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BE406 Whiskey Production: A Comparison With Beer Production

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<strong>BE406</strong><br />

<strong>Whiskey</strong> <strong>Production</strong>: A <strong>Comparison</strong><br />

<strong>With</strong> <strong>Beer</strong> <strong>Production</strong><br />

� Index<br />

Names: James Murphy & Brendan O'Mahony<br />

ID: 52563631, 52322706<br />

Abstract – 2<br />

Introduction - 2<br />

• <strong>Whiskey</strong> and <strong>Beer</strong>: A Brief History - 2<br />

The Process of <strong>Whiskey</strong> production - 4<br />

• Step 1: Malting - 4<br />

• Step 2: Mashing - 6<br />

• Step 3: Fermentation - 7<br />

• Step 4: Distillation - 8<br />

• Step 5: Maturation - 10<br />

A <strong>Comparison</strong>: <strong>Beer</strong> <strong>Production</strong> Vs. <strong>Whiskey</strong> <strong>Production</strong> - 10<br />

Conclusion - 11<br />

References - 11<br />

1


� Abstract<br />

In this essay, the aim is to describe in detail the processes involved in the<br />

production of whiskey, and then to compare this process with that of beer, and to see<br />

what, if any differences lie within each. The origins of <strong>Whiskey</strong> and <strong>Beer</strong> are quite<br />

old, but the principles behind the production technique are still the same today, albeit<br />

the technology has changed to ensure improvements in quality etc. The six steps in<br />

the production of whiskey are Malting, Mashing, Fermentation, Distillation and<br />

Maturation, and these will be covered in great detail. The comparison between the<br />

two alcoholic beverages will focus solely on the production process changes, and does<br />

not embody and difference between the characteristics of each particular drink. It is<br />

from this comparison that it is hoped that the differences, if any in production process,<br />

will be clearly illustrated.<br />

� Introduction<br />

<strong>Whiskey</strong> is a barrel-aged alcohol made from grains or malts. It acquires its<br />

colour and flavour from the wooden barrels over time, and in this way whiskey differs<br />

from other grain alcohols. Through the distilling process, it keeps most of its flavour<br />

from the fermented mash by being distilled at a lower proof, and in this way has a<br />

stronger flavour than vodka. It has no other ingredients added to it, unlike other spirits<br />

like gin, etc.<br />

<strong>Beer</strong> has many definitions, amongst them are:<br />

i. A fermented alcoholic beverage brewed from malt and flavoured with hops.<br />

ii. A fermented beverage brewed by traditional methods that is then<br />

dealcoholised so that the finished product contains no more than 0.5 percent<br />

alcohol.<br />

iii. A carbonated beverage produced by a method in which the fermentation<br />

process is either circumvented or altered, resulting in a finished product<br />

having an alcohol content of no more than 0.01 percent.<br />

iv. A beverage made from extracts of roots and plants: birch beer.<br />

v. A serving of one of these beverages.<br />

• <strong>Whiskey</strong> and <strong>Beer</strong>: A Brief History<br />

The origin of whiskey is somewhat unclear, but the general consensus is this:<br />

In 6 th century AD, Irish missionary monks journeyed to the Middle East where it is<br />

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thought they observed the Arabs using the alembic * to distil perfume. Modern<br />

distillation process can be traced back to the Arabs, however it is the distillation, and<br />

production of <strong>Whiskey</strong> that is accredited to the Irish people. The monks brought back<br />

the new method of distillation back to Ireland, where they then developed their own<br />

version, the “Pot Still”. The knowledge quickly spread throughout the church, and<br />

over the monastery walls.<br />

<strong>Beer</strong> on the other hand is quite an ancient tradition, with archaeological<br />

records dating back to the time of the Sumerians in Mesopotamia, about 6000 years<br />

old, where a tablet depicts people drinking a beverage through reeds and becoming,<br />

“blissful, relaxed and exhilarated”. Another mention of beer from ancient times is in<br />

the “Epic of Gilgamesh” a 3900-year-old poem in honour of the goddess of brewing,<br />

“Ninkasi”. <strong>Beer</strong> developed independently throughout most of the world, with different<br />

cultures having there own take on beer, for instance the pre-Columbian civilisations in<br />

the America’s used corn instead of barley. <strong>Beer</strong> was quite popular with the Romans<br />

and Greeks, until wine became freely available in the empire. <strong>Beer</strong> was deemed a<br />

barbarians drink, and few places in the empire brewed it. In the middle ages,<br />

European monks were the guardians of literature and science, as well as the art of beer<br />

making. Both whiskey and beer production today are hugely profitable products, and<br />

are controlled by multinational conglomerates such as Diageo.<br />

The actual development of production of Irish whiskey has not changed<br />

enormously. <strong>Production</strong> still follows the same principle steps as initial distillation<br />

practices, albeit the technology has changed, and has become more refined. These<br />

changes were introduced also to brewing, and so a common bond is shared between<br />

them historically. One particular difference between whiskey and beer is the addition<br />

of hops to beer. This took place only recently (with respect to beer’s history), around<br />

the 15 th century.<br />

� Industrialisation of beer really took off with the invention of the steam engine<br />

in 1765.<br />

� Prior to the late 18 th century, malt was primarily wood-roasted, which gave it a<br />

dark colour and smoked flavour, but with the increasing availability of coal,<br />

when used in production processes, it lightened the colour and eliminated the<br />

smoke flavour.<br />

* An Alembic is an alchemical still consisting of two retorts connected by a tube. Technically, the<br />

alembic is only the upper part (the capital or still-head), but the word was often used to refer to the<br />

entire distillation apparatus.<br />

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� The invention of the thermometer and hydrometer in the 19 th century,<br />

improved quality control, with regards to increasing efficiency and<br />

attenuation.<br />

� In 1817, Daniel Wheeler invented the drum roaster allowed for the creation of<br />

very dark, roasted malts, contributing to the flavour of porters and stouts.<br />

� In 1857 Louis Pasteur discovered the role of yeast in fermentation. This gave<br />

more control in preventing the souring of beer by undesirable microorganisms.<br />

� In the1950s, Morton Coutts developed the technique of continuous<br />

fermentation. This process revolutionised the industry. During the continuous<br />

brewing process materials are added to one end of the system and<br />

continuously withdrawn from the other end. The standard system for brewing<br />

beer had ingredients put in together and then after a period of time (15 weeks)<br />

the brewed beer is removed and bottled altogether at the same time. This<br />

process is still used by many of the world's major breweries today, including<br />

Guinness.<br />

� The Process of <strong>Whiskey</strong> <strong>Production</strong><br />

The production of whiskey as a process is actually is quite simple. The most<br />

important part in making whiskey is the three main ingredients; Malted barley, water,<br />

and yeast. These ingredients undergo a process, which consists of five major steps, to<br />

produce whiskey. The steps are as follows; Step 1: Malting, Step 2: Mashing, Step<br />

3: Fermentation, Step 4: Distillation, and Step 5: Maturation. We will now look at<br />

each step individually to show practices involved in modern whiskey production.<br />

• Step 1: Malting<br />

Malting is the first step in whiskey production and it is a step that is made up<br />

of many smaller steps. It usually takes up to 5 - 7 days. The object of malting is to<br />

develop Enzymes from the barley and modify the starch present in the grain into<br />

fermentable sugars. First off the barley is collected from the fields, dried and stored.<br />

The drying and storage of barley is an important process in itself, as the moisture<br />

content must be lowered to prevent the germination of the seeds. This is very<br />

important in the likes of Ireland as the field barley tends be typically high in moisture.<br />

The barley, on intake, is dried for 2~3 hours at an air temperature no higher than<br />

52°C. The barley can then be stored at 25°C for 1-2weeks in an airtight silo or<br />

concrete bunker. For long term storage the temperature must be lowered to about<br />

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Embryo<br />

15°C and respiration in the barley grains maintained by keeping silos aerobic. Simply<br />

moving the grain from silo to silo can do this.<br />

The next step involves the steeping of the barley grain in water. In steeping the<br />

coat or husk of the grain is penetrated by the water, which increases the moisture<br />

content of the grain in turn increasing the grains metabolism and subsequent<br />

respiration. When these factors are increased the aeration of the grain must also be<br />

increased to insure that the metabolism does not become anaerobic. If this where to<br />

happen toxicity in the grain would increase in the form of CO2 and Ethanol. During<br />

steeping the early stages of embryonic growth are initiated, and this growth is<br />

continued through germination. It should be noted that regular aeration of the grain is<br />

carried out during the steeping process.<br />

A grain of barley consists of two main parts, the Embryo and the Endosperm.<br />

The embryo is the most important part of the grain as it houses all the organs that<br />

would develop into plant. The embryo is made up of three parts, the cotyledon (seed<br />

leaf), the epicotyl (shoot), and the radicle (root). The barley seed is a monocot due to<br />

it having only one cotyledon. The Endosperm contains the food source for the<br />

embryo, starch, protein, and its cell wall. The endosperm is utilised by the Embryo in<br />

the early stages of germination. The starch is converted, hydrolytically, to fermentable<br />

or simple sugars by enzymes that are secreted by the barley during germination.<br />

Below is a diagram of what a grain of barley looks like, and the subsequent reactions<br />

undergone during germination.<br />

Two forms of starch exist in the grain, amylase and amylopectin. The<br />

following enzymes degrade to starch into smaller polysaccharides; α-amalyse, β-<br />

amalyse, α-glucosidase, and phosphorylase. The most important of the enzymes<br />

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would be α-amalyse and β-amalyse. α-amalyse is synthesised once germination<br />

begins while β-amalyse is present in the grain in an inactive form, which subsequently<br />

becomes active during germination. α-amalyse is involved in the modification of the<br />

starch, attacking it randomly and cleaving it into short polysaccharides known as<br />

dextrins. β-amalyse attacks non-reducing ends of the starch producing maltose.<br />

Germination is usually carried out in drum or Box maltings. In Box malting<br />

the air temperature, which is saturated with moisture, is controlled and passed through<br />

the grain via holes in the box floor to maintain aeration of the grain. Turners are also<br />

employed to keep the grain free and to assist in the equal passage of air throughout the<br />

bed from the floor. This system provides ideal conditions for the germination of the<br />

barley irrespective of the atmospheric conditions.<br />

Once the barley grain begins sprouting, it is termed “green malt”, and is ready<br />

for drying. The “green malt” as it is termed on the completion of germination<br />

transferred to a malt kiln, which is a large drum with a furnace at the base, for drying.<br />

Hot air, from a hot air chamber located above the furnace and beneath the kiln, moves<br />

up through the grain, usually assisted by a fan. This heat is distributed evenly through<br />

out the grain. This drying step stops germination (denatures the enzyme β-amalyse)<br />

and changes the malt to a condition suitable for milling. Depending on whether the<br />

kiln is an open or closed kiln and what fuel is used in the furnace a flavour can be<br />

imparted to the malt. E.g. peat is usually burned for a scotch whiskey, while the likes<br />

of Jameson use a closed kiln allowing no smoke to come in contact with the drying<br />

malt, ensuring that the taste of the malt and barley are present in the final product.<br />

• Step 2: Mashing<br />

The grounded malted barley or grist is then added to a mash tun along with a<br />

precise amount of hot water. The mash tun is a circular metal vessel, which has<br />

mechanical stirrers that revolve and rotate to ensure thorough mixing of the grist and<br />

hot Water. The objective in mashing the malt is to dissolve as much of the valuable<br />

malt as possible. Enzymatic actions are undergone in the mashing process to convert<br />

starch to sugar. This enzyme action is influenced to a large extent by the<br />

concentration of the mash, its pH, and the water temperature. The resulting product is<br />

a sugary liquid known as the wort. The wort will contain intermediate products as<br />

well sugars.<br />

The wort is then collected in a wort receiver, which is located beneath the<br />

perforated floor of the mash tun. This allows the wort to drain and the grain to be<br />

6


etained in the tun. This process usually involves application of more water to ensure<br />

that no wort is left with the grain.<br />

The water used tends to play an important part in the final product. As water’s<br />

quantity in regards to type’s of minerals and organisms varies from region to region<br />

the location of production is as important as the barley grain used as to ship water<br />

would be costly and involve a lot of time and labour. Jameson whiskey is produced in<br />

Midleton cork (also the home of Irish Distillers Ltd) due to the waters being generally<br />

soft, as hard water would be unsuitable for the process. Regular analysis of water<br />

sources such as springs and burns assists in the prevention of contamination.<br />

It should be noted that there is also a technique employed by American<br />

distillery’s known as “double mashing” that uses low levels of cereal adjuncts, such as<br />

rice or maze, that are high in starch. These cheaper sources of extract are employed<br />

due to their ability to exploit high enzyme activity. This process also dilutes any<br />

unwanted nitrogenous compounds. Another technique used in the making of bourbon<br />

and Tennessee whiskeys is “sour mash”. This involves the use of a portion of a<br />

previous mashing batch to start the next batch. Its quite similar to what is mentioned<br />

above with reference to the final wash, except this portion tends to come from the<br />

final mash product. The ides of this practice is to maintain consistency. The reason for<br />

the name is because the practice is quite similar to the making of sourdough bread.<br />

• Step 3: Fermentation<br />

Fermentation is the conversion of sugars, contained in the wort, to alcohol.<br />

This is done under the action of yeast, producing alcohol and carbon dioxide<br />

[C6H12O6 —> 2 (C2H5OH) + 2 (CO2)] with an emission of heat. Yeast, upon<br />

introduction to the wort, can convert fermentable sugars in three ways i) aerobically<br />

through respiration, but only if there is a high abundance of oxygen available through<br />

out the process, ii) growth or multiplication, by utilising the sugars to form new cell<br />

materials, or by iii) fermentation. Fermentation is an anaerobic reaction.<br />

During fermentation yeast can be seen to act in three stages. The first stage is<br />

the lag stage where not much fermentation is observed, due the yeast generally<br />

adapting to its new environment. Precautions need to be taken during the addition of<br />

the yeast to the wort as were bacterial contamination to occur it would cause a great<br />

deal of damage to the batch leading to poor fermentation, poor yield of spirit, and<br />

poor quality/taste in the final product. To prevent such an event strict cleaning and<br />

sterilisation is performed to ensure that the mashing and fermenting process remain<br />

bacteria free at all times.<br />

7


The second stage is the stage of rapid fermentation or the log phase. During<br />

the log phase the fermentation rate is at it’s highest. Temperatures sore during this log<br />

phase and should be monitored with great care. If the temperature increases to rapidly<br />

or exceeds 35°C the yeast will be denatured and a high percentage of spirits lost. In<br />

this phase rotating metal blades, known as switchers, are usually used to quell the<br />

froth caused to the production CO2.<br />

The final stage is the slowing and termination of the fermentation reaction, which<br />

tends to be down to there being no fermentable sugars left in the wort. Generally<br />

fermenting never lasts more than 48 hours and any fermentation that may occur past<br />

the mark is considered to be insignificant. This being said the rate of fermentation is<br />

variable and down to such factors as temperature, type and amount of yeast used, its<br />

condition, type of malt, purity of water and amount of suspended solids in the wort.<br />

The product yielded after distillation of the wort is a weak beer substance known as<br />

the wash.<br />

• Step 4: Distillation<br />

Distilling of the wash (product from fermentation) involves vaporisation and<br />

condensation. This simple means heating the liquid to vapour then cooling it back to<br />

liquid. Distillation is a means of separating the alcohol and the solids/liquid/residue in<br />

the wash. The reason this separation is needed is because the wash is made up of dead<br />

yeast etc from the fermentation process. It is necessary that solids/residues from the<br />

fermentation process remain suspended during the distillation process so that they do<br />

not stick to the sides and burn the still. To prevent this three rotating arms attached to<br />

brass and copper chains are used, inside the still, to keep the wash agitated and<br />

constantly moving. This device is known as a rummager.<br />

The still is two large copper pots of different sizes that are bridged (connected)<br />

at the top by what is known as a swan neck. Below is a picture of a simple two copper<br />

pot still.<br />

Spirit still<br />

Swan neck<br />

Still containing<br />

wash<br />

8


The wash is placed in one of the copper pots, usually the large of the two and<br />

is heated to high enough temperatures that promote the formation of alcohol vapour.<br />

This varies from whiskey to whiskey as it relies upon the percentages of alcohol, litres<br />

of wash, and measured distillate collection of the still. A more accurate way of<br />

measuring cut off point is % of alcohol rather than temperature. Anyways, the alcohol<br />

vapour will rise to the swan neck and subsequent condenser, which is a series of pipes<br />

wrapped in a cooling (cold-water) jacket. It is here, in the condenser, that the alcohol<br />

vapour will condense into liquid and be collected in the smaller of the two copper<br />

pots. This pot is known as the spirit still. The newly condensed alcohol tends to be of<br />

about ~20% and termed low wines. This percentage will differ from distillery to<br />

distillery depending on materials, methods, and desired product but his is the general<br />

figure expected. This alcohol strength is measured in the spirit safe. Prior to the<br />

alcohol flowing into the spirit still it passes through the spirit safe, which is a control<br />

point of distillation. It is here in the spirit safe that the alcohol may be tested for<br />

strength by an internal hydrometer located in the safe.<br />

The height of the wash’s froth is monitored during distillation as high<br />

temperatures may cause the froth to reach excessive heights and spill into the spirit<br />

still via the bridging swan neck. A small window in the first pot monitors this, and<br />

adjustments to temperature are made accordingly.<br />

The majority of whiskeys undergo a second distillation of the first distillation<br />

product. The original Irish distillation process dictates that a triple distillation be<br />

performed in the making of whiskey. This is employed by most if not all whiskey<br />

produced in Ireland, such as Jameson’s distillery, Midleton, Co. Cork. “The<br />

distillation of Jameson follows the traditional method employed for whiskey<br />

distillation in Ireland. Distillation is carried out using traditional techniques in Pot<br />

Stills. The Irish tradition requires three distillation stages… Grain <strong>Whiskey</strong>, is also<br />

distilled through three columns. Unlike the practice elsewhere, the columns include<br />

a <strong>Beer</strong> Column, Extractive column, and Rectifying column… By products from the<br />

plant are dried and sold as distillers dried grains. All residual process liquid streams<br />

are finally processed through an on site effluent plant.” – Barry Crockett of<br />

Jameson Distillery, Midleton, Co. Cork.<br />

Jameson believes each distillation lends to the final whiskey products<br />

smoothness and superior quality. Once triple distillation is completed the product is<br />

termed “new whiskey” and is ready for the maturation stage.<br />

9


• Step 5: Maturation<br />

Oak casks tend to be the standard used for maturation of new whiskey, as well<br />

as blending of different whiskeys from different distillation batches and matured<br />

whiskeys, and the process of maturation can take anything from 3 to 15 years<br />

depending on the quality desired. The reason for oak casks being used opposed to<br />

other wooden casks is oaks ability to absorb impurities and its ability to allow the<br />

whiskey to breath. An interesting part of the maturation process is the loss of alcohol<br />

through evaporation. This is generally termed the “angels share”, and it is usually<br />

about 10 to 8 percent of the alcohol in the first year, with a loss of 4% every year<br />

after. A good whiskey is estimated to lose approximately 30% of its original volume<br />

before being bottled. The process of maturation tends to change from distillery to<br />

distillery depending on what flavour, quality, and final taste is desired. Traditions of<br />

production also tend to dictate maturation process used for the whiskey.<br />

The maturation of Jameson whiskey is done in oak casks that have been<br />

previously seasoned by holding bourbon and sherry. This is done to make the final<br />

taste of the whiskey more distinct with a smooth after taste. Jameson also employs<br />

blending of different batches of whiskey to acquire good flavour in taste.<br />

� A <strong>Comparison</strong>: <strong>Beer</strong> <strong>Production</strong> vs. <strong>Whiskey</strong> <strong>Production</strong><br />

<strong>Beer</strong> production and whiskey production are very similar in the fact that they<br />

both require malted barley. The initial ingredients for production of both drinks are<br />

the same, although inferior American beers choose to substitute barley with rice, corn,<br />

or other cheap starch rich grains. Brewery malt is usually manipulated in various ways<br />

(e.g. roasting) to create different flavours and colours, creating a range that stretches<br />

from Pilsner or light beers to dark lagers and stouts such as Guinness. For beers, hops<br />

are added to the wort prior to fermentation to add taste. It is this addition of hops that<br />

makes beer what it is and gives it its flavour. Once the hop flavour has taken to the<br />

wort it is then cooled the hops extracted prior to fermentation.<br />

The production process of fermentation for both beer and whiskey undergo the<br />

same reactions except that the fermentation of beer tends to go for a much longer<br />

period of time, 7-10days, and at a much lower temperature of 7-25°C depending on<br />

the type of beer being brewed, opposed to whiskey fermentation, which is run at a<br />

temperatures as high as 25-30°C and lasts for only 48 hours yielding a weak hopless<br />

beer that is known as wash. However continuous fermentation can be used to speed<br />

up the fermentation of beer to times as quick as 24 – 30 hours. Fermentation is the last<br />

10


step of brewing; it is then blended and matured for anything from 1 to 4 weeks in oak<br />

casks.<br />

The yeast used during the fermentation of beer tends to be recycled and used<br />

in the brewing of other batches of beer. In some cases the yeast is not full extracted<br />

from the final beer resulting in what is known as a “vice-beer”. Vice beer tend to be<br />

very white in colour and sometimes cloudy, and example of a vice beer would be<br />

Stella Artois <strong>Beer</strong> from Belgium. Neither of these methods are practiced in the<br />

production of whiskey.<br />

Due to production processes and final maturation processes being quite<br />

similar, in the use of oak casks, similar flavours can be observed in good whiskeys<br />

and good beers, independent of actual alcohol levels.<br />

� Conclusion<br />

From the above, it can be seen that both <strong>Whiskey</strong> and <strong>Beer</strong> are very similar in<br />

the production processes, though distillation and maturation really separates the two<br />

products. While both have similar production backgrounds, their histories are quite<br />

different, whiskey being a homegrown effort for the Irish. Although not really<br />

touched upon in this essay, both drinks are quite different, and the different varieties<br />

ensure a multitude of ways to make a mess of yourself, especially when mixed. The<br />

best and worst whiskies come down to a matter of taste, though Midleton was one of<br />

the more highly regarded whiskies available. As for beer, the numerous brands, and<br />

styles make it impossible for one to recommend any brand in particular.<br />

� References<br />

The dictionary of beer and brewing, 2 nd edition, by Dab Rabin and Carl Forget<br />

1000 years of Irish whiskey, by Malachy Magee<br />

Malting and brewing science, 2 nd edition, by D.E. Briggs<br />

http://www.ces.purdue.edu/extmedia/AE/AE-117.html<br />

www.mindspring.com/~mccarthys/whiskey/corn.htm<br />

http://www.whisky.com/index.html<br />

http://www.le-brewery.com/productionofbeer.htm<br />

http://www.beerinfo.com/vlib/<br />

http://www.tourismvictoria.com/Content/EN/349.asp<br />

http://en.wikipedia.org/wiki/<strong>Beer</strong><br />

Barry Crockett of Jameson Distillery, Midleton. Co. Cork, and The Old Jameson<br />

Distillery, Smithfield village. Co. Dublin.<br />

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