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Statistical and Low Temperature Physics - University of Liverpool

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To liquefy Air<br />

I shall start with the liquefying <strong>of</strong> air. The same principles are<br />

used in liquefying helium.<br />

The cooling <strong>of</strong> air is achieved by expansion.<br />

In an ideal gas, expansion against a moving piston converts<br />

internal energy to work, thus cooling it down.<br />

In a real gas, work must also be done against the attraction<br />

between atoms or molecules. This work is much larger than the<br />

work done against the moving piston, <strong>and</strong> is the principal<br />

means <strong>of</strong> cooling. It is called the Joule-Thomson effect.<br />

<strong>Statistical</strong> <strong>Physics</strong> 11 Oct - Dec 2009

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