PACS MSDS EN

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Safety Data Sheet Acc. to EU Regulations 1907/2006 (REACH), 1272/2008 [CLP] and 2015/830 Product Name : Polyaluminium chloride hydroxide sulfate Date of issue : 28 July 2015 SDS No : SDS-ACH-01 Revision Date : 04 July 2016 Revision No : 01 Page No : 4 / 12 6.1.2 For emergency responders : Wear protective equipment. Protect the eyes, skin and mucous membranes from the exposure. Take all necessary precautions if slippery action on the ground occurs. 6.2 Environmental precautions : Keep away from drains, surface and ground water and soil. Do not allow material to be released to the environment without proper official permits. See section 13 for disposal. 6.3 Methods and material for containment and cleaning up 6.3.1 For containment : No special measure is required. Material itself is coagulant with basic character. For containment sand or soil will be enough. It is suggested to keep sufficient containment material on site. 6.3.2 For cleaning up : Following the clean up, flush the area with water to get rid of slippery action. Do not use solvents for cleaning. Ventilate area after cleaning. Wash water does not cause any harm on industrial water treatment facilities. İn case of biological water treatment systems, dilution with water is recommended. Amount of dilution, in order to overcome the effect on the activated sludge, varies w.r.to the structure of the biological treatment systems. 6.3.3 Other information : In case of long term exposures, irritation may develop on skin, eye and mucous membranes. If spillage forms pond, access to this spill site should be prevented up to the total cleaning-disposal of this spill. 6.4 Reference to other sections : See sections 7-8 and section 13 7. Handling and storage 7.1 Precautions for safe handling 7.1.1 Protective measures Measures to prevent fire : There are no fire or explosion hazards of the material. No special measures required to prevent fire. Measures to prevent aerosol and dust generation : The packaging should not have leaks, keep containers tightly closed. In case of deformed packaging, make handling after spill control. Use PPE during handling and usage. Measures to protect the environment : Keep away from drains, surface and ground water and soil. Do not allow material to be released to the environment without proper official permits. 7.1.2 Advice on general occupational hygiene : Smoking, eating and drinking should be prohibited in application areas. Avoid spillage and migration of material on wheels. Wash hands thoroughly after use and handling. Remove contaminated clothing and personal protective equipment before entering the eating areas. 7.2 Conditions for safe storage, including any incompatibilities Technical measures and storage conditions : Do not store together with acids and oxidizing agents. The solutions of aluminium compounds may hydrolyze. PACS of ACH Ltd has low tendency to hydrolyze. Prevent contact with chlorites, hypochlorites, sulfites. Incompatible also with Iron salts, aluminium sulfate and other polyaluminium salts. Necessary precautions should be taken in order to prevent mixing with these incompatible materials PACS should not be stored together with all of the incompatible material listed above. Packaging materials : PACS may cause reaction and corrosion on the surface of some metals (Aluminium, copper, zinc, and alloys of these , galvanized metals). Therefore plastic (PE, PVC, PP etc.) or fiberglass containers should be used. Requirements for storage rooms and vessels : Store in well ventilated storage rooms. Even though this material is classified as non-hazardous for transportation, it is recommended to take necessary general precautions for transportation. It can be transported as bulk liquid in the plastic containers (IBC). It should be kept in its original containers in the storage area and spill should be prevented. Storage class : Not applicable
Safety Data Sheet Acc. to EU Regulations 1907/2006 (REACH), 1272/2008 [CLP] and 2015/830 Product Name : Polyaluminium chloride hydroxide sulfate Date of issue : 28 July 2015 SDS No : SDS-ACH-01 Revision Date : 04 July 2016 Revision No : 01 Page No : 5 / 12 Further information on storage conditions : Store in cool and dry conditions in well closed containers. Temperature of storage area should not exceed 55 o C. 7.3 Specific end use(s) Recommendations : PACS is a flocculant-coagulant for the treatment of water used for human consumption – drinking and use. PACS complies the specifications set by the Standard EN883 (2004). Industrial sector specific solutions : No data available. 8. Exposure controls/personal protection 8.1 Control parameters Occupational exposure limit values : No data available for PACS which is a substance in liquid form REL value of solid forms of Soluble Aluminum salts were given below for info only. OSHA PEL = no data available , ACGIH TLV = No data available NIOSH REL –TWA (8hr) (as Al) powder = 2 mg/m3 irritation, respiration. 8.2 Exposure controls 8.2.1 Appropriate engineering controls : Substance/mixture related measures to prevent exposure during identified uses: General hygiene practice and correct usage of PPE is sufficient. As a good practice; wash hands after handling, remove the contaminated clothing and material. Do not smoke, do not eat-drink during handling and usage. Structural measures to prevent exposure: No special structural measure required. facilities can be used. Secondary containment for the storage areas will be a good practice. Relevant storage Organizational measures to prevent exposure: (Administrative) Eye protection, skin protection, breathing protection, confined space entry procedures, PPE usage procedures are necessary. Administrative measures should be taken in order to minimize the exposure amount and period to least possible levels. Technical measures to prevent exposure: (Engineering) There are no engineering measure other than secondary containment. 8.2.2 Personal protection equipment : 8.2.2.1 Eye and face protection: Safety glasses ( as per Standard ISO EN 166) 8.2.2.2 Skin protection: Protective clothing (as per Standard ISO EN 471) Hand protection: Rubber gloves (Work gloves as per Standard ISO EN 374 and 388) . Other skin protection: Safety shoes (as per Standards EN 345-1 or EN 20345 S3 for shoes and S5 for boots) 8.2.2.3 Respiratory protection: Substance is in liquid form. In normal use breathing protection is not necessary. In case of aerosols and exposure of dried material, prevent exposure by using FFP1 dust masks as per standard ISO EN 149:2001 and CE0086. 8.2.2.4 Thermal hazards: There are no thermal hazard of PACS 8.2.3 Environmental exposure controls
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