioactive<br />

molecules such as DNA, heparin, peptides<br />

and metal-based drugs. The central<br />

questions are how can we design suitable<br />

polymers to encapsulate the drug and<br />

how does the polymer affect the<br />

properties of the nanoparticle?<br />

Next to self-assembled block copolymers<br />

<strong>CAMD</strong> researchers are focussing on<br />

coating of inorganic nanoparticles such as<br />

gold nanoparticles or nanodiamonds to<br />

generate drug carriers that have added<br />

features such as they can be imaged or<br />

they can be used in hypothermia. On the<br />

quest for suitable drug delivery carriers for<br />

various drugs we developed a synthetic<br />

tool kit to achieve the best possible<br />

cellular uptake. We are interested in<br />

stabilizing the micelles by crosslinking,<br />

which often leads to better cell uptake. In<br />

addition, by replacing the more tradition<br />

PEG shell of micelles by other polymers<br />

such as polymers with a zwitterionic<br />

structure, we can create drug carriers that<br />

are not only nontoxic, but also show very<br />

high uptake efficiency.<br />

<strong>CAMD</strong> researchers are inspired by<br />

Nature’s building blocks such as sugars,<br />

proteins and polysaccharides. Synthetic<br />

routes are developed to create drug<br />

carriers that combine the tailored<br />

properties of synthetic polymers with the<br />

bioactivity of natural products. Drug<br />

carriers coated with albumin or sugars<br />

show high bioactivity, while at the same<br />

time the synthesis of these carriers can be<br />

very simple.<br />

In vitro<br />

In vivo<br />

Fig. 4. Preparation of self-assembled<br />

core-shell nanoparticles for the delivery of<br />

drugs into cancer cells, and the subsequent<br />

study of the movement of these nanoparticles<br />

in multicellular cancer models and in vivo.


Research<br />

Grants <strong>2015</strong><br />

•MREII grant for FT-IR system, $110,894<br />

(Granville/Zetterlund/Stenzel/Boyer/Luci<br />

en)<br />

•Emerging anode materials for li-s<br />

batteries - ba14017, Gentle, Ian; Wang,<br />

Da-wei; Aguez-Zinsou, Kondo-Francois;<br />

Boyer, Cyrille. (BAOSTEEL-AUSTRALIA<br />

Joint research & development centre<br />

shared grant); $250,000<br />

•Beamtime application at Australian<br />

Synchrotron, including travel grant<br />

(Zetterlund)<br />

•Internal equipment grant from Chem Eng<br />

to purchase new GPC system (about 60k)<br />

– (Boyer)<br />

•Expanding quartz crystal microbalance<br />

(QCM) capabilities for solid-liquid<br />

interfaces ($5.6 K) (Granville)


Publications<br />

in <strong>2015</strong><br />

pH-, thermo- and electrolyte-responsive polymer<br />

gels derived from a well-defined,<br />

RAFT-synthesized, poly<br />

(2-vinyl-4,4-dimethylazlactone) homopolymer via<br />

one-pot post-polymerization modification<br />

European Polymer Journal (<strong>2015</strong>), 62, 204–213<br />

Y. Pei, O. R. Sugita, J. Y. Quek, P. J. Roth, A. B. Lowe<br />

Nanoparticles Based on Star Polymers as<br />

Theranostic Vectors: Endosomal-Triggered Drug<br />

Release Combined with MRI Sensitivity<br />

Advanced Healthcare Materials (<strong>2015</strong>), 4, 148–156<br />

Y. Li, H. T. T. Duong, S. Laurent, A. MacMillan, R. M.<br />

Whan, L. Vander Elst, R. N. Muller, J. Hu, A. Lowe ,<br />

C. Boyer, T. P. Davis<br />

Simultaneous ROMP and Titania Sol-Gel<br />

Reactions and a New Approach to Nanodispersed<br />

Organic/Inorganic Hybrid Materials<br />

Journal of Materials Chemistry C (<strong>2015</strong>), 3,<br />

693–702. J. A. van Hensbergen, M. Liu, R. P.<br />

Burford, A. B. Lowe<br />

Thiol-reactive Functional Poly(meth)acrylates:<br />

Multicomponent Monomer Synthesis, RAFT<br />

(Co)polymerization and Highly Efficient<br />

Thiol–para-Fluoro Postpolymerization<br />

Modification<br />

Polymer Chemistry (<strong>2015</strong>), 6, 436–447<br />

J.-M. Noy, M. Koldevitz, P. J. Roth<br />

RAFT Dispersion Polymerization in Nonpolar<br />

Media: Polymerization of 3 Phenylpropyl<br />

Methacrylate in n Tetradecane with Poly(stearyl<br />

methacrylate) Homopolymers as Macro Chain<br />

Transfer Agents<br />

Macromolecules (<strong>2015</strong>), 18 (1), 236-244<br />

Y. Pei, L. Thurairajah, O. R. Sugita, A. B. Lowe<br />

Graphene Oxide (GO) Nanosheets as Oil-in-Water<br />

Emulsion Stabilizers: Influence of Oil Phase<br />

Polarity<br />

Journal of Colloid and Interface Science (<strong>2015</strong>),<br />

442, 67–74<br />

S. C. Thickett, P. B. Zetterlund<br />

Multicomponent Isocyanide-based Synthesis of<br />

Reactive Styrenic and (Meth)acrylic Monomers<br />

and their RAFT (Co)polymerization<br />

Polymer Chemistry (<strong>2015</strong>) ,6, 44-54<br />

S. Schmidt, M. Koldevitz, J.-M. Noy, P. J. Roth<br />

ROMP Synthesis of Novel Thermo, pH and Salt<br />

Responsive (Co)Polymers Containing the<br />

Morpholino Functional Group<br />

Journal of Polymer Science, Part A: Polymer<br />

Chemistry (<strong>2015</strong>), 53, 50-58<br />

J. A. van Hensbergen, S. Ganda, P. J. Roth, R. P.<br />

Burford, A. B. Lowe<br />

RAFT-prepared α-Difunctional<br />

Poly(2-vinyl-4,4-dimethylazlactone)s and their<br />

Derivatives: Synthesis and Effect of End Groups on<br />

Inverse Aqueous Temperature Solubility<br />

Polymer Chemistry (<strong>2015</strong>) ,6, 118-127<br />

J. Y. Quek, X. Liu, T. P. Davis, P. J. Roth, A. B. Lowe<br />

Surface modification of polydopamine coated<br />

particles via glycopolymer brush synthesis for<br />

protein binding and FLIM testing<br />

Polymer Chemistry (<strong>2015</strong>) ,6, 2504–2511<br />

S. P. Le-Masurier, H. T. T. Duong, C. Boyer, A. M.<br />

Granville<br />

Biocompatible Glycopolymer Nanocapsules via<br />

Inverse Miniemulsion Periphery RAFT<br />

Polymerization for the Delivery of Gemcitabine<br />

Biomacromolecules (<strong>2015</strong>), 16 (7), 2144–2156<br />

R. H. Utama, Y. Jiang, P. B. Zetterlund, M. H. Stenzel<br />

RAFT Polymerization in Supercritical Carbon<br />

Dioxide Based on an Induced Precipitation<br />

Approach: Synthesis of 2-Ethoxyethyl<br />

methacrylate/Acrylamide Block Copolymers<br />

Journal of Polymer Science, Part A: Polymer<br />

Chemistry (<strong>2015</strong>), 53, 2351–2356<br />

G. Hawkins, P. B. Zetterlund, F. Aldabbagh<br />

An Innovative Approach to Implementation of<br />

Organotellurium-Mediated Radical Polymerization<br />

(TERP) in Emulsion Polymerization<br />

Macromolecules (<strong>2015</strong>), 48 (13), 4312–4318<br />

Y. Sugihara, S. Yamago, P. B. Zetterlund<br />

Polymerization Induced Self-Assembly: Tuning of<br />

Nano-Object Morphology by Use of CO2<br />

Polymer Chemistry (<strong>2015</strong>), 6, 2249 - 2254<br />

S. Dong, W. Zhao, F. P. Lucien, S. Perrier, and P. B.<br />

Zetterlund<br />

Factors Influencing the Preparation of Hollow<br />

Polymer-Graphene Oxide Nanocapsules via<br />

Pickering Miniemulsion Polymerization<br />

Polymer (<strong>2015</strong>), 63, 1-9<br />

G. H. Teo, Y. H. Ng, P. B. Zetterlund, S. C. Thickett<br />

Online SAXS Analysis of Shell Formation during<br />

Nanocapsule Synthesis via Inverse Miniemulsion<br />

Periphery RAFT Polymerization (IMEPP)<br />

Macromolecular Rapid Communications (<strong>2015</strong>), 36,<br />

1267-1271. R. H. Utama, M. Dulle, S. Förster, M. H.<br />

Stenzel, P. B. Zetterlund<br />

Controlled/Living Radical Polymerization in<br />

Dispersed Systems: An Update<br />

Chemical Reviews (<strong>2015</strong>), 115 (18),9745-9800<br />

Per B. Zetterlund, Stuart C. Thickett, Sébastien<br />

Perrier, Elodie Bourgeat-Lami, Muriel Lansalot


Publications<br />

in <strong>2015</strong><br />

Synthesis of Crosslinked Polymeric Nanocapsules<br />

using Catanionic Vesicle Templates Stabilized by<br />

Compressed CO2<br />

Soft Matter (<strong>2015</strong>), 11, 8613-8620<br />

S. Dong, P. T. Spicer, F. P. Lucien, P. B. Zetterlund<br />

Visible-Light-Regulated Controlled/Living Radical<br />

Polymerization in Miniemulsion<br />

ACS Macro Letters (<strong>2015</strong>), 4 (10), 1139–1143,<br />

K. Jung, J. Xu, P. B. Zetterlund, C. Boyer<br />

Surface Modification of Polydivinylbenzene<br />

Microspheres with a Fluorinated Glycopolymer<br />

using Thiol-Halogen Click Chemistry<br />

Macro-Glycoligands – Methods and Protocols<br />

(<strong>2015</strong>), Chapter 10, 123-135<br />

Song, Wentao; Granville, Anthony M<br />

Copolymerization of an indazole ligand into the<br />

self-polymerization of dopamine for enhanced<br />

binding with metal ions<br />

Journal of Materials Chemistry B (<strong>2015</strong>), 3, 7457 –<br />

7465. Fan, Ka Wai; Roberts, Justine J.; Martens,<br />

Penny J.; Stenzel, Martina H.; Granville, Anthony M<br />

RAFT Inverse Miniemulsion Periphery<br />

Polymerization in Binary Solvent Mixtures for<br />

Synthesis of Nanocapsules<br />

European Polymer Journal (<strong>2015</strong>), 73, 324-334<br />

F. Ishizuka, R. H. Utama, S. Kim, M. H. Stenzel, and<br />

P. B. Zetterlund<br />

Micropatterned Surfaces for Atmospheric Water<br />

Condensation via Controlled Radical<br />

Polymerization and Thin Film Dewetting<br />

ACS Applied Materials and Interfaces (<strong>2015</strong>), 7<br />

(38), 21562–21570. Ian Wong,Guo Hui Teo, Chiara<br />

Neto, and Stuart C. Thickett<br />

Macromolecular and Inorganic Nanomaterials<br />

Scaffolds for Carbon Monoxide Delivery: Recent<br />

Developments and Future Trends<br />

ACS Biomaterials Science and Engineering (<strong>2015</strong>), 1<br />

(10), 895–913. Nguyen, Diep; Boyer, Cyrille<br />

Polymerization-Induced Self-Assembly Using<br />

Visible Light Mediated Photoinduced Electron<br />

Transfer-Reversible Addition-Fragmentation Chain<br />

Transfer Polymerization<br />

ACS Macro Letters (<strong>2015</strong>), 4(9), 984-990<br />

Yeow, Jonathan; Xu, Jiangtao; Boyer, Cyrille<br />

Organic Electron Donor-Acceptor Photoredox<br />

Catalysts: Enhanced Catalytic Efficiency toward<br />

Controlled Radical Polymerization<br />

ACS Macro Letters (<strong>2015</strong>), 4(9), 926-932.<br />

Xu, Jiangtao; Shanmugam, Sivaprakash; Boyer,<br />

Cyrille<br />

CO-Releasing Polymers Exert Antimicrobial<br />

Activity<br />

Biomacromolecules (<strong>2015</strong>), 16(9), 2776-2786.<br />

Nguyen, Diep; Nguyen, Thuy-Khanh; Rice, Scott A.;<br />

Boyer, Cyrille<br />

Stereo-, Temporal and Chemical Control through<br />

Photoactivation of Living Radical Polymerization:<br />

Synthesis of Block and Gradient Copolymers<br />

Journal of the American Chemical Society (<strong>2015</strong>),<br />

137(31), 9988-9999.<br />

Shanmugam, Sivaprakash; Boyer, Cyrille<br />

Exploiting Metalloporphyrins for Selective Living<br />

Radical Polymerization Tunable over Visible<br />

Wavelengths<br />

Journal of the American Chemical Society (<strong>2015</strong>),<br />

137(28), 9174-9185. Shanmugam, Sivaprakash; Xu,<br />

Jiangtao; Boyer, Cyrille<br />

Multi-responsive polymers<br />

European Polymer Journal (<strong>2015</strong>), 69, 438-440<br />

Boyer, Cyrille; Hoogenboom, Richard<br />

Inhalable curcumin formulations: Micronization<br />

and bioassay<br />

Chemical Engineering Journal (<strong>2015</strong>), 279,<br />

799-808. Kurniawansyah, Firman; Duong, Hien T.<br />

T.; Luu, Thai Danh; Mammucari, Raffaella; Vittorio,<br />

Orazio; Boyer, Cyrille; Foster, Neil.<br />

Catalyst-free visible light-induced RAFT<br />

photopolymerization<br />

ACS Symposium Series (<strong>2015</strong>), volume 1187,<br />

chapter13, 247-267. Xu, Jiangtao; Shanmugam,<br />

Sivaprakash; Corrigan, Nathaniel Alan; Boyer,<br />

Cyrille<br />

Visible Light Photocatalytic Thiol-Ene Reaction: An<br />

Elegant Approach for Fast Polymer<br />

Postfunctionalization and Step-Growth<br />

Polymerization<br />

Macromolecules (<strong>2015</strong>), 48(3), 520-529<br />

Xu, Jiangtao; Boyer, Cyrille<br />

The use of nanoparticles to deliver nitric oxide to<br />

hepatic stellate cells for treating liver fibrosis and<br />

portal hypertension<br />

Small <strong>2015</strong>, 11(19), 2291-2304<br />

Duong, Hien T. T.; Dong, Zhixia; Su, Lin; Boyer,<br />

Cyrille; George, Jacob; Davis, Thomas P.; Wang,<br />

Jianhua


Publications<br />

in <strong>2015</strong><br />

Nanoparticles Based on Star Polymers as<br />

Theranostic Vectors: Endosomal-Triggered Drug<br />

Release Combined with MRI Sensitivity<br />

Advanced Healthcare Materials (<strong>2015</strong>), 4(1),<br />

148-156. Li, Yang; Duong, Hien T. T.; Laurent,<br />

Sophie; MacMillan, Alexandre; Whan, Renee<br />

Megan; Vander Elst, Luce; Muller, Robert N.; Hu,<br />

Jinming; Lowe, Andrew; Boyer, Cyrille<br />

Utilizing the electron transfer mechanism of<br />

chlorophyll a under light for controlled radical<br />

polymerization<br />

Chemical Science (<strong>2015</strong>), 6(2), 1341-1349.<br />

Shanmugam, Sivaprakash; Xu, Jiangtao; Boyer,<br />

Cyrille<br />

Organo- photocatalysts for photoinduced electron<br />

transfer-reversible addition-fragmentation chain<br />

transfer (PET-RAFT) polymerization<br />

Polymer Chemistry (<strong>2015</strong>), 6(31), 5615-5624<br />

Xu, Jiangtao; Shanmugam, Sivaprakash; Duong,<br />

Hien T.; Boyer, Cyrille<br />

Carbohydrate-Specific Uptake of Fucosylated<br />

Polymeric Micelles by Different Cancer Cell Lines<br />

Biomacromolecules (<strong>2015</strong>), 16 (7), 1948-1957.<br />

K. Babiuch, A. Dag, J. Zhao, H. Lu, M. H. Stenzel<br />

Incorporating ruthenium into advanced drug<br />

delivery carriers-an innovative generation of<br />

chemotherapeutics<br />

Journal of Chemical Technology and Biotechnology<br />

(<strong>2015</strong>), 90, 1177-1195.<br />

B. M. Blunden, M. H. Stenzel<br />

Correlation between Molecular Weight and Branch<br />

Structure of Glycopolymers Stars and Their<br />

Binding to Lectins<br />

Macromolecules (<strong>2015</strong>), 48, 346-357.<br />

Y. Chen, M. S. Lord, A. Piloni, M. H. Stenzel<br />

Polymer-Albumin Conjugate for the Facilitated<br />

Delivery of Macromolecular Platinum Drugs<br />

Macromolecule Rapid Communications (<strong>2015</strong>),<br />

36(10), 890-897<br />

A. Dag, Y. Jiang, K. J. Abd Karim, G. Hart-Smith, W.<br />

Scarano, M. H. Stenzel<br />

Controlling the morphology of glyco-nanoparticles<br />

in water using block copolymer mixtures: the effect<br />

on cellular uptake<br />

Polymer Chemistry (<strong>2015</strong>), 6, 7812-7820<br />

A. Dag, H. Lu, M. H. Stenzel<br />

Origami with ABC Triblock Terpolymers Based on<br />

Glycopolymers: Creation of Virus-Like<br />

Morphologies<br />

ACS Macro Letters (<strong>2015</strong>), 4, 579-583<br />

A. Dag, J. Zhao, M. H. Stenzel<br />

Core-Cross-Linking Accelerates Antitumor<br />

Activities of Paclitaxel-Conjugate Micelles to<br />

Prostate Multicellular Tumor Spheroids: A<br />

Comparison of 2D and 3D Models<br />

Biomacromolecules (<strong>2015</strong>), 16, 1470-1479<br />

A. W. Du, H. Lu, M. H. Stenzel<br />

In Vivo Evaluation of Folate Decorated<br />

Cross-Linked Micelles for the Delivery of Platinum<br />

Anticancer Drugs<br />

Biomacromolecules (<strong>2015</strong>), 16, 515-523.<br />

J. Eliezar, W. Scarano, N. R. B. Boase, K. J. Thurecht,<br />

M. H. Stenzel<br />

An Oligonucleotide Transfection Vector Based on<br />

HSA and PDMAEMA Conjugation: Effect of<br />

Polymer Molecular Weight on Cell Proliferation<br />

and on Multicellular Tumor Spheroids<br />

Macromolecule Bioscience (<strong>2015</strong>), 15, 965-978.<br />

Y. Jiang, C. K. Wong, M. H. Stenzel<br />

Dual-Responsive pH and Temperature Sensitive<br />

Nanoparticles Based on Methacrylic Acid and<br />

Di(ethylene glycol) Methyl Ether Methacrylate for<br />

the Triggered Release of Drugs<br />

Macromolecule Bioscience (<strong>2015</strong>), 15, 1091-1104<br />

Y. Y. Khine, Y. Jiang, A. Dag, H. Lu, M. H. Stenzel<br />

Enhanced transcellular penetration and drug<br />

delivery by crosslinked polymeric micelles into<br />

pancreatic multicellular tumor spheroids<br />

Biomaterial Science (<strong>2015</strong>), 3, 1085-1095<br />

H. Lu, R. H. Utama, U. Kitiyotsawat, K. Babiuch, Y.<br />

Jiang, M. H. Stenzel<br />

Albumin nanoparticles increase the anticancer<br />

efficacy of albendazole in ovarian cancer xenograft<br />

model<br />

Journal of Nanobiotechnology (<strong>2015</strong>), 13-25<br />

L. Noorani, M. Stenzel, R. Liang, M. H.<br />

Pourgholami, D. L. Morris<br />

Glycopolymer Self-Assemblies with Gold(I)<br />

Cornplexed to the Core as a Delivery System for<br />

Auranofin<br />

Macromolecules (<strong>2015</strong>), 48, 1065-1076<br />

S. Pearson, H. Lu, M. H. Stenzel<br />

Light-responsive azobenzene-based glycopolymer<br />

micelles for targeted drug delivery to melanoma<br />

cells<br />

European Polymer Journal (<strong>2015</strong>), 69, 616-627.<br />

S. Pearson, D. Vitucci, Y. Y. Khine, A. Dag, H. Lu, M.<br />

Save, L. Billon, M. H. Stenzel


Publications<br />

in <strong>2015</strong><br />

Dual-drug delivery of curcumin and platinum drugs<br />

in polymeric micelles enhances the synergistic<br />

effects: a double act for the treatment of<br />

multidrug-resistant cancer<br />

Biomaterials Science (<strong>2015</strong>), 3, 163-174.<br />

W. Scarano, P. de Souza, M. H. Stenzel<br />

N-Vinylcarbazole as Versatile Photoinaddimer of<br />

Photopolymerization under Household UV LED<br />

Bulb (392 nm)<br />

Macromolecular Rapid Communications (<strong>2015</strong>), 36,<br />

1675-1680. P. Xiao, J. Lalevee, J. Zhao, M. H.<br />

Stenzel<br />

A new role of curcumin: as a multicolor<br />

photoinitiator for polymer fabrication under<br />

household UV to red LED bulbs<br />

Polymer Chemistry (<strong>2015</strong>), 6, 5053-5061.<br />

J. Zhao, J. Lalevee, H. Lu, R. MacQueen, S. H. Kable,<br />

T. W. Schmidt, M. H. Stenzel, P. Xiao<br />

Prepared from Thermoresponsive Fluorescent<br />

Protein-Polymer Bioconjugates: Capture of and<br />

<strong>Report</strong> on Drug and Protein Payloads<br />

Angewandte Chemie International Edition (<strong>2015</strong>),<br />

54, 5317-5322. C. K. Wong, A. J. Laos, A. H.<br />

Soeriyadi, J. Wiedenmann, P. M. G. Curmi, J. J.<br />

Gooding, C. P. Marquis, M. H. Stenzel, P. Thordarson<br />

Iron oxide nanoparticle-mediated hyperthermia<br />

stimulates dispersal in bacterial biofilms and<br />

enhances antibiotic efficacy<br />

Nature scientific reports (<strong>2015</strong>), 5, Article number:<br />

18385. T.-K. Nguyen, H. TT Duong, R.<br />

Selvanayagam, C. Boyer, N. Barraud


Highlights, Awards<br />

& Other Activities<br />

Awards:<br />

Cyrille Boyer; <strong>2015</strong> Malcolm McIntosh<br />

Prize for Physical Scientist of the Year -<br />

one of the six Prime Minister's Science<br />

Prizes.<br />

Cyrille Boyer; Australian academy of<br />

Science prize - Le Fèvre prize<br />

Siva Shanmugam; Pacifichem <strong>2015</strong> poster<br />

competition winner<br />

Yanyan Jiang; RACI Polymer Division<br />

O’Donnell award<br />

<strong>CAMD</strong> seminar series:<br />

Prof. Dr. Robert Luxenhofer, University of<br />

Wuerzburg, Germany<br />

Prof. Dr. Philipp Vana,<br />

Georg-August-University Göttingen,<br />

Germany<br />

Dr. James Oliver, Colorado School of<br />

Mines, USA<br />

High impact papers:<br />

Utilizing the electron transfer mechanism<br />

of chlorophyll a under light for controlled<br />

radical polymerization<br />

Chemical Science (<strong>2015</strong>), 6(2), 1341-1349.<br />

Shanmugam, Sivaprakash; Xu, Jiangtao;<br />

Boyer, Cyrille<br />

Controlled/Living Radical Polymerization<br />

in Dispersed Systems: An Update<br />

Chemical Reviews, <strong>2015</strong>,115 (18),<br />

9745-9800<br />

Per B. Zetterlund, Stuart C. Thickett,<br />

Sébastien Perrier, Elodie Bourgeat-Lami,<br />

Muriel Lansalot<br />

Exploiting Metalloporphyrins for<br />

Selective Living Radical Polymerization<br />

Tunable over Visible Wavelengths<br />

Journal of the American Chemical Society<br />

(<strong>2015</strong>), 137(28), 9174-9185<br />

Shanmugam, Sivaprakash; Xu, Jiangtao;<br />

Boyer, Cyrille<br />

Stereo-, Temporal and Chemical Control<br />

through Photoactivation of Living Radical<br />

Polymerization: Synthesis of Block and<br />

Gradient Copolymers<br />

Journal of the American Chemical Society<br />

(<strong>2015</strong>), 137(31), 9988-9999.<br />

Shanmugam, Sivaprakash; Boyer, Cyrille


Highlights, Awards<br />

& Other Activities<br />

Recognition and Services:<br />

Cyrille Boyer selected as one of the 100<br />

Innovators by Knowledge of Nation<br />

Per Zetterlund appearing as Expert<br />

Witness (topic: coatings) in hearing in<br />

Melbourne in April<br />

Cyrille Boyer nominated as High-end<br />

Foreign Experts by Chinese Government<br />

and invited professorship in China at<br />

Qingdao University, Shandong, China<br />

Cyrille Boyer - invited professorship in<br />

France (Ecole Nationale Superieur de<br />

Chimie de Montpellier, University of<br />

Montpellier)<br />

Editorial Publications:<br />

Cyrille Boyer - Guest editor role: Special<br />

issue on Stimuli Responsive Polymers<br />

published by European Polymer Journal<br />

Cyrille Boyer - Associate Editor for RSC<br />

Advanced since August <strong>2015</strong><br />

Martina Stenzel - Associate editor for<br />

Beilstein Journal of Nanotechnology<br />

Martina Stenzel - Publication committee<br />

of Materials Research Society<br />

Per Zetterlund co-organizing symposium<br />

entitled “Radical Polymerization Kinetics<br />

and Process Modelling” at Pacifichem in<br />

Dec 15 (Hawaii)<br />

Per Zetterlund / Anthony Granville – 1<br />

day Polymer Research in NSW<br />

symposium (UNSW)<br />

Martina Stenzel - Short film on UNSW<br />

TV<br />

Martina Stenzel - Postgraduate<br />

coordinator in the school of chemistry


Highlights, Awards<br />

& Other Activities<br />

Invited keynote presentations:<br />

Cyrille Boyer; invited by Chinese<br />

Government as International Expert in<br />

<strong>2015</strong> (Lecture tour in China - Fudan,<br />

Shanghai Univeristy, Qiangdao University,<br />

Shanghai Jiao Tong, Beijing Institute of<br />

Technology, Beijing University of Chemical<br />

Technology, Soochow University)<br />

Martina Stenzel; Polymer Pacific<br />

Conference, 8th to 12th December <strong>2015</strong>,<br />

Hawaii, US<br />

Seminars by <strong>CAMD</strong> researchers:<br />

Per Zetterlund; Kobe University (Japan)<br />

Per Zetterlund; Osaka City University<br />

(Japan)<br />

Cyrille Boyer; invited lectures at Polymer<br />

Advanced Technology <strong>2015</strong> (June <strong>2015</strong>,<br />

Hangzhou, China)<br />

Cyrille Boyer; invited lectures at American<br />

Chemical Society National Conference in<br />

<strong>2015</strong><br />

Cyrille Boyer; invited lecture at PACIFIC<br />

CHEM in <strong>2015</strong> (Hawaii, USA)<br />

Cyrille Boyer; invited lecture at Fusion<br />

conference in <strong>2015</strong> (Ascott, UK)<br />

Cyrille Boyer; invited lecture at<br />

APNGM15, Sept <strong>2015</strong>, Budapest, Hungry<br />

Martina Stenzel; invited lectures at<br />

Congress of European Polymer Federation<br />

(June <strong>2015</strong>, Dresden, Germany)<br />

Martina Stenzel; invited lectures at<br />

Functional Polymeric Materials, August<br />

<strong>2015</strong>, (August <strong>2015</strong>, Ascot, UK )<br />

Martina Stenzel; invited lectures at ACS<br />

meeting Polymers in Medicine<br />

(September <strong>2015</strong>, US)<br />

Martina Stenzel; invited lectures at<br />

NanoDDS (September <strong>2015</strong>, US)<br />

Martina Stenzel; 24th <strong>Annual</strong> Meeting of<br />

the Australian Society of Biomaterials and<br />

Tissue Engineering, 7 - 10 April <strong>2015</strong>,<br />

Sydney, Australia<br />

Martina Stenzel; 35th Australian Polymer<br />

Symposium, 12th – 15th July <strong>2015</strong>, Gold<br />

Coast, Australia

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!