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Water & Wastewater Asia September/October 2022

Water & Wastewater Asia is an expert source of industry information, cementing its position as an indispensable tool for trade professionals in the water and wastewater industry. As the most reliable publication in the region, industry experts turn this premium journal for credible journalism and exclusive insight provided by fellow industry professionals. Water & Wastewater Asia incorporates the official newsletter of the Singapore Water Association (SWA).

Water & Wastewater Asia is an expert source of industry information, cementing its position as an indispensable tool for trade professionals in the water and wastewater industry. As the most reliable publication in the region, industry experts turn this premium journal for credible journalism and exclusive insight provided by fellow industry professionals. Water & Wastewater Asia incorporates the official newsletter of the Singapore Water Association (SWA).

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SINGAPORE FOCUS<br />

MARICULTURE WATER RECYCLING<br />

3E-NF membrane has been used for<br />

seawater fish farm wastewater recycling,<br />

laundry wastewater recycling, municipal<br />

wastewater recycling for cooling tower<br />

feed water, and more. In particular, the<br />

membrane is suited for desalination pretreatment.<br />

The 3E NF membrane module<br />

Desalination plants generally use two types<br />

of membranes: UF as a pre-treatment<br />

to remove suspended particles, and RO<br />

to remove the dissolved solids. The UF<br />

membrane pre-treatment for the seawater<br />

desalination is unable to remove hardness<br />

and the majority of organic pollution, and<br />

consequently the RO system is prone to<br />

fouling and scaling. This leads to more<br />

production downtime for the RO system<br />

cleaning and maintenance as well. While<br />

the water industry has been assessing<br />

the removal of hardness through NF<br />

membranes for a long time, no spiral-wound<br />

NF membrane can replace the existing<br />

UF membranes due to the space and flux<br />

constraints.<br />

On the other hand, HF NF membranes<br />

improve desalination pre-treatment.<br />

As they have the same configuration<br />

as UF membranes and are capable of<br />

removing hardness, they are a one-toone<br />

replacement that will reduce the<br />

overall capital and operating expense<br />

of the desalination plants. With a wide<br />

range of salt rejections to better suit<br />

difficult feedwater qualities and permeate<br />

standards, 3E NF membranes, can deliver<br />

clean water with valuable ions preserved.<br />

One of the company’s products was used in<br />

a seawater fish farm to achieve low energy<br />

water recycling in Singapore. Led by the<br />

Singapore government and Singapore<br />

Fish Culture Association, along with Ngee<br />

Ann Polytechnic’s Environmental & <strong>Water</strong><br />

Technology Centre of Innovation, Aquarium<br />

Iwarna, a marine ornamental fish import<br />

and export company, cooperated with 3E<br />

for the commissioning and installation of a<br />

nanofiltration membrane wastewater reuse<br />

system offering a 0.5m 3 /h capacity.<br />

The system delivered the following<br />

specifications:<br />

• Feed: 38,000.0ppm<br />

• Flux: 0.4±0.5 litres per hour<br />

• Salt rejection: 20±0.3% (2000ppm<br />

MgSO 2<br />

)<br />

• Operational pressure: 2.0 bar<br />

With the 3E nanofiltration membrane, water<br />

can be taken directly from the fish pond,<br />

reducing equipment and overall operation<br />

costs. More than that, the 3E-NF can<br />

remove green algae via a variety of methods,<br />

including backwashing, resulting in a more<br />

stable system operation, in contrast to<br />

conventional nanofiltration and reverse<br />

osmosis membranes which are sensitive and<br />

prone to the blooming of green algae in sea<br />

water.<br />

SUPPORTING WATER RECLAMATION<br />

With up to 40LMH/bar flux, 3E-NF05<br />

can also be used to achieve one-to-one<br />

replacement of the traditional UF membrane<br />

for the seawater desalination to reduce the<br />

RO membrane fouling and scaling issue<br />

without any footprint enlarge.<br />

In another project, a 3E-NF05 HF<br />

membrane system, with a 2,000m 3 per<br />

day capacity NF-RO membrane system<br />

design for cooling tower feed water, was<br />

supplied, commissioned, and installed for<br />

the Shangdong Kytoland <strong>Water</strong>tech. The<br />

organisation had decided to use this system<br />

in order to reduce demand of the Anqiu<br />

thermal power plant for tap water, and to<br />

preserve current drinking water resources.<br />

After careful investigation, the 3E NF-RO<br />

membrane was utilised in 2020 to treat<br />

the reclaimed water, meeting discharge<br />

standards; it was used for the cooling<br />

tower’s water at the thermal power plant<br />

after reaching the same standards as well.<br />

With the NF-RO reclaimed water treatment<br />

equipment, 3E thus attained its first<br />

reclaimed water reuse project.<br />

The system thus presented the following<br />

parameters:<br />

• Effective membrane area: 61.0m 2<br />

• <strong>Water</strong> flow rate: 128±0.5 ton/day per bar<br />

• Operation pressure: Maximum 3.0 bar<br />

• Salt rejection: 2000ppm; MgSO 4<br />

: 10±1%<br />

• Maximum free-chloride resistance:<br />

1000ppm<br />

With the 3E-NF membranes, the overall<br />

system will be able to run in a more stable<br />

manner with a low maintenance cost. This<br />

is due to the compact surface which is<br />

not easily polluted, while also offering a<br />

membrane flux that is close to ultrafiltration<br />

membranes. In comparison, ultrafiltration<br />

membranes offer a molecular weight<br />

rejection rate of more than 5000da, which<br />

cannot intercept the hardness of and organic<br />

matter in water, resulting in the scaling and<br />

pollution of the back RO membrane.<br />

In addition, the 3E-NF membrane can<br />

be used in a variety of ways, including<br />

backwash to remove biological pollutants,<br />

among others; its operating conditions<br />

are also similar to those of ordinary<br />

ultrafiltration membranes. Altogether, the<br />

use of 3E-NF has supported a more reliable,<br />

stable and feasible reuse of municipal<br />

wastewater.<br />

WATER & WASTEWATER ASIA | SEPTEMBER/OCTOBER <strong>2022</strong> 13

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