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Geology and Resources of ·vanadium

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BIBLIOGRAPHY ON THE GEOLOGY AND<br />

RESOURCES OF VANADIUM TO 1968<br />

By R. P. FISCHER <strong>and</strong> JANE P. 0HL<br />

INTRODUCTION<br />

PURPOSE AND SCOPE<br />

This bibliography, which contains nearly 1,400 bibliographic<br />

references, was compiled to aid studies on the geology <strong>and</strong> resources<br />

<strong>of</strong> vanadium. It covers literature published through 1967 <strong>and</strong> contains<br />

references to a few papers published in the early part <strong>of</strong> 1968. Most<br />

references included are to original sources <strong>of</strong> information on the<br />

distribution <strong>and</strong> occurrence <strong>of</strong> vanadium-bearing deposits, on the<br />

geochemical relations <strong>of</strong> vanadium in rocks <strong>and</strong> deposits, <strong>and</strong> on<br />

vanadium mineralogy; some references on the exploitation <strong>and</strong><br />

metallurgical treatment <strong>of</strong> vanadium source materials are also<br />

included.<br />

The following paragraphs summarize the geologic distribution <strong>of</strong><br />

vanadium <strong>and</strong> briefly explain the arrangement <strong>of</strong> the bibliographic<br />

references <strong>and</strong> the index, in order to help a student underst<strong>and</strong><br />

the organization <strong>of</strong> the index <strong>and</strong> to guide him in its use. A list <strong>of</strong><br />

vanadium minerals <strong>and</strong> their chemical formulas is included.<br />

GEOLOGIC DISTRIBUTION OF VANADIUM<br />

Vanadium averages about 150 parts per million (ppm) in the<br />

Earth's crust; it is more abundant than copper, lead, or zinc. Silicic<br />

igneous rocks have an average content <strong>of</strong> about 50 ppm vanadium,<br />

whereas the mafic rocks commonly contain 100-200 ppm. S<strong>and</strong>stone<br />

<strong>and</strong> limestone normally contain only about 20 ppm vanadium, but<br />

ordinary shale generally has almost as much vanadium as the mafic<br />

igneous rocks <strong>and</strong> carbonaceous shale commonly has even more.<br />

Vanadium generally does not occur as an essential part <strong>of</strong> any rockforming<br />

mineral; rather, in igneous rocks the vanadium ions replace<br />

those <strong>of</strong> iron <strong>and</strong> aluminum in the common iron <strong>and</strong> ferromagnesian<br />

minerals, <strong>and</strong> in sedimentary rocks the vanadium is mainly associated<br />

with clay minerals or organic matter.<br />

Magmatic <strong>and</strong> pyrometasomatic ore deposits associated with mafic<br />

igneous rocks are commonly enriched in vanadium-most titaniferous<br />

magnetite deposits contain nearly 0.5 percent V 20 5 (about 0.3 percent<br />

vanadium or 3,000 ppm), <strong>and</strong> some contain 1,72 to 2 percent V205;<br />

non-titaniferous magnet.ite deposits commonly contain about 0.1 to<br />

v

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