Products for Fertilizer Treatment
Products for Fertilizer Treatment
Products for Fertilizer Treatment
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Pigments & Additives Division<br />
Specialties Business<br />
<strong>Products</strong> <strong>for</strong><br />
<strong>Fertilizer</strong> <strong>Treatment</strong><br />
> Pigment preparations<br />
> Dyes<br />
> Waxes<br />
Exactly your chemistry.
<strong>Products</strong> <strong>for</strong> the <strong>Fertilizer</strong> <strong>Treatment</strong><br />
For fertilizer treatment application<br />
Clariant offers a wide range of<br />
products which includes:<br />
> Pigment preparations<br />
> Dyes<br />
> Waxes<br />
Our main purpose is to serve our<br />
customers with products, solutions<br />
and tailor-made products.<br />
2<br />
Contents<br />
Introduction 3<br />
Colorants 4<br />
Waxes 9
Introduction<br />
Pigment preparations<br />
Flexonyl ® , Colanyl ® , Ecosperse ® are<br />
highly concentrated aqueous pigment<br />
preparations which are distinguished<br />
by high tinting strength, excellent light<br />
fastness and low viscosity. These are<br />
particularly developed <strong>for</strong> NPK and<br />
DAP fertilizer <strong>for</strong> mass coloration and<br />
surface coating.<br />
Licosperse ® is a finely dispersed<br />
oil-based preparation especially<br />
developed <strong>for</strong> the use in oil coating<br />
or anticaking <strong>for</strong>mulations.<br />
Dyes<br />
Vitasyn ® is a range of water-soluble<br />
food colorants which meet most of<br />
the toxicological regulations. All dyes<br />
are in compliance with the european<br />
E-dyes, selected dyes could be<br />
offered as FD&C certified dyes.<br />
Clariant recommends these products<br />
particularly <strong>for</strong> mass coloration of<br />
liquid fertilizers or powder fertilizers.<br />
Duasyn ® is a range of water-soluble<br />
dyes. These dyes are recommended<br />
especially <strong>for</strong> water-based fertilizers<br />
<strong>for</strong> mass coloration.<br />
Fat is a range of nonionic extenderfree<br />
solvent dyes. They have good<br />
solubility in almost all organic solvents,<br />
especially in oil. The Fat dyes are<br />
recommended <strong>for</strong> oil-based coating<br />
of fertilizers.<br />
General applications of Clariant Pigments and Additives<br />
Waxes<br />
Licowax ® , are solid waxes based<br />
on wax esters, montan wax and<br />
ethoxylated wax acids. They are<br />
highly suitable <strong>for</strong> incorporation into<br />
slow release fertilizers.<br />
Product Mass treatment Surface treatment Slow Recommended<br />
release application<br />
Flexonyl ®<br />
Colanyl ®<br />
Ecosperse ®<br />
Licosperse ®<br />
Vitasyn ®<br />
Duasyn ®<br />
Fat<br />
Licowax ®<br />
high oil- water- oil- watertemperature<br />
slurry based based based based<br />
3
Colorants<br />
Pigment preparations<br />
The use of colorants helps to differentiate<br />
between qualities of fertilizer.<br />
Clariant’s pigment preparations are<br />
especially selected colorants <strong>for</strong><br />
economic fertilizer <strong>for</strong>mulations as<br />
well as <strong>for</strong> premium qualities.<br />
4<br />
Advantages<br />
> Pigment preparations suitable <strong>for</strong><br />
water-based (Flexonyl, Colanyl,<br />
Ecosperse) and <strong>for</strong> oil-based<br />
<strong>for</strong>mulations (Licosperse)<br />
> Low viscosity, easily pumpable<br />
> High tinting strength<br />
> Medium to excellent light fastness<br />
> Economic in use<br />
> Visualization of high quality fertilizer<br />
The colorants could be used <strong>for</strong><br />
mass coloration and surface coating.<br />
Selected products have excellent<br />
stability against phosphoric acid as<br />
well as good stability against acidic<br />
and alkaline medias.<br />
Dosage:<br />
Surface treatment:<br />
50.......600 g colorant /1 t of fertilizer<br />
Mass treatment:<br />
300.....1500 g colorant /1 t of fertilizer
Following Pigment preparations are especially recommended <strong>for</strong><br />
Aqueous systems <strong>for</strong> mass or surface treatment<br />
Product Colour Pigment Suitable Suitable Delivery Description<br />
Index content application application <strong>for</strong>m<br />
[approx. %] [*m / **s]<br />
Flexonyl ® P.Y.74 45 m / s aqueous liquid bright greenish yellow shade<br />
Yellow 5GX-LA preparation with excellent tinting strength<br />
Flexonyl ® P.Y.13 30 m / s aqueous liquid greenish yellow, good opacity<br />
Yellow GRX preparation with good tinting strength, excellent<br />
stability in phosphoric acid<br />
Flexonyl ® P.R.2 60 m / s aqueous liquid bright red shade with excellent<br />
Red 2R preparation tinting strength, good opacity<br />
Flexo ® P.R.2 30 m / s aqueous liquid bright red shade with good<br />
Red FRR-AV preparation tinting strength and opacity,<br />
stability in phosphoric acid<br />
Colanyl ® P.R.112 45 m / s aqueous liquid bright red shade with good<br />
Red FGR 131 preparation tinting strength and opacity<br />
Flexonyl ® P.R.57:1 30 s aqueous liquid bluish red with excellent tinting<br />
Rubine WF 571 preparation strength, very economic<br />
Flexonyl ® P.V.23 35 s aqueous liquid reddish violet with excellent<br />
Violet WF 023 preparation tinting strength, excellent light<br />
fastness<br />
Flexonyl ® P.B.15:1/ 50 m / s aqueous liquid reddish blue shade,<br />
Blue A4R P.B.15:3 preparation good stability in phosphoric acid<br />
Flexonyl ® P.B.15 50 m / s aqueous liquid reddish blue with excellent<br />
Blue AN-LA preparation tinting strength<br />
Ecosperse ® P.G.7 15 m / s aqueous liquid bluish green shade, excellent<br />
Green GNX preparation stability in phosphoric acid<br />
Flexonyl ® P.G.7 50 m / s aqueous liquid bluish green shade with high<br />
Green SP-GG preparation tinting strength, good stability<br />
in phosphoric acid<br />
Ecosperse ® P.Bl.7 24 m / s aqueous liquid black with excellent tinting<br />
Black preparation strength and opacity<br />
* m = Mass treatment<br />
** s = Surface treatment<br />
5
Oil-based systems <strong>for</strong> surface treatment<br />
* m = Mass treatment<br />
** s = Surface treatment<br />
6<br />
Product Colour Pigment Suitable Suitable Delivery Description<br />
Index content application application <strong>for</strong>m<br />
[approx. %] [*m / **s]<br />
Licosperse ® P.Y.13 27 s oil-based liquid greenish yellow with<br />
Yellow GR VP 2561 preparation high tinting strength<br />
Licosperse ® P.R.112 25 s oil-based liquid bright red shade with high tinting<br />
Red FGRD VP 2546 preparation strength and excellent opacity<br />
Licosperse ® P.B.15 15 s oil-based liquid standard reddish blue shade<br />
Blue AN 30 preparation<br />
Licosperse ® P.G.7 25 s oil-based liquid greenish blue shade with<br />
Green G VP 2749 preparation high tinting strength<br />
Licosperse ® P.Bl.7 18 s oil-based liquid black with high tinting strength<br />
Black P VP 2616 preparation and excellent opacity
Dyes<br />
Dyes of Clariant are especially selected<br />
colorants, highly suitable <strong>for</strong> fertilizer<br />
mass treatment or surface coating. The<br />
dyes could also be used <strong>for</strong> fertilizer<br />
blends.<br />
Water-soluble dyes<br />
* m = Mass treatment<br />
** s = Surface treatment<br />
Advantages<br />
> Water-soluble dyes (Vitasyn,<br />
Duasyn) <strong>for</strong> mass treatment<br />
and oil-soluble dyes in powder<br />
<strong>for</strong>m (Fat) <strong>for</strong> surface coating<br />
> High solubility in water<br />
or good solubility in oil<br />
> Excellent tinting strength<br />
> Low to medium light fastness<br />
> Highly visible indication of fertilizers<br />
Selected products have excellent<br />
stability against phosphoric acid as<br />
well as good stability against acidic<br />
and alkaline medias.<br />
Dosage:<br />
Surface treatment:<br />
20.........50 g colorant /1 t of fertilizer<br />
Mass treatment:<br />
Product Colour Suitable Suitable Delivery Description<br />
Index application application <strong>for</strong>m<br />
[*m / **s]<br />
50.......100 g colorant /1 t of fertilizer<br />
Vitasyn ® F.Y.4 m aqueous powder bright reddish yellow with high<br />
Tartrazine X 90 E102 tinting strength, good stability<br />
FD&C Yellow 5 in phosphoric acid<br />
Vitasyn ® F.Y.3 m aqueous powder bright orange with high tinting<br />
Orange RGL 90 E 110 strength, good stability in<br />
FD&C Yellow 6 phosphoric acid<br />
Vitasyn ® F.R.7 m aqueous powder bright red with high tinting<br />
Ponceau 4RC 82 E124 strength, good stability in<br />
phosphoric acid<br />
Duasyn ® A.B.9 m aqueous powder economic greenish blue,<br />
Acid Blue AE 03 good stability in phosphoric acid<br />
Duasyn ® A.B.93 m aqueous powder royal blue with high tinting<br />
Ink Blue SLK strength, good stability in<br />
phosphoric acid<br />
7
Oil-soluble dyes<br />
Fat Dyes are a range of extender-free<br />
dyes. They have a good solubility in all<br />
organic solvents, especially in oil.<br />
* m = Mass treatment<br />
** s = Surface treatment<br />
8<br />
Product Colour Suitable Suitable Delivery Description<br />
Index application application <strong>for</strong>m<br />
[*m / **s]<br />
Fat Yellow 3G S.Y.16 s oil-based powder bright greenish yellow<br />
Fat Orange R 01 S.Y.14 s oil-based powder bright orange,<br />
high tinting strength<br />
Fat Red 5B 02 S.R.27 s oil-based powder bluish red<br />
Fat Blue B 01 S.B.35 s oil-based powder bright reddish blue
Waxes<br />
Polar polyethylene waxes<br />
They are highly suitable <strong>for</strong> incorporation<br />
into fertilizer surface coating,<br />
as binder or suitable <strong>for</strong> slow release<br />
effects.<br />
Product Drop point Acid value Suitable Delivery Description<br />
[ °C ] [ mg KOH / g ] application <strong>for</strong>m<br />
[*m / **s]<br />
Licowax ® PED 521 ~105 ~17 s granule polar polyethylene wax,<br />
strong external lubricant effect<br />
Licowax ® PED 522 ~104 ~17 s granule polar polyethylene wax,<br />
strong external lubricant effect<br />
Test method DIN 51801/2 ISO 2114<br />
ASTM D 127<br />
* m = Mass treatment<br />
** s = Surface treatment<br />
Advantages<br />
> Low solubility in cold water<br />
> Easy to disperse in hot water<br />
> Easy to combine with colorants<br />
and / or polar solvents<br />
Dosage:<br />
500.......2000 g wax /1 t fertilizer<br />
9
Other waxes<br />
Advantages<br />
> Antiblocking properties<br />
> Easy to combine with colorants<br />
* m = Mass treatment<br />
** s = Surface treatment<br />
10<br />
Dosage:<br />
500.......2000 g wax /1 t fertilizer<br />
Product Drop point Acid value Suitable Delivery Description<br />
[ °C ] [ mg KOH / g ] application <strong>for</strong>m<br />
[*m / **s]<br />
Licowax ® C ~142 6 s powder Amide wax, especially used<br />
<strong>for</strong> melt spraying<br />
Licowax ® E ~82 18 s powder Montan wax, used <strong>for</strong> melt<br />
spraying, improved handling<br />
TP Licowax ® EC 25 ~73 4 s powder Montan wax, reduction<br />
of evaporation
Literature<br />
Legal status of waxes from Clariant with respect to food legislation DA 8250 E<br />
General leaflet Licowax, Ceridust, Licolub, Licomont DA 8048 E<br />
Living Colors DP 5023 E<br />
Sales Range <strong>for</strong> the printing ink, paints and plastics industries and special applications DP 5525 E<br />
Waxes by Clariant DA 8320 E<br />
Pigment preparation <strong>for</strong> <strong>Fertilizer</strong> (Licosperse) DP 6183 E<br />
Colanyl Flyer DP 6178 E<br />
Shade card Flexonyl LA/ Flexonyl 100 grade DP 7052 E<br />
These brochures you can find at www.pa.clariant.com<br />
11
Please note<br />
This in<strong>for</strong>mation is based on our present state of knowledge and is intended to provide<br />
general notes on our products and their uses. It should not there<strong>for</strong>e be construed<br />
as guaranteeing specific properties of the products described or their suitability <strong>for</strong><br />
a particular application. Any existing industrial property rights must be observed.<br />
The quality of our products is guaranteed under our General Conditions of Sale.<br />
® = Trademark of Clariant registered in numerous countries<br />
Edition: September 2006<br />
www.pa.clariant.com<br />
Exactly your chemistry.<br />
Clariant International Ltd.<br />
Pigments & Additives Division<br />
Marketing Specialties Business<br />
Rothausstrasse 61<br />
4132 Muttenz<br />
Switzerland<br />
Phone: +41/61/ 469-7981<br />
Fax: +41/61/ 469-7577 DA 8330_E 09/06