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20.2 Outline a procedure for separating a mixture

20.2 Outline a procedure for separating a mixture

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(r)<br />

(1)H2SO4/HONO NH2<br />

(2)Cu,CU2O,H2O OH<br />

ClN 2<br />

ClN2 CH3 + H3C<br />

OH<br />

20.32 Write equations <strong>for</strong> simple chemical tests that would distinguish between<br />

(a) Benzylamine and benzamide<br />

(b) Allyamine and popylamine<br />

(c) P-Toluidine and N-methylaniline<br />

(d) Cyclohexylamine and piperidine<br />

(e) Pyridine and benzene<br />

(f) Cyclohexylamine and aniline<br />

(g) Triethylamine and diethylamine<br />

(h) Tripropylammonium chloride and tetrapropylammonium chloride<br />

(i) Tetrapropylammonium chloride and tetrapropylammonium hydroxide<br />

Answer:<br />

(a)<br />

(b)<br />

NH 2<br />

CONH 2<br />

Br 2<br />

Br 2<br />

Br<br />

NH 2<br />

Br<br />

no reaction<br />

Br<br />

CH 3<br />

H3C<br />

H 3C<br />

N N<br />

N N<br />

OH<br />

CH 3<br />

OH

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