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wasi katalog zum download (14 mb)

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Important Facts on<br />

Stainless Steel<br />

Sulphur (S) Melting point 118° C<br />

Sulphur produces the most pronounced segretation of all steel accompanying<br />

elements. Iron Sulphide, leads to red shortness or hot shortness, as the low<br />

melting point Sulphide eutectics surround the grains in reticular fashion, so<br />

that only slight cohesion of the latter occurs and during hot forming the grain<br />

boundaries tend to break down. This is further increased by the action of oxygen.<br />

As sulphur possesses a considerable affinity for manganese, it is co<strong>mb</strong>ined<br />

in the form of Mn sulphide, as this is the least dangerous of all existing<br />

inclusions, being present distributed in point form in the steel. Toughness in<br />

transverse direction is reduced significantly by S. S is added intentionally to<br />

steels for automatic machining up to 0.4%, as the friction on the tool cutting<br />

edge reduced by the lubricating action permits increased life between work<br />

piece and tool. In addition, short chips occur when free-cutting steels are<br />

machined. S increases susceptibility to welding cracks.<br />

Silicon (Si) Melting point <strong>14</strong><strong>14</strong>° C<br />

Si is contained in all steel in the same way as Manganese, as iron ores incorporate<br />

a quantity of it according to their composition. In Steel production itself,<br />

Silicon is absorbed into the melt from the refractory furnace linings.<br />

But only those steels are called Silicon Steels which have an Si content of<br />

>0.40%. Si is not a metal, but a metalloid as are also, for example, Phosphorus<br />

and Sulphur. Si deoxidizes. It promotes Graphite precipitation and restricts<br />

the Gamma phase significantly, increases strength and wear resistance (Si-Mn<br />

heat treatable steels); significant increase in the elastic limit, thus useful alloying<br />

element in spring steels. It significantly increases scale resistance, so that<br />

heat resisting steels are alloyed with it. The possible content is limited however<br />

on account of its impairing hot and cold formability. With 12% Si, acid<br />

resistance is achieved to a large extent, but such grades can only be produced<br />

as very hard, brittle steel castings which can be machined only by grinding.<br />

On account of significant reduction of electrical conductivity, coercive<br />

field intensity and low wattage loss, Si is used in steels for electrical quality<br />

sheet.<br />

Nitrogen (N) Melting point –210° C<br />

This element can occur both as a steel parasite and as an alloying element.<br />

Parasitic because of the reduction in toughness through precipitation processes,<br />

causing susceptibility to ageing and blue brittleness (deformation in the<br />

blue heat range of 300° C - 350° C) and on account of the possibility of initiation<br />

of intercrystaline stress cracks in unalloyed and low alloy steels. As an<br />

alloying element, N extends the gamma phase and stabilizes the austenitic<br />

structure. In Austenitic Steels increases strength and above all the yield point<br />

plus mechanical properties in the heat. As a result of Nitride formation during<br />

nitriding, N permits high surface hardness to be achieved (= nitriding).<br />

12<br />

607

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