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Alexander Barcza

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CoMnSi-based metamagnets CoMnSi<br />

The metamagnet – CoMnSi<br />

sample was quenched from 1000 ◦ C<br />

60.0<br />

M (Am 2 /kg)<br />

50.0<br />

40.0<br />

30.0<br />

20.0<br />

10.0<br />

4000 Oe<br />

0.0<br />

100 200 300 400 500 600<br />

T (K)<br />

Bińczycka et al., phys. stat. sol. (a) 35 K69 (1976)<br />

Johnson et al., phys. stat. sol (a) 20 331 (1973)<br />

Nizioł et al., phys. stat. sol. (a) 45 591 (1978)<br />

There are 3 phase transitions in CoMnSi<br />

antiferro- to ferromagnetic<br />

(metamagnetic) phase transition<br />

at Tt = 200 − 360 K,<br />

ferro- to paramagnetic phase<br />

transition at T C 410 K,<br />

orthorhombic to hexagonal<br />

structural phase transition at<br />

Tstructural = 917 ◦ C.<br />

! phase transition temperatures are very<br />

sample dependent !<br />

A <strong>Barcza</strong>, K G Sandeman (DMG) CoMnSi-based magnetocaloric compounds 14th August 2007 8 / 27

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