Topics in Current Chemistry

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The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage includes all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non specialist reader, whether at the university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. As a rule, contributions are specially commissioned. The editors and publishers will, however, always be pleased to receive suggestions and supplementary information. Papers are accepted for Topics in Current Chemistry in English. In references Topics in Current Chemistry is abbreviated Top Curr Chem and is cited as a journal. Visit the TCC content at http://www.springerlink.com/ Library of Congress Control Number: 2004112159 ISSN 0340-1022 ISBN 3-540-20948-4 Springer-Verlag Berlin Heidelberg New York DOI 10.1007/b83770 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other ways, and storage in data banks. Duplication of this publication or parts thereof is only permitted under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable to prosecution under the German Copyright Law. Springer-Verlag is a part of Springer Science+Business Media springeronline.com Springer-Verlag Berlin Heidelberg 2004 Printed in Germany The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: KünkelLopka, Heidelberg/design & production GmbH, Heidelberg Typesetting: Stürtz AG, Würzburg Printed on acid-free paper 02/3020 ra – 5 4 3 2 1 0
Volume Editor Prof. Dr. Hartmut Yersin Insitut für Physikalische und Theoretische Chemie Universität Regensburg Universitätsstraße 31 93053 Regensburg Germany hartmut.yersin@chemie.uni-regensburg.de Editorial Board Prof. Dr. Armin de Meijere Institut für Organische Chemie der Georg-August-Universität Tammannstraße 2 37077 Göttingen, Germany E-mail: ameijer1@uni-goettingen.de Prof. Dr. Horst Kessler Institut für Organische Chemie TU München Lichtenbergstraße 4 85747 Garching, Germany E-mail: kessler@ch.tum.de Prof. Steven V. Ley University Chemical Laboratory Lensfield Road Cambridge CB2 1EW, Great Britain E-mail: vl1000@cus.cam.ac.uk Prof. Dr. Joachim Thiem Institut für Organische Chemie Universität Hamburg Martin-Luther-King-Platz 6 20146 Hamburg, Germany E-mail: thiem@chemie.uni-hamburg.de Prof. Dr. Fritz Vögtle KekulØ-Institut für Organische Chemie und Biochemie der Universität Bonn Gerhard-Domagk-Straße 1 53121 Bonn, Germany E-mail: voegtle@uni-bonn.de Prof. K.N. Houk Department of Chemistry and Biochemistry University of California 405 Hilgard Avenue Los Angeles, CA 90024-1589, USA E-mail: houk@chem.ucla.edu Prof. Jean-Marie Lehn Institut de Chimie UniversitØ de Strasbourg 1 rue Blaise Pascal, B.P.Z 296/R8 67008 Strasbourg Cedex, France E-mail: lehn@chimie.u-strasbg.fr Prof. Stuart L. Schreiber Chemical Laboratories Harvard University 12 Oxford Street Cambridge, MA 02138-2902, USA E-mail: sls@slsiris.harvard.edu Prof. Barry M. Trost Department of Chemistry Stanford University Stanford, CA 94305-5080, USA E-mail: bmtrost@leland.stanford.edu Prof. Hisashi Yamamoto Arthur Holly Compton Distinguished Professor Department of Chemisty The University of Chicago 5735 South Ellis Avenue Chicago, IL 60637 733-702-5059, USA E-mail: yamamoto@uchicago.edu
Page 1 and 2: 241 Topics in Current Chemistry Edi
Page 3: Transition Metal and Rare Earth Com
Page 7 and 8: Preface For a long time, the proper
Page 9 and 10: Contents Triplet Emitters for OLED
Page 11 and 12: Contents of Volume 214 Transition M
Page 13 and 14: 120 C. Daniel 4.1 Dissociative vs N
Page 15 and 16: 122 C. Daniel here, would be the tr
Page 17 and 18: 124 C. Daniel Zeta with polarizatio
Page 19 and 20: 126 C. Daniel The difficulty for th
Page 21 and 22: 128 C. Daniel Scheme 3 mathematical
Page 23 and 24: 130 C. Daniel racy will be produced
Page 25 and 26: 132 C. Daniel [12] has been applied
Page 27 and 28: 134 C. Daniel tation of ground stat
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Page 31 and 32: 138 C. Daniel @U=@Q þ KU ¼ 0 ð4
Page 33 and 34: 140 C. Daniel packet, the centre of
Page 35 and 36: Table 1 Calculated electronic allow
Page 37 and 38: 144 C. Daniel Table 2 Calculated el
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Page 41 and 42: 148 C. Daniel Scheme 7 sponding to
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162 C. Daniel 48. Werner H-J (1987)
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164 C. Daniel 127. Aarnts MP, Wilms
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Top Curr Chem (2004) 241:97--118 DO
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Excited States and Optical Spectros
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Top Curr Chem (2004) 241:27--63 DOI
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Luminescent Cyclometalated Diimine
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66 A. Hauser et al. ceptor, play an
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68 A. Hauser et al. serve as therma
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70 A. Hauser et al. Fig. 4 Single c
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72 A. Hauser et al. are superimposa
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74 A. Hauser et al. and the finesse
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76 A. Hauser et al. Fig. 10 Mechani
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78 A. Hauser et al. k et D ¼ X A w
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80 A. Hauser et al. Fig. 14 FLN spe
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82 A. Hauser et al. The intrinsic l
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84 A. Hauser et al. Fig. 15 Quantum
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86 A. Hauser et al. Fig. 17 Scheme
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88 A. Hauser et al. Fig. 20 a Trans
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94 A. Hauser et al. below 2 K, the
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96 A. Hauser et al. 19. Sugano S, T
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168 P.A. Tanner 14 Conclusions ....
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170 P.A. Tanner ration, the stoichi
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172 P.A. Tanner Fig. 2 a Plot of la
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174 P.A. Tanner with smaller unit c
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176 P.A. Tanner Oh for elpasolites.
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178 P.A. Tanner Fig. 4a-g Infrared,
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180 P.A. Tanner Table 2 (continued)
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182 P.A. Tanner Table 3 Comparison
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184 P.A. Tanner belled. The unit ce
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186 P.A. Tanner sion curve for this
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188 P.A. Tanner so that B ð4Þ 0
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190 P.A. Tanner coordinates. One of
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192 P.A. Tanner
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194 P.A. Tanner where Wl ¼ ½Š l
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196 P.A. Tanner
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198 P.A. Tanner electric dipole mom
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200 P.A. Tanner respectively, where
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202 P.A. Tanner modified form in mo
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204 P.A. Tanner M00;f 1;q ¼ X n ½
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206 P.A. Tanner The sign of the int
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208 P.A. Tanner try notation of Gri
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210 P.A. Tanner Finally, it is note
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212 P.A. Tanner The actual assignme
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214 P.A. Tanner Fig. 13 35 K Raman
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216 P.A. Tanner terial, so that the
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218 P.A. Tanner Fig. 14a-c Electron
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220 P.A. Tanner 2 6 X 6 l;m;n 6 4
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222 P.A. Tanner allowed, and in var
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224 P.A. Tanner Table 7 Calculated
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226 P.A. Tanner Fig. 16 Lowest f-d,
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228 P.A. Tanner Fig. 18a, b 10 K f-
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230 P.A. Tanner It is interesting t
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232 P.A. Tanner Table 9 Selected en
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234 P.A. Tanner Fig. 20 Plots of Sl
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236 P.A. Tanner values are obtained
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238 P.A. Tanner X ½B k qCk q i ð
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240 P.A. Tanner their calculation h
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242 P.A. Tanner 13 Energy Transfer
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244 P.A. Tanner Table 11 (continued
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246 P.A. Tanner Fig. 24a-j Energy t
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248 P.A. Tanner Table 13 Structural
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250 P.A. Tanner s=6, although the c
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252 P.A. Tanner ask 2 ¼ 1 4 h es;a
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254 P.A. Tanner The HLO model has g
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256 P.A. Tanner Fig. 25a, b Lumines
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258 P.A. Tanner when excitation is
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260 P.A. Tanner Fig. 26 a Partial e
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262 P.A. Tanner 13.4.3 Upconversion
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264 P.A. Tanner ! 4 I15=2aG8½ŠD 0
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266 P.A. Tanner Fig. 27 a Power dep
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268 P.A. Tanner The study of f-d tr
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270 P.A. Tanner 41. Knudsen GP, Vos
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272 P.A. Tanner 119. Malta OL, Gouv
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274 P.A. Tanner 207. Tanner PA, Mak
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276 P.A. Tanner 290. Hehlen MP, Gü
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278 P.A. Tanner 379. Berry ME, May
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2 H. Yersin trix molecules with sub
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4 H. Yersin into substates, the tot
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6 H. Yersin Fig. 2 Example of an op
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8 H. Yersin 3 Exciton Formation and
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10 H. Yersin gram is simplified and
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12 H. Yersin to-matrix charge trans
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14 H. Yersin triplet excitons, are
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16 H. Yersin tions, but also induce
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18 H. Yersin 5 Photophysical Proper
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20 H. Yersin 5.3 Phosphorescence De
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22 H. Yersin 5.6 Electronic Charge
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24 H. Yersin 3. Tai WP, Inoue K, Oh
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26 H. Yersin 71. Wohlgenannt M, Tan
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280 Author Index Volumes 201-241 Br
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282 Author Index Volumes 201-241 Ga
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284 Author Index Volumes 201-241 Ko
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286 Author Index Volumes 201-241 Mu
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288 Author Index Volumes 201-241 Sh
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290 Author Index Volumes 201-241 Wu
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292 Subject Index DMCT 1, 12 DNA 56
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294 Subject Index Resonant energy t
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