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Steel grade characteristics of NSSC FW1 - Stemcor

Steel grade characteristics of NSSC FW1 - Stemcor

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<strong>Stemcor</strong> Stainless (UK) is the<br />

agent and sales channel for<br />

<strong>NSSC</strong>’s FW <strong>grade</strong>s<br />

in the UK and Ireland


Introducing new products from <strong>NSSC</strong><br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Materials Design <strong>of</strong> FW Series<br />

1


Sn Added, Extra-low interstitial Ferritic Stainless <strong>Steel</strong><br />

― The FW Series<br />

~ Resource-saving and highly corrosion resistant <strong>NSSC</strong>® <strong>FW1</strong> and FW2 ~<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

2


Basic Technology Underlying the <strong>NSSC</strong> FW Series<br />

~ Effects <strong>of</strong> adding Sn ~<br />

Effects <strong>of</strong> Sn on corrosion<br />

resistance<br />

Appearance after 168 hr immersion test<br />

14 Cr (for comparison)<br />

Immersed 168 hrs in a 0.5% NaCl water solution at 80ºC<br />

30mm x 30mm, with #600 polish finish<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

2~5<br />

nm<br />

Schematic <strong>of</strong> Sn's<br />

form <strong>of</strong> existence based on<br />

results <strong>of</strong> surface analyses<br />

Passivity 不働態皮膜 film<br />

(Fe,Cr) 2O3 + (Sn-O,Sn)<br />

Metal 金属母地 substrate<br />

(Cr-Sn-Low C,N)<br />

Cr<br />

incrassation<br />

Cr<br />

濃化<br />

3


<strong>FW1</strong> and FW2 – Corrosion resistance and formability,<br />

an exceptional combination<br />

409L<br />

430<br />

Copyright© Source : 2010 2011 <strong>NSSC</strong>. All All Rights Reserved. Reserved.<br />

<strong>NSSC</strong> <strong>FW1</strong><br />

Corrosion Resistance<br />

304<br />

<strong>NSSC</strong> FW2<br />

(14Cr-0.1Sn-LC,Nb) (16Cr-0.3Sn-LC,Nb)<br />

441<br />

→Excellence<br />

316<br />

Schematic Illustration<br />

Ferritic type<br />

Austenitic type


Advantages and steel <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />

[Advantages]<br />

<strong>NSSC</strong> <strong>FW1</strong> (Forward 1) 14Cr-0.1Sn-LC, N<br />

1. While <strong>FW1</strong> is a 14% Cr steel, it delivers corrosion and rust resistance that is<br />

equal to or better than 17% Cr (<strong>NSSC</strong> 430D and TP439) steels. A small amount<br />

<strong>of</strong> Sn is added to strengthen the passivity film.<br />

2. <strong>FW1</strong> <strong>of</strong>fers among the best formability <strong>of</strong> our high-purity ferritic steels, and<br />

excellent post-forming surface properties (anti-ridging).<br />

3. Thorough alloy-saving efforts have been made (Ni and Mo-free, reduced Cr<br />

content, and appropriate content <strong>of</strong> trace elements) to minimize the effects <strong>of</strong><br />

fluctuating raw material prices.<br />

[Chemical composition] (Mass%)<br />

Grade<br />

values<br />

Representative examples<br />

[Mechanical <strong>characteristics</strong>]<br />

C Si Mn P S Cr Sn Nb+Ti N<br />

13.75 0.10<br />

0.010 0.50 0.50 0.040 0.030 ~ 15.00 ~ 0.25 10(C+N) 0.015<br />

0.004 0.12 0.10 0.024 0.001 14.4 0.11 0.20 0.010<br />

Yield strength 0.2% <strong>of</strong>fset<br />

(N/mm)<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Tensile strength<br />

(N/mm)<br />

Elongation<br />

(%)<br />

Hardness<br />

(HV)<br />

Grade values 175 360 28 180<br />

Representative examples<br />

260 420 35 130<br />

(Surface finish: 2B, thick plate; 0.6mm, JIS13B, L direction)<br />

5


Pitting<br />

resistance<br />

potential<br />

<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />

Good<br />

↑<br />

Potential at which pitting<br />

occurs (Vv.s.AGCL)<br />

Appearance after<br />

salt spray test<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

~ Corrosion resistance ~<br />

Tp.430<br />

(17Cr)<br />

Tp.430<br />

(17Cr)<br />

SUS430LX<br />

(17Cr-Ti-LC)<br />

SUS430LX<br />

(17Cr-Ti-LC)<br />

#600 polish<br />

TIG + #600 polish<br />

<strong>NSSC</strong><strong>FW1</strong><br />

(14Cr-0.1Sn-LC)<br />

Continuously sprayed for 168 hrs with a 5% NaCl water solution at 35ºC, Complies with JISZ2371.<br />

50mm x 100mm, with #600 polish finish<br />

Pitting resistance<br />

potential <strong>of</strong> Tp304<br />

(18cr-8Ni)<br />

The corrosion resistance <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong> (14Cr-0.1Sn-LC) is superior to SUS430XL (17Cr-Ti-LC)<br />

6


<strong>NSSC</strong> <strong>FW1</strong> steel <strong>grade</strong> <strong>characteristics</strong><br />

~ Formability and moldability ~<br />

Limit drawing value (cylinder drawing test)<br />

良<br />

↑<br />

Good<br />

Limit draw ratio<br />

限界絞り比<br />

2.30<br />

2.25<br />

2.20<br />

2.15<br />

2.10<br />

2.05<br />

2.00<br />

<strong>NSSC</strong><strong>FW1</strong><br />

(14Cr-0.1Sn-LC)<br />

<strong>NSSC</strong><strong>FW1</strong><br />

(14Cr)<br />

Surface roughness after press forming (Cylinder drawing)<br />

<strong>NSSC</strong><strong>FW1</strong><br />

(14Cr-0.1Sn-LC)<br />

SUS430LX<br />

(17Cr-TI-LC)<br />

SUS430LX<br />

(17Cr)<br />

SUS430LX<br />

(17Cr-Ti-LC)<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

LDR level<br />

<strong>of</strong> Tp304<br />

Tp.430<br />

(17Cr)<br />

SUS430<br />

(17Cr)<br />

良<br />

↑<br />

エリクセン高さ,mm<br />

Flangeability (Erichsen test)<br />

Tp304 level: ~ 14mm<br />

10<br />

Good<br />

Erichsen height, mm<br />

9<br />

8<br />

7<br />

6<br />

<strong>NSSC</strong><strong>FW1</strong><br />

(14Cr-0.1Sn-LC)<br />

SUS430LX<br />

(17Cr-Ti-LC)<br />

Tp430<br />

(17Cr)<br />

<strong>NSSC</strong> <strong>FW1</strong> SUS430LX SUS430<br />

<strong>NSSC</strong><strong>FW1</strong> (14 Cr - 0.1 Sn-LC)<br />

<strong>of</strong>fers better formability than<br />

SUS430LX (17 Cr-Ti-LC), with less<br />

surface roughness after it is formed.<br />

(Thickness: 0.6mm, draw rate: 2.0)<br />

7


<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

~ Characteristics <strong>of</strong> welded areas ~<br />

Flangeability <strong>of</strong> TIG welded areas<br />

Good (Erichsen test)<br />

Erichsen height, mm ↑<br />

Good<br />

↑<br />

Welding heat input, J/cm<br />

H=60・E・I/v<br />

H:溶接入熱(J/cm),E:アーク電圧(V)<br />

I:溶接電流(A),v:溶接速度(cm/min)<br />

H: Welding heat input (J/cm), E: Arc voltage (V),<br />

I: Weld current (A), v: Weld speed (cm/min)<br />

Corrosion resistance <strong>of</strong> TIG welded areas<br />

(salt water immersion test)<br />

<strong>NSSC</strong><strong>FW1</strong>/TIG unfinished<br />

SUS430LX (<strong>NSSC</strong> 430D)/TIG unfinished SUS430/TIG unfinished<br />

● Test conditions: TIG welding was performed so that an uranami bead<br />

<strong>of</strong> about 1.5mm is made.<br />

Surface condition: TIG welded and unfinished (2B), and TIG welded<br />

and polish finished to #600<br />

Immersion solution and time: 168 hrs in 0.5% NaCl solution at 80ºC<br />

<strong>NSSC</strong> <strong>FW1</strong> (14Cr-0.1Sn) can be TIG welded under the same conditions as SUS<br />

430LX (17CR), a conventional extra-low interstitial ferritic steel.<br />

Formability and corrosion resistance <strong>of</strong> the welded areas are also good.<br />

8


Stainless steel composition<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Advantages <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />

Reduce rare metal content by<br />

Iron<br />

Nickel<br />

Chrome<br />

SUS304<br />

Major generic<br />

steel <strong>grade</strong><br />

23%<br />

SUS430LX<br />

Generic Niless<br />

steel <strong>grade</strong><br />

Rate <strong>of</strong> reduction in chrome content<br />

9


Sn Added, Extra-low interstitial Ferritic Stainless <strong>Steel</strong><br />

― The FW Series<br />

~ Resource-saving and highly corrosion resistant <strong>NSSC</strong> FW2 ~<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Nippon <strong>Steel</strong> & Sumikin Stainless <strong>Steel</strong> Corporation<br />

10


Advantages and steel <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> FW2<br />

[Advantages]<br />

1. While FW2 is a 16% Cr steel, it delivers corrosion and rust resistance that is<br />

equal to that <strong>of</strong> SUS304 (18C-8Ni) under regular conditions.<br />

2. FW2 <strong>of</strong>fers among the best formability <strong>of</strong> ferritic steels. By selecting the<br />

appropriate forming conditions (drawability), FW2 <strong>of</strong>fers mold formability<br />

equal to that <strong>of</strong> SUS304.<br />

3. Thorough alloy-saving efforts have been made (Ni, Mo, and Cu-free, reduced<br />

Cr content) to minimize the effects <strong>of</strong> fluctuating raw material prices.<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

<strong>NSSC</strong> FW2 (Forward 2) 16Cr-0.3Sn-LC, N<br />

[Chemical composition] (Mass%)<br />

Grade<br />

values<br />

Representative examples<br />

C Si Mn P S Cr Sn Nb+Ti N<br />

15.75 0.3<br />

0.010 0.50 0.50 0.040 0.030 ~ 17.00 ~ 0.45 10(C+N) 0.015<br />

0.005 0.07 0.06 0.02 0.001 16.4 0.31 0.22 0.01<br />

[Mechanical <strong>characteristics</strong>]<br />

0.2% bearing force<br />

(N/mm)<br />

Tensile strength<br />

(N/mm)<br />

Elongation<br />

(%)<br />

Hardness<br />

(HV)<br />

Grade values 205 390 25 200<br />

Representative examples 279 463 32 144<br />

(Surface finish: 2B, thick plate; 0.6mm, JIS13B, L direction)<br />

11


<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> FW2<br />

~ Corrosion resistance 1~<br />

Improved salt spray corrosion test (salt water environment)<br />

<strong>NSSC</strong> FW2<br />

(16Cr-0.3Sn)<br />

Test sample shape: 50 x 100 with top end bent at 90º angle. Surface: Finished at<br />

#600<br />

Solution: 24 hrs in 0.5% NaCl + 2% H 2O 2 at 35ºC. Other conditions comply with<br />

JISZ2371<br />

Rust resistance in salt water environments was greatly<br />

improved over SUS430 and is equal to that <strong>of</strong> SUS304.<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

SUS304<br />

(18Cr-8Ni)<br />

SUS430<br />

(17Cr)<br />

12


Various formability <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong><br />

<strong>FW1</strong> and FW2<br />

Formability (plate thickness: 0.6mm)<br />

By selecting the appropriate forming conditions, <strong>NSSC</strong> <strong>FW1</strong><br />

and FW2 can be mold formed in the same way as SUS304.<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Drawability Bulge expandability<br />

Average<br />

r value<br />

LDR n value<br />

Hydraulic bulge<br />

height (mm)<br />

<strong>NSSC</strong> <strong>FW1</strong> 1.7 2.3 0.22 31.5<br />

<strong>NSSC</strong> FW2 1.7 2.3 0.24 30.5<br />

SUS430 1.0 2.0 0.16 27.0<br />

SUS304 1.1 2.1 0.42 40.5<br />

13


<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />

~ Formability and moldability ~<br />

Results from comparative simulations <strong>of</strong> moldability under the same conditions<br />

SUS304;h=52mm<br />

Blank: 240 x 240mm<br />

Punch: 100 x 100mm,<br />

Corners: r 20mm, rp 10mm<br />

Die: 103 x 103mm, rd 5mm<br />

Friction coefficient: 0.10, Plate thickness: 0.8mm<br />

Fold pressure: 20 tons<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Crack<br />

<strong>NSSC</strong> 180;h=24mm<br />

<strong>NSSC</strong> <strong>FW1</strong>;h=32mm<br />

14


Apply high lubrication film<br />

Smaller fold pressure<br />

<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong><br />

~ Formability and moldability ~<br />

Results from simulations <strong>of</strong> moldability under appropriate conditions<br />

Fold pressure: 10 tons Fold pressure: 10 tons<br />

<strong>NSSC</strong> 180;<br />

H=52mm<br />

<strong>NSSC</strong> 180;<br />

H=52mm<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

<strong>NSSC</strong> <strong>FW1</strong>;<br />

h=60mm<br />

Friction coefficient: 0.06 Friction coefficient: 0.06<br />

<strong>NSSC</strong> <strong>FW1</strong>;<br />

h=60mm<br />

15


<strong>Steel</strong> <strong>grade</strong> <strong>characteristics</strong> <strong>of</strong> <strong>NSSC</strong> FW2<br />

~ Formability and moldability ~<br />

Multi-drawing <strong>characteristics</strong> ~ Appearance after multi drawing ~<br />

4 th stage<br />

drawing<br />

<strong>NSSC</strong> FW2<br />

(16Cr-0.3Sn)<br />

3 rd stage<br />

drawing<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

SUS304<br />

(18Cr-8Ni)<br />

<br />

J4(14Cr-1Ni-Mn)<br />

Plate thickness: 0.6mm (cold-finished once) Blank diameter: 80mm Lubricant: J.W. #122<br />

Punch diameters (mm): 1st stage 40 2nd stage 35 3rd stage 30 4th stage 25<br />

<strong>NSSC</strong> FW2 leads to forming by multi-drawing without<br />

developing any cracks.<br />

Season cracking occurs with SUS304.<br />

16


100%<br />

26%<br />

18%<br />

16%<br />

Advantages <strong>of</strong> <strong>NSSC</strong> FW2 -Resource-saving-<br />

Rare metal (Cr, Ni) use can be reduced by 40%.<br />

Fe<br />

Iron<br />

8%Ni<br />

Nickel<br />

Stainless steel composition Small amounts <strong>of</strong> added Sn improves corrosion resistance, and thereby<br />

0%<br />

18%Cr<br />

Chrom<br />

e<br />

18%Cr-8%Ni<br />

SUS304 (generic steel)<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

・Equal corrosion<br />

resistance<br />

・Good<br />

formability<br />

・Good<br />

weldability<br />

Fe<br />

Iron<br />

16%Cr<br />

Chrom<br />

e<br />

16%Cr-0.3Sn<br />

<strong>NSSC</strong> FW2<br />

0%<br />

40%<br />

100%<br />

←Rate <strong>of</strong> reduction in rare metal content<br />

17


IH (induction-heating) rice cookers<br />

Lithium-ion battery cases<br />

(Deep drawing applications)<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Examples <strong>of</strong> <strong>NSSC</strong> <strong>FW1</strong> applications<br />

Large rectangular vats<br />

Candidate applications for <strong>NSSC</strong> <strong>FW1</strong><br />

Washing<br />

machine drums<br />

Rice washing bowls<br />

Building materials and<br />

architectural members<br />

Hinges<br />

18


Examples <strong>of</strong> <strong>NSSC</strong> FW2 applications<br />

Kitchen sinks Cooking trays<br />

Yukihira pan<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

Expanded metal<br />

(mesh)<br />

All existing applications where<br />

SUS304 (18 Cr-8 Ni) is used are<br />

candidate applications for FW2.<br />

19


Range <strong>of</strong> manufacturability <strong>of</strong> cold-finished<br />

products from <strong>NSSC</strong> <strong>FW1</strong> and FW2<br />

Shape Thickness (mm) Width (mm) Length (mm)<br />

Cutlength sheets 0.3 ~ 4.0 300 ~ 1,250/1524 8,000 max.<br />

Coils 0.3 ~ 4.0 200 ~ 1,250/1524<br />

* Available in high-gloss 2B finish.<br />

* A variety <strong>of</strong> finishes, including BA, are also available.<br />

* Please inquire for dimensions and specifications not<br />

shown here.<br />

Copyright© 2011 <strong>NSSC</strong>. All Rights Reserved.<br />

20


Nikkei Excellent Product or Service Award 2010<br />

~ <strong>NSSC</strong> <strong>FW1</strong> is awarded the Grand Award in the Nikkei Sangyo Shimbun Awards ~<br />

坂村 健 先生 内館 牧子 氏<br />

Copyright© 2011 <strong>NSSC</strong>. 2011 All Rights <strong>NSSC</strong>. Reserved.<br />

All Rights Reserved.<br />

"The fact that the stainless steel sheets<br />

developed by Nippon <strong>Steel</strong> & Sumikin<br />

Stainless <strong>Steel</strong> Corporation addresses<br />

the resource-scarce situation in Japan is<br />

worthy <strong>of</strong> much praise."<br />

"One <strong>of</strong> the more important products were<br />

the stainless steel sheets developed by<br />

Nippon <strong>Steel</strong> & Sumikin Stainless <strong>Steel</strong><br />

Corporation. This is a good example <strong>of</strong><br />

industry addressing the issue <strong>of</strong> resource<br />

scarcity and their fluctuating supply."<br />

日経産業新聞 2011.2.5 より<br />

21


Product<br />

type<br />

Thin<br />

sheets<br />

Thick<br />

sheets<br />

Copyright© 2011 <strong>NSSC</strong>. 2011 All Rights <strong>NSSC</strong>. Reserved.<br />

All Rights Reserved.<br />

Primary <strong>characteristics</strong><br />

Corrosion<br />

resistance<br />

Corrosion<br />

resistance<br />

Mold<br />

formability<br />

Strength<br />

<strong>NSSC</strong><br />

suggestions<br />

FW Series<br />

Duplex<br />

stainless steel<br />

22

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