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XIII European Conference on the Spectroscopy of ... - ecsbm 2009

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Palermo, August 28 – September 2, <strong>2009</strong> 13 th ECSBM −−−− Book <strong>of</strong> Abstracts<br />

Tracking structural changes in soluti<strong>on</strong> with 100 ps<br />

time-resolved X-ray scattering<br />

MARCO CAMMARATA<br />

ESRF, Grenoble, France<br />

Reacti<strong>on</strong>s are at <strong>the</strong> core <strong>of</strong> life and chemistry. The fast time scales usually involved have<br />

prevented direct structural studies up to very recently. In <strong>the</strong> last years <strong>the</strong> intrinsicly pulsed<br />

nature <strong>of</strong> synchrotr<strong>on</strong> sources has been used to allow laser pump / x-ray probe studies with a time<br />

resoluti<strong>on</strong> <strong>of</strong> 100ps.<br />

Examples coming from chemistry and biophysics will be discussed toge<strong>the</strong>r with <strong>the</strong> key<br />

ingredients <strong>of</strong> <strong>the</strong> experimental technique.<br />

X-ray free electr<strong>on</strong> lasers will allow to push <strong>the</strong> time resoluti<strong>on</strong> even fur<strong>the</strong>r but wavelength and<br />

positi<strong>on</strong> stability, toge<strong>the</strong>r with o<strong>the</strong>r beam characteristics, will be crucial for <strong>the</strong> success <strong>of</strong> such<br />

experiments.<br />

References<br />

[1] Cammarata, M. et al., Nature Methods, 5, 881 (2008)<br />

[2] Ihee, H. et al., Science, 309, 1223 (2005)<br />

[3] Cammarata, M et al., Rev. Sci. Instrum. 80: 015101 (<strong>2009</strong>)<br />

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