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Macromolecules, Vol. 37, No. 5, 2004 Notes 1993<br />

Figure 4. UV-vis spectra <strong>of</strong> copolymers 1,2, and 3 and monomer 5 in chlor<strong>of</strong>orm containing 1% ethanol.<br />

The successful syntheses <strong>of</strong> these block copolymers will<br />

facilitate the study <strong>of</strong> novel supramolecular polymers<br />

<strong>with</strong> interesting assembly properties.<br />

Acknowledgment. This work was supported by the<br />

MRSEC program <strong>of</strong> the National Science Foundation<br />

under Award (DMR 9400488). G.N.T. thanks ONR for<br />

a Young Investigators Award and 3M Corporation for<br />

a Non-tenured Faculty Award. The authors thank Dr.<br />

Craig Hawker for fruitful discussion and providing the<br />

alkoxyamine initiator.<br />

Supporting Information Available: Synthetic procedures<br />

and materials characterization data. This material is<br />

available free <strong>of</strong> charge via the Internet at http://pubs.acs.org.<br />

References and Notes<br />

(1) Ikkala, O.; Brinke, G. T. Science 2002, 295, 2407-2409.<br />

(2) Lehn, J.-M. Supramolecular ChemistrysConcepts and Prospectives;<br />

VCH: Weinheim, 1995.<br />

(3) Balzani, V.; Juris, A.; Venturi, M.; Campagna, S.; Serroni,<br />

S. Chem. Rev. 1996, 96, 759-833.<br />

(4) Lohmeijer, B. G. G.; Schubert, U. S. J. Polym. Sci., Polym<br />

Chem. 2003, 41, 1413-1427.<br />

(5) Potts, K. T.; Usifer, D. A. Macromolecules 1988, 21, 1985-<br />

1991.<br />

(6) Hanabusa, K.; Nakano, K.; Koyama, T.; Shirai, H.; Hojo,<br />

N.; Kurose, A. Makromol. Chem. 1990, 191, 391-396.<br />

(7) Hanabusa, K.; Nakamura, A.; Koyama, T.; Shirai, H.<br />

Makromol. Chem. 1992, 193, 1309-1319.<br />

(8) Chujo, Y.; Sada, K.; Saegusa, T. Macromolecules 1993, 26,<br />

6320-6323.<br />

(9) Chujo, Y.; Sada, K.; Saegusa, T. Macromolecules 1993, 26,<br />

6315-6319.<br />

(10) Chujo, Y.; Sada, K.; Saegusa, T. Polym. J. 1993, 23, 599-<br />

608.<br />

(11) Johnson, R. M.; Ng, C.; Samson, C. C. M.; Fraser, C. L.<br />

Macromolecules 2000, 33, 8618-8628.<br />

(12) Lamba, J. J. S.; Fraser, C. L. J. Am. Chem. Soc. 1997, 119,<br />

1801-1802.<br />

(13) McAlvin, J. E.; Fraser, C. L. Macromolecules 1999, 32,<br />

1341-1347.<br />

(14) McAlvin, J. E.; Fraser, C. L. Macromolecules 1999, 32,<br />

6925-6932.<br />

(15) McAlvin, J. E.; Scott, S. B.; Fraser, C. L. Macromolecules<br />

2000, 33, 6953-6964.<br />

(16) Park, C. M.; McAlvin, J. E.; Fraser, C. L.; Thomas, E. L.<br />

Chem. Mater. 2002, 14, 1225-1230.<br />

(17) Smith, A. P.; Fraser, C. L. Macromolecules 2003, 36, 2654-<br />

2660.<br />

(18) Wu, X. F.; Collings, J. E.; McAlvin, J. E.; Cutts, R. W.;<br />

Fraser, C. L. Macromolecules 2001, 34, 2812-2821.<br />

(19) Wu, X. F.; Fraser, C. L. Macromolecules 2000, 33, 4053-<br />

4060.<br />

(20) Schubert, U. S.; Eschbaumer, C. Angew. Chem., Int. Ed.<br />

2002, 41, 2892-2926.<br />

(21) Gohy, J. F.; Lohmeijer, B. G. G.; Schubert, U. S. Macromol.<br />

Rapid Commun. 2002, 23, 555-560.<br />

(22) Schubert, U. S.; Eschbaumer, C.; Andres, P.; H<strong>of</strong>meier, H.;<br />

Weidl, C. H.; Herdtweck, E.; Dulkeith, E.; Morteani, A.;<br />

Hecker, N. E.; Feldmann, J. Synth. Met. 2001, 121, 1249-<br />

1252.<br />

(23) Schubert, U. S.; Eschbaumer, C.; Hien, O.; Andres, P. R.<br />

Tetrahedron Lett. 2001, 42, 4705-4707.<br />

(24) Schubert, U. S.; H<strong>of</strong>meier, H. Macromol. Rapid Commun.<br />

2002, 23, 561-566.<br />

(25) Calzia, K. J.; Tew, G. N. Macromolecules 2002, 35, 6090-<br />

6093.<br />

(26) Newkome, G. R.; He, E. J. Mater. Chem. 1997, 7, 1237-<br />

1244.<br />

(27) Benoit, D.; Chaplinski, V.; Braslau, R.; Hawker, C. J. J. Am.<br />

Chem. Soc. 1999, 121, 3904-3920.<br />

(28) Hawker, C. J.; Bosman, A. W.; Harth, E. Chem. Rev. 2001,<br />

101, 3661-3688.<br />

(29) Donovan, M. S.; Sanford, T. A.; Lowe, A. B.; Sumerlin, B.<br />

S.; Mitsukami, Y.; McCormick, C. L. Macromolecules 2002,<br />

35, 4570-4772.<br />

(30) Nakamoto, K. J. Phys. Chem. 1960, 64, 1420-1425.<br />

(31) Lee, J.; Hogen-Esch, T. E. Macromolecules 2001, 34, 2805-<br />

2811.<br />

(32) Evans, R. A.; Rizzardo, E. Macromolecules 1996, 29, 6983-<br />

6989.<br />

(33) Ganachaud, F.; Monteiro, M. J.; Gilbert, R. G.; Dourges, M.<br />

A.; Thang, S. H.; Rizzardo, E. Macromolecules 2000, 33,<br />

6738-6745.<br />

(34) Moad, G.; Mayadunne, R. T. A.; Rizzardo, E.; Skidmore, M.;<br />

Thang, S. H. Macromol. Symp. 2003, 192, 1-12.<br />

(35) Donovan, M. S.; Sanford, T. A.; Lowe, A. B.; Sumerlin, B.<br />

S.; Mitsukami, Y.; McCormick, C. L. Macromolecules 2002,<br />

35, 4570-4772.<br />

(36) Gotz, H.; Harth, E.; Schiller, S. M.; Frank, C. W.; Knoll, W.;<br />

Hawker, C. J. J. Polym. Sci., Polym. Chem. 2002, 40, 3379-<br />

3391.<br />

(37) Peter, K.; Thelakkat, M. Macromolecules 2003, 36, 1779-<br />

1785.<br />

MA0352375

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