Steel grade characteristics of NSSC FW1 - Stemcor
Steel grade characteristics of NSSC FW1 - Stemcor
Steel grade characteristics of NSSC FW1 - Stemcor
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<strong>Stemcor</strong> Stainless (UK) is the<br />
agent and sales channel for<br />
<strong>NSSC</strong>’s FW <strong>grade</strong>s<br />
in the UK and Ireland
Introducing new products from <strong>NSSC</strong><br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Materials Design <strong>of</strong> FW Series<br />
1
Sn Added, Extra-low interstitial Ferritic Stainless <strong>Steel</strong><br />
― The FW Series<br />
~ Resource-saving and highly corrosion resistant <strong>NSSC</strong>® <strong>FW1</strong> and FW2 ~<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
2
Basic Technology Underlying the <strong>NSSC</strong> FW Series<br />
~ Effects <strong>of</strong> adding Sn ~<br />
Effects <strong>of</strong> Sn on corrosion<br />
resistance<br />
Appearance after 168 hr immersion test<br />
14 Cr (for comparison)<br />
Immersed 168 hrs in a 0.5% NaCl water solution at 80ºC<br />
30mm x 30mm, with #600 polish finish<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
2~5<br />
nm<br />
Schematic <strong>of</strong> Sn's<br />
form <strong>of</strong> existence based on<br />
results <strong>of</strong> surface analyses<br />
Passivity 不働態皮膜 film<br />
(Fe,Cr) 2O3 + (Sn-O,Sn)<br />
Metal 金属母地 substrate<br />
(Cr-Sn-Low C,N)<br />
Cr<br />
incrassation<br />
Cr<br />
濃化<br />
3
<strong>FW1</strong> and FW2 – Corrosion resistance and formability,<br />
an exceptional combination<br />
409L<br />
430<br />
Copyright© Source : 2010 2011 <strong>NSSC</strong>. All All Rights Reserved. Reserved.<br />
<strong>NSSC</strong> <strong>FW1</strong><br />
Corrosion Resistance<br />
304<br />
<strong>NSSC</strong> FW2<br />
(14Cr-0.1Sn-LC,Nb) (16Cr-0.3Sn-LC,Nb)<br />
441<br />
→Excellence<br />
316<br />
Schematic Illustration<br />
Ferritic type<br />
Austenitic type
Advantages and steel <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />
[Advantages]<br />
<strong>NSSC</strong> <strong>FW1</strong> (Forward 1) 14Cr-0.1Sn-LC, N<br />
1. While <strong>FW1</strong> is a 14% Cr steel, it delivers corrosion and rust resistance that is<br />
equal to or better than 17% Cr (<strong>NSSC</strong> 430D and TP439) steels. A small amount<br />
<strong>of</strong> Sn is added to strengthen the passivity film.<br />
2. <strong>FW1</strong> <strong>of</strong>fers among the best formability <strong>of</strong> our high-purity ferritic steels, and<br />
excellent post-forming surface properties (anti-ridging).<br />
3. Thorough alloy-saving efforts have been made (Ni and Mo-free, reduced Cr<br />
content, and appropriate content <strong>of</strong> trace elements) to minimize the effects <strong>of</strong><br />
fluctuating raw material prices.<br />
[Chemical composition] (Mass%)<br />
Grade<br />
values<br />
Representative examples<br />
[Mechanical <strong>characteristics</strong>]<br />
C Si Mn P S Cr Sn Nb+Ti N<br />
13.75 0.10<br />
0.010 0.50 0.50 0.040 0.030 ~ 15.00 ~ 0.25 10(C+N) 0.015<br />
0.004 0.12 0.10 0.024 0.001 14.4 0.11 0.20 0.010<br />
Yield strength 0.2% <strong>of</strong>fset<br />
(N/mm)<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Tensile strength<br />
(N/mm)<br />
Elongation<br />
(%)<br />
Hardness<br />
(HV)<br />
Grade values 175 360 28 180<br />
Representative examples<br />
260 420 35 130<br />
(Surface finish: 2B, thick plate; 0.6mm, JIS13B, L direction)<br />
5
Pitting<br />
resistance<br />
potential<br />
<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />
Good<br />
↑<br />
Potential at which pitting<br />
occurs (Vv.s.AGCL)<br />
Appearance after<br />
salt spray test<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
~ Corrosion resistance ~<br />
Tp.430<br />
(17Cr)<br />
Tp.430<br />
(17Cr)<br />
SUS430LX<br />
(17Cr-Ti-LC)<br />
SUS430LX<br />
(17Cr-Ti-LC)<br />
#600 polish<br />
TIG + #600 polish<br />
<strong>NSSC</strong><strong>FW1</strong><br />
(14Cr-0.1Sn-LC)<br />
Continuously sprayed for 168 hrs with a 5% NaCl water solution at 35ºC, Complies with JISZ2371.<br />
50mm x 100mm, with #600 polish finish<br />
Pitting resistance<br />
potential <strong>of</strong> Tp304<br />
(18cr-8Ni)<br />
The corrosion resistance <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong> (14Cr-0.1Sn-LC) is superior to SUS430XL (17Cr-Ti-LC)<br />
6
<strong>NSSC</strong> <strong>FW1</strong> steel <strong>grade</strong> <strong>characteristics</strong><br />
~ Formability and moldability ~<br />
Limit drawing value (cylinder drawing test)<br />
良<br />
↑<br />
Good<br />
Limit draw ratio<br />
限界絞り比<br />
2.30<br />
2.25<br />
2.20<br />
2.15<br />
2.10<br />
2.05<br />
2.00<br />
<strong>NSSC</strong><strong>FW1</strong><br />
(14Cr-0.1Sn-LC)<br />
<strong>NSSC</strong><strong>FW1</strong><br />
(14Cr)<br />
Surface roughness after press forming (Cylinder drawing)<br />
<strong>NSSC</strong><strong>FW1</strong><br />
(14Cr-0.1Sn-LC)<br />
SUS430LX<br />
(17Cr-TI-LC)<br />
SUS430LX<br />
(17Cr)<br />
SUS430LX<br />
(17Cr-Ti-LC)<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
LDR level<br />
<strong>of</strong> Tp304<br />
Tp.430<br />
(17Cr)<br />
SUS430<br />
(17Cr)<br />
良<br />
↑<br />
エリクセン高さ,mm<br />
Flangeability (Erichsen test)<br />
Tp304 level: ~ 14mm<br />
10<br />
Good<br />
Erichsen height, mm<br />
9<br />
8<br />
7<br />
6<br />
<strong>NSSC</strong><strong>FW1</strong><br />
(14Cr-0.1Sn-LC)<br />
SUS430LX<br />
(17Cr-Ti-LC)<br />
Tp430<br />
(17Cr)<br />
<strong>NSSC</strong> <strong>FW1</strong> SUS430LX SUS430<br />
<strong>NSSC</strong><strong>FW1</strong> (14 Cr - 0.1 Sn-LC)<br />
<strong>of</strong>fers better formability than<br />
SUS430LX (17 Cr-Ti-LC), with less<br />
surface roughness after it is formed.<br />
(Thickness: 0.6mm, draw rate: 2.0)<br />
7
<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
~ Characteristics <strong>of</strong> welded areas ~<br />
Flangeability <strong>of</strong> TIG welded areas<br />
Good (Erichsen test)<br />
Erichsen height, mm ↑<br />
Good<br />
↑<br />
Welding heat input, J/cm<br />
H=60・E・I/v<br />
H:溶接入熱(J/cm),E:アーク電圧(V)<br />
I:溶接電流(A),v:溶接速度(cm/min)<br />
H: Welding heat input (J/cm), E: Arc voltage (V),<br />
I: Weld current (A), v: Weld speed (cm/min)<br />
Corrosion resistance <strong>of</strong> TIG welded areas<br />
(salt water immersion test)<br />
<strong>NSSC</strong><strong>FW1</strong>/TIG unfinished<br />
SUS430LX (<strong>NSSC</strong> 430D)/TIG unfinished SUS430/TIG unfinished<br />
● Test conditions: TIG welding was performed so that an uranami bead<br />
<strong>of</strong> about 1.5mm is made.<br />
Surface condition: TIG welded and unfinished (2B), and TIG welded<br />
and polish finished to #600<br />
Immersion solution and time: 168 hrs in 0.5% NaCl solution at 80ºC<br />
<strong>NSSC</strong> <strong>FW1</strong> (14Cr-0.1Sn) can be TIG welded under the same conditions as SUS<br />
430LX (17CR), a conventional extra-low interstitial ferritic steel.<br />
Formability and corrosion resistance <strong>of</strong> the welded areas are also good.<br />
8
Stainless steel composition<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Advantages <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />
Reduce rare metal content by<br />
Iron<br />
Nickel<br />
Chrome<br />
SUS304<br />
Major generic<br />
steel <strong>grade</strong><br />
23%<br />
SUS430LX<br />
Generic Niless<br />
steel <strong>grade</strong><br />
Rate <strong>of</strong> reduction in chrome content<br />
9
Sn Added, Extra-low interstitial Ferritic Stainless <strong>Steel</strong><br />
― The FW Series<br />
~ Resource-saving and highly corrosion resistant <strong>NSSC</strong> FW2 ~<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Nippon <strong>Steel</strong> & Sumikin Stainless <strong>Steel</strong> Corporation<br />
10
Advantages and steel <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> FW2<br />
[Advantages]<br />
1. While FW2 is a 16% Cr steel, it delivers corrosion and rust resistance that is<br />
equal to that <strong>of</strong> SUS304 (18C-8Ni) under regular conditions.<br />
2. FW2 <strong>of</strong>fers among the best formability <strong>of</strong> ferritic steels. By selecting the<br />
appropriate forming conditions (drawability), FW2 <strong>of</strong>fers mold formability<br />
equal to that <strong>of</strong> SUS304.<br />
3. Thorough alloy-saving efforts have been made (Ni, Mo, and Cu-free, reduced<br />
Cr content) to minimize the effects <strong>of</strong> fluctuating raw material prices.<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
<strong>NSSC</strong> FW2 (Forward 2) 16Cr-0.3Sn-LC, N<br />
[Chemical composition] (Mass%)<br />
Grade<br />
values<br />
Representative examples<br />
C Si Mn P S Cr Sn Nb+Ti N<br />
15.75 0.3<br />
0.010 0.50 0.50 0.040 0.030 ~ 17.00 ~ 0.45 10(C+N) 0.015<br />
0.005 0.07 0.06 0.02 0.001 16.4 0.31 0.22 0.01<br />
[Mechanical <strong>characteristics</strong>]<br />
0.2% bearing force<br />
(N/mm)<br />
Tensile strength<br />
(N/mm)<br />
Elongation<br />
(%)<br />
Hardness<br />
(HV)<br />
Grade values 205 390 25 200<br />
Representative examples 279 463 32 144<br />
(Surface finish: 2B, thick plate; 0.6mm, JIS13B, L direction)<br />
11
<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> FW2<br />
~ Corrosion resistance 1~<br />
Improved salt spray corrosion test (salt water environment)<br />
<strong>NSSC</strong> FW2<br />
(16Cr-0.3Sn)<br />
Test sample shape: 50 x 100 with top end bent at 90º angle. Surface: Finished at<br />
#600<br />
Solution: 24 hrs in 0.5% NaCl + 2% H 2O 2 at 35ºC. Other conditions comply with<br />
JISZ2371<br />
Rust resistance in salt water environments was greatly<br />
improved over SUS430 and is equal to that <strong>of</strong> SUS304.<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
SUS304<br />
(18Cr-8Ni)<br />
SUS430<br />
(17Cr)<br />
12
Various formability <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong><br />
<strong>FW1</strong> and FW2<br />
Formability (plate thickness: 0.6mm)<br />
By selecting the appropriate forming conditions, <strong>NSSC</strong> <strong>FW1</strong><br />
and FW2 can be mold formed in the same way as SUS304.<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Drawability Bulge expandability<br />
Average<br />
r value<br />
LDR n value<br />
Hydraulic bulge<br />
height (mm)<br />
<strong>NSSC</strong> <strong>FW1</strong> 1.7 2.3 0.22 31.5<br />
<strong>NSSC</strong> FW2 1.7 2.3 0.24 30.5<br />
SUS430 1.0 2.0 0.16 27.0<br />
SUS304 1.1 2.1 0.42 40.5<br />
13
<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />
~ Formability and moldability ~<br />
Results from comparative simulations <strong>of</strong> moldability under the same conditions<br />
SUS304;h=52mm<br />
Blank: 240 x 240mm<br />
Punch: 100 x 100mm,<br />
Corners: r 20mm, rp 10mm<br />
Die: 103 x 103mm, rd 5mm<br />
Friction coefficient: 0.10, Plate thickness: 0.8mm<br />
Fold pressure: 20 tons<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Crack<br />
<strong>NSSC</strong> 180;h=24mm<br />
<strong>NSSC</strong> <strong>FW1</strong>;h=32mm<br />
14
Apply high lubrication film<br />
Smaller fold pressure<br />
<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />
~ Formability and moldability ~<br />
Results from simulations <strong>of</strong> moldability under appropriate conditions<br />
Fold pressure: 10 tons Fold pressure: 10 tons<br />
<strong>NSSC</strong> 180;<br />
H=52mm<br />
<strong>NSSC</strong> 180;<br />
H=52mm<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
<strong>NSSC</strong> <strong>FW1</strong>;<br />
h=60mm<br />
Friction coefficient: 0.06 Friction coefficient: 0.06<br />
<strong>NSSC</strong> <strong>FW1</strong>;<br />
h=60mm<br />
15
<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> FW2<br />
~ Formability and moldability ~<br />
Multi-drawing <strong>characteristics</strong> ~ Appearance after multi drawing ~<br />
4 th stage<br />
drawing<br />
<strong>NSSC</strong> FW2<br />
(16Cr-0.3Sn)<br />
3 rd stage<br />
drawing<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
SUS304<br />
(18Cr-8Ni)<br />
<br />
J4(14Cr-1Ni-Mn)<br />
Plate thickness: 0.6mm (cold-finished once) Blank diameter: 80mm Lubricant: J.W. #122<br />
Punch diameters (mm): 1st stage 40 2nd stage 35 3rd stage 30 4th stage 25<br />
<strong>NSSC</strong> FW2 leads to forming by multi-drawing without<br />
developing any cracks.<br />
Season cracking occurs with SUS304.<br />
16
100%<br />
26%<br />
18%<br />
16%<br />
Advantages <strong>of</strong> <strong>NSSC</strong> FW2 -Resource-saving-<br />
Rare metal (Cr, Ni) use can be reduced by 40%.<br />
Fe<br />
Iron<br />
8%Ni<br />
Nickel<br />
Stainless steel composition Small amounts <strong>of</strong> added Sn improves corrosion resistance, and thereby<br />
0%<br />
18%Cr<br />
Chrom<br />
e<br />
18%Cr-8%Ni<br />
SUS304 (generic steel)<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
・Equal corrosion<br />
resistance<br />
・Good<br />
formability<br />
・Good<br />
weldability<br />
Fe<br />
Iron<br />
16%Cr<br />
Chrom<br />
e<br />
16%Cr-0.3Sn<br />
<strong>NSSC</strong> FW2<br />
0%<br />
40%<br />
100%<br />
←Rate <strong>of</strong> reduction in rare metal content<br />
17
IH (induction-heating) rice cookers<br />
Lithium-ion battery cases<br />
(Deep drawing applications)<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Examples <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong> applications<br />
Large rectangular vats<br />
Candidate applications for <strong>NSSC</strong> <strong>FW1</strong><br />
Washing<br />
machine drums<br />
Rice washing bowls<br />
Building materials and<br />
architectural members<br />
Hinges<br />
18
Examples <strong>of</strong> <strong>NSSC</strong> FW2 applications<br />
Kitchen sinks Cooking trays<br />
Yukihira pan<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
Expanded metal<br />
(mesh)<br />
All existing applications where<br />
SUS304 (18 Cr-8 Ni) is used are<br />
candidate applications for FW2.<br />
19
Range <strong>of</strong> manufacturability <strong>of</strong> cold-finished<br />
products from <strong>NSSC</strong> <strong>FW1</strong> and FW2<br />
Shape Thickness (mm) Width (mm) Length (mm)<br />
Cutlength sheets 0.3 ~ 4.0 300 ~ 1,250/1524 8,000 max.<br />
Coils 0.3 ~ 4.0 200 ~ 1,250/1524<br />
* Available in high-gloss 2B finish.<br />
* A variety <strong>of</strong> finishes, including BA, are also available.<br />
* Please inquire for dimensions and specifications not<br />
shown here.<br />
Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />
20
Nikkei Excellent Product or Service Award 2010<br />
~ <strong>NSSC</strong> <strong>FW1</strong> is awarded the Grand Award in the Nikkei Sangyo Shimbun Awards ~<br />
坂村 健 先生 内館 牧子 氏<br />
Copyright© 2011 <strong>NSSC</strong>. 2011 All Rights <strong>NSSC</strong>. Reserved.<br />
All Rights Reserved.<br />
"The fact that the stainless steel sheets<br />
developed by Nippon <strong>Steel</strong> & Sumikin<br />
Stainless <strong>Steel</strong> Corporation addresses<br />
the resource-scarce situation in Japan is<br />
worthy <strong>of</strong> much praise."<br />
"One <strong>of</strong> the more important products were<br />
the stainless steel sheets developed by<br />
Nippon <strong>Steel</strong> & Sumikin Stainless <strong>Steel</strong><br />
Corporation. This is a good example <strong>of</strong><br />
industry addressing the issue <strong>of</strong> resource<br />
scarcity and their fluctuating supply."<br />
日経産業新聞 2011.2.5 より<br />
21
Product<br />
type<br />
Thin<br />
sheets<br />
Thick<br />
sheets<br />
Copyright© 2011 <strong>NSSC</strong>. 2011 All Rights <strong>NSSC</strong>. Reserved.<br />
All Rights Reserved.<br />
Primary <strong>characteristics</strong><br />
Corrosion<br />
resistance<br />
Corrosion<br />
resistance<br />
Mold<br />
formability<br />
Strength<br />
<strong>NSSC</strong><br />
suggestions<br />
FW Series<br />
Duplex<br />
stainless steel<br />
22