UAN 30 N Product Safety Information Sheet EN - Linzer Agro Trade
UAN 30 N Product Safety Information Sheet EN - Linzer Agro Trade
UAN 30 N Product Safety Information Sheet EN - Linzer Agro Trade
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Page: 1 / 5<br />
Borealis <strong>Agro</strong>linz Melamine GmbH<br />
St.-Peter-Strasse 25<br />
A-4021 Linz/Austria<br />
Tel. +43 732 6914-DW<br />
Fax +43 732 6914-DW<br />
www.borealisgroup.com<br />
<strong>Product</strong> <strong>Safety</strong> <strong>Information</strong> <strong>Sheet</strong><br />
according to 1907/2006/EC, Article 32<br />
Printing date: 04.02.2010 Revision: 04.02.2010<br />
1* Identification of substance<br />
<strong>Product</strong> details:<br />
<strong>Trade</strong> name: Ammonium nitrate-urea solution <strong>30</strong>% N<br />
Article number: -<br />
Application of the substance / the preparation: Plant nutrient<br />
Manufacturer/Supplier:<br />
Manufacturer:<br />
Borealis <strong>Agro</strong>linz Melamine GmbH<br />
St.-Peter-Straße 25<br />
A-4021 Linz / Austria<br />
product.safety@borealisgroup.com<br />
Emergency information:<br />
Pho. (+43) 732/6914-2466 or 2991<br />
Fax (+43) 732/6914-2403<br />
2* Hazards identification<br />
Hazard designation: Void<br />
<strong>Information</strong> pertaining to particular dangers for man and environment:<br />
The product does not have to be labelled due to the calculation procedure of the "General<br />
Classification guideline for preparations of the EU" in the latest valid version.<br />
3* Composition/information on ingredients<br />
Chemical characterization:<br />
Description: Aqueous solution containing organic nitrogen compounds<br />
Dangerous components: Void<br />
4 First aid measures<br />
General information: No special measures required.<br />
After inhalation: Supply fresh air; consult doctor in case of symptoms.<br />
After skin contact:<br />
Instantly wash with water and soap and rinse thoroughly.<br />
Instantly remove any clothing soiled by the product.<br />
After eye contact: Rinse opened eye for 15 minutes under running water. Then consult doctor.<br />
After swallowing:<br />
Drink plenty of water (if possible with medicinal activated charcoal)<br />
After swallowing immediately consult a doctor.<br />
<strong>Information</strong> for doctor:<br />
Treatment: symptomatical treatment (decontamination, vitalfunctions), no specific antidot known.<br />
In the case of inhalation remain under medical observation for 48 hours.<br />
Swallowing of large amounts can cause incident of gastrointestinal tract.<br />
May produce methemoglobinemia, which at higher concentration will lead to cyanosis.<br />
5 Fire fighting measures<br />
Suitable extinguishing agents:<br />
CO2, water sprinklejet or alcohol resistant foam.<br />
Use fire fighting measures that suit the environment.<br />
Unsuitable extinguishing agents (for safety reasons): Water jet.<br />
(Contd. on page 2)
Page: 2 / 5<br />
Borealis <strong>Agro</strong>linz Melamine GmbH<br />
St.-Peter-Strasse 25<br />
A-4021 Linz/Austria<br />
Tel. +43 732 6914-DW<br />
Fax +43 732 6914-DW<br />
www.borealisgroup.com<br />
<strong>Product</strong> <strong>Safety</strong> <strong>Information</strong> <strong>Sheet</strong><br />
according to 1907/2006/EC, Article 32<br />
Printing date: 04.02.2010 Revision: 04.02.2010<br />
<strong>Trade</strong> name: Ammonium nitrate-urea solution <strong>30</strong>% N<br />
Special hazards caused by the material, its products of combustion or flue gases:<br />
Formation of poisonous gases during heating or in fires.<br />
Nitrogen oxides (NOx)<br />
Ammonia (NH3)<br />
Protective equipment:<br />
Wear full protective suit.<br />
Independent respiratory apparatus is recommended.<br />
Additional information: In case of fire and/or explosion do not breathe fumes.<br />
6 Accidental release measures<br />
Person-related safety precautions: Wear protective clothing.<br />
Measures for environmental protection:<br />
Prevent material from reaching sewage system, holes and cellars.<br />
Measures for cleaning/collecting:<br />
Absorb with liquid-binding material (sand, sawdust).<br />
Do not mix product with sawdust or flammable material (e.g. petrol, Diesel fuel-oil).<br />
Dispose of the material collected according to regulations.<br />
7 Handling and storage<br />
(Contd. of page 1)<br />
Handling:<br />
<strong>Information</strong> for safe handling:<br />
Avoid desiccate<br />
For safety reasons flush pump with water before operation in any case. After every operation flush<br />
pump with water to avoid formation of any solid residues. Do not operate pump while valves are<br />
shut (see item 8 and TRGS 511, 4.4).<br />
<strong>Information</strong> on protection against explosions and fires:<br />
Keep away from open flames, hot surfaces and sources of ignition.<br />
Keep away from flammable materials.<br />
Storage:<br />
Requirements to be met by storagerooms and containers: Do not use containers of zinc.<br />
<strong>Information</strong> on storage in one common storage facility:<br />
Store away from flammable, oxidant or explosiv substances.<br />
Further information about storage conditions: Prevent from drying out.<br />
8 Exposure controls and personal protection<br />
Additional information about design of technical systems:<br />
Pumps must be designed and operated that no dangerous reactions can occur. For transferring<br />
and pumping only pumps without compression glands should be used.<br />
Components with critical values that require monitoring at the workplace:<br />
The product does not contain any relevant quantities of materials with critical values that have to<br />
be monitored at the workplace.<br />
Additional information:<br />
The lists that were valid during the compilation were used as basis.<br />
Additional instruction for repairs:<br />
Take out any residues of the product by thoroughly washing out containers, tubes, pumps and any<br />
other apparatus with water before handling with heat and fire (welding / burning). Authorized<br />
personnel has to clear in writing any handling with heat and fire. An expert has to supervise<br />
permanently the handling (see TRGS 511, 4.4).<br />
(Contd. on page 3)
Page: 3 / 5<br />
Borealis <strong>Agro</strong>linz Melamine GmbH<br />
St.-Peter-Strasse 25<br />
A-4021 Linz/Austria<br />
Tel. +43 732 6914-DW<br />
Fax +43 732 6914-DW<br />
www.borealisgroup.com<br />
<strong>Product</strong> <strong>Safety</strong> <strong>Information</strong> <strong>Sheet</strong><br />
according to 1907/2006/EC, Article 32<br />
Printing date: 04.02.2010 Revision: 04.02.2010<br />
<strong>Trade</strong> name: Ammonium nitrate-urea solution <strong>30</strong>% N<br />
(Contd. of page 2)<br />
Personal protective equipment:<br />
General protective and hygienic measures:<br />
The usual precautionary measures should be adhered to in handling the chemicals.<br />
Keep away from foodstuffs, beverages and food.<br />
Do not eat, drink or smoke while working.<br />
Avoid contact with the eyes.<br />
Breathing equipment: Not necessary if room is well-ventilated.<br />
Protection of hands: Protective gloves<br />
Material of gloves: PVC, PE<br />
Penetration time of glove material:<br />
The exact break through time has to be found out by the manufacturer of the protective gloves and<br />
has to be observed.<br />
Eye protection: <strong>Safety</strong> glasses<br />
Body protection: Protective work clothing<br />
9 Physical and chemical properties<br />
General <strong>Information</strong>:<br />
Form: Fluid<br />
Colour: Colourless<br />
Odour: Like ammonia<br />
Change in condition:<br />
Melting point/Melting range:<br />
Boiling point/Boiling range:<br />
-9°C<br />
210°C<br />
Flash point: not applicable<br />
Self-inflammability: <strong>Product</strong> is not self igniting.<br />
Danger of explosion: <strong>Product</strong> is not explosive.<br />
Density at 20°C: 1,<strong>30</strong> g/cm³<br />
Solubility in / Miscibility with:<br />
water:<br />
Completely miscible<br />
pH-value at 20°C: 6 - 8<br />
Viscosity<br />
dynamic at 20°C:<br />
3 - 10 mPa s<br />
10 Stability and reactivity<br />
Conditions to be avoided: No decomposition if used according to specifications.<br />
Materials to be avoided:<br />
strong base<br />
corrode base metalls.<br />
Dangerous reactions: Reacts with strong alkali<br />
Dangerous products of composition:<br />
Nitrogen oxides (NOx)<br />
Ammonia (NH3)<br />
11* Toxicological information<br />
Primary irritant effect:<br />
Skin: No irritation.<br />
Eye: No irritation.<br />
Sensitization: No sensitizing effect known.<br />
(Contd. on page 4)
Page: 4 / 5<br />
Borealis <strong>Agro</strong>linz Melamine GmbH<br />
St.-Peter-Strasse 25<br />
A-4021 Linz/Austria<br />
Tel. +43 732 6914-DW<br />
Fax +43 732 6914-DW<br />
www.borealisgroup.com<br />
<strong>Product</strong> <strong>Safety</strong> <strong>Information</strong> <strong>Sheet</strong><br />
according to 1907/2006/EC, Article 32<br />
Printing date: 04.02.2010 Revision: 04.02.2010<br />
<strong>Trade</strong> name: Ammonium nitrate-urea solution <strong>30</strong>% N<br />
(Contd. of page 3)<br />
Additional toxicological information:<br />
When used and handled according to specifications, the product does not have any harmful<br />
effects according to our experience and the information provided to us.<br />
12 Ecological information<br />
General notes:<br />
Water hazard class 1 (Self-assessment): slightly hazardous for water.<br />
Do not allow product to reach ground water, water bodies or sewage system.<br />
Danger of eutrophication.<br />
13 Disposal considerations<br />
<strong>Product</strong>:<br />
Recommendation:<br />
Recycling is preferred to disposal or incineration. Contact the proper local authorities.<br />
Contact manufacturer.<br />
Must not be disposed of together with household garbage. Do not allow product to reach sewage<br />
system.<br />
Waste disposal key number: ÖNORM S2100: 51507, Fertilizer residues<br />
European waste catalogue:<br />
06 10 02 wastes containing dangerous substances<br />
Unclean packaging:<br />
Recommendation: Dispose of packaging according to regulations on the disposal of packagings.<br />
Recommended cleaning agent: Water, if necessary with cleaning agent.<br />
14 Transport information<br />
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic):<br />
ADR/RID-GGVS/E Class: -<br />
15* Regulatory information<br />
Designation according to EC guidelines:<br />
The product is not subject to identification regulations under EC Directives and the Ordinance on<br />
Hazardous Materials (GefStoffV).<br />
Observe the normal safety regulations when handling chemicals.<br />
National regulations:<br />
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.<br />
Other regulations, limitations and prohibitive regulations:<br />
VOC (Switzerland): Free from VOCs<br />
TRGS 511: D I<br />
16* Other information<br />
The above information is based on the current state of our knowledge and experience at the time<br />
this document was prepared. It is provided without warranty as to completeness and accuracy,<br />
does not constitute a binding assurance of product characteristics and hence shall not form the<br />
basis for any warranty or other liability claims of whatever kind. Nor shall it establish an<br />
independent legal relationship. The user shall himself or herself determine the suitability of the<br />
product for the intended purpose of use, and shall comply with all relevant regulations when<br />
processing or using the product, including any conflicting third-party industrial property rights and<br />
any safety measures also required.<br />
(Contd. on page 5)
Page: 5 / 5<br />
Borealis <strong>Agro</strong>linz Melamine GmbH<br />
St.-Peter-Strasse 25<br />
A-4021 Linz/Austria<br />
Tel. +43 732 6914-DW<br />
Fax +43 732 6914-DW<br />
www.borealisgroup.com<br />
<strong>Product</strong> <strong>Safety</strong> <strong>Information</strong> <strong>Sheet</strong><br />
according to 1907/2006/EC, Article 32<br />
Printing date: 04.02.2010 Revision: 04.02.2010<br />
<strong>Trade</strong> name: Ammonium nitrate-urea solution <strong>30</strong>% N<br />
(Contd. of page 4)<br />
Training hints:<br />
Before handling, storing or using the present substance for the first time, employees must be<br />
informed about its properties and about measures to ensure safety and environment protection.<br />
User: Steffen Pfeiffer (<strong>Product</strong> Stewardship)<br />
* Data compared to the previous version altered.