Crimea TITAN. New developments for the new advancement: Special TiO2 Grades for Coatings, Plastics and Décor Paper from New Plant (ASEFAPI. XXV Congreso Técnico Barcelona, 7 de Noviembre de 2013).
NEW DEVELOPMENTS FOR THE NEW ADVANCEMENT: SPECIAL TIO2 GRADES FOR COATINGS, PLASTICS AND DECOR PAPER FROM NEW PLANT CRIMEA TITAN / EMSA TECNOLOGÍA QUÍMICA, S.A.U. Sr. Andriy Gonchar, Head of R&D Department Crimea Titan Sr. David Roldán, Coatings and Construction Country Manager EMSA Tecnología Química S.A.U - https://servireach.com/files/2113/8366/5682/SERVIREACH_ASEFAPI_2013.pdf
NEW DEVELOPMENTS FOR THE
NEW ADVANCEMENT: SPECIAL
TIO2 GRADES FOR COATINGS,
PLASTICS AND DECOR PAPER
FROM NEW PLANT
CRIMEA TITAN / EMSA
TECNOLOGÍA QUÍMICA, S.A.U.
Sr. Andriy Gonchar, Head of R&D
Department Crimea Titan
Sr. David Roldán, Coatings and
Construction Country Manager EMSA
Tecnología Química S.A.U - https://servireach.com/files/2113/8366/5682/SERVIREACH_ASEFAPI_2013.pdf
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CRIMEA <strong>TITAN</strong><br />
<strong>Crimea</strong> Titan.<br />
<strong>New</strong> Developments <strong>for</strong> <strong>the</strong> <strong>New</strong><br />
Advancement: <strong>Special</strong> TiO 2 <strong>Gra<strong>de</strong>s</strong><br />
<strong>for</strong> <strong>Coatings</strong>, <strong>Plastics</strong> <strong>and</strong> <strong>Décor</strong><br />
<strong>Paper</strong> <strong>from</strong> <strong>New</strong> <strong>Plant</strong><br />
Andriy Gonchar, Head of R&D Department
CRIMEA <strong>TITAN</strong><br />
In 2006 R&D Department of <strong>Crimea</strong> Titan has started<br />
intensive researches <strong>for</strong> <strong>de</strong>velopment of <strong>the</strong> <strong>new</strong> premium<br />
gra<strong>de</strong>s of titanium dioxi<strong>de</strong> <strong>for</strong> different applications:<br />
- Paints <strong>and</strong> <strong>Coatings</strong><br />
- <strong>Plastics</strong><br />
- Laminate <strong>Paper</strong><br />
In 2012 year project was launched <strong>for</strong> building of <strong>the</strong> <strong>new</strong><br />
plant <strong>for</strong> titanium dioxi<strong>de</strong> manufacturing in Armyansk,<br />
<strong>Crimea</strong>, Ukraine.<br />
Approximate period of project works <strong>and</strong> building is 2012-<br />
2015<br />
<strong>New</strong> plant capacity will be 120 000 MT per year<br />
2
CRIMEA <strong>TITAN</strong><br />
Geographical location of <strong>the</strong> <strong>new</strong> TiO 2 plant<br />
CRIMEA <strong>TITAN</strong><br />
Ukraine,<br />
AR <strong>Crimea</strong>,<br />
Armyansk
CRIMEA <strong>TITAN</strong><br />
Geographical location of <strong>the</strong> <strong>new</strong> TiO 2 plant<br />
Place <strong>for</strong> construction of<br />
<strong>the</strong> <strong>new</strong> plant <strong>for</strong> TiO 2<br />
manufacturing<br />
4
CRIMEA <strong>TITAN</strong><br />
Old buildings be<strong>for</strong>e <strong>the</strong> construction of a <strong>new</strong> TiO 2 plant<br />
5
CRIMEA <strong>TITAN</strong><br />
Old buildings be<strong>for</strong>e <strong>the</strong> construction of a <strong>new</strong> TiO 2 plant<br />
6
CRIMEA <strong>TITAN</strong><br />
April <strong>2013</strong>: tear-down of <strong>the</strong> old buildings be<strong>for</strong>e <strong>the</strong> construction of a <strong>new</strong> TiO 2 plant<br />
7
CRIMEA <strong>TITAN</strong><br />
April <strong>2013</strong>: tear-down of <strong>the</strong> old buildings be<strong>for</strong>e <strong>the</strong> construction of a <strong>new</strong> TiO 2 plant<br />
8
CRIMEA <strong>TITAN</strong><br />
April <strong>2013</strong>: tear-down of <strong>the</strong> old buildings be<strong>for</strong>e <strong>the</strong> construction of a <strong>new</strong> TiO 2 plant<br />
9
CRIMEA <strong>TITAN</strong><br />
May <strong>2013</strong>: tear-down of <strong>the</strong> old buildings be<strong>for</strong>e <strong>the</strong> construction of a <strong>new</strong> TiO 2 plant<br />
10
CRIMEA <strong>TITAN</strong><br />
May <strong>2013</strong>: tear-down of <strong>the</strong> old buildings be<strong>for</strong>e <strong>the</strong> construction of a <strong>new</strong> TiO 2 plant<br />
11
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> TiO 2 plant according to <strong>the</strong> Basic Design<br />
12
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> TiO 2 plant according to <strong>the</strong> Basic Design<br />
13
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> TiO 2 plant according to <strong>the</strong> Basic Design<br />
14
CRIMEA <strong>TITAN</strong><br />
The <strong>new</strong> titanium dioxi<strong>de</strong> plant is:<br />
• High environmental st<strong>and</strong>ards<br />
• High-effective energy consumption<br />
• Manufacturing of high quality TiO 2 gra<strong>de</strong>s<br />
<strong>for</strong> different specific applications<br />
15
CRIMEA <strong>TITAN</strong><br />
What are <strong>the</strong> products of <strong>the</strong> <strong>new</strong> TiO 2 plant?<br />
Four<br />
<strong>Gra<strong>de</strong>s</strong><br />
<strong>for</strong> Paints<br />
<strong>and</strong><br />
<strong>Coatings</strong><br />
Three<br />
<strong>Gra<strong>de</strong>s</strong><br />
<strong>for</strong><br />
<strong>Plastics</strong><br />
One<br />
Gra<strong>de</strong> <strong>for</strong><br />
<strong>Décor</strong><br />
<strong>Paper</strong><br />
16
CRIMEA <strong>TITAN</strong><br />
Four <strong>New</strong> TiO 2 <strong>Gra<strong>de</strong>s</strong><br />
<strong>for</strong><br />
Paints <strong>and</strong> <strong>Coatings</strong>.<br />
17
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
TIOXIDE TR92<br />
<strong>Crimea</strong> TiOx-295<br />
KRONOS 2315<br />
PRETIOX RGZW<br />
TIOXIDE TR81<br />
TIONA 595<br />
PROPERTIES<br />
•Easy Dispersibility<br />
•High Opacity<br />
•Good Initial Gloss<br />
•Good Gloss Retention<br />
•High Durability<br />
APPLICATION<br />
•Automotive finishes <strong>and</strong> refinishes<br />
•Coil <strong>Coatings</strong><br />
•Pow<strong>de</strong>r coatings<br />
•Marine <strong>Coatings</strong><br />
TRONOX R-KB-6<br />
TRONOX CR-828<br />
18
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
<strong>Crimea</strong> TiOx-295<br />
TiO 2<br />
Content<br />
Inorganic coating<br />
Organic treatment<br />
93-95% typical<br />
Alumina, Zirconia<br />
present<br />
Loss at 105 o C
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
DuPont TS-6200<br />
<strong>Crimea</strong> TiOx-225<br />
TIONA 696<br />
DuPont R960<br />
TIONA RCL-6<br />
TIONA RCL-9<br />
TIONA 596<br />
PROPERTIES<br />
•Dispersibility<br />
•High Opacity<br />
•Good Gloss Retention<br />
•Superior Durability<br />
APPLICATION<br />
•Exterior <strong>Coatings</strong><br />
•Automotive Finishes <strong>and</strong> Refinishes<br />
•Coil <strong>Coatings</strong><br />
•Pow<strong>de</strong>r <strong>Coatings</strong><br />
•Marine <strong>Coatings</strong><br />
•Aerospace <strong>Coatings</strong><br />
KRONOS 2160<br />
KRONOS 2360<br />
TRONOX CR-880<br />
TRONOX CR-826<br />
20
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
<strong>Crimea</strong> TiOx-225<br />
TiO 2<br />
Content<br />
Inorganic coating<br />
Organic treatment<br />
91-93% typical<br />
Alumina, Silica<br />
present<br />
Loss at 105 o C
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
Kemira RDI<br />
<strong>Crimea</strong> TiOx-275<br />
KRONOS 2020<br />
Kemira RODI<br />
Tiona 568<br />
DuPont R900<br />
PRETIOX RGU<br />
PROPERTIES<br />
•Excellent Dispersibility<br />
•High Opacity<br />
•High Gloss<br />
•Low Oil Absorption<br />
•Low conductivity<br />
APPLICATION<br />
•Electro<strong>de</strong>position paints<br />
•Automotive (Primers)<br />
•Can <strong>Coatings</strong><br />
•Coil <strong>Coatings</strong><br />
•Water-borne <strong>and</strong> Solvent-borne<br />
Industrial <strong>and</strong> Decorative <strong>Coatings</strong><br />
•Wood Paints<br />
•Rubber<br />
•<strong>Plastics</strong> (usable)<br />
•Can use in Printing Inks<br />
Sachtleben R210<br />
TRONOX CR-800<br />
TRONOX R-KB-3<br />
TIOXIDE R-TC-90<br />
22
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
<strong>Crimea</strong> TiOx-275<br />
TiO 2 Content<br />
Inorganic coating<br />
Organic treatment<br />
94-96% typical<br />
Alumina<br />
present<br />
Loss at 105oC
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
Kemira RDI-S<br />
<strong>Crimea</strong> TiOx-275S<br />
KRONOS 2063<br />
Ishihara R630<br />
PRETIOX RX-I<br />
PROPERTIES<br />
•Super Dispersibility<br />
•High Opacity<br />
•Excellent High Gloss<br />
•Low Oil Absorption<br />
•Blue un<strong>de</strong>rtone<br />
APPLICATION<br />
•Printing Inks<br />
•Can <strong>Coatings</strong><br />
•Coil <strong>Coatings</strong><br />
•Wood Paints<br />
•Water-born or solvent-born coatings<br />
with very high gloss<br />
KRONOS 2090<br />
TRONOX R-FD-I<br />
TIOXIDE TR52<br />
24
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PAINTS <strong>and</strong> COATINGS<br />
<strong>Crimea</strong> TiOx-275S<br />
TiO 2 Content<br />
Inorganic coating<br />
Organic treatment<br />
94-96% typical<br />
Alumina<br />
present<br />
Loss at 105oC
CRIMEA <strong>TITAN</strong><br />
Three <strong>New</strong> TiO 2 <strong>Gra<strong>de</strong>s</strong><br />
<strong>for</strong> <strong>Plastics</strong><br />
26
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PLASTICS<br />
DuPont R104<br />
KRONOS 2230<br />
KRONOS 2500<br />
TIOXIDE TR-23<br />
TIOXIDE R-FC5<br />
TIOXIDE TR28<br />
TIOXIDE TR38<br />
<strong>Crimea</strong> TiOx-106<br />
PROPERTIES<br />
•Outst<strong>and</strong>ing Dispersion <strong>and</strong><br />
Processing<br />
•High Hydrophobic feature<br />
•No Migration of Organic Compound<br />
•Lacing Resistance<br />
•High Opacity<br />
•Blue Tint Tone <strong>and</strong> High Brightness<br />
APPLICATION<br />
•Polyolefin Masterbatch<br />
•Flexible PVC (interior)<br />
•High Temperature Cast Films<br />
•Thin Films<br />
TIONA 125<br />
TIONA 188<br />
TRONOX R-FK-2<br />
TRONOX CR-470<br />
TRONOX 834<br />
TRONOX 8400<br />
27
CRIMEA <strong>TITAN</strong><br />
<strong>Crimea</strong> TiOx-106<br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PLASTICS<br />
TiO 2<br />
Content<br />
Inorganic coating<br />
Organic treatment<br />
97-98% typical<br />
Alumina<br />
present<br />
Loss at 105 o C
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PLASTICS<br />
KRONOS 2211<br />
<strong>Crimea</strong> TiOx-276<br />
TIONA RL-91<br />
KRONOS 2225<br />
KRONOS 2233<br />
KRONOS 2450<br />
PROPERTIES<br />
•Excellent Dispersion <strong>and</strong><br />
processibility<br />
•High Hydrophobic feature<br />
•No Migration of Organic Compound<br />
•High Opacity<br />
•Blue Tint Tone <strong>and</strong> High Brightness<br />
APPLICATION<br />
•Polyolefin Masterbatch<br />
•Polyethylene<br />
•Polypropylene<br />
•PVC (Interior)<br />
•PVC (Exterior, Chalking)<br />
•PVC Pipe<br />
TIONA 90<br />
KEMIRA 405<br />
DuPont R350<br />
29
CRIMEA <strong>TITAN</strong><br />
<strong>Crimea</strong> TiOx-276<br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PLASTICS<br />
TiO 2<br />
Content<br />
Inorganic coating<br />
Organic treatment<br />
95-96% typical<br />
Alumina<br />
present<br />
Loss at 105 o C
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PLASTICS<br />
TRONOX R-FK-3<br />
TRONOX 435<br />
KRONOS 2220<br />
KRONOS 2222<br />
<strong>Crimea</strong> TiOx-226<br />
PROPERTIES<br />
•Easily Incorporated in Vinyl <strong>and</strong><br />
Polyolefins<br />
•Minimized Hygroscopic Property<br />
•Excellent Color Retention<br />
•No Migration of Organic Compound<br />
•High Durability<br />
•Good Chalk Resistance<br />
•Effective UV Screen<br />
APPLICATION<br />
•PVC (Exterior, Nonchalking)<br />
•Agricultural Films<br />
•Outdoor Furniture<br />
•PVC Plastisol<br />
TIONA 168<br />
TIOXIDE R-TC30<br />
DuPont R105<br />
31
CRIMEA <strong>TITAN</strong><br />
<strong>Crimea</strong> TiOx-226<br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong>s <strong>for</strong> PLASTICS<br />
TiO 2<br />
Content<br />
Inorganic coating<br />
Organic treatment<br />
91-93% typical<br />
Alumina, Silica<br />
present<br />
Loss at 105 o C
CRIMEA <strong>TITAN</strong><br />
One <strong>New</strong> TiO 2 Gra<strong>de</strong><br />
<strong>for</strong> <strong>Décor</strong> <strong>Paper</strong><br />
33
CRIMEA <strong>TITAN</strong><br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong> <strong>for</strong> <strong>Décor</strong> PAPER<br />
KRONOS 2081<br />
<strong>Crimea</strong> TiOx-350<br />
TRONOX 820<br />
KRONOS 2800<br />
KRONOS 2087<br />
PROPERTIES<br />
•Outst<strong>and</strong>ing Greying Resistance<br />
to <strong>Paper</strong> Laminate<br />
•Good Yellowing Resistance to High<br />
<strong>and</strong> Low Pressure Laminate<br />
•Excellent Opacity<br />
•Dispersed readily in Water<br />
Crenox R-PL-2<br />
Sachtleben R610L<br />
KRONOS 2084<br />
TIONA RCL-722<br />
APPLICATION<br />
•High <strong>and</strong> Low Pressure<br />
Laminate<br />
•Printing Inks <strong>for</strong> <strong>Décor</strong> <strong>Paper</strong><br />
•Melamine moulding pow<strong>de</strong>rs<br />
DuPont R796+<br />
DuPont R794<br />
34
CRIMEA <strong>TITAN</strong><br />
<strong>Crimea</strong> TiOx-350<br />
<strong>New</strong> <strong>TiO2</strong> gra<strong>de</strong> <strong>for</strong> <strong>Décor</strong> PAPER<br />
TiO 2<br />
Content<br />
Inorganic coating<br />
Organic treatment<br />
87-90% typical<br />
Aluminium Compounds<br />
none<br />
Loss at 105 o C
CRIMEA <strong>TITAN</strong><br />
What is planned capacity of manufacturing of<br />
different TiO 2 gra<strong>de</strong>s?<br />
Four<br />
<strong>Gra<strong>de</strong>s</strong><br />
<strong>for</strong> Paints<br />
<strong>and</strong><br />
<strong>Coatings</strong><br />
Three<br />
<strong>Gra<strong>de</strong>s</strong><br />
<strong>for</strong><br />
<strong>Plastics</strong><br />
One<br />
Gra<strong>de</strong> <strong>for</strong><br />
<strong>Décor</strong><br />
<strong>Paper</strong><br />
40 000 MT<br />
per year<br />
40 000 MT<br />
per year<br />
40 000 MT<br />
per year<br />
36
CRIMEA <strong>TITAN</strong><br />
THANK YOU<br />
FOR YOUR ATTENTION!
CRIMEA <strong>TITAN</strong><br />
For all fu<strong>the</strong>r questions of supply on Spanish market please get in<br />
touch with our exclusive distributor in Spain – company<br />
EMSA TECNOLOGIA QUIMICA SAU<br />
Headquarters<br />
Av. Diagonal, 662-664 <strong>Plant</strong>a 2ª Módulo B 08028 <strong>Barcelona</strong><br />
Tel. +34 934 701 196 Fax. +34 933 718 428<br />
emsaquimica@emsaquimica.com · www.emsaquimica.com<br />
<strong>Crimea</strong> Titan, PJSC<br />
info@titanexport.com<br />
www.titanexport.com
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