Download MSDS of furfuryl alcohol - International Furan Chemicals BV

EU SAFETY DATA SHEET 

according to Regulation (EC) N° 1907/2006 and 453/2010 

Furfuryl Alcohol 

1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY 

1.1 

1.2 

1.3 

1.4 

Product identifier 

Chemical name 2-Furanmethanol 

Synonyms Furan-2-ylmethanol, 2-Furan carbinol, Furfural alcohol, 2-Furyl carbinol, 

2-Furyl methanol, 2-Hydroxymethyl furan 

Formula C5H6O2 

Molecular mass 98,10 FL-N°. 13.019 

CAS-N°. 98-00-0 FEMA-N°. 2491 

EC-N°. 202-626-1 Annex-1 N°. 603-018-00-2 

Registration number 01-2119493965-18-0003 

Relevant identified uses of the substance and uses advised against 

Use / Activity Exposure scenario 

- Manufacturing of blends / formulation ES 2 

- Manufacturing of polymers ES 3 

- Manufacturing of moulds using formulations containing the substance (foundry) ES 4 

- Manufacturing of refractories, abrasive wheels, friction (brake pads, clutch ES 5 

facing), carbon impregnation using formulations containing the substance 

- Wood impregnation / modification ES 6 

- Professional end-use of acid resistant coating ES 7 

Uses advised against None 

Details of the supplier of the safety data sheet 

Manufacturer International Furan Chemicals B.V 

Address Rotterdam Airportplein 7, 3045AP, Rotterdam, The Netherlands 

Telephone number +31-10-238 0555 

Telefax number +31-10-238 0550 

E-mail address manfred.van.der.starre@furan.com / adriaan.bonke@furan.com 

Emergency telephone numbers 

+32(0)14 58 45 45 (24h/24 h) 

Information centre on dangerous goods (BIG) 

Technische Schoolstraat 43 A, B-2440 Geel, Belgium 

2. HAZARDS IDENTIFICATION 

2.1 

Classification of the substance 

EU-GHS / CLP (inserted CLP00/updated ATP01) 

Hazard Class(es) / Hazard Class and Category Code(s) 

Carcinogenicity Carc. 2 

Acute toxicity Acute Tox. 3 * (inhalation) 

Acute Tox. 4 * (oral) 

Acute Tox. 4 * (dermal) 

Specific target organ toxicity — repeated exposure STOT RE 2 * 

Serious eye irritation Eye Irrit. 2 

Specific target organ toxicity — single exposure STOT SE 3 

EU-DSD / DPD 

Indication(s) of danger and risk phrase(s) 

Carc Cat 3 R40 

Toxic R23 

Harmful R21/22-48/20 

Irritant R36/37 

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2.2 

2.3 

Label elements 

EU-GHS / CLP 

Hazard pictogram(s) 

Signal word Danger 

Hazard statement(s) 

H351 Suspected of causing cancer. 

H331 Toxic if inhaled. 

H312 Harmful in contact with skin. 

H302 Harmful if swallowed. 

H373 May cause damage to organs through prolonged or repeated exposure. 

H319 Causes serious eye irritation. 

H335 May cause respiratory irritation. 

Precautionary statements 

P201 Obtain special instructions before use. 

P261 Avoid breathing vapours. 

P271 Use only outdoors or in a well-ventilated area. 

P281 Use personal protective equipment as required. 

P301 + P312 IF SWALLOWED: Call a POISON CENTRE or doctor / physician if you feel 

unwell. 

P302 + P352 IF ON SKIN: Wash with plenty of soap and water. 

P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable 

for breathing. 

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact 

lenses, if present and easy to do. Continue rinsing. 

P314 Get medical advice/attention if you feel unwell. 

P330 Rinse mouth 

P337 + P313 If eye irritation persists: Get medical advice / attention. 

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. 

P501 Disposal: Dispose of contents / container in accordance with local / regional 

regulations. 

Other hazards 

Furfuryl alcohol does not meet the criteria for PBT or vPvB according to 

Regulation 1907/2006. 

3. COMPOSITION / INFORMATION ON INGREDIENTS 

Main constituent Identity Percentage 

Furfuryl alcohol CAS-N°. 98-00-0 >98 % 

EC N°. 202-626-1 

4. FIRST AID MEASURES 

4.1 

Description of first aid measures 

Inhalation Fresh air, rest. Get medical advice / attention if you feel unwell. 

Skin contact Remove contaminated clothes, rinse skin with water or shower. 


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4.2 

4.3 

Eye contact First rinse with plenty of water (remove lenses if possible). 

If eye irritation persists: Get medical advice / attention. 

Ingestion Rinse mouth. Get medical advice / attention if you feel unwell. 

Most important symptoms and effects, both acute and delayed 

Acute Symptoms and effects 

Respiratory irritation (nose and upper respiratory tract) 

Eye irritation. May cause CNS depression, characterized by potential dizziness, 

drowsiness and nausea. 

Delayed symptoms and effects 

Respiratory irritation (nose and upper respiratory tract) and eye/skin irritation. 

Indication of any immediate medical attention and special treatment needed 

Not applicable. 

5. FIRE FIGHTING MEASURES 

5.1 

5.2 

5.3 

Extinguishing media 

Alcohol-resistant foam, water, powder, carbon dioxide. 

Special hazards arising from the substance 

Toxic by inhalation. Combustible. 

In case of fire toxic gases are formed (carbon monoxide and/or carbon dioxide). 

Advice for fire fighters 

6. ACCIDENTAL RELEASE MEASURES 

6.1 

6.2 

6.3 

6.4 

Self-contained breathing apparatus. 

In case of fire: keep containers cool by spraying with water. 

Personal precautions, protective equipment and emergency procedures 

Ventilation. 

Gloves, boots. 

Filter respirator for organic vapours (filter type A), safety goggles. 

Environmental precautions 

Do not discharge into sewer, surface water or soil. 

Methods and material for containment and cleaning up 

Dam spilled substance in and carefully remove with special vacuum cleaner; 

recycle if possible. Wash away remainder with water. Flush water into sewage. 

Take up small amounts spilled product with an inert absorbent. Dispose of as 

hazardous waste. 

Reference to other sections 

See also the sections 8 and 13. 

7. HANDLING AND STORAGE 


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7.1 

7.2 

7.3 

Precautions for safe handling 

Use only in well ventilated areas. 

No open flames and no smoking. 

Above 65 ˚C closed system. 

Conditions for safe storage, including any incompatibilities 

Keep container tightly closed. 

Store in a dark area. 

Keep away from oxidants and strong acids. 

Recommended storage temperature: 20 ºC. 

Specific end use(s) 

If used in food: comply with food safety regulation (HACCP). 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION 

8.1 

Control parameters 

Limit values 

Country 8 hours (TWA) Short term (15 min.) Notation 

mg/m3 ppm mg/m3 ppm 

Austria 20 5 skin 

Belgium 41 10 61 15 skin 

Czech Republic 20 5 40 10 C (40 mg/m3 ), skin 

Denmark 20 5 n.d. n.d. skin 

Finland 8,1 2 41 10 skin 

France 40 10 n.d. n.d. skin 

Germany n.d.(previous 40 mg/ m3 ) n.d. (previous 60 mg/ m3 ) skin 

Italy 20 5 61 15 skin 

Netherlands 20 5 200 50 skin 

Norway 20 5 n.d. n.d. skin 

Poland 30 7,5 60 15 

Portugal 40 10 60 15 skin 

Slovakia 41 10 n.d. n.d. C (41 mg/m3 ), skin 

Slovenia 41 10 n.d. n.d. skin 

Spain 20 5 61 15 skin 

Sweden 8 2 40 10 skin 

Switzerland 40 10 40 10 skin 

n.d. not determined 

The exposure limits may be exceeded before the odour is perceived. 

DNEL / DMEL 

Workers short term exposition 

DNEL worker (acute, inhalation - systemic) 2 187 mg/m 3 

DNEL worker (acute, inhalation - local) 8 mg/m 3 

DNEL worker (acute, dermal - systemic) 5.6 mg/kg bw/day 

Workers long term exposition 

DNEL worker (long-term, inhalation - systemic) 8 mg/m 3 

DNEL worker (long-term, inhalation - local) 8 mg/m 3 

DNEL worker (long-term, dermal - systemic) 4 mg/kg bw/day 


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8.2 

8.2.1 

8.2.2 

8.2.3 

Consumers short term exposition 

DNEL general population (acute, inhalation - systemic) 1 312 mg/m 3 

DNEL general population (acute, inhalation - local) 0.82 mg/m 3 

DNEL general population (acute, dermal - systemic) 3.3 mg/kg bw/day 

Consumers long term exposition 

DNEL general population (long-term, inhalation - systemic) 1.6 mg/m 3 

DNEL general population (long-term, inhalation - local) 0.82 mg/m 3 

DNEL general population (long-term, oral - systemic) 4.4 mg/kg bw/day 

DNEL general population (long-term, dermal - systemic) 3.3 mg/kg bw/day 

PNEC 

Aquatic 

- fresh water PNEC aquatic (freshwater) 0.17 mg/L 

- marine water PNEC aquatic (marine water) 0.017 mg/L 

- intermittent release 

Sedimentary 

PNEC aquatic (intermittent release) 1.7 mg/L 

fresh water sediment 

PNEC sediment: 

marine water sediment 

0.861 mg/kg sediment dw 

PNEC marine-sediment 

Terrestrial 

0.086 mg/kg sediment dw 

- soil PNEC soil 0.0724 mg/kg dw 

Secondary poisoning 

- food chain PNEC oral 5.89 mg/kg food 

Exposure controls 

Appropriate engineering controls 

Ventilation and local exhaust. 

Individual protection measures, such as personal protective 

a) Eye/face protection 

Safety goggles. 

b) Skin protection 

Hand protection Gloves butyl rubber 0,7 mm Breakthrough time > 8 hours 

Gloves neoprene 0,75 mm Breakthrough time > 4 hours 

Other Protective clothing. 

c) Respiratory protection 

In case of insufficient local exhaust: filter respirator for organic vapours (filter type A). 

d) Thermal hazards 

Not applicable. 

Environmental exposure controls 

Direct polluted air of the local exhaust ventilation out of the plant in a manner in 

accordance with environmental regulations. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

9.1 

Information on basic physical and chemical properties 


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9.2 

Appearance Colourless to yellow viscous liquid. 

Odour Typical; slightly pungent. 

Odour threshold (mg/m 3 ) 33 

pH (30% solution) 4 - 6 

Melting point / freezing point (˚C) - 15 

Boiling point (˚C) at 1013 hPa 170 

Flash point (˚C) 65 (tag closed cup) 

Evaporation rate (ether=1) 443 

Flammability (solid, gas) Not applicable. 

Upper / lower explosive limits (vol%) 1,8 - 16,3 

Vapour pressure at 20 ˚C (hPa) 0,53 

Vapour density (air=1) 3,38 

Relative density (water=1) 1,13 

Solubility(ies) 

- Water solubility at 25 ˚C (g/l) Complete. 

- Fat solubility Good 

Partition coefficient (log K octanol/water) 0,28 

Auto-ignition temperature (˚C) 491 

Decomposition temperature Not applicable. 

Viscosity at 25 ˚C (mPa.s) 4,62 

Explosive properties Non explosive 

Oxidizing properties None 

Other information 

Miscibility with Solvents (ethanol, ether, chloroform, methanol, 

1-propanol, iso-amylalcohol, ethyl acetate). 

Conductivity (pS/m) Not available 

Heat of combustion (kJ/kg) 26.000 

10. STABILITY AND REACTIVITY 

10.1 

10.2 

10.3 

10.4 

10.5 

10.6 

Reactivity 

Chemical stability 

Not reactive. 

Discolours on exposure to light. 

Unstable in water. 

Possibility of hazardous reactions 

Exothermic polymerization with explosive violence in the presence of (strong) 

acids. 

Conditions to avoid 

Incompatible materials 

Avoid contact with air and light. 

Reacts violently with oxidants and strong acids (polymerization). 

Hazardous decomposition products 

Upon decomposition emits carbon monoxide, carbon dioxide and/or low 

molecular weight hydrocarbons. 


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11. TOXICOLOGICAL INFORMATION 

11.1 

Information on toxicological effects 

11.1.1 Acute toxicity 

LD50 (oral, rat) (mg/kg) 177 

LD50 (dermal, rabbit) (mg/kg) 400 

LC50 (inhalation, rat, 4 hours) (mg/l) 0,82 – 2,07 

11.1.2 Skin corrosion/irritation No evidence that the substance is irritating to skin. 

No classification warranted. 

11.1.3 Serious eye damage/irritation The substance is irritating to eyes. 

11.1.4 Respiratory or skin sensitization Concluded not to be sensitizing. 

11.1.5 Germ cell mutagenicity Concluded not be genotoxic in vivo. 

11.1.6 Carcinogenicity Suspected of causing cancer. Tumours incidence in rats 

and mice considered to be related to tissue damage 

resulting from repeat exposure and respiratory irritation 

i.e. represent conversion of highly specialized nasal 

epithelium to more resistant types of epithelium and 

represent adaptive responses to chronic irritation. 

11.1.7 Reproductive toxicity No evidence of adverse effects on reproduction or 

development. 

11.1.8 STOT- single exposure From acute toxicity studies, evident that the substance 

may cause respiratory irritation particularly to the upper 

respiratory tract and the nose. 

11.1.9 STOT- repeated exposure From repeated-dose toxicity studies, evident that the 

substance may cause respiratory irritation particularly to 

the upper respiratory tract and the nose. May cause 

damage to the respiratory system - through prolonged or 

repeated exposure. 

11.1.10 Aspiration hazard Does not present an aspiration hazard. 

11.1.11 Likely routes of exposure The substance may be absorbed into the body by 

inhalation, after ingestion and through the skin. 

12 ECOLOGICAL INFORMATION 

12.1 

12.2 

12.3 

Toxicity 

LC50 (fish, 96 hours) (mg/l) 362 

EC50 (Daphnia, 48 hours) (mg/l) 224 

IC50 (algae, 96 hours) (mg/l) 170 

Persistence and degradability 

Biodegradability Readily biodegradable. 

Oxygen demand 

– biological (5 days) in gO2/g (BOD5) 0,81 

– biological (20 days) in gO2/g (BOD20) Not available 

– chemical in gO2/g (COD) 1,75 

BOD5 : COD 0,46 

Bioaccumulative potential 

BCF (Bioconcentration factor) 

(conc. in organisms / conc. in water) 

0,96 

Risk of bio accumulation is low (BCF




12.4 

12.5 

12.6 

Mobility in soil 

Adsorption coefficient (Koc) solid phase / liquid 

phase 

Results of PBT and vPvB assessment 

34 

Highly mobile. 

The substance is not considered as PBTor vPvB. 

Other adverse effects 

Ozone depletion potential (ODP) (CCl3F = 1) Not applicable 

Photochemical ozone creation potential (C2H4 = 1) Not available 

Global warming potential (GWP) (CO2 = 1) Not applicable 

Water hazard class (WGK Germany) 1 (slightly hazardous to water) 

13 DISPOSAL CONSIDERATIONS 

13.1 

Waste treatment methods 

Recycling by distillation. 

Removal to an authorized waste incinerator for 

solvents or as chemical waste in accordance with 

local regulations. Do not discharge wastewater into 

sewer. 

European waste list (EURAL) 07 01 04 

14 TRANSPORT INFORMATION 

14.1 

14.2 

14.3 

14.4 

14.5 

14.6 

14.7 

UN Number 

UN proper shipping name 

Transport hazard class(es) 

Packing group 


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2874 

FURFURYL ALCOHOL 

6.1 

Environmental hazards 

Marine pollutant No 

Specials precautions for user 

Risk label(s) 6.1 

Tunnel category (E) 

Hazard Identification Number (Kemler code) 60 

ERICard 6-03 

Emergency Schedules (EmS) 

- Fire schedule Alfa (F - A) 

- Spillage schedule Alfa (S - A) 

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 

Ship type required 3 

Pollution category Y 

III




15 REGULATORY INFORMATION 

15.1 

15.2 

Safety, health and environmental regulations/legislation specific for the substance 

Approved as a flavouring agent in the EU FL N°. 13.019 (Regulation (EC) No 2232/96) 

Chemical safety assessment 

A Chemical Safety Assessment has been carried out for furfuryl alcohol. 

16 OTHER INFORMATION 

Changes to the previous version. 

Classification and labelling according to Regulation (EC) No 453/2010 

Abbreviations and acronyms 

DNEL Derived No Effect Level 

DMEL Derived Minimal Effect Level 

DSD / DPD Dangerous Substances Directive / Dangerous Preparations Directive 

EC50 Effect Concentration, 50 percent 

ERIC Emergency Response Intervention Card 

GHS / CLP Globally Harmonised System / Classification, Labelling and Packaging 

IC50 Inhibitory Concentration, 50 percent 

LC50 Lethal Concentration, 50 percent 

LD50 Lethal Dose, 50 percent 

PBT Persistent, Bioaccumulative and Toxic 

PNEC Predicted No Effect Concentration 

TOD Total Oxygen Demand 

TWA Time Weighted Average 

vPvB very Persistent and very Bioaccumulative 

Literature references and sources for data 

Reach Registration Dossier 

EaSi-Pro View Substance Report, Haskoning, Oct. 2007 

Full text of indication(s) of danger, R phrases and safety advise which are not written out in full 

under Sections 2 to 15 

R21/22 Harmful in contact with skin and if swallowed. 

R23 Toxic by inhalation. 

R36/37 Irritating to eyes and respiratory system. 

R40 Limited evidence of a carcinogenic effect. 

R48/20 Harmful: danger of serious damage to health by prolonged exposure through 

inhalation. 


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Annex 1 Use descriptor system 

Full text of the sectors of use 

SU1 Agriculture, forestry, fishery 

SU2 Mining (including offshore industries) 

SU3 Industrial Manufacturing (all) 

SU4 Manufacture of food products 

SU5 Manufacture of textiles, leather, fur 

SU6 Manufacture of pulp, paper and paper products 

SU7 Printing and reproduction of recorded media 

SU8 Manufacture of bulk, large scale chemicals (including petroleum products) 

SU9 Manufacture of fine chemicals 

SU10 Formulation [mixing] of preparations and/or re-packaging 

SU11 Manufacture of rubber products 

SU12 Manufacture of plastics products, including compounding and conversion 

SU13 Manufacture of other non-metallic mineral products, e.g. plasters, cement 

SU14 Manufacture of basic metals 

SU15 Manufacture of fabricated metal products, except machinery and equipment 

SU16 Manufacture of computer, electronic and optical products, electrical equipment 

SU17 General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment 

SU18 Manufacture of furniture 

SU19 Building and construction work 

SU20 Health services 

SU21 Private households (general public, consumers) 

SU22 Public domain (administration, education, entertainment, services, craftsmen) 

SU23 Recycling 

SU24 Scientific Research and Development 

Full text of the process categories 

PROC0 Other Process or activity 

PROC1 Use in closed process, no likelihood of exposure 

PROC2 Use in closed, continuous process with occasional controlled exposure (e.g. sampling) 

PROC3 Use in closed batch process (synthesis or formulation) 

PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises 

PROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or 

significant contact) 

PROC6 Calendering operations 

PROC7 Spraying in industrial settings and applications 

PROC8 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated 

facilities 

PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing) 

PROC10 Roller application or brushing of adhesiveand other coating 

PROC11 Spraying outside industrial settings or applications 

PROC12 Use of blow agents in manufacture of foam 

PROC13 Treatment of articles by dipping and pouring 

PROC14 Production of preparations or articles by tabletting, compression, extrusion, pelettisation 

PROC15 Use a laboratory reagent 

PROC16 Using material as fuel sources, limited exposure to unburned product to be expected 

PROC17 Lubrication at high energy conditions and in partly open process 

PROC18 Greasing at high energy conditions 

PROC19 Hand-mixing with intimate contact and only PPE available. 


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PROC20 Heat and pressure transfer fluids in dispersive use but closed systems 

PROC21 Low energy manipulation of substances bound in materials and/or articles 

PROC22 Potentially closed processing operations (with minerals) at elevated temperature 

PROC23 Open processing and transfer operations (with minerals) at elevated temperature 

PROC24 High (mechanical) energy work-up of substances bound in materials and/or articles 

PROC25 Hot work operations with metals 

Full text of the product categories 

PC0 Other product 

PC1 Adhesive, sealant 

PC2 Adsorbens 

PC3 Air care product 

PC4 Anti-Freeze or de-icing product 

PC5 Artists supply or hobby preparation 

PC6 Automotive care product 

PC7 Base metals or alloy 

PC8 Biocidal product (e.g. disinfectant, pest control) 

PC9 Coating or paint, filler, puttie, thinner 

PC10 Building and construction mixture (not covered elsewhere) 

PC11 Explosive 

PC12 Fertilizer 

PC13 Fuel 

PC14 Metal surface treatment (including galvanic and electroplating) product 

PC15 Non-metal-surface treatment product 

PC16 Heat transfer fluid 

PC17 Hydraulic fluid 

PC18 Ink or toner 

PC19 Intermediate 

PC20 ph-regulator, flocculant, precipitant, neutralization agent, or other unspecific 

PC21 Laboratory chemical 

PC22 Lawn and garden preparation, including fertilizers 

PC23 Leather tanning, - dye,- finishing,- impregnation or care product 

PC24 Lubricant, greas or release product 

PC25 Metal working fluid 

PC26 Paper and board dye, finishing and impregnation product 

PC27 Plant protection product 

PC28 Perfume or fragrance 

PC29 Pharmaceutical 

PC30 Photochemical 

PC31 Polish or wax blend 

PC32 Polymer preparations and compounds 

PC33 Semiconductor 

PC34 Textile dyes, finishing and impregnating products 

PC35 Washing and cleaning products (including solvent based products) 

PC36 Water softeners 

PC37 Water treatment chemicals 

PC38 Welding and soldering products, flux products 

PC39 Cosmetics, personal care products 

PC40 Extraction agents 


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Full text of the environmental release categories 

ERC 1 Manufacture of substances 

ERC 2 Formulation of preparations (mixtures) 

ERC 3 Formulation in materials 

ERC 4 Industrial use of processing aids in processes and products, not becoming part of an article 

ERC 5 Industrial use resulting in inclusion into or onto a matrix 

ERC 6a Industrial use resulting in manufacture of another substance (use of intermediates) 

ERC 6b Industrial use of reactive processing aids 

ERC 6c Industrial use of monomers for polymerization 

ERC 6d Industrial use of auxiliaries for polymerisaton processes 

ERC 7 Industrial use of substances in closed systems 

ERC 8a Wide dispersive indoor use of processing aids in open systems 

ERC 8b Wide dispersive indoor use of reactive substances in open systems. 

ERC 8c Wide dispersive indoor use resulting in inclusion into or onto a matrix. 

ERC 8d Wide dispersive outdoor use of processing aids in open systems 

ERC 8e Wide dispersive outdoor use of reactive substances in open systems 

ERC 8f Wide dispersive outdoor use resulting in inclusion into or onto a matrix 

ERC 9a Wide dispersive indoor use of substances in closed systems. 

ERC 9b Wide dispersive outdoor use of substances in closed systems. 

ERC 10a Wide dispersive outdoor use of long-life articles and materials with low release. 

ERC 10b Wide dispersive outdoor use of long-life articles and materials with high or intended release 

ERC 11a Wide dispersive indoor use of long-life articles and materials with low release. 

ERC 11b Wide dispersive indoor use of long-life articles and materials with high or intended release. 


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Annex 2 Exposure scenario’s 

Exposure scenario ES 2 

Manufacturing of blends/formulations 

2.1 Exposure scenario 

Environment: ERC 2 

Worker 

Mixing in a closed process, no likelihood of exposure PROC 1 

Mixing in a closed, continuous process with occasional controlled exposure PROC 2 

Mixing in a closed batch process, indoors with LEV PROC 3 

Mixing in a batch process where opportunity for exposure arises, indoors with LEV PROC 4 

Mixing in a batch process where the process is in stages and provides the 

opportunity for significant contact at any stage, indoors with LEV 

Transfer of the substance or transfer of formulations containing the substance 

(large amounts), indoors without LEV 


(small amounts), indoors without LEV 

PROC 5 

PROC 8b 

PROC 9 

Quality control, indoors with LEV PROC 15 


(small amounts), indoors with LEV 


(large amounts), outdoors 

Operational conditions and risk management measures 

Control of environmental exposure: Manufacturing of blends/formulations 

Product characteristics 

Amounts used 

Daily use at a site




Organizational measures to prevent/limit release from site 

Conditions and measures related to municipal sewage treatment plant 

Municipal STP Yes [Water: 87.4%] 

Discharge rate of STP >= 2E3 m3/d 

Application of the STP sludge on agricultural soil Yes 

Conditions and measures related to external treatment of waste for disposal 

Conditions and measures related to external recovery of waste 

Additional good practice advice beyond the REACH CSA 

Control of workers exposure for "Mixing in a closed process, no likelihood of exposure" [PROC 1] 


Substance in preparation No L L 

Amounts used 

Frequency and duration of use/exposure 

Duration of activity >4 hours L L 

Human factors not influenced by risk management 

Other given operational conditions affecting workers exposure 

Place of use Indoors L L 

Inhal*) Derm*) 

Loc Sys Loc Sys 

Surface of skin exposed One hand face only (240 cm2) L L 

Technical conditions and measures at process level (source) to prevent release 

Level of containment Use in closed process, no likelihood of 

exposure 

Technical conditions and measures to control dispersion from source towards the worker 

L L 

Local Exhaust Ventilation No L L L L 

Organisational measures to prevent /limit releases, dispersion and exposure 

Conditions and measures related to personal protection, hygiene and health evaluation 

Respiratory protection Respiratory protection is not used L L 

Eye protection Wear chemical goggles AL AL 


*) The route of exposure (Inhalation, Dermal) and type of effect (Local, Systemic and Acute or Long term) for which the 

determinant has been used for exposure estimation are reported. 

Control of workers exposure for "Mixing in a closed, continuous process with occasional controlled 

exposure" [PROC 2] 






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Amounts used 






Surface of skin exposed Two hands face (480 cm2) L L 


Level of containment Use in closed, continuous process with 

occasional controlled exposure 

L L 










Control of workers exposure for "Mixing in a closed batch process, indoors with LEV" [PROC 3] 



Amounts used 










Level of containment Use in closed batch process (synthesis or 

formulation) 


L L 

Local Exhaust Ventilation Yes L L L L 






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Control of workers exposure for "Mixing in a batch process where opportunity for exposure arises, 

indoors with LEV" [PROC 4] 



Amounts used 










Level of containment Use in batch and other process (synthesis) 

where opportunity for exposure arises 


L L 









Control of workers exposure for "Mixing in a batch process where the process is in stages and provides 

the opportunity for significant contact at any stage, indoors with LEV" [PROC 5] 



Amounts used 








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Control of workers exposure for "Transfer of the substance or transfer of formulations containing the 

substance (large amounts), indoors without LEV" [PROC 8b] 



Amounts used 


Duration of activity 15 mins - 1 hour L L 













Gloves Wear chemically resistant gloves (tested to 

type EN374) with "basic" employee training 

[Dermal: 90%] 

AL AL 






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substance (small amounts), indoors without LEV" [PROC 9] 



Amounts used 

















[Dermal: 90%] 

AL AL 





Control of workers exposure for "Quality control, indoors with LEV" [PROC 15] 



Amounts used 











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substance (small amounts), indoors with LEV" [PROC 9] 



Amounts used 


















[Dermal: 90%] 

AL AL 





substance (large amounts), outdoors" [PROC 8b] 




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Substance in preparation 

Amounts used 


No L L 




Place of use Outdoors L L 











[Dermal: 90%] 

AL AL 




2.2 Exposure estimation for Manufacturing of blends / formulations 

2.2.1. Exposure estimation for the environment (Manufacturing of blends/formulations) 

2.2.1.1. Environmental releases 

Table 1. Summary of the local releases to the environment 

Compartment Release factor 

estimation 

method 

Explanation / Justification 

Water Release rate Release factor after on site risk management (%): 0.4 

Local release rate (kg/day): 25 

Explanation/Justification: 

There is no company specific data available. The local release rate has 

been set to the maximum rate at which the local environmental risks are 

controlled. 

Air Other method 

(estimation) 

Release factor after on site risk management (%): 0.1 

Local release rate (kg/day): 6.25 


There is no company specific data available. The 0.1% is an estimation 

based on the properties and use of the substance. 

Soil Other method Release factor after on site risk management (%): 0 


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Compartment Release factor 

estimation 

method 

(Company specific 

data) 



There is no direct emission to soil 

Summed releases from all life cycle stages: see Supplement. 

2.2.1.2. Environmental exposure 

Table 2. Summary of exposure concentrations 

Protection target Exposure concentration Explanation / Justification 

Water: Fresh Water 

(Pelagic) 


(Sediment) 

Water: Marine Water 

(Pelagic) 


(Sediment) 

Local PEC: 0.16 mg/L 

Local concentration: 0.158 mg/L 

Local PEC: 0.808 mg/kg dw 




Air Local PEC: 4.79E-4 mg/m³ 

Soil: Agricultural Soil Local PEC: 0.05 mg/kg dw 

Local concentration: 0.049 mg/kg dw 

For regional PECs: see Supplement. 

2.2.1.3. Indirect exposure of humans via the environment 

EUSES 2.1 

Exposure via inhalation 

The exposure concentrations in air are reported in the Table "Summary of exposure concentrations" of the preceding section 

2.2.1.2 "Environmental exposure". 

Exposure via food consumption: Total daily intake for humans 

Table 3. Summary of estimated daily human doses and concentrations in food 

Type of 

food 

Drinking 

water 

Daily human dose through intake Explanation / Justification 

Total estimated daily intake for humans: 

0.005 mg/kg bw/day 

Estimated daily dose 

through intake from 

local exposure 

Concentration in food 

from local exposure 

0.004 mg/kg bw/day 0.132 mg/L 

Fish 3.05E-4 mg/kg bw/day 0.186 mg/kg 

Leaf crops 6.2E-4 mg/kg bw/day 0.036 mg/kg 


2011-06-07





food 


Root crops 1.88E-4 mg/kg bw/day 0.034 mg/kg 

Meat 3.09E-8 mg/kg bw/day 7.18E-6 mg/kg 

Milk 5.75E-7 mg/kg bw/day 7.18E-5 mg/kg 

Dose from regional exposure: see 

Supplement. 

2.2.2. Exposure estimation for Worker for Mixing in a closed process, no likelihood of exposure 

Table 4. Summary of exposure concentrations for contributing scenario: Mixing in a closed process, no likelihood 

of exposure 

Route of 

exposure and 

type of effects 

Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 

Dermal: Acute, 

Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 

term, Systemic 

Exposure 

concentration 

Method / name of exposure 

assessment 

0.041 mg/m³ Method: External exposure 

estimation tool 

Name: TRA workers 




0.041 mg/m³ Method: Extended TRA 

workers 

Name: TRA workers extended 


workers 


Method: Conditions of use 

(OC/RMM) 

Name: Conditions of use 

1.029 mg/kg 

bw/day 

Method: External exposure 



0.1 mg/cm² Method: Extended TRA 

workers 


0.343 mg/kg 

bw/day 

Method: Extended TRA 

workers 



Representativity and reliability: 

ECETOC TRA 

Remark on exposure value: 

Acute, local = long-term, local 


ECETOC TRA 


Acute, systemic = 3 x long-term, systemic 


ECETOC TRA 



2.2.2. Exposure estimation for Worker for Mixing in a closed, continuous process with occasional controlled 

exposure 


2011-06-07




Table 5. Summary of exposure concentrations for contributing scenario: Mixing in a closed, continuous process 

with occasional controlled exposure 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


4.113 mg/kg 

bw/day 





workers 


1.371 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 



2.2.2. Exposure estimation for Worker for Mixing in a closed batch process, indoors with LEV 

Table 6. Summary of exposure concentrations for contributing scenario: Mixing in a closed batch process, indoors 

with LEV 


exposure and 


Inhalation: 

Acute, Local 

Exposure 

concentration 


assessment 






ECETOC TRA 



Inhalation: 3.678 mg/m³ Method: External exposure Representativity and reliability: 


2011-06-07





exposure and 


Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 




workers 



workers 



(OC/RMM) 


0.102 mg/kg 

bw/day 





workers 


0.034 mg/kg 

bw/day 


workers 



ECETOC TRA 




ECETOC TRA 



2.2.2. Exposure estimation for Worker for Mixing in a batch process where opportunity for exposure arises, indoors 

with LEV 

Table 7. Summary of exposure concentrations for contributing scenario: Mixing in a batch process where 

opportunity for exposure arises, indoors with LEV 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Exposure 

concentration 


assessment 








workers 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 


workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 



2.2.2. Exposure estimation for Worker for Mixing in a batch process where the process is in stages and provides the 

opportunity for significant contact at any stage, indoors with LEV 

Table 8. Summary of exposure concentrations for contributing scenario: Mixing in a batch process where the 

process is in stages and provides the opportunity for significant contact at any stage, indoors with LEV 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 



Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 

0.207 mg/kg 

bw/day 


assessment 





workers 


0.069 mg/kg 

bw/day 


workers 




ECETOC TRA 



2.2.2. Exposure estimation for Worker for Transfer of the substance or transfer of formulations containing the 

substance (large amounts), indoors without LEV 

Table 9. Summary of exposure concentrations for contributing scenario: Transfer of the substance or transfer of 

formulations containing the substance (large amounts), indoors without LEV 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Dermal: Long 


Exposure 

concentration 

0.686 mg/kg 

bw/day 


assessment 


workers 




substance (small amounts), indoors without LEV 


formulations containing the substance (small amounts), indoors without LEV 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07




2.2.2. Exposure estimation for Worker for Quality control, indoors with LEV 

Table 11. Summary of exposure concentrations for contributing scenario: Quality control, indoors with LEV 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


0.102 mg/kg 

bw/day 





workers 


0.034 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




substance (small amounts), indoors with LEV 


formulations containing the substance (small amounts), indoors with LEV 


exposure and 


Inhalation: 

Acute, Local 

Exposure 

concentration 


assessment 






ECETOC TRA 



2011-06-07





exposure and 


Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 





workers 



workers 



(OC/RMM) 


0.207 mg/kg 

bw/day 





workers 


0.069 mg/kg 

bw/day 


workers 





ECETOC TRA 




ECETOC TRA 




substance (large amounts), outdoors 


formulations containing the substance (large amounts), outdoors 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Exposure 

concentration 


assessment 









ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 


workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




2011-06-07




SUPPLEMENT 

Regional environmental exposure from the releases of all exposure scenarios covered 

in the CSR of the lead-Registrant 

The following PECs are calculated based on the releases of all generic exposure scenarios, taking into account the total EU 

tonnages for the 7 life cycle stages. 

1. Total releases 

• Water: 465 tonnes/year 

• Air: 115 tonnes/year 

• Soil: 0 tonnes/year 

2. Regional exposure: environment 

Table. Summary of predicted regional exposure concentrations (Regional PEC) 

Protection target Regional PEC 

Fresh Water (Pelagic) 0.002 mg/L 

Fresh Water (Sediment) 0.007 mg/kg dw 

Marine Water (Pelagic) 1.53E-4 mg/L 

Marine Water (Sediment) 6.86E-4 mg/kg dw 

Air 2.5E-6 mg/m³ 

Agricultural Soil 8.03E-4 mg/kg dw 

3. Regional exposure: man via environment 

Regional total estimated daily intake for humans: 8.701E-5 mg/kg bw/day 

Table. Summary of estimated daily human doses through intake and concentrations in food from regional exposure 

Type of food Estimated daily dose from regional 

exposure 

Drinking water 4.67E-5 mg/kg bw/day 0.002 mg/L 



Root crops 4.51E-6 mg/kg bw/day 8.23E-4 mg/kg 



Concentration in food from regional 

exposure 


2011-06-07





Manufacturing of polymers 


Environment: ERC 6c 

Worker 

Manufacturing polymers in a closed process, no likelihood of exposure (indoors) PROC 1 

Manufacturing polymers in a closed, continuous process with occasional controlled 

exposure (indoors) 

PROC 2 

Manufacturing polymers in a closed batch process (indoors with LEV) PROC 3 

Manufacturing polymers in a batch process where opportunity for exposure arises 

(indoors with LEV) 

PROC 4 

Transfer of the substance (indoors) PROC 8b 

Quality control, indoors with LEV PROC 15 

Manufacturing polymers in a closed process, no likelihood of exposure (outdoors) PROC 1 

Manufacturing polymers in a closed, continuous process with occasional controlled 

exposure (outdoors) 

PROC 2 

Transfer of the substance (outdoors) PROC 8b 

Manufacturing polymers in a closed batch process (outdoors) PROC 3 

Manufacturing polymers in a batch process where opportunity for exposure arises 

(outdoors) 


Control of environmental exposure: Manufacturing of polymers 


Amounts used 

Daily use at a site




Municipal STP Yes [Water: 87.4%] 






Control of workers exposure for "Manufacturing polymers in a closed process, no likelihood of 

exposure (indoors) " [PROC 1] 



Amounts used 











exposure 


L L 









Control of workers exposure for "Manufacturing polymers in a closed, continuous process with 

occasional controlled exposure (indoors) " [PROC 2] 



Amounts used 




2011-06-07













L L 










Control of workers exposure for "Manufacturing polymers in a closed batch process (indoors with LEV) 

" [PROC 3] 



Amounts used 











formulation) 


L L 







2011-06-07







Control of workers exposure for "Manufacturing polymers in a batch process where opportunity for 

exposure arises (indoors with LEV) " [PROC 4] 



Amounts used 













L L 









Control of workers exposure for "Transfer of the substance (indoors) " [PROC 8b] 



Amounts used 









2011-06-07













[Dermal: 90%] 

AL AL 





Control of workers exposure for "Quality control, indoors with LEV" [PROC 15] 



Amounts used 




















2011-06-07




Control of workers exposure for "Manufacturing polymers in a closed process, no likelihood of 

exposure (outdoors) " [PROC 1] 



Amounts used 











exposure 


L L 









Control of workers exposure for "Manufacturing polymers in a closed, continuous process with 

occasional controlled exposure (outdoors) " [PROC 2] 



Amounts used 










2011-06-07








L L 









Control of workers exposure for "Transfer of the substance (outdoors) " [PROC 8b] 



Amounts used 


















[Dermal: 90%] 

AL AL 





2011-06-07




Control of workers exposure for "Manufacturing polymers in a closed batch process (outdoors) " 

[PROC 3] 



Amounts used 


Duration of activity 1 - 4 hours L L 









formulation) 


L L 









Control of workers exposure for "Manufacturing polymers in a batch process where opportunity for 

exposure arises (outdoors) " [PROC 4] 



Amounts used 










2011-06-07








L L 








[Dermal: 90%] 

AL AL 




3.2 Exposure estimation for Manufacturing of polymers 

3.2.1. Exposure estimation for the environment (Manufacturing of polymers) 



Compartme 

nt 

Release factor 

estimation method 







controlled. 


(estimation) 

Soil ERC 

(ERC 6c) 






Release factor after on site risk management (%): 0 





2011-06-07






(Pelagic) 


(Sediment) 


(Pelagic) 


(Sediment) 










For regional PECs see Supplement. 








food 

Drinking 

water 
















Supplement. 

3.2.2. Exposure estimation for Worker for Manufacturing polymers in a closed process, no likelihood of exposure 

(indoors) 


2011-06-07




Table 4. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a closed 

process, no likelihood of exposure (indoors) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


1.029 mg/kg 

bw/day 





workers 


0.343 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 



3.2.2. Exposure estimation for Worker for Manufacturing polymers in a closed, continuous process with occasional 

controlled exposure (indoors) 

Table 5. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a closed, 

continuous process with occasional controlled exposure (indoors) 


exposure and 


Inhalation: 

Acute, Local 

Exposure 

concentration 


assessment 






ECETOC TRA 




2011-06-07





exposure and 


Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 





workers 



workers 



(OC/RMM) 


4.113 mg/kg 

bw/day 





workers 


1.371 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 



3.2.2. Exposure estimation for Worker for Manufacturing polymers in a closed batch process (indoors with LEV) 

Table 6. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a closed batch 

process (indoors with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Exposure 

concentration 


assessment 








workers 


Inhalation: 1.226 mg/m³ Method: Extended TRA 



ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 

0.102 mg/kg 

bw/day 


assessment 

workers 



(OC/RMM) 






workers 


0.034 mg/kg 

bw/day 


workers 




ECETOC TRA 



3.2.2. Exposure estimation for Worker for Manufacturing polymers in a batch process where opportunity for 

exposure arises (indoors with LEV) 

Table 1. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a batch 

process where opportunity for exposure arises (indoors with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 






ECETOC TRA 




ECETOC TRA 




ECETOC TRA 



2011-06-07





exposure and 


Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 


workers 


0.686 mg/kg 

bw/day 


workers 



3.2.2. Exposure estimation for Worker for Transfer of the substance (indoors) 


Table 7. Summary of exposure concentrations for contributing scenario: Transfer of the substance (indoors) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 



3.2.2. Exposure estimation for Worker for Quality control, indoors with LEV 


ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07




Table 8. Summary of exposure concentrations for contributing scenario: Quality control, indoors with LEV 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


0.102 mg/kg 

bw/day 





workers 


0.034 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 



3.2.2. Exposure estimation for Worker for Manufacturing polymers in a closed process, no likelihood of exposure 

(outdoors) 

Table 2. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a closed 

process, no likelihood of exposure (outdoors) 


exposure and 


Inhalation: 

Acute, Local 

Exposure 

concentration 


assessment 






ECETOC TRA 





2011-06-07





exposure and 


Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 




workers 



workers 



(OC/RMM) 


1.029 mg/kg 

bw/day 





workers 


0.343 mg/kg 

bw/day 


workers 



ECETOC TRA 




ECETOC TRA 



3.2.2. Exposure estimation for Worker for Manufacturing polymers in a closed, continuous process with occasional 

controlled exposure (outdoors) 

Table 9. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a closed, 

continuous process with occasional controlled exposure (outdoors) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Exposure 

concentration 


assessment 








workers 


Inhalation: 2.861 mg/m³ Method: Extended TRA 



ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 

4.113 mg/kg 

bw/day 


assessment 

workers 



(OC/RMM) 






workers 


1.371 mg/kg 

bw/day 


workers 



3.2.2. Exposure estimation for Worker for Transfer of the substance (outdoors) 


ECETOC TRA 



Table 10. Summary of exposure concentrations for contributing scenario: Transfer of the substance (outdoors) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 






ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 


workers 


0.686 mg/kg 

bw/day 


workers 



3.2.2. Exposure estimation for Worker for Manufacturing polymers in a closed batch process (outdoors) 

Table 3. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a closed batch 

process (outdoors) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


1.029 mg/kg 

bw/day 





workers 


0.343 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 



3.2.2. Exposure estimation for Worker for Manufacturing polymers in a batch process where opportunity for 

exposure arises (outdoors) 


2011-06-07




Table 11. Summary of exposure concentrations for contributing scenario: Manufacturing polymers in a batch 

process where opportunity for exposure arises (outdoors) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07




SUPPLEMENT 






















exposure 








exposure 


2011-06-07





Manufacturing of moulds using formulations containing the substance (market sector: 

foundry) 



Worker 

Formulation of sand mixtures containing the substance in a manner that opportunity 

for contact with the substance occurs (indoors with LEV) 

Formulation of sand mixtures containing the substance in a manner that opportunity 

for significant contact with the substance occurs (indoors with LEV) 

Formulation of sand mixtures containing the substance in a manner that contact 

with the substance occurs (indoors with LEV) 

PROC 3 

PROC 4 

PROC 5 

Transfer of formulations containing the substance PROC 8b 

Manufacturing of moulds PROC 14 


Control of environmental exposure: Manufacturing of mixtures in moulds (foundry) 


Amounts used 

Daily use at a site = 2E3 m3/d 






2011-06-07




Control of workers exposure for "Formulation of sand mixtures containing the substance in a manner 

that opportunity for contact with the substance occurs (indoors with LEV) " [PROC 3] 


Substance in preparation Yes L L 

Concentration of substance in product > 25% L L 

Amounts used 











formulation) 


L L 










that opportunity for significant contact with the substance occurs (indoors with LEV) " [PROC 4] 




Amounts used 









2011-06-07








L L 











that contact with the substance occurs (indoors with LEV) " [PROC 5] 




Amounts used 




















2011-06-07




Control of workers exposure for "Transfer of formulations containing the substance" [PROC 8b] 




Amounts used 

















[Dermal: 90%] 

AL AL 





Control of workers exposure for "Manufacturing of moulds " [PROC 14] 




Substance in preparation Yes L L L L 

Concentration of substance in product 1 - 5% [Inhalation: 80%; Dermal: 80%] L L L L 

Amounts used 







2011-06-07














4.2 Exposure estimation for Manufacturing of of moulds using formulations containing the substance 

(market sector: foundry) 

4.2.1. Exposure estimation for the environment (Manufacturing of mixtures in moulds (foundry)) 



Compartme 

nt 









controlled. 


(estimation) 

Soil ERC 

(ERC 6c) 












(Pelagic) 


(Sediment) 




Water: Marine Water Local PEC: 0.016 mg/L 


2011-06-07





(Pelagic) Local concentration: 0.016 mg/L 


(Sediment) 











Table3. Summary of estimated daily human doses and concentrations in food 


food 

Drinking 

water 
















Supplement. 

4.2.2. Exposure estimation for Worker for Formulation of sand mixtures containing the substance in a manner that 

opportunity for contact with the substance occurs (indoors with LEV) 

Table 4. Summary of exposure concentrations for contributing scenario: Formulation of sand mixtures containing 

the substance in a manner that opportunity for contact with the substance occurs (indoors with LEV) 


exposure and 


Exposure 

concentration 


assessment 




2011-06-07





exposure and 


Exposure 

concentration 


assessment 

Acute, Local estimation tool 


Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 






workers 



workers 



(OC/RMM) 


0.102 mg/kg 

bw/day 





workers 


0.034 mg/kg 

bw/day 


workers 



ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




opportunity for significant contact with the substance occurs (indoors with LEV) 


the substance in a manner that opportunity for significant contact with the substance occurs (indoors with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Exposure 

concentration 


assessment 









ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 


workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




contact with the substance occurs (indoors with LEV) 


the substance in a manner that contact with the substance occurs (indoors with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 



ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 



Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 

0.207 mg/kg 

bw/day 


assessment 






workers 


0.069 mg/kg 

bw/day 


workers 




ECETOC TRA 



4.2.2. Exposure estimation for Worker for Transfer of formulations containing the substance 

Table 4. Summary of exposure concentrations for contributing scenario: Transfer of formulations containing the 

substance 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Dermal: Long 


Exposure 

concentration 

0.686 mg/kg 

bw/day 


assessment 


workers 


4.2.2. Exposure estimation for Worker for Manufacturing of moulds 


Table 7. Summary of exposure concentrations for contributing scenario: Manufacturing of moulds 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC 




2011-06-07




SUPPLEMENT 




















Table Summary of estimated daily human doses through intake and concentrations in food from regional exposure 


exposure 








exposure 


2011-06-07





Manufacturing of refractories, abrasive wheels, friction (brake pads, clutch facing), carbon 

impregnation using formulations containing the substance 



Worker 

Mixing in a closed batch process (indoors with LEV) PROC 3 

Mixing in a batch process where opportunity for exposure arises (indoors with LEV) PROC 4 


Pressing, curing and hardening of refractories, abrasive wheels, friction, carbon 

impregnation (indoors with LEV) 

Mixing in a batch process in a manner that contact with the substance occurs 

(indoors with LEV) 

Pressing, curing and hardening of refractories, abrasive wheels, friction, carbon 

impregnation (indoors without LEV) 


PROC 14 

PROC 5 

PROC 14 

Control of environmental exposure: Manufacturing of refractories and related material 


Amounts used 






2011-06-07





Control of workers exposure for "Mixing in a closed batch process (indoors with LEV) " [PROC 3] 






Amounts used 









formulation) 


L L 









Control of workers exposure for "Mixing in a batch process where opportunity for exposure arises 

(indoors with LEV) " [PROC 4] 






Amounts used 






2011-06-07









L L 














Amounts used 

















[Dermal: 90%] 

AL AL 






2011-06-07




Control of workers exposure for "Pressing, curing and hardening of refractories, abrasive wheels, 

friction, carbon impregnation (indoors with LEV) " [PROC 14] 






Amounts used 

















Control of workers exposure for "Mixing in a batch process in a manner that contact with the substance 

occurs (indoors with LEV) " [PROC 5] 






Amounts used 








2011-06-07














Control of workers exposure for "Pressing, curing and hardening of refractories, abrasive wheels, 

friction, carbon impregnation (indoors without LEV) " [PROC 14] 





Concentration of substance in product < 1% [Inhalation: 90%; Dermal: 90%] L L L L 

Amounts used 

















2011-06-07




5.2 Exposure estimation for Manufacturing of refractories, abrasive wheels, friction (brake pads, clutch 

facing), carbon impregnation using formulations containing the substance 

5.2.1. Exposure estimation for the environment (Manufacturing of refractories and related material) 



Compartme 

nt 









controlled. 


(estimation) 

Soil ERC 

(ERC 6c) 












(Pelagic) 


(Sediment) 


(Pelagic) 


(Sediment) 
















2011-06-07







food 

Drinking 

water 
















Supplement. 

5.2.2. Exposure estimation for Worker for Mixing in a closed batch process (indoors with LEV) 

Table 4. Summary of exposure concentrations for contributing scenario: Mixing in a closed batch process (indoors 

with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 



ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 



Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 

0.063 mg/kg 

bw/day 


assessment 






workers 


0.021 mg/kg 

bw/day 


workers 




ECETOC TRA 



5.2.2. Exposure estimation for Worker for Mixing in a batch process where opportunity for exposure arises (indoors 

with LEV) 


opportunity for exposure arises (indoors with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


1.233 mg/kg 

bw/day 





workers 



ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Dermal: Long 


Exposure 

concentration 

0.411 mg/kg 

bw/day 


assessment 



workers 





substance 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 



5.2.2. Exposure estimation for Worker for Pressing, curing and hardening of refractories, abrasive wheels, friction, 

carbon impregnation (indoors with LEV) 

Table 7. Summary of exposure concentrations for contributing scenario: Pressing, curing and hardening of 

refractories, abrasive wheels, friction, carbon impregnation (indoors with LEV) 


2011-06-07





exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


0.618 mg/kg 

bw/day 





workers 


0.206 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 



5.2.2. Exposure estimation for Worker for Mixing in a batch process in a manner that contact with the substance 

occurs (indoors with LEV) 

Table 8. Summary of exposure concentrations for contributing scenario: Mixing in a batch process in a manner that 

contact with the substance occurs (indoors with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Exposure 

concentration 


assessment 









ECETOC TRA 




ECETOC TRA 



2011-06-07





exposure and 


Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 


workers 



workers 



(OC/RMM) 


0.123 mg/kg 

bw/day 





workers 


0.041 mg/kg 

bw/day 


workers 





ECETOC TRA 



5.2.2. Exposure estimation for Worker for Pressing, curing and hardening of refractories, abrasive wheels, friction, 

carbon impregnation (indoors without LEV) 

Table 9. Summary of exposure concentrations for contributing scenario: Pressing, curing and hardening of 

refractories, abrasive wheels, friction, carbon impregnation (indoors without LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 

Exposure 

concentration 


assessment 








workers 



workers 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 



Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 

1.029 mg/kg 

bw/day 


assessment 


(OC/RMM) 






workers 


0.343 mg/kg 

bw/day 


workers 




ECETOC TRA 




2011-06-07




SUPPLEMENT 






















exposure 








exposure 


2011-06-07





Wood impregnation/modification 



Worker 

Mixing in a batch process where opportunity for exposure arises (indoors with LEV) PROC 4 


Impregnation of wood under pressure in autoclave, drying and curing of wood 

(automated process) 

PROC 13 

Transfer of formulations containing the substance (outdoors) PROC 8b 


Control of environmental exposure: Wood impregnation/modification 

Site specific assessment 


Amounts used 







2011-06-07




Control of workers exposure for "Mixing in a batch process where opportunity for exposure arises 

(indoors with LEV) " [PROC 4] 



Amounts used 













L L 












Amounts used 











2011-06-07











[Dermal: 90%] 

AL AL 





Control of workers exposure for "Impregnation of wood under pressure in autoclave, drying and curing 

of wood (automated process) " [PROC 13] 


Amounts used 













Control of workers exposure for "Transfer of formulations containing the substance (outdoors) " [PROC 

8b] 



Amounts used 








2011-06-07















[Dermal: 90%] 

AL AL 




6.2 Exposure estimation for Wood impregnation/modification 

6.2.1. Exposure estimation for the environment (Wood impregnation/modification) 



Compartme 

nt 




Water Release rate Release factor after on site risk management (%): 0 



Based on the available information about how the substance is used at 

this industrial site, the emission to water is considered to be negligible. 

This process takes place in an autoclave. 

Air Release rate Release factor after on site risk management (%): 0 



Based on the available information about how the substance is used at 

this industrial site, the emission to air is considered to be negligible. This 

process takes place in an autoclave. 

Soil ERC 

(ERC 6c) 






2011-06-07






(Pelagic) 


(Sediment) 


(Pelagic) 


(Sediment) 


Local concentration: 0 mg/L 


Local PEC: 1.53E-4 mg/L 

Local concentration: 0 mg/L 

Local PEC: 7.73E-4 mg/kg dw 


Soil: Agricultural Soil Local PEC: 8.03E-4 mg/kg dw 

Local concentration: 0 mg/kg dw 









food 

Drinking 

water 
















Supplement. 

6.2.2. Exposure estimation for Worker for Mixing in a batch process where opportunity for exposure arises (indoors 

with LEV) 


2011-06-07





opportunity for exposure arises (indoors with LEV) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 





substance 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Exposure 

concentration 


assessment 








ECETOC TRA 




ECETOC TRA 


2011-06-07





exposure and 


Exposure 

concentration 


assessment 


Systemic Name: TRA workers Remark on exposure value: 


Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 



workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 



ECETOC TRA 



6.2.2. Exposure estimation for Worker for Impregnation of wood under pressure in autoclave, drying and curing of 

wood (automated process) 

Table 6. Summary of exposure concentrations for contributing scenario: Impregnation of wood under pressure in 

autoclave, drying and curing of wood (automated process) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Exposure 

concentration 


assessment 

0 mg/m³ Method: External exposure 


Name: Assessment based on 

site specific information 







Not applicable 


Based on the available information about 

how the substance is used at this industrial 

site, the worker exposure is considered to 

be negligible. This process takes place in 

an autoclave, without the near presence of 

a worker. 








2011-06-07





exposure and 


Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 










(OC/RMM) 


0 mg/kg bw/day Method: External exposure 





(OC/RMM) 


0 mg/kg bw/day Method: External exposure 







a worker. 









a worker. 









a worker. 









a worker. 









a worker. 


2011-06-07




6.2.2. Exposure estimation for Worker for Transfer of formulations containing the substance (outdoors) 


substance (outdoors) 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 


2.058 mg/kg 

bw/day 





workers 


0.686 mg/kg 

bw/day 


workers 




ECETOC TRA 




ECETOC TRA 




ECETOC TRA 




2011-06-07




SUPPLEMENT 






















exposure 








exposure 


2011-06-07





Professional end-use of acid resistant coatings 



Worker 

Mixing and loading PROC 8a 

Laminating and cladding acid resistant coatings PROC 10 


Control of environmental exposure: Professional end-use of acid resistant coatings 


Amounts used 

Daily wide dispersive use = 5.5E-5 tonnes/day 

Frequency and duration of use 

Environment factors not influenced by risk management 

Receiving surface water flow rate >= 1.8E4 m3/d 

Other given operational conditions affecting environmental exposure 


Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil 

Organizational measures to prevent/limit release from site 

Conditions and measures related to municipal sewage treatment plant 

Municipal STP Yes 






Control of workers exposure for "Mixing and loading" [PROC 8a] 




Amounts used 




2011-06-07









Surface of skin exposed Two hands (960 cm2) L L 






Respiratory protection Respiratory protection capable offering a 

95% reduction in inhaled concentrations of 

the substance 

L L 

Body protection Wear specialistic full body protection 

[Dermal: 98%] 

AL AL 





Control of workers exposure for "Laminating and cladding acid resistant coatings" [PROC 10] 




Amounts used 








Surface of skin exposed Two hands (960 cm2) L L 






Respiratory protection Respiratory protection capable offering a 

95% reduction in inhaled concentrations of 

the substance 

L L 


2011-06-07




Body protection Wear specialistic full body protection 

[Dermal: 98%] 

AL AL 





7.2 Exposure estimation for Professional end-use of acid resistant coatings 

7.2.1. Exposure estimation for the environment (Professional end-use of acid resistant coatings) 



Compartme 

nt 

Water ERC 

(ERC 8c) 

Air ERC 

(ERC 8c) 

Soil ERC 

(ERC 8c) 





Local release rate (kg/day): 5.5E-4 






The following PECs are calculated based on the total EU tonnage used by professional workers. 




(Pelagic) 


(Sediment) 


(Pelagic) 


(Sediment) 


Local concentration: 3.48E-6 mg/L 


Local PEC: 1.53E-4 mg/L 

Local concentration: 3.48E-7 mg/L 

Local PEC: 7.75E-4 mg/kg dw 


Soil: Agricultural Soil Local PEC: 8.04E-4 mg/kg dw 

Local concentration: 1.09E-6 mg/kg 

dw 



2011-06-07





The following exposure concentrations are calculated based on the total EU volume used by professional workers. 







food 

Drinking 

water 
















Supplement. 

7.2.2. Exposure estimation for Worker for Mixing and loading 

Table 46. Summary of exposure concentrations for contributing scenario: Mixing and loading 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Exposure 

concentration 


assessment 









ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 


Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 


Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 


assessment 


workers 



workers 



(OC/RMM) 


0.822 mg/kg 

bw/day 





workers 


0.274 mg/kg 

bw/day 


workers 




ECETOC TRA 



7.2.2. Exposure estimation for Worker for Laminating and cladding acid resistant coatings 

Table 6. Summary of exposure concentrations for contributing scenario: Laminating and cladding acid resistant 

coatings 


exposure and 


Inhalation: 

Acute, Local 

Inhalation: 

Acute, 

Systemic 

Inhalation: 

Long term, 

Local 

Inhalation: 

Long term, 

Systemic 


Local 

Exposure 

concentration 


assessment 








workers 



workers 



(OC/RMM) 




ECETOC TRA 




ECETOC TRA 




2011-06-07





exposure and 



Systemic 

Dermal: Long 

term, Local 

Dermal: Long 


Exposure 

concentration 

1.647 mg/kg 

bw/day 


assessment 





workers 


0.549 mg/kg 

bw/day 


workers 




ECETOC TRA 




2011-06-07




SUPPLEMENT 






















exposure 








exposure 


2011-06-07

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