Modern Spectroscopy

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6.2 POLYATOMIC MOLECULES 177 Figure 6.26 Rotational transitions accompanying a P u S þ g infrared vibrational transition in a D 1h linear polyatomic molecule. For C 1v the g and u subscripts and s and a labels should be dropped Figure 6.27 The 1 1 0 51 0 , P u S þ g infrared band of acetylene. (The unusual vertical scale allows both the very intense Q branch and the weak P and R branches to be shown conveniently)
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MODERN SPECTROSCOPY Fourth Edition
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Copyright # 1987, 1992, 1996, 2004
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vi CONTENTS Exercises 38 Bibliograp
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viii CONTENTS 6.1.4 Vibration-rotat
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x CONTENTS 8.2.1.2 Processes in Aug
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Preface to first edition Modern Spe
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Preface to second edition A new edi
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Preface to third edition One of the
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Preface to fourth edition Spectrosc
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Units, dimensions and conventions T
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UNITS, DIMENSIONS AND CONVENTIONS x
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Useful Conversion Factors Unit cm 7
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1 Some Important Results in Quantum
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1.2 THE EVOLUTION OF QUANTUM THEORY
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levels in Figure 1.1 except that ~n
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1.2 THE EVOLUTION OF QUANTUM THEORY
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1.3 THE SCHRÖDINGER EQUATION AND S
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Table 1.1 Some Y ‘m‘ wave funct
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3. Plot 4pr2R2 n‘ against r (or r
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Table 1.3 Some values of the nuclea
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1.3.5 The rigid rotor 1.3 THE SCHR
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the molecule may have even at the a
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2 Electromagnetic Radiation and its
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2.2 ABSORPTION AND EMISSION OF RADI
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For the vibrational energy level: N
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2.2 ABSORPTION AND EMISSION OF RADI
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Here, t is the time taken for N n t
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although, as we shall see in Chapte
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2.2 Calculate in hertz the broadeni
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42 3 GENERAL FEATURES OF EXPERIMENT
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4 Molecular Symmetry The theory of
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4.1.2 Plane of symmetry, s 4.1 ELEM
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plane. This example also illustrate
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4.1 ELEMENTS OF SYMMETRY 79 racemic
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All the other four structures in Fi
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4.2.2 S n point groups An Sn point
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(Figure 4.11j), for example, and al
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Molecules belonging to the I h poin
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4.3 POINT GROUP CHARACTER TABLES 89
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4.3.4 I h character table The I h c
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In molecules such as trans-1,2-difl
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(b) F I, s H F Point group Cs δ +
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5 Rotational Spectroscopy 5.1 Linea
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.3 ROTATIONAL RAMAN SPECTROSCOPY 1
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5.4 STRUCTURE DETERMINATION FROM RO
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5.4 STRUCTURE DETERMINATION FROM RO
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5.2 Rearrange Equation (5.20) into
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138 6 VIBRATIONAL SPECTROSCOPY Tabl
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140 6 VIBRATIONAL SPECTROSCOPY Figu
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142 6 VIBRATIONAL SPECTROSCOPY temp
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144 6 VIBRATIONAL SPECTROSCOPY wher
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146 6 VIBRATIONAL SPECTROSCOPY tran
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148 6 VIBRATIONAL SPECTROSCOPY Figu
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150 6 VIBRATIONAL SPECTROSCOPY From
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Page 418: 6.2 POLYATOMIC MOLECULES 179 Figure
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Page 454: BIBLIOGRAPHY 197 Bellamy, L. J. (19
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Table 7.1 Ground configurations and
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204 7 ELECTRONIC SPECTROSCOPY Each
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206 7 ELECTRONIC SPECTROSCOPY One a
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208 7 ELECTRONIC SPECTROSCOPY accor
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210 7 ELECTRONIC SPECTROSCOPY Nowad
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212 7 ELECTRONIC SPECTROSCOPY 1. Of
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214 7 ELECTRONIC SPECTROSCOPY Figur
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218 7 ELECTRONIC SPECTROSCOPY Altho
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220 7 ELECTRONIC SPECTROSCOPY where
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224 7 ELECTRONIC SPECTROSCOPY This
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226 7 ELECTRONIC SPECTROSCOPY MOs a
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228 7 ELECTRONIC SPECTROSCOPY is ca
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232 7 ELECTRONIC SPECTROSCOPY The g
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234 7 ELECTRONIC SPECTROSCOPY motio
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236 7 ELECTRONIC SPECTROSCOPY For a
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238 7 ELECTRONIC SPECTROSCOPY In de
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240 7 ELECTRONIC SPECTROSCOPY 7.2.5
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242 7 ELECTRONIC SPECTROSCOPY Table
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246 7 ELECTRONIC SPECTROSCOPY It is
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250 7 ELECTRONIC SPECTROSCOPY maxim
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252 7 ELECTRONIC SPECTROSCOPY Secti
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254 7 ELECTRONIC SPECTROSCOPY Promo
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260 7 ELECTRONIC SPECTROSCOPY Where
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264 7 ELECTRONIC SPECTROSCOPY 2s ch
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268 7 ELECTRONIC SPECTROSCOPY 4. Wh
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270 7 ELECTRONIC SPECTROSCOPY The g
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276 7 ELECTRONIC SPECTROSCOPY elect
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278 7 ELECTRONIC SPECTROSCOPY 7.3.3
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282 7 ELECTRONIC SPECTROSCOPY Examp
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286 7 ELECTRONIC SPECTROSCOPY in Fi
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288 7 ELECTRONIC SPECTROSCOPY 7.7 D
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290 8 PHOTOELECTRON AND RELATED SPE
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338 9 LASERS AND LASER SPECTROSCOPY
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Appendix A Character Tables Index t
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Table A.7 C 5 I C 5 C 2 5 C 3 5 C 4
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Table A.14 C 5v I 2C 5 2C 2 5 5s v
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Table A.22 C 2h I C 2 i s h A g 1 1
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Table A.27 D 2d I 2S 4 C 2 2C 0 2 2
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Table A.33 D 3h I 2C 3 3C 2 s h 2S
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Table A.38 S 4 I S 4 C 2 S 3 4 A 1
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Table A.43 O h I 8C 3 6C 2 6C 4 3C
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Appendix B Symmetry Species of Vibr
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Table B.2 (continued ) Point group
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Table B.2 (continued ) Point group
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Index of Atoms and Molecules The sy
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EXAFS, 329 on graphite, SEXAFS, 333
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TlBr=TlI in attenuated total reflec
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CH 3I (methyl iodide) principal axe
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Twelve Atoms C 4H 8 (cyclobutane) r
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Subject Index Note. Insertion of
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CRDS (cavity ring-down spectroscopy
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Electric component, of electromagne
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Intensity alternation, 128, 129ff,
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Nebulae, 119ff Neodymium-YAG laser,
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Ratio recording, 68 Rayleigh, Lord,
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Term values electronic, 240ff rotat
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