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MODERN SPECTROSCOPY Fourth Edition
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Copyright # 1987, 1992, 1996, 2004
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vi CONTENTS Exercises 38 Bibliograp
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viii CONTENTS 6.1.4 Vibration-rotat
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x CONTENTS 8.2.1.2 Processes in Aug
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Preface to first edition Modern Spe
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Preface to second edition A new edi
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Preface to third edition One of the
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Preface to fourth edition Spectrosc
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Units, dimensions and conventions T
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UNITS, DIMENSIONS AND CONVENTIONS x
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Useful Conversion Factors Unit cm 7
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1 Some Important Results in Quantum
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1.2 THE EVOLUTION OF QUANTUM THEORY
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levels in Figure 1.1 except that ~n
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1.2 THE EVOLUTION OF QUANTUM THEORY
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1.3 THE SCHRÖDINGER EQUATION AND S
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1.3 THE SCHRÖDINGER EQUATION AND S
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Table 1.1 Some Y ‘m‘ wave funct
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3. Plot 4pr2R2 n‘ against r (or r
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1.3 THE SCHRÖDINGER EQUATION AND S
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Table 1.3 Some values of the nuclea
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1.3.5 The rigid rotor 1.3 THE SCHR
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1.3 THE SCHRÖDINGER EQUATION AND S
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the molecule may have even at the a
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2 Electromagnetic Radiation and its
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2.2 ABSORPTION AND EMISSION OF RADI
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For the vibrational energy level: N
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2.2 ABSORPTION AND EMISSION OF RADI
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Here, t is the time taken for N n t
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although, as we shall see in Chapte
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2.2 Calculate in hertz the broadeni
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42 3 GENERAL FEATURES OF EXPERIMENT
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44 3 GENERAL FEATURES OF EXPERIMENT
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46 3 GENERAL FEATURES OF EXPERIMENT
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48 3 GENERAL FEATURES OF EXPERIMENT
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50 3 GENERAL FEATURES OF EXPERIMENT
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52 3 GENERAL FEATURES OF EXPERIMENT
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54 3 GENERAL FEATURES OF EXPERIMENT
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56 3 GENERAL FEATURES OF EXPERIMENT
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58 3 GENERAL FEATURES OF EXPERIMENT
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60 3 GENERAL FEATURES OF EXPERIMENT
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62 3 GENERAL FEATURES OF EXPERIMENT
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64 3 GENERAL FEATURES OF EXPERIMENT
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66 3 GENERAL FEATURES OF EXPERIMENT
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68 3 GENERAL FEATURES OF EXPERIMENT
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70 3 GENERAL FEATURES OF EXPERIMENT
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4 Molecular Symmetry The theory of
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4.1.2 Plane of symmetry, s 4.1 ELEM
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plane. This example also illustrate
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4.1 ELEMENTS OF SYMMETRY 79 racemic
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All the other four structures in Fi
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4.2.2 S n point groups An Sn point
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(Figure 4.11j), for example, and al
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Molecules belonging to the I h poin
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4.3 POINT GROUP CHARACTER TABLES 89
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4.3 POINT GROUP CHARACTER TABLES 91
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4.3 POINT GROUP CHARACTER TABLES 93
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4.3 POINT GROUP CHARACTER TABLES 95
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4.3.4 I h character table The I h c
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In molecules such as trans-1,2-difl
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(b) F I, s H F Point group Cs δ +
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5 Rotational Spectroscopy 5.1 Linea
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.2 ROTATIONAL INFRARED, MILLIMETRE
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5.3 ROTATIONAL RAMAN SPECTROSCOPY 1
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5.3 ROTATIONAL RAMAN SPECTROSCOPY 1
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5.3 ROTATIONAL RAMAN SPECTROSCOPY 1
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5.3 ROTATIONAL RAMAN SPECTROSCOPY 1
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5.4 STRUCTURE DETERMINATION FROM RO
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5.4 STRUCTURE DETERMINATION FROM RO
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5.2 Rearrange Equation (5.20) into
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138 6 VIBRATIONAL SPECTROSCOPY Tabl
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140 6 VIBRATIONAL SPECTROSCOPY Figu
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142 6 VIBRATIONAL SPECTROSCOPY temp
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144 6 VIBRATIONAL SPECTROSCOPY wher
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146 6 VIBRATIONAL SPECTROSCOPY tran
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148 6 VIBRATIONAL SPECTROSCOPY Figu
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150 6 VIBRATIONAL SPECTROSCOPY From
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152 6 VIBRATIONAL SPECTROSCOPY Figu
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154 6 VIBRATIONAL SPECTROSCOPY purp
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156 6 VIBRATIONAL SPECTROSCOPY Figu
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158 6 VIBRATIONAL SPECTROSCOPY Figu
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160 6 VIBRATIONAL SPECTROSCOPY Figu
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162 6 VIBRATIONAL SPECTROSCOPY has
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164 6 VIBRATIONAL SPECTROSCOPY Tabl
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166 6 VIBRATIONAL SPECTROSCOPY Tabl
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168 6 VIBRATIONAL SPECTROSCOPY just
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170 6 VIBRATIONAL SPECTROSCOPY whic
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172 6 VIBRATIONAL SPECTROSCOPY Acet
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174 6 VIBRATIONAL SPECTROSCOPY wher
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176 6 VIBRATIONAL SPECTROSCOPY Figu
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178 6 VIBRATIONAL SPECTROSCOPY even
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180 6 VIBRATIONAL SPECTROSCOPY Figu
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182 6 VIBRATIONAL SPECTROSCOPY Figu
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184 6 VIBRATIONAL SPECTROSCOPY 6.2.
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186 6 VIBRATIONAL SPECTROSCOPY Figu
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188 6 VIBRATIONAL SPECTROSCOPY This
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190 6 VIBRATIONAL SPECTROSCOPY Figu
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192 6 VIBRATIONAL SPECTROSCOPY The
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194 6 VIBRATIONAL SPECTROSCOPY Figu
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196 6 VIBRATIONAL SPECTROSCOPY 6.2
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7 Electronic Spectroscopy 7.1 Atomi
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Electrons in the atom concerned may
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Table 7.1 (continued ) Atom Z Groun
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7.1.2.2 Coupling of angular momenta
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7.1 ATOMIC SPECTROSCOPY 207 Figure
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7.1 ATOMIC SPECTROSCOPY 209 Table 7
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Table 7.3 Derivation of terms arisi
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7.1.3 Spectra of alkali metal atoms
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7.1 ATOMIC SPECTROSCOPY 215 Some ex
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7.1 ATOMIC SPECTROSCOPY 217 Figure
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Both the calculated wavelengths of
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7.1 ATOMIC SPECTROSCOPY 221 Figure
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An obvious difference between the e
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For the coupling of the orbital ang
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AO is antisymmetric to this reflect
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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Rule 4: þ$j ; þ$þ; $ ð7:70Þ Th
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The ground configuration of oxygen
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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maximum at v 0 > 0 indicates qualit
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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Hence, D 0 0 can be obtained from ~
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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7.2 ELECTRONIC SPECTROSCOPY OF DIAT
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For non-linear polyatomic molecules
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7.3 ELECTRONIC SPECTROSCOPY OF POLY
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orbital more than counterbalances t
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7.3.1.3 Benzene 7.3 ELECTRONIC SPEC
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7.3 ELECTRONIC SPECTROSCOPY OF POLY
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7.3 ELECTRONIC SPECTROSCOPY OF POLY
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7.3 ELECTRONIC SPECTROSCOPY OF POLY
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pushed down. The result, as shown i
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for transitions between non-degener
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Gðc 0 vÞ ¼Gðc 00 vÞ in Equatio
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7.3 ELECTRONIC SPECTROSCOPY OF POLY
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7.3 ELECTRONIC SPECTROSCOPY OF POLY
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7.3 ELECTRONIC SPECTROSCOPY OF POLY
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Exercises 7.1 Indicate which of the
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8 Photoelectron and Related Spectro
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Figures 8.1(a) and 8.1(b) illustrat
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8.1 PHOTOELECTRON SPECTROSCOPY 293
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8.1 PHOTOELECTRON SPECTROSCOPY 295
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In most cases of closed-shell molec
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8.1 PHOTOELECTRON SPECTROSCOPY 299
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Figure 8.9 The He I ultraviolet pho
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spectroscopy to be 1.4144 A˚ in th
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8.1 PHOTOELECTRON SPECTROSCOPY 305
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degeneracy. The only relatively sim
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The spectrum below shows that the O
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8.1 PHOTOELECTRON SPECTROSCOPY 311
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Figure 8.17 A short, barely resolve
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8.2 AUGER ELECTRON AND X-RAY FLUORE
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8.2 AUGER ELECTRON AND X-RAY FLUORE
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8.2 AUGER ELECTRON AND X-RAY FLUORE
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8.2 AUGER ELECTRON AND X-RAY FLUORE
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8.2 AUGER ELECTRON AND X-RAY FLUORE
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8.2 AUGER ELECTRON AND X-RAY FLUORE
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8.3 EXTENDED X-RAY ABSORPTION FINE
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8.3 EXTENDED X-RAY ABSORPTION FINE
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8.3 EXTENDED X-RAY ABSORPTION FINE
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8.3 EXTENDED X-RAY ABSORPTION FINE
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8.4 EXAFS spectra of platinum metal
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9 LASERS AND LASER SPECTROSCOPY 9.1
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9.1 GENERAL DISCUSSION OF LASERS 33
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The four-level system in Figure 9.2
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9.1 GENERAL DISCUSSION OF LASERS 34
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9.1.6 Harmonic generation In the co
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9.2 EXAMPLES OF LASERS 347 Figure 9
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produce pulses as short a 8 fs. Com
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9.2 EXAMPLES OF LASERS 351 Figure 9
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9.2 EXAMPLES OF LASERS 353 Figure 9
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The spectroscopy of ion lasers is g
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9.2 EXAMPLES OF LASERS 357 two-leve
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Each of the lasing vibrational tran
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direction of one or more normal coo
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employing laser radiation, were des
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spectrum and only the a 2u and e u
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3.5 Two-photon and multiphoton ab
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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vibrational spectroscopy but from e
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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Figure 9.40 shows the 11 0360 band
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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Hz ¼ 110 cm 1 ) and separated by 0
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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9.3 USES OF LASERS IN SPECTROSCOPY
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dispersed fluorescence (DF), spectr
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- Page 876: 408 APPENDIX A CHARACTER TABLES Tab
- Page 880: 410 APPENDIX A CHARACTER TABLES Tab
- Page 884: 412 APPENDIX A CHARACTER TABLES Tab
- Page 888: 414 APPENDIX A CHARACTER TABLES Tab
- Page 892: 416 APPENDIX A CHARACTER TABLES Tab
- Page 896: 418 APPENDIX A CHARACTER TABLES Tab
- Page 900: 420 APPENDIX A CHARACTER TABLES Tab
- Page 904: 422 APPENDIX A CHARACTER TABLES Tab
- Page 908: 424 APPENDIX B SYMMETRY SPECIES OF
- Page 912: 426 APPENDIX B SYMMETRY SPECIES OF
- Page 916: 428 APPENDIX B SYMMETRY SPECIES OF
- Page 922: EXAFS, 329 on graphite, SEXAFS, 333
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