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R-657.pdf - Nalco

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Managing microbio control<br />

programs Reprint R-657<br />

By Tim Nahley, <strong>Nalco</strong> Company<br />

Microbiological control programs play a key role in<br />

maintaining machine runnability and product quality.<br />

In the December 1995 issue of PIMA Magazine, we<br />

discussed how performance and economics can vary<br />

from mill to mill—even between mills that produce<br />

the same grades. Five key elements influence your results<br />

and bottom line. The elements listed in Figure 1<br />

affect either the growth of microorganisms in paper<br />

machine systems or the development of microbiological<br />

deposits, or both. In the first article, system inoculation—the<br />

first element—was discussed. In this<br />

article, the effects of the remaining four elements will<br />

be reviewed.<br />

Microbiological Growth Requirements—Uncontrolled<br />

paper systems provide an excellent environment<br />

for microorganisms to thrive. These systems<br />

provide the right nutrients, pH and temperature<br />

ranges to support microbiological activity. These<br />

growth requirements differ from mill to mill—even<br />

on identical grades, depending on the way the paper<br />

is made and the machine is operated. Operational<br />

changes can often affect microbiological growth<br />

requirements and ultimately, the overall performance<br />

and economics of the microbiological deposit control<br />

program.<br />

Nutrient loading—The nutrients available in any<br />

particular machine system are the result of several<br />

variables, one being grade structure. The fiber source<br />

will affect microbiological activity through the introduction<br />

of nutrients, particularly in post-consumer<br />

fiber grades. Coated versus uncoated grades can<br />

affect the degree of nutrients, since many coating formulations<br />

contain ingredients bacteria use as food.<br />

Starch is a well known nutrient for increasing microbiological<br />

growth. Changes in the amounts of starch<br />

used for internal or surface sizing or in coating formulations<br />

often influence the results and costs of a<br />

microbiological deposit control program.<br />

The retention program also plays a key role in machine<br />

system nutrient loading. Additives not retained<br />

in the sheet build up in the water and stock systems<br />

of a paper machine. Once there, they become an excellent<br />

media for microbiological growth. Differences<br />

in the performance of a retention program from<br />

Reprinted by permission from PIMA Magazine, December 1995<br />

Key Elements Influencing Performance and Economics<br />

of Microbiological Deposit Control Programs<br />

■ System Inoculation<br />

■ Microbiological Growth Requirements<br />

■ Control Philosophy<br />

■ Mill Design<br />

■ Stock Management & Housekeeping<br />

Figure 1<br />

machine to machine, or fluctuations in retention on<br />

the same machine, will have a major impact on the<br />

microbiological control program.<br />

An increasingly important cause of nutrient loading<br />

in paper mills is closure. As less water is discharged<br />

from paper mills, contaminants in the water begin to<br />

cycle up. Again, nutrients build up as closure increases,<br />

making microbiological control more challenging.<br />

System pH—pH is a critical factor affecting the<br />

growth of microbiological organisms in paper mill<br />

systems. Although microorganisms can live within the<br />

pH range of most papermaking processes (pH 4-8),<br />

the degree of growth will be different within this<br />

range. As pH increases from acid to neutral to alkaline,<br />

the environment becomes more favorable for<br />

vigorous microbiological activity.<br />

System temperature—Temperature also influences<br />

the performance of a microbiological control program.<br />

Generally, as machine temperature increases past<br />

130°F, the activity of many microorganisms begins<br />

to decrease. There are, however, thermophilic bacteria<br />

that can thrive under these conditions.<br />

Oxygen requirements—Oxygen levels not only<br />

affect the metabolism of microorganisms in a machine<br />

system, but also affect the type of organisms present.<br />

This results in the existence of a variety of organisms<br />

over a range of oxygen levels, all requiring a<br />

different approach to treatment. Changes in the


oxygen levels due to factors such as temperature or<br />

machine closure will change the microbial population<br />

of the machine and require different control methods.<br />

Control Philosophy—The method a mill chooses<br />

for microbiological deposit control plays a large role<br />

in the performance and economics of the program.<br />

Whether a mill chooses to use an on-machine oxidizer<br />

(such as chlorine), non-oxidizing biocides, or controls<br />

deposits primarily thorough boilouts and washups<br />

greatly affects results and costs. There are tradeoffs<br />

for each of these methods.<br />

The use of microbiological control chemicals will provide<br />

advantages in machine runnability. Line item<br />

chemical costs, however, can run into dollars per ton.<br />

Minimal use of these agents in conjunction with frequent<br />

boilouts and washups will keep chemical costs<br />

low but at the expense of machine downtime. Total<br />

machine downtime and product quality should be considered<br />

relative to deposit control costs.<br />

Mill Design—One factor seldom considered for its<br />

impact on the performance and economics of a microbiological<br />

deposit control program is mill design.<br />

A survey of 12 alkaline fine paper mills showed a wide<br />

range of results and costs. When analyzed, the mills<br />

with larger machines typically had fewer microbiological<br />

related problems and higher chemical costs<br />

per ton than those with smaller machines. A combination<br />

of the following conditions may be the reason.<br />

The larger mills have larger chests with longer turnover<br />

times. The longer turnover times, particularly<br />

in coated broke silos, can require more biological control<br />

agents. These larger machines were also newer<br />

and had less maintenance-related downtime than the<br />

smaller, older machines. Consequently, the smaller<br />

machines had more opportunities for boilouts and<br />

wash-ups. Finally, the machine time of the larger<br />

machine was more costly, so the machines were kept<br />

cleaner to maximize time between boilouts.<br />

Mill design, particularly cross connections between<br />

machines, is an important consideration. A two<br />

machine mill, one producing food grade products and<br />

one producing boxboard, with a common white water<br />

system, must consider how the performance of the<br />

program on one machine will affect the other.<br />

Headbox and approach piping design and the type of<br />

construction materials can also affect the rate at<br />

which deposition occurs. For instance, open and air<br />

padded headbox designs will typically develop<br />

biofilms faster than a hydraulic headbox design.<br />

Machine speed also plays a role but in this case, it is<br />

Printed in U.S.A. 3-04<br />

the ability of the machine to tolerate deposits that<br />

make it to the sheet that will affect runnability. A<br />

faster machine is less tolerant of sheet deposits and<br />

will develop more breaks than a slower machine.<br />

Stock Management and Housekeeping Practices—Stock<br />

management and housekeeping practices<br />

will affect the efficiency of the microbiological<br />

control program. The way in which stock is stored as<br />

well as housekeeping procedures, such as boilouts and<br />

wash-ups, can differ between mills.<br />

Stock chests can be an area of concern. The consistency<br />

of stock streams in conjunction with chest and<br />

silo design constraints can result in channeling and<br />

dead zones where stock can stagnate, which promotes<br />

microbiological activity. Biological control agents<br />

never reach these areas due to the channeling. As<br />

chest levels rise and fall, this highly contaminated<br />

stock will be transferred to the machine where the<br />

machine microbiological control program can be overwhelmed.<br />

Regarding housekeeping, effective wash-ups at each<br />

opportunity will reduce deposit-related runnability<br />

problems and also the frequency required for boilout.<br />

Proper boilouts will help to minimize chemical<br />

requirements by completely eliminating microbiological<br />

deposits that would serve to reinoculate the system<br />

if not properly removed.<br />

The performance and economics of a microbiological<br />

control program are affected by a<br />

variety of factors. Many of these are in turn<br />

affected by the variables of each papermaking operation.<br />

The variables that have the most significant<br />

impact on the control program include:<br />

• fresh water quality<br />

• fiber source<br />

• additives<br />

• grade structure<br />

• retention program<br />

• mill closure<br />

• operating pH<br />

• operating temperatures<br />

• system & machine design<br />

• stock management practices<br />

• boilout & wash-up practices<br />

To prevent unplanned microbiological-related problems<br />

resulting from operational changes, consult with<br />

your in-house and supplier experts. Taking time to<br />

discuss potential changes in any of the areas on the<br />

potential impact of the microbiological control program<br />

will be time well spent.<br />

<strong>Nalco</strong> Company 1601 West Diehl Road • Naperville, Illinois 60563-1198<br />

SUBSIDIARIES AND AFFILIATES IN PRINCIPAL LOCATIONS AROUND THE WORLD

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