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Products for Fertilizer Treatment

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Pigments & Additives Division<br />

Specialties Business<br />

<strong>Products</strong> <strong>for</strong><br />

<strong>Fertilizer</strong> <strong>Treatment</strong><br />

> Pigment preparations<br />

> Dyes<br />

> Waxes<br />

Exactly your chemistry.


<strong>Products</strong> <strong>for</strong> the <strong>Fertilizer</strong> <strong>Treatment</strong><br />

For fertilizer treatment application<br />

Clariant offers a wide range of<br />

products which includes:<br />

> Pigment preparations<br />

> Dyes<br />

> Waxes<br />

Our main purpose is to serve our<br />

customers with products, solutions<br />

and tailor-made products.<br />

2<br />

Contents<br />

Introduction 3<br />

Colorants 4<br />

Waxes 9


Introduction<br />

Pigment preparations<br />

Flexonyl ® , Colanyl ® , Ecosperse ® are<br />

highly concentrated aqueous pigment<br />

preparations which are distinguished<br />

by high tinting strength, excellent light<br />

fastness and low viscosity. These are<br />

particularly developed <strong>for</strong> NPK and<br />

DAP fertilizer <strong>for</strong> mass coloration and<br />

surface coating.<br />

Licosperse ® is a finely dispersed<br />

oil-based preparation especially<br />

developed <strong>for</strong> the use in oil coating<br />

or anticaking <strong>for</strong>mulations.<br />

Dyes<br />

Vitasyn ® is a range of water-soluble<br />

food colorants which meet most of<br />

the toxicological regulations. All dyes<br />

are in compliance with the european<br />

E-dyes, selected dyes could be<br />

offered as FD&C certified dyes.<br />

Clariant recommends these products<br />

particularly <strong>for</strong> mass coloration of<br />

liquid fertilizers or powder fertilizers.<br />

Duasyn ® is a range of water-soluble<br />

dyes. These dyes are recommended<br />

especially <strong>for</strong> water-based fertilizers<br />

<strong>for</strong> mass coloration.<br />

Fat is a range of nonionic extenderfree<br />

solvent dyes. They have good<br />

solubility in almost all organic solvents,<br />

especially in oil. The Fat dyes are<br />

recommended <strong>for</strong> oil-based coating<br />

of fertilizers.<br />

General applications of Clariant Pigments and Additives<br />

Waxes<br />

Licowax ® , are solid waxes based<br />

on wax esters, montan wax and<br />

ethoxylated wax acids. They are<br />

highly suitable <strong>for</strong> incorporation into<br />

slow release fertilizers.<br />

Product Mass treatment Surface treatment Slow Recommended<br />

release application<br />

Flexonyl ®<br />

Colanyl ®<br />

Ecosperse ®<br />

Licosperse ®<br />

Vitasyn ®<br />

Duasyn ®<br />

Fat<br />

Licowax ®<br />

high oil- water- oil- watertemperature<br />

slurry based based based based<br />

3


Colorants<br />

Pigment preparations<br />

The use of colorants helps to differentiate<br />

between qualities of fertilizer.<br />

Clariant’s pigment preparations are<br />

especially selected colorants <strong>for</strong><br />

economic fertilizer <strong>for</strong>mulations as<br />

well as <strong>for</strong> premium qualities.<br />

4<br />

Advantages<br />

> Pigment preparations suitable <strong>for</strong><br />

water-based (Flexonyl, Colanyl,<br />

Ecosperse) and <strong>for</strong> oil-based<br />

<strong>for</strong>mulations (Licosperse)<br />

> Low viscosity, easily pumpable<br />

> High tinting strength<br />

> Medium to excellent light fastness<br />

> Economic in use<br />

> Visualization of high quality fertilizer<br />

The colorants could be used <strong>for</strong><br />

mass coloration and surface coating.<br />

Selected products have excellent<br />

stability against phosphoric acid as<br />

well as good stability against acidic<br />

and alkaline medias.<br />

Dosage:<br />

Surface treatment:<br />

50.......600 g colorant /1 t of fertilizer<br />

Mass treatment:<br />

300.....1500 g colorant /1 t of fertilizer


Following Pigment preparations are especially recommended <strong>for</strong><br />

Aqueous systems <strong>for</strong> mass or surface treatment<br />

Product Colour Pigment Suitable Suitable Delivery Description<br />

Index content application application <strong>for</strong>m<br />

[approx. %] [*m / **s]<br />

Flexonyl ® P.Y.74 45 m / s aqueous liquid bright greenish yellow shade<br />

Yellow 5GX-LA preparation with excellent tinting strength<br />

Flexonyl ® P.Y.13 30 m / s aqueous liquid greenish yellow, good opacity<br />

Yellow GRX preparation with good tinting strength, excellent<br />

stability in phosphoric acid<br />

Flexonyl ® P.R.2 60 m / s aqueous liquid bright red shade with excellent<br />

Red 2R preparation tinting strength, good opacity<br />

Flexo ® P.R.2 30 m / s aqueous liquid bright red shade with good<br />

Red FRR-AV preparation tinting strength and opacity,<br />

stability in phosphoric acid<br />

Colanyl ® P.R.112 45 m / s aqueous liquid bright red shade with good<br />

Red FGR 131 preparation tinting strength and opacity<br />

Flexonyl ® P.R.57:1 30 s aqueous liquid bluish red with excellent tinting<br />

Rubine WF 571 preparation strength, very economic<br />

Flexonyl ® P.V.23 35 s aqueous liquid reddish violet with excellent<br />

Violet WF 023 preparation tinting strength, excellent light<br />

fastness<br />

Flexonyl ® P.B.15:1/ 50 m / s aqueous liquid reddish blue shade,<br />

Blue A4R P.B.15:3 preparation good stability in phosphoric acid<br />

Flexonyl ® P.B.15 50 m / s aqueous liquid reddish blue with excellent<br />

Blue AN-LA preparation tinting strength<br />

Ecosperse ® P.G.7 15 m / s aqueous liquid bluish green shade, excellent<br />

Green GNX preparation stability in phosphoric acid<br />

Flexonyl ® P.G.7 50 m / s aqueous liquid bluish green shade with high<br />

Green SP-GG preparation tinting strength, good stability<br />

in phosphoric acid<br />

Ecosperse ® P.Bl.7 24 m / s aqueous liquid black with excellent tinting<br />

Black preparation strength and opacity<br />

* m = Mass treatment<br />

** s = Surface treatment<br />

5


Oil-based systems <strong>for</strong> surface treatment<br />

* m = Mass treatment<br />

** s = Surface treatment<br />

6<br />

Product Colour Pigment Suitable Suitable Delivery Description<br />

Index content application application <strong>for</strong>m<br />

[approx. %] [*m / **s]<br />

Licosperse ® P.Y.13 27 s oil-based liquid greenish yellow with<br />

Yellow GR VP 2561 preparation high tinting strength<br />

Licosperse ® P.R.112 25 s oil-based liquid bright red shade with high tinting<br />

Red FGRD VP 2546 preparation strength and excellent opacity<br />

Licosperse ® P.B.15 15 s oil-based liquid standard reddish blue shade<br />

Blue AN 30 preparation<br />

Licosperse ® P.G.7 25 s oil-based liquid greenish blue shade with<br />

Green G VP 2749 preparation high tinting strength<br />

Licosperse ® P.Bl.7 18 s oil-based liquid black with high tinting strength<br />

Black P VP 2616 preparation and excellent opacity


Dyes<br />

Dyes of Clariant are especially selected<br />

colorants, highly suitable <strong>for</strong> fertilizer<br />

mass treatment or surface coating. The<br />

dyes could also be used <strong>for</strong> fertilizer<br />

blends.<br />

Water-soluble dyes<br />

* m = Mass treatment<br />

** s = Surface treatment<br />

Advantages<br />

> Water-soluble dyes (Vitasyn,<br />

Duasyn) <strong>for</strong> mass treatment<br />

and oil-soluble dyes in powder<br />

<strong>for</strong>m (Fat) <strong>for</strong> surface coating<br />

> High solubility in water<br />

or good solubility in oil<br />

> Excellent tinting strength<br />

> Low to medium light fastness<br />

> Highly visible indication of fertilizers<br />

Selected products have excellent<br />

stability against phosphoric acid as<br />

well as good stability against acidic<br />

and alkaline medias.<br />

Dosage:<br />

Surface treatment:<br />

20.........50 g colorant /1 t of fertilizer<br />

Mass treatment:<br />

Product Colour Suitable Suitable Delivery Description<br />

Index application application <strong>for</strong>m<br />

[*m / **s]<br />

50.......100 g colorant /1 t of fertilizer<br />

Vitasyn ® F.Y.4 m aqueous powder bright reddish yellow with high<br />

Tartrazine X 90 E102 tinting strength, good stability<br />

FD&C Yellow 5 in phosphoric acid<br />

Vitasyn ® F.Y.3 m aqueous powder bright orange with high tinting<br />

Orange RGL 90 E 110 strength, good stability in<br />

FD&C Yellow 6 phosphoric acid<br />

Vitasyn ® F.R.7 m aqueous powder bright red with high tinting<br />

Ponceau 4RC 82 E124 strength, good stability in<br />

phosphoric acid<br />

Duasyn ® A.B.9 m aqueous powder economic greenish blue,<br />

Acid Blue AE 03 good stability in phosphoric acid<br />

Duasyn ® A.B.93 m aqueous powder royal blue with high tinting<br />

Ink Blue SLK strength, good stability in<br />

phosphoric acid<br />

7


Oil-soluble dyes<br />

Fat Dyes are a range of extender-free<br />

dyes. They have a good solubility in all<br />

organic solvents, especially in oil.<br />

* m = Mass treatment<br />

** s = Surface treatment<br />

8<br />

Product Colour Suitable Suitable Delivery Description<br />

Index application application <strong>for</strong>m<br />

[*m / **s]<br />

Fat Yellow 3G S.Y.16 s oil-based powder bright greenish yellow<br />

Fat Orange R 01 S.Y.14 s oil-based powder bright orange,<br />

high tinting strength<br />

Fat Red 5B 02 S.R.27 s oil-based powder bluish red<br />

Fat Blue B 01 S.B.35 s oil-based powder bright reddish blue


Waxes<br />

Polar polyethylene waxes<br />

They are highly suitable <strong>for</strong> incorporation<br />

into fertilizer surface coating,<br />

as binder or suitable <strong>for</strong> slow release<br />

effects.<br />

Product Drop point Acid value Suitable Delivery Description<br />

[ °C ] [ mg KOH / g ] application <strong>for</strong>m<br />

[*m / **s]<br />

Licowax ® PED 521 ~105 ~17 s granule polar polyethylene wax,<br />

strong external lubricant effect<br />

Licowax ® PED 522 ~104 ~17 s granule polar polyethylene wax,<br />

strong external lubricant effect<br />

Test method DIN 51801/2 ISO 2114<br />

ASTM D 127<br />

* m = Mass treatment<br />

** s = Surface treatment<br />

Advantages<br />

> Low solubility in cold water<br />

> Easy to disperse in hot water<br />

> Easy to combine with colorants<br />

and / or polar solvents<br />

Dosage:<br />

500.......2000 g wax /1 t fertilizer<br />

9


Other waxes<br />

Advantages<br />

> Antiblocking properties<br />

> Easy to combine with colorants<br />

* m = Mass treatment<br />

** s = Surface treatment<br />

10<br />

Dosage:<br />

500.......2000 g wax /1 t fertilizer<br />

Product Drop point Acid value Suitable Delivery Description<br />

[ °C ] [ mg KOH / g ] application <strong>for</strong>m<br />

[*m / **s]<br />

Licowax ® C ~142 6 s powder Amide wax, especially used<br />

<strong>for</strong> melt spraying<br />

Licowax ® E ~82 18 s powder Montan wax, used <strong>for</strong> melt<br />

spraying, improved handling<br />

TP Licowax ® EC 25 ~73 4 s powder Montan wax, reduction<br />

of evaporation


Literature<br />

Legal status of waxes from Clariant with respect to food legislation DA 8250 E<br />

General leaflet Licowax, Ceridust, Licolub, Licomont DA 8048 E<br />

Living Colors DP 5023 E<br />

Sales Range <strong>for</strong> the printing ink, paints and plastics industries and special applications DP 5525 E<br />

Waxes by Clariant DA 8320 E<br />

Pigment preparation <strong>for</strong> <strong>Fertilizer</strong> (Licosperse) DP 6183 E<br />

Colanyl Flyer DP 6178 E<br />

Shade card Flexonyl LA/ Flexonyl 100 grade DP 7052 E<br />

These brochures you can find at www.pa.clariant.com<br />

11


Please note<br />

This in<strong>for</strong>mation is based on our present state of knowledge and is intended to provide<br />

general notes on our products and their uses. It should not there<strong>for</strong>e be construed<br />

as guaranteeing specific properties of the products described or their suitability <strong>for</strong><br />

a particular application. Any existing industrial property rights must be observed.<br />

The quality of our products is guaranteed under our General Conditions of Sale.<br />

® = Trademark of Clariant registered in numerous countries<br />

Edition: September 2006<br />

www.pa.clariant.com<br />

Exactly your chemistry.<br />

Clariant International Ltd.<br />

Pigments & Additives Division<br />

Marketing Specialties Business<br />

Rothausstrasse 61<br />

4132 Muttenz<br />

Switzerland<br />

Phone: +41/61/ 469-7981<br />

Fax: +41/61/ 469-7577 DA 8330_E 09/06

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