Wood Preservatives Labels - BC Hydro

1-FEB-2010 

2009-3865 

DIRECTIONS FOR USE 

USE RESTRICTION: Do not install CobraRods in wood which is 

submerged or at a waterline i.e. not for use in marine or fresh water pilings. 

CobraRods are for Remedial treatment of Utility Pole Structures 

dimensional lumber (round stock, square stock). For protection of non-food 

contact wood against fungal decay and insects. CobraRods can be used 

for most wood species. 

CobraRods are effective against some kinds of termites. The Cobra TM 

Rod is to be inserted in wood with permanent or periodical moisture content 

above the fibre saturation point (25%-30%) etc. The rate of application for 

Cobra TM Rods is dependent upon the volume of wood to be treated. The 

recommended load is up to 6 kg Boric Acid per cu. metre of wood 

depending upon requirements for treatment. The loading should not be less 

than 2 kg of Boric Acid per cu. metre of wood. Rods contain 1.45 times 

equivalent Boric Acid (BAE). 

For inserting the Rods, the three step process is as follows: 

1. Drill 12.5mm holes to accommodate the rod size needed. 

2. Insert the correct size and quantity of Cobra TM Rods needed into the predrilled 

holes (determined from area to be treated.) Leave enough headroom 

to accommodate a 1/16" oversize plug. Never hammer the Cobra TM Rod 

during installation. 

3. The headspace should have a 1.5mm oversized plug hammered into the 

pole. 

Inspections can be carried out every 3-8 years for Industrial wood 

structures. If reuseable plugs are used new rods may be inserted into 

existing holes during the reinspection process and the same plugs tapped 

back into place. The angle at which the rods are installed is accomplished 

by using a drill guide at the groundline zone. This will ensure the rods are 

placed in the most advantageous location for best diffusion results. The 

sapwood and heartwood interface in the outer shell is the best area, 

ensuring chemical loads are sufficient to provide adequate decay protection. 

If the wood is decayed sufficiently to cause diminished strength properties 

beyond functional requirements, DO NOT install Cobra TM Rods. Be careful 

during installation to not cause unacceptable structural damage to the wood 

during installation of rods. 

Note: Boring pattern selected shall comply with the Canadian Electrical 

Association Publication 118-D-318A, 1990, "Development of an Application 

Guide for the Use of Vapam" or if an alternative boring pattern is to be used, 

the applicator must receive written confirmation from the owner(s) of the 

pole stating that the selected boring pattern is acceptable and will not result 

in significant pole strength loss. Bore hole diameter shall not exceed 

12.5mm when treating poles with CobraRods. 

Rates: Apply to achieve a loading of 6 kg of Boric Acid per m 3 of wood in 

the treated zone. An average per pole will be approximately 0.144kg of 

CobraRod. 

The distance between the CobraRods should be a maximum 20-25 cm in 

the zone to be protected. 

Cobra TM Rod 

CAUTION POISON 

Wood Preservative for Remedial 

Treatment of Utility Poles, Posts, Land Pilings, 

Millwork, Decks, Window Joinery 

and nonfood contact wood. 

Preventative and Remedial Protection of Wood Against 

Fungal Decay and Wood boring Insects 

COMMERCIAL - READ THE LABEL BEFORE USING 

KEEP OUT OF REACH OF CHILDREN 

MAY BE HARMFUL IF SWALLOWED 

GUARANTEE: 

Disodium Octaborate Tetrahydrate 

(Na2 B8O13)...............................90.6% 

Copper as elemental 

(Present as copper hydroxide)...1.8% 

Boric Acid ....................................4.7% 

Registration No.: 25580 

Pest Control Products Act 

Net Contents 500 rods Number/Pkg 2 X 250 rods 

Total weight 8.45 kg. 

TOXICOLOGICAL INFORMATION Contains disodium octaborate tetrahydrate. 

Treat symptomatically. 

DISPOSAL 

1. Follow provincial instructions for any required additional cleaning of the 

container prior to its disposal or reconditioning. 

2. Make the empty container unsuitable for further use. 

3. Dispose of the container in accordance with provincial requirements. 

4. For information on the disposal of unused, unwanted product, contact the 

manufacturer or the provincial regulatory agency. Contact the 

manufacturer and the provincial regulatory agency in case of a spill, and 

for clean-up of spills. 

Registrant: Genics Inc. 

561 Acheson Rd. 53016 Hwy 60 

Acheson, AB T7X 5A7 

Phone: (780) 962-1000 

Fax: (780) 926-1052 

See reverse label for complete instructions 

COBRARODS BY SIZE AND BORIC ACID EQUIVALENT 

Dimensions Weight BAE 

(dia. x length) size imperial grams (ounces) grams (ounces) 

6mm x 12mm 1/4” x 1/2” 0.51g (0.018oz) .77g (0.027oz) 

8mm x 12mm 1/3” x 1/2” 1.30g (0.046oz) 1.90g (0.067oz) 

8mm x 24mm 1/3” x 1” 2.61g (0.092oz) 3.80g (0.134oz) 

8mm x 65mm 1/3” x 2 5/8” 6.00g (0.212oz) 8.73g (0.308oz) 

12mm x 50mm 1/2” x 2” 11.25g (0.397oz) 16.33g (0.576oz) 

12mm x 100mm 1/2” x 4” 22.25g (0.785oz) 32.32g (1.14 oz) 

18mm x 75mm 3/4” x 3” 36.57g (1.29 oz) 53.30g (1.88 oz) 

11mm x 120mm 25/64”x4 1/2” 16.90g (0.596oz) 24.50g (0.864oz) 

DIAMETER THICK SIZE IMPERIAL 

Wafers 18mm x 2mm long 3/4” x 1/16” 

Pellets 6mm x 6mm long 1/4” x 1/4” 

PRECAUTIONS- KEEP OUT OF REACH OF CHILDREN. Wear 

gloves when handling Cobra"Rods. Avoid rubbing eyes while working 

with product. May be harmful, avoid contact with eyes and skin, avoid 

breathing dust, use only in a well ventilated area, wear freshly laundered 

clothes daily, store and wash all protective clothing separately from 

household laundry, wash clothes in detergent and hot water before 

reuse. May be fatal if swallowed. Store out of reach of children. Store in 

a dry location and out of contact with food and feed. Dispose of on-site 

empty containers in household garbage. Wash hands thoroughly after 

handling this product and before eating or smoking. Do not contaminate 

water courses or ground. Do not hammer the CobraRods to avoid 

shattering. 

FIRST-AID 

If in eyes: Hold eye open and rinse slowly and gently with water for 

15–20 minutes. Remove contact lenses, if present, after the first 5 minutes, 

then continue rinsing eye. Call a poison control centre or doctor for 

treatment advice. 

If swallowed: Call a poison control centre or doctor immediately for 

treatment advice. Have person sip a glass of water if able to swallow. 

Do not induce vomiting unless told to do so by a poison control centre 

or doctor. Do not give anything by mouth to an unconscious person. 

If inhaled: Move person to fresh air. If person is not breathing, call 911 

or an ambulance, then give artificial respiration, preferably by mouth-to mouth, 

if possible. Call a poison control centre or doctor for further treatment advice. 

If on skin or clothing: Take off contaminated clothing. Rinse skin 

immediately with plenty of water for 15–20 minutes. Call a poison control 

centre ordoctor for treatment advice. 

Take container, label or product name and Pest Control Product Registration 

Number with you when seeking medical attention. 

NOTICE TO USER - 

This pest control product is to be used only in accordance with the 

directions on the label. It is an offence under the Pest Control Products 

Act to use this product in a way that is inconsistent with the directions on 

the label. The user assumes the risk to persons or property that arises 

from any such use of this product.

****************************** 

This label transcript service is offered by the Pest Management Regulatory Agency to provide 

efficient searching for label information. This service and this information do not replace the 

official hard-copy label. The PMRA does not provide any guarantee or assurance that the 

information obtained through this service is accurate, current or correct, and is therefore not 

liable for any loss resulting, directly or indirectly, from reliance upon this service.

CobraRod 

Chemical Product and Company Identification 

Material Safety Data Sheet 

DATE OF ISSUE January 1, 2007 

Supersedes June 24, 2004 

Trade name (as labeled): CobraRod 

Product Class:............................................................Fungicide/Wood Preservative 

Product description:...................................................Fungicide in the form of solid fused glass rod; used to prevent decay in wood structures by 

inserting into pre-drilled holes. 

PCP Registration No.: ...............................................25580 

EPA Registration No.:...............................................71653-2 

Manufacturer’s Name: ..............................................GENICS INC. 

561 Acheson Rd. 53016 Hwy 60 

Acheson, Alberta 

Canada T7X 5A7 

Emergency Phone:........................................ (780) 975-1937 

or CHEMTREC .. (800) 424-9300 

Genics Business Phone: ............................................(780) 962-1000 

Composition / Information on Ingredients 

Name % W/W CAS # ACGIH TLV OSHA PEL 

Anhydrous Disodium Octaborate 88 - 91% 12008-41-12 NE NE 

Copper (from Copper Hydroxide) 1.5 - 3% 20427-59-2 1 mg/m 3 (Cu dust + mist) 1 mg/m 3 (Cu dust + mist) 

Boric Acid 4 - 8% 10043-35-3 NE NE 

*NE = Not Established 

Hazard Identification (toxicological properties) 

Name Toxicological Data 

Cobra Rod LD50 oral rat >3500 mg/kg B.W. 

There are no medical conditions known to be aggravated by exposure to this product. 

Product ingredients not listed as a carcinogen or potential carcinogen on the following lists: US OSHA Z LIST, NTP, IARC, CAL/OSHA. 

Emergency Overview 

CobraRods are a dark green, solid, glass-like substance that are not flammable, combustible, or explosive and have low acute oral and zero dermal 

irritation. CobraRods are not intended for ingestion. CobraRods have low acute toxicity and small amounts accidentally swallowed are not likely 

to cause effects. Some rods may have sharp edges and in cases where they are completely swallowed these sharp edges may cause grazing of the 

intestinal tract. 

First Aid Measures 

Eyes: Properly used CobraRods present no hazard to eyes. 

Swallowing: Primary risk from choking, administer first aid for such and take to hospital. 

Inhalation: Properly used CobraRods present no inhalation risk. 

Fire: Product is non-combustible. Extinguishing media N/A. 

Skin: Skin contact does not present any unusual hazard. Areas in contact with CobraRods can be washed with soap and water. 

Handling and Storage Procedures 

• CobraRods cause zero dermal irritation to the skin. 

• Do not use in situations where food could become contaminated. 

• Keep out of reach of children at all times. 

• Store in dry conditions in original container, out of reach of children. 

• Use only as a wood preservative. 

• When inserting, push home using a wooden or plastic dowel. 

• Never strike the rod with a hammer or similar object as this may result in the rod shattering. 

Exposure Controls – Personal Protection 

Ventilation Requirements: No special ventilation system required. 

Eye Protection: Safety glasses 

GENlCS lNC. CobraRod MSDS 

Page 1 of 2

Respiratory Protection: None required under routine conditions of use. 

Body Protection: None needed under normal conditions of use. 

Hygienic Practices: Wash hands before eating or smoking. 

Physical and Chemical Properties 


DATE OF ISSUE January 1, 2007 

Supersedes June 24, 2004 

Vapour Density: NA Evaporation Rate (water =1): NA Density: 2.223 g/ml 

Melting Point/Range: 1000 o C Solubility in Water: 21% Boiling Point: NA 

Vapour Pressure mm Hq @20 o C: NA Appearance and Colour: Green-black, hard, glass-like rods. Flashpoint: NA 

Stability and Reactivity 

Stability: Stable Conditions to Avoid: No known conditions to avoid. 

Hazardous Decomposition Products: None Incompatibility (Materials to Avoid): No known materials to avoid. 

Hazardous Polymerization: Will not Occur 

Ecological Information 

♦ Boron and Copper are essential micronutrients for healthy plant growth, however, this product can be harmful to boron or copper sensitive plants 

in high quantities. Care should be taken to minimize the amount of product released to the environment. 

♦ Boron and Copper are naturally occurring and ubiquitous in the environment. 

♦ This product has a relatively low mammalian toxicity. 

♦ This product is not known to pose any adverse effect on aquatic life when applied as per label instructions. 

♦ This product is completely soluble in water and leachable through normal soil. 

Transportation Information 

• Not classified as dangerous goods under ADR or PGR regs. 

• No special requirements necessary. 

• In the event of a road accident, CobraRods should be collected in a suitable container (i.e. plastic bag) and returned to manufacturer, used 

according to label instructions, or disposed of according to disposal regulations. 

Other Information 

• Take care when administering first aid for choking especially in cases where patients are unconscious. 

• If possible seek qualified first aid assistance. 

Prepared by: 

Genics Inc. 

Phone: (780) 962-1000 or toll-free 1-877-943-6427 

Fax: (780) 962-1052 

Information contained in this MSDS refers only to the specific material designated and does not relate to any process or use with any other materials. 

This information is furnished free of charge and is based on data believed to be reliable as of the date hereof. It is intended for use by persons 

possessing technical knowledge at their own discretion and risk. Since actual use is beyond our control, no guarantee, expressed or implied, and no 

liability is assumed by Genics Inc. in conjunction with the use of this information. Nothing herein is to be construed as a recommendation to infringe 

any patents. 

GENlCS lNC. CobraRod MSDS 

Page 2 of 2

29-NOV-2007 

2005-3800 

COP-R-PLASTIC 

WOOD PRESERVING COMPOUND 

INDUSTRIAL 

DANGER 

POISON 

EYE IRRITANT 

READ THE LABEL BEFORE USING! 

REGISTRATION NUMBER 25708 PEST CONTROL PRODUCT ACT 


EYE IRRITANT 

GUARANTEE: 

Sodium Fluoride ..............................................................44.4% 

Elemental Copper present as Copper Naphthenate ……..2.0% 

NOTICE TO USER: 

This pest control product is to be used only in accordance with the directions on the label. It is an offence under the Pest Control 

Products Act to use this product in a way that is inconsistent with the directions on the label. The user assumes the risk to persons for 

property that arises from any such use of this product. 

NET CONTENTS 18.93 L (5 gallons) 

MANUFACTURED FOR: 

North Star Structural Contractors, Ltd. 

980 Ellicott Street 

Buffalo, NY 14209 

11/07

PRECAUTIONS 


FOR EXTERIOR USE ONLY! 

NOT FOR USE IN DWELLINGS. 

Fatal if swallowed. Irritating to the skin and eyes. Do not get in eyes, on skin or on clothing. May be fatal if inhaled. Do not breath 

vapours. Wear chemical resistant gloves, long-sleeved shirts, long pants and protective eyewear when handling or applying the product. 

Use a cartridge respirator appropriate for the job conditions, e.g. poorly ventilated areas. This product should not be applied by spray 

methods. Wash hands and face thoroughly with soap and water after handling and before eating, drinking, smoking or using the toilet. 

Avoid contamination of feed and food stuffs. 

This product is toxic to fish and wildlife. Do not apply directly to water. Do not apply to wood in direct contact with water or situated 

in areas that may be flooded at certain times of the year. Do not contaminate water by cleaning equipment or disposal of waste. 

STORAGE 

Store between -18°C and 60°C. Store only in original container. Keep closed when not in use. Do not store with fertilizer, food or feed. 

FIRST AID 

IF SWALLOWED: Call a poison control centre or doctor immediately for treatment advice. Do not induce vomiting unless told to do so 

by a poison control centre or doctor. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person. 

IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a 

poison control centre or doctor for treatment advice. 

IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by 

mouth-to-mouth, if possible. Call a poison control centre or doctor for further treatment advice. 

IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 

minutes, then continue rinsing eye. Call a poison control centre or doctor for treatment advice. 

Take container, label or product name and Pest Control Product Registration Number with you when seeking medical attention. 

TOXICOLOGICAL INFORMATION 

This product contains petroleum distillate. Vomiting may cause aspiration pneumonia. 


This product is to be used only for the remedial treatment of exterior industrial wood products having no opportunity for prolonged or 

direct skin contact with people or animals or contact with food, feed or drinking water. This product is not to be used in children’s 

playground equipment. 

EXTERNAL TREATMENT: Apply 1.5 mm (1/16”) to pole or timber exterior. Typical pole application is from 7.5 cm (3”) above to 45.5 

cm (18”) below groundline and lower where deeper decay is suspected. Application on poles to be restored should extend the length of 

wrap-around type repair systems. Wrap the treated area with water-proof bandage, OSMOSHIELD. 

INTERNAL TREATMENT: For control of internal decay in poles and other timbers, holes may be drilled in areas of the pole or timber 

where protection is required. Fill decay pockets and voids using a grease gun or other pressurized applicator. Plug application holes with 

secure-fitting dowels. 

Do not use this preservative where it may contaminate food, feed or drinking water. Do not use where it will be in direct contact with 

water. May be used on green-house and garden timbers in contact with non-food producing plants only. 

DISPOSAL 

DISPOSAL: (1) Tripe- or pressure-rinse the empty container. Add the rinsings to the treatment site.; (2) Follow provincial instructions 

for any required additional cleaning of the container prior to its disposal; (3) Make the empty container unsuitable for further use; (4) 

Dispose of the container in accordance with provincial requirements; (5) For information on the disposal of unused, unwanted product, 

contact the manufacturer or the provincial regulatory agency. Contact the manufacturer and the provincial regulatory agency in case of 

a spill. 

11/07

****************************** 






MATERIAL SAFETY DATA SHEET: COP-R-PLASTIC WOOD PRESERVING COMPOUND 

SECTION I 

MSDS NUMBER: 2-NS 

MSDS CODE: NS 

SYNONYMS: N/A 

MANUFACTURED BY: North Star Structural Contractors, Ltd. 

DIVISION: Utilities Division 

REGISTRATION NUMBER: PCP Reg. No. 25708 

VENDOR: N/A 

EMERGENCY PHONE: CANUTEC: (613) 996-6666 collect 

OTHER CALLS: (716) 882-5905 

ADDRESS: 980 Ellicott Street, Buffalo, NY 14209 

MSDS PREPARED BY: Teri Muchow 

DATE PREPARED: September 18, 2003 

DATE LAST REVISED: March 16, 2006 

∗ADDITIONAL INFORMATION∗ 

CANUTEC'S EMERGENCY TELEPHONE NUMBER IS TO BE USED ONLY IN THE EVENT OF CHEMICAL EMERGENCIES 

INVOLVING A SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT INVOLVING CHEMICALS. 

SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION 

TRADE NAME: Cop-R-Plastic 

Wood Preserving Compound 

CAS OSHA PEL ACGIH TLV 

OTHER 

% 

INGREDIENT NAME 

Copper Naphthenate (8% Cu) 1338-02-9 1 mg/M 3 

1 mg/M 

as Cu 

3 

N/A 20.00 

as Cu 

Sodium Fluoride, Tech. 7681-49-4 2.5 mg/M 3 

2.5 mg/M 

as F 

3 

RQ = 1000 pounds 44.40 

as F 

Petroleum Distillates 68476-30-2 500 ppm 300 ppm N/A 17.44 

SECTION III - CHEMICAL CHARACTERISTICS 

PERCENT VOLATILE THEORETICAL VOC 

BOILING MELTING FREEZING SPECIFIC GRAVITY BY VOLUME 

CONTENT 

POINT 

POINT 

POINT 

(H20 = 1) 

(PERCENT OF WEIGHT) 

N/A N/A N/A 1.42 N/A N/A 

WEIGHT PER 

VAPOR 

VAPOR 

EVAPORATION RATE 

GALLON 

pH: 

PRESSURE 

DENSITY DENSITY BASIS (N-BUAC) = 1 

11.83 LB/gal 6.2 at 25°C N/A 1.39 g/cc N/A N/A 

SOLUBILITY IN WATER: N/A REACTIVITY IN WATER: N/A 

APPEARANCE AND ODOR: Dark green thixotropic paste, faint naphthenic acid or faint organic solvent odor. 

SECTION IV - FIRE AND EXPLOSION HAZARD DATA 

FLASH POINT METHOD FLAMMABLE LIMITS IN AIR (%) AUTOIGNITION TEMPERATURE 

150°F (65.6°C) TCC N/A N/A 

NFPA CODES HEALTH 2 HMIS CODES: HEALTH 2 

FLAMMABILITY 2 FLAMMABILITY 2 

REACTIVITY 0 REACTIVITY 0 

OTHER N/A PROTECTION B 

EXTINGUISHER MEDIA: CO2, Dry chemical , water fog, foam 

SPECIAL FIRE FIGHTING PROCEDURES: Toxic vapors given off during combustion. Use proper protection equipment such as a selfcontained 

breathing apparatus. Sealed containers of product should be cooled with water to avoid potential explosion. 

COP-R-PLASTIC MSDS 

Page 1 of 3

UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and will travel along the ground and may be potentially 

ignited by independent heat or ignition source located distant from the material. Unopened containers may explode if heat from an 

independent fuel source, such as a fire, is not controlled. See Sec. IX. 

SECTION V - REACTIVITY DATA 

IS THIS CHEMICAL STABLE UNDER NORMAL CONDITIONS OF HANDLING/STORAGE (Y/N)? Y 

CONDITIONS TO AVOID (REGARDING STABILITY): Extremely high temperatures. 

INCOMPATIBILITY (MATERIALS TO AVOID): Strong acid and oxidizers. 

HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen fluoride, CO, CO2, CU fumes, sulfur fumes. 

HAZARDOUS POLYMERIZATION POSSIBLE (Y/N)? N 

CONDITIONS TO AVOID (REGARDING POLYMERIZATION): N/A 

SECTION VI - HEALTH HAZARDS 

ROUTES OF ENTRY: Eyes, skin, inhalation. 

SIGNS AND SYMPTOMS OF ACUTE OVEREXPOSURE: Eye - Test results indicate that Cop-R-Plastic is moderately irritating 

for the unwashed eye and mildly irritating for the washed eye. Eye irritation may result from contact with mists, liquid or vapors. 

Skin – test results indicate that this material is moderately irritating to skin. Moderate irritation leading to dermatitis may result 

from prolonged or repeated exposures. No significant systematic effects from absorption are expected under conditions of 

anticipated use. A skin sensitization study indicates that this product is not a skin sensitizer. Inhalation – due to the physical 

characteristics of this product, it was not possible to conduct an acute inhalation study. Data on the components used in the 

formulation of this material provide evidence that vapors or mist may irritate the nose, throat, and lungs and cause signs and 

symptoms of central nervous system depression. 

CHRONIC OVEREXPOSURE: Prolonged or repeated exposure may result in dermatitis. 

CHEMICAL LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN?: 

• NATIONAL TOXICOLOGY PROGRAM (Y/N): N 

• IARC MONOGRAPHS (Y/N): N 

• OSHA (Y/N): N 

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Unknown - treat as copper and petroleum poisoning 

TOXICITY DATA 

Acute Oral LD50 492 mg/kg 

Dermal LD50 > 2,000 mg/kg 

Primary Eye Irritation moderately irritating to unwashed 

eye 

Dermal Irritation moderately irritating 

Skin Sensitization NOT a skin sensitizer 

EMERGENCY AND FIRST AID PROCEDURES 

EMERGENCY PHONE NUMBER OF MANUFACTURER: CANUTEC (613) 996-6666 collect 

1. INHALATION: Move victim to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped, give artificial 

respiration. Keep victim warm and quiet. Get medical attention. 

2. EYE CONTACT: Flush with large amounts of water. Get medical attention. 

3. SKIN CONTACT: Thoroughly wash the exposed area with soap and water. 

4. INGESTION: DO NOT INDUCE VOMITING! Aspiration of product into lungs may cause chemical pneumonitis. Keep victim 

warm and quiet. Get medical attention immediately. 

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE 

HAZARD CLASS: 6.1 PACKAGING GROUP: III 

US DOT ID : Sodium fluoride, solid, mixture 

UN/NA NUMBER: 1690 

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in dry area. Do not store near open flames. Empty drums may 

present explosive hazards. Do not store or use near heat or open flames, such as welding or cutting torches. 

OTHER PRECAUTIONS: Read and follow label instructions. 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition and contain spill as soon as 

possible. Recover as much product as possible for reuse. Absorbents compatible with petroleum may be used to soak up spill. Do not 

allow spill material or residue to reach water. Major spills need to be reported to the National Response Center. 

WASTE DISPOSAL METHODS: See label; Do not contaminate water (product is toxic to fish). Bury in approved landfill. Dispose in 

accordance with Federal, State and local laws. 


Page 2 of 3

SECTION VIII - CONTROL MEASURES 

RESPIRATORY PROTECTION: Normally not needed. If TLV of any component is exceeded, a NIOSH/MSHA self-contained breathing 

apparatus with full face piece operated in the pressure demand or other positive pressure modes is advised. Contact industrial hygienist. 

VENTILATION REQUIREMENTS: Yes 

LOCAL EXHAUST: Normally sufficient 

MECHANICAL: In enclosed spaces. 

PROTECTIVE GLOVES: PVA, PVC, neoprene or other chemically resistant gloves. 

EYE PROTECTION: Chemical goggles 

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: As necessary to avoid skin contact. 

WORK/HYGIENIC PRACTICES: Wash hands before eating, smoking, or after work. Launder clothing before reuse. 

N/A = Not Applicable 

HAZARDOUS MATERIALS INFORMATION SYSTEM (HMIS) 

PERSONAL PROTECTION INDEX 

NOTICE: The information herein is given in good faith but no warranty, expressed or implied, is made, and Timber 

Specialties Co. expressly disclaims liability from reliance on such information. 

Information on this form is furnished for the purpose of compliance with the Workplace Hazardous Materials Information System 

and shall not be used for any other purpose. Use or dissemination of all or any part of this information for any other purpose 

may result in a violation of law or constitute grounds for legal action. 


Page 3 of 3

06-MAR-2007 

Sasco Products Limited 

IMPEL ® (BORON) RODS 

Wood Preservative 

Protection of Wood against Fungal Decay and Insects 

COMMERCIAL 

READ THE LABEL BEFORE USING 


HARMFUL OR FATAL IF SWALLOWED 


GUARANTEE: 

ANHYDROUS DISODIUM OCTABORATE 

(Na2B8O13)..... 98% 

ROD SIZE: .......... WEIGHT/ROD: .......... NUMBER/PKG: .......... 

NET CONTENTS: ..........KG 

NUMBER PLASTIC OR WOOD PLUGS/PKG: .......... 

REGISTRATION NO. 21324 PEST CONTROL PRODUCTS ACT 

Developed by: Canadian Importer and Agent: 

WOOD-SLIMP GmbH SASCO PRODUCTS LTD. 

Ottoplatz 19 31 Ilsley Ave., 

CH-7001 Chur, Dartmouth, Nova Scotia 

Switzerland Canada B3B 1L5 

26-NOV-2007 Notification - Change in Registrant 

DIRECTIONS FOR USE: 

IMPEL (BORON) RODS are recommended for pre-treatment and remedial protection of non-food contact wood and wood products against decay and insects. 

IMPEL is not effective against termites. 

The IMPEL (BORON) ROD is to be used in lumber with a permanent or periodical moisture content above the fibre saturation point (30%), e.g. window frames, bottom sill members or logs. 

The IMPEL (BORON) ROD is inserted in a drilled hole, 9.5-20mm. The hole is covered by a cap (plug). Never hammer the IMPEL (BORON) ROD during installation. By using a plastic cap 

it is possible to carry out inspections, e.g. in conjunction with the maintenance of the surface treatment. If the IMPEL (BORON) ROD has dissolved, the timber has been subjected to a 

moisture content above the fibre saturation point, and a new IMPEL (BORON) ROD can be inserted in the hole. 

When the wood is dry, painting, or any other type of surface coating may be applied if desired. The remedial treatment is carried out at positions particularly susceptible to decay, e.g. end 

grain, joints etc. In placing of the IMPEL (BORON) RODS use caution not to cause structural damage to window or casement etc. 

The distance between the IMPEL (BORON) RODS should be 20 - 25cm in the zone to be protected. 

PRECAUTIONS 

May be harmful or fatal if swallowed. KEEP OUT OF REACH OF CHILDREN. Store in a dry location and out of contact with food and feed. 

Wash hands thoroughly after handling this product and before eating or smoking. 

FIRST AID 

If in eyes: Flush with plenty of water, contact a physician or a poison control centre. 

If on skin: Wash with plenty of soap and water. 

If swallowed: Call a physician or poison control centre. Drink 1 or 2 glasses of water and induce vomiting by touching the back of the throat with finger. 



Contains Anhydrous Disodium Octaborate. Treat symptomatically. 

DISPOSAL 

1. Triple- or pressure-rinse the empty container. Add the rinsings to the spray mixture in the tank. 

Kai R. Spangenberg EFTF I/S 

Storhaven 7B 

Vejle 7100 

Denmark

2. Follow provincial instruction for any required additional cleaning of the container prior to its disposal. 


4. Dispose of the container in accordance with provincial requirements. 

5. For information on disposal of unused, unwanted product, contact the manufacturer or the provincial regulatory agency. Contact the manufacturer and the provincial regulatory agency in 

case of a spill, and for clean-up of spills 

NOTICE TO USER: This pest control product is to be used only in accordance with the directions on the label. It is an offence under the Pest Control 

Products Act to use this product in a way that is inconsistent with the directions on the label. The user assumes the risk to persons or property that arises 

from any such use of this product.

****************************** 






MATERIAL SAFETY DATA SHEET 

IMPEL® (BORON) RODS II 

NATURE OF HAZARD(S): SEE RELEVANT SUBSECTION 

PRODUCT DESCRIPTION/USE: 

* Fungicide in the form of solid fused glass rod. 

* Used to prevent decay in wood structures by inserting into pre-drilled holes. 

HAZARDOUS CONTENTS: 

100% Anhydrous Disodium Octoborate 

(B202 + Na2B407) 

CAS# 1330-43-4 for Anhydrous Borax, LD50 oral administration 1680 mg/kg B.W. 

TLV for Disodium Octoborate 2mg/m 3 NGV 

SAFETY IN USE: 

* Wear suitable gloves (neoprene/PVC). 

* Do not use in situations where food could become contaminated. 

* Keep out of reach of children at all times. 

* Store in dry conditions in original container. 

* Use only as a wood preservative. 

* When inserting push home using a wooden or plastic dowel. 

* Never strike the rod with a hammer or similar object as this may result in the rod shattering. 

SAFETY IN HANDLING/STORAGE: 

* Wear suitable gloves. 

* Store in dry conditions in original container, out of reach of children. 

Shelf Life: 1 - 2 years in sealed packages. 

SAFETY IN TRANSPORT: UN No: 

* Not classified as dangerous goods under ADR or PGR regs. 

* No special requirements necessary 

FIRST AID: 

EYES: Properly used IMPEL® (BORON) RODS II present no hazard to eyes. 

SWALLOWING: Primary risk from choking, administer first aid for such and take to hospital. 

INHALATION: Properly used IMPEL® (BORON) RODS II present no inhalation risk. 

Sasco Products Limited March 2005 

31 Ilsley Avenue, Dartmouth Ph: (902) 468-2126 

Nova Scotia, Canada B3B 1L5 www.sasco.ns.ca Fax: (902) 468-2642

MATERIAL SAFETY DATA SHEET (cont'd) 

PRODUCT NAME: IMPEL® (BORON) RODS II 

FIRE: Product is non-combustible. 

Extinguishing media n/a. 

SKIN CONTACT: Areas in contact with IMPEL® (BORON) RODS II should be washed with soap 

and water. 

HAZARDOUS DECOMPOSITION PRODUCTS: None 

ACCIDENT: In the event of road accident IMPEL® (BORON) RODS II should be collected in a 

suitable container (ie. plastic bag) and returned to manufacturer or disposed of 

according to disposal regulations. 

OTHER INFORMATION: 

Some IMPEL® (BORON) RODS II may have sharp edges and in cases where they are completely 

swallowed these sharp edges may cause grazing of the intestinal tract. 

* Take care when administering first aid for choking especially in cases where patients are 

unconscious. 

* If possible seek qualified first aid assistance. 

Sasco Products Limited March 2005 

31 Ilsley Avenue, Dartmouth Ph: (902) 468-2126 

Nova Scotia, Canada B3B 1L5 www.sasco.ns.ca Fax: (902) 468-2642

Sasco Products Limited 

IMPEL ® 

(BORON) RODS II 

Wood Preservative for Remedial 

Treatment of Utility Poles 

Protection of Wood against Fungal Decay and Insects 

COMMERCIAL 



HARMFUL OR FATAL IF SWALLOWED 


GUARANTEE: 

ANHYDROUS DISODIUM OCTABORATE 

(NA 2 B 8 O 13 )..... 98% 

Rod size: 12mm x 100mm Weight/Rod: 24 grams 

Number/Pkg: .......... Net contents: ..........Kg 

Number plastic or wood plugs/pkg: .......... 

REGISTRATION NO. 23398 

PEST CONTROL PRODUCTS ACT. 

Canadian Importer and Agent: 

WOOD-SLIMP GmbH SASCO PRODUCTS LTD. 

Ottoplatz 19 31 Ilsley Ave., 

CH-7001 Chur, Dartmouth, Nova Scotia 

Switzerland Canada B3B 1L5 


IMPEL® (BORON) RODS II for Remedial treatment of Utility Pole 

Structures are recommended for protection of non-food contact wood, 

against decay and insects. IMPEL® (BORON) RODS II can be used for all 

kinds of wood species. 

IMPEL® (BORON) RODS II are not effective against all kinds of termites. 

The IMPEL® (BORON) RODS II are to be used inside in wood with a 

permanent or periodical moisture content above the fibre saturation point 

(30%) for Poles, etc. The rate of application for IMPEL® (BORON) RODS 

II is dependent upon the volume of wood to be treated. The recommended 

load is up to 6 kg of Boric Acid per cu. metre of wood depending upon 

requirements for treatment. The loading should not be less than 2 kg of 

Boric Acid per cu. metre of wood. IMPEL® (BORON) RODS II contain 

1.45 times equivalent Boric Acid (BAE). 

For inserting the Rods, the three step process is as follows: 

1. Drill 12.5mm holes to accommodate the rod size needed. 

2. Insert the correct size and quantity of IMPEL® (BORON) RODS II 

needed into the pre-drilled holes (determined from area to be treated). 

3. The holes are covered by caps (plugs). Never hammer the IMPEL® 

(BORON) RODS II during installation. 

By using plastic or wood caps it is possible to carry out inspections perhaps 

in conjunction with the regular maintenance maybe every 5-8 years. If the 

rods have dissolved, new IMPEL® (BORON) RODS II are inserted into the 

holes. The remedial treatment is carried out at positions particularly 

susceptible to decay such as around groundline or other sensitive positions. 

In placing of the IMPEL® (BORON) RODS II use caution not to cause 

structural damage to the wood. If the pole is condemned, do not treat with 

IMPEL® (BORON) RODS II. 

RECOMMENDED 

DRILLING PATTERN 

Groundline 

Spiral pole 

drilling geometry 

Note: Boring pattern selected shall comply 

with the Canadian Electrical Association 

Publication 118-D-318A, 1990, “Development 

of an Application Guide for the Use of 

Vapam” or if an alternative boring pattern is to 

be used, the applicator must receive written 

confirmation from the owner(s) of the pole 

stating that the selected boring pattern is 

acceptable and will not result in significant 

pole strength loss. Bore hole diameter shall not 

exceed 12.5mm when treating poles with 


Rates: Apply to achieve a loading of 6 kg of 

Boric Acid per m 3 

of wood. An average per 

pole will be approximately 0.144kg of 


The distance between the IMPEL® (BORON) RODS II should be 20 - 25cm 

in the zone to be protected. 

PRECAUTIONS 

May be harmful, avoid contact with eyes and skin, avoid breathing dust, use 

only in a well ventilated area, wear freshly laundered clothes daily, store and 

wash all protective clothing separately from household laundry, wash 

clothes in detergent and hot water before reuse. May be fatal if swallowed. 

KEEP OUT OF REACH OF CHILDREN. Store in a dry location and out of 

contact with food and feed. Dispose of on-site empty containers in 

household garbage. Wash hands thoroughly after handling this product and 

before eating or smoking. Do not contaminate water courses or ground. 

RECOMMENDED NUMBER OF IMPEL (BORON) RODS II PER 

SIZE FOR GROUNDLINE* TREATMENT 

Pole 

Diameter @ 

Groundline 

(cm) 

20 

23 

25 

28 

30 

33 

36 

38 

41 

43 

46 

48 

51 

53 

56 

58 

61 

Pole 

Circumference 

@ Groundline 

(cm) 

63-70 

71-77 

78-87 

88-94 

95-102 

103-110 

111-117 

118-125 

126-133 

134-143 

144-150 

151-158 

159-166 

167-174 

175-181 

182-188 

189-198 

Volume 

(Cu. 

meter) 

0.020 

0.025 

0.031 

0.037 

0.044 

0.052 

0.061 

0.069 

0.079 

0.089 

0.100 

0.112 

0.123 

0.136 

0.150 

0.163 

0.178 

Remedial 

Treatments 

(6 kg BAE/Cu.meter) 

12mm x 100mm Rods 

35 gram BAE/rod 

4 

5 

6 

7 

8 

9 

11 

12 

14 

16 

18 

20 

NR 

NR 

NR 

NR 

NR 

Preventative 

Treatments 

(2 kg 

BAE/cu.meter) 

12mm x 100mm 

Rods 

35 gram BAE/rod 

2 

2 

2 

3 

3 

3 

4 

4 

5 

6 

6 

7 

8 

8 

9 

10 

11 

*GROUNDLI NE ZONE = The 60cm zone from 15cm above ground to 45cm below. 

NOTE: A minimum of 2 rods is recommended even on smaller poles for 

adequate preservative distribution. 

NR = Not Recommended. (Ask for technical advice) 

FIRST AID 

• If in eyes: Flush with plenty of water, call a physician. 

• If on skin: Wash with plenty of soap and water. 

• If swallowed: Call a physician or poison control centre. Drink 1 or 2 

glasses of water and induce vomiting by touching the back of the throat 

with finger. 

• If dust inhaled: Clear passageways; call a physician. 

• Take container, label or product name and Pest Control Product 

Registration Number with you when seeking medical attention. 


Contains Anhydrous Disodium Octaborate. 

DISPOSAL 

1. Follow provincial instruction for any required additional cleaning of the 

container prior to its disposal. 


3. Dispose the container in accordance with provincial requirements. 

4. For information on disposal of unused, unwanted product, contact the 

manufacturer or the provincial regulatory agency. Contact the 

manufacturer and the provincial regulatory agency in case of a spill, and 


NOTICE TO USER: This control product is to be used only in accordance 

with the directions on this label. It is an offence under the Pest Control 

Products Act to use a control product under unsafe conditions. 

NOTICE TO BUYER: Seller’s guarantee shall be limited to the terms set 

out on this label and, subject thereto, the buyer assumes the risk to persons 

or property arising from the use or handling of this product and accepts the 

product on that condition. 

April 6, 2005

01-FEB-2008 2007-5485 

UNIVAR CANADA LTD 

9800 Van Horne Way 

Richmond, B.C., V6X 1W5 

POST & POLE FUMIGANT 

A fumigant for controlling decay and insects in wood poles 

Contains Metam 

COMMERCIAL 

Guarantee: Metam (Sodium, anhydrous) 380 grams per litre 

* Equivalent to 487 grams (dihydrate) per litre 

Registration No. 19343 PEST CONTROL PRODUCT ACT 


WARNING POISON 

PRECAUTIONS 

KEEP OUT OF REACH OF CHILDREN, HARMFUL IF INHALED OR SWALLOWED, IRRITATING TO EYES, NOSE, THROAT AND SKIN. AVOID BREATHING VAPOUR. DO NOT GET IN EYES, ON 

SKIN OR ON CLOTHING. 

When using product in enclosed area, use a NIOSH/MSHA approved pesticide respirator. Wear rubber gloves, protective clothing and goggles or face shield.Wash hands, arms and face thoroughly with 

soap and water after handling and before eating or smoking. Routinely shower or bathe after work and wash all clothing with soap and hot water before reusing. In case of contact, immediately remove 

contaminated clothing and wash thoroughly with soap and water. Do not transport or store Guardsman Post & Pole Fumigant with any food or feed intended for human or animal consumption. Keep 

container tightly closed when not in use. Keep children and pets away from treated poles. 

FIRST AID 

If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15–20 minutes. Call a poison control centre or doctor for treatment advice. If in eyes: Hold eye open 

and rinse slowly and gently with water for 15–20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control centre or doctor for treatment advice. 

If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to mouth, if possible. Call a poison control centre or doctor for 

further treatment advice. If swallowed: Call a poison control centre or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so 

by a poison control centre or doctor. Do not give anything by mouth to an unconscious person. 



Vapours and aerosols can irritate eyes, nose and respiratory passages. Treat symptomatically. No other adverse clinical effects have been associated with exposure to Guardsman Post & Pole Fumigant. 

ENVIRONMENTAL HAZARDS 

This product is toxic to fish. Do not apply directly to water or wetlands. Do not contaminate water by cleaning of equipment or disposal of waste. Apply this product only as specified on the label. 

SPILL AND CLEANUP 

Make sure all personnel involved in the spill cleanup follow good industrial hygiene practices. Any person entering either a significant spill area or an unknown concentration of a vapour or mist should use 

a positive pressure, air-supplied respirator with escape pack. Small spills can be handled routinely. Use adequate ventilation and/or wear a NIOSH/MSHA approved pesticide respirator to prevent inhalation 

exposure. Wear protective clothing to prevent skin and eye contact. Use the following procedures: Absorb spillage with an absorbent. Sweep up spilled material being careful not to create dust. Place 

sweepings in a chemical waste container for disposal. Generously cover contaminated area with a slurry of common powdered household laundry detergent and water. Using a stiff brush, work the slurry 

into cracks and crevices. Allow to stand for 2-3 minutes then flush with water. Repeat if necessary. Dispose of all wastes in accordance with instructions in the DISPOSAL statement. Large spills should be 

handled according to predetermined plan. 

PRODUCT INFORMATION 

GUARDSMAN POST & POLE FUMIGANT is a fumigant solution. When used as directed, it will arrest internal decay and control insects present in poles, pilings and similar large exterior timber members. 

During this sterilization of the treated area, a fungi-toxic residue is deposited in the cells of wood. Poles known to have internal decay should be scheduled for treatment before they have decayed to the 

point where replacement is necessary. 

PRODUCT LIMITATIONS: To be used only in the remedial treatment of utility poles, and piling, and outdoor construction timbers (bridges). 

TREATED WOOD LIMITATIONS: GUARDSMAN POST & POLE FUMIGANT should only be used for treatment of wood having NO opportunities for: 1. direct contact with, or becoming a deleterious 

component of drinking water; 2. use in residential construction, food/feed storage/production or animal housing and playground equipment; 3. prolonged skin contact. 


APPLICATION METHOD 

When a pole is detected with rot or insect damage, dig the soil away from the base of the pole to a depth of 30 cm. Drill 15 mm holes in each quarter of the pole at ground line. These holes should be a 45 

degrees angle downward and to a depth equal to or slightly greater than the radius of the pole. Inject equal amounts of Guardsman Post & Pole Fumigant into all holes using a total of 600 mL per pole. In 

severely diseased poles use 1.2 L per pole. Plug the holes with treated wood plugs, taking the precautions of wearing safety goggles to avoid splashing any of the liquid Guardsman Post & Pole Fumigant 

into the eyes. When the Guardsman Post & Pole Fumigant treatment is for the control of insects, the pole should be wrapped over the treated area with 120 cm laminated kraft paper. Staple and seal the 

seam and top edge with 2.5 cm masking tape. FOR THE CONTROL OF DECAY IN POLES. NO WRAPPINGS IS NECESSARY. Backfill and tamp the excavated area to form a seal against the kraft paper. 

The kraft paper should be removed and disposed of, when convenient, after 2 months. 

PROHIBITIONS 

Do not contaminate water, food, or feed by storage or disposal. Open dumping is prohibited. 

STORAGE 

Keep container tightly closed when not in use. Do not store near seeds, fertilizers or foodstuffs. Protect from temperatures below -17deg Product crystalizes at lower temperatures. Warm or store at higher 

temperatures and mix to redissolve crystal and assure uniformity before use. Do not warm above 30 deg C. 

DISPOSAL 

1. For refillable containers: This container may be returned to the point of purchase (distributor/dealer), if in a clean, dry and refillable condition. Do not reuse this container for any purpose other than 

refilling with same product. For containers in a non-refillable condition, dispose of as below. 

2. For non-refillable containers: Triple or pressure-rinse the empty container. Add the rinsings to the treatment site. Follow provincial instructions for any required additional cleaning of the container prior to 

its disposal. Make the empty container unsuitable for further use. Dispose of the container in accordance with provincial requirements. 

For information on disposal of unused, unwanted product, contact the manufacturer or the provincial regulatory agency. Contact the manufacturer and the provincial regulatory agency in case of a spill, and 


NOTICE TO USER 

This pest controlled product is to be used only in accordance with the directions on this label. It is an offence under the PEST CONTROL PRODUCTS ACT to use this product in a way that is inconsistent 

with the directions on the label. The user assumes the risk to persons or property that arises from any such use of this product. 

NET CONTENTS 

NET WEIGHT 

Lt

****************************** 







NR00899 

Post & Pole Fumigant 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Product Id: NR00899 

Product Name: Post & Pole Fumigant 

Synonyms: None 

Chemical Family: Sodium methyldithiocarbamate solution 

Application: Agricultural fumigant. 

Distributed By: 

Univar Canada Ltd. 

9800 Van Horne Way 

Richmond, BC 

V6X 1W5 

Prepared By: The Safety, Health and Environment Department of Univar Canada Ltd. 

Preparation date of MSDS: 23 February 2011 

Telephone number of preparer: 1-866-686-4827 

24-Hour Emergency Telephone Number (CANUTEC): (613) 996-6666 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

Ingredients Percentage 

(W/W) 

LD50s and LC50s Route & Species: 

Other inert ingredients 

Not Available 

67.2 Not available. 

Metam-sodium 

32.7 Oral LD50 (Rat) = 450 mg/kg 

137-42-8 

Dermal LD50 (Rat) = 636 mg/kg 

Dermal LD50 (Rabbit) = 800 mg/kg 

Inhalation LC50 (Rat) > 6.8 mg/L 4 h 

Note: Registration number under the Canadian Pest Control Products Act : 19343 

3. HAZARDS IDENTIFICATION 

Potential Acute Health Effects: 

Eye Contact: Causes moderate eye irritation. 

Skin Contact: Harmful if absorbed through the skin. Corrosive. May cause an allergic skin reaction. 

Inhalation: Harmful if inhaled. Causes irritation of the mouth, nose and throat. Causes irritation of the respiratory tract, 

experienced as nasal discomfort and discharge, with chest pain and coughing. Irritates mucous membranes. Headache, 

nausea, vomiting, dizziness, drowsiness and loss of consciousness may occur. 

Ingestion: Ingestion of this product would cause headache, dizziness, fatigue and central nervous system depression. 

Causes vomiting, nausea, and diarrhea. Harmful if swallowed. 

NR00899 


Page 1 of 6

4. FIRST AID MEASURES 

Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes 

and get medical attention immediately after flushing. Hold eyelids open during flushing. 

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Get medical 

attention. Remove contaminated clothing and launder before reuse. If irritation persists or signs of toxicity occur, seek 

medical attention. 

Inhalation: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate 

medical attention. 

Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water and seek medical attention. Never give 

anything by mouth to an unconscious person. If vomiting occurs spontaneously, keep head below hips to prevent 

aspiration of liquid into the lungs. 

Notes to Physician: Treat symptomatically. Contact a poison control centre for additional treatment information. 

5. FIRE FIGHTING MEASURES 

Flash Point: >93.3 °C / >200 °F 

Flash Point Method: Tag Closed Cup 

Autoignition Temperature: Not available. 

Flammable Limits in Air (%): Not Available. 

Extinguishing Media: Use extinguishing media appropriate for surrounding fire. 

Special Exposure Hazards: This product is not flammable. However, this product may support combustion under fire 

conditions and will generate toxic fumes under fire conditions. NOTE: Dilution with water may cause generation of 

flammable and toxic fumes of MTC and Hydrogen Sulfide. 

Hazardous Decomposition/Combustion Materials (under fire conditions): Hydrogen sulphide. Oxides of nitrogen. 

Methyl Isothiocyanate (MITC) 

Special Protective Equipment: Fire fighters should wear full protective clothing, including self-contained breathing 

equipment. 

NFPA RATINGS FOR THIS PRODUCT ARE: Not Available. 

HMIS RATINGS FOR THIS PRODUCT ARE: Not Available. 

6. ACCIDENTAL RELEASE MEASURES 

Personal Precautionary Measures: Restrict access to unprotected personnel. Wear appropriate protective equipment. 

Environmental Precautionary Measures: Prevent entry into sewers or streams, dike if needed. Do not contaminate 

surface water. 

Procedure for Clean Up: Try to work upwind of spill. Cover with absorbent (clay, sawdust, straw, kitty litter etc.), to 

absorb the liquid. Sweep into an open drum. Clean the area with common powdered household detergent and a stiff brush 

and just enough water to make a slurry. Absorb and sweep into the same open drum. Rinse with water, absorb and add to 

the waste drum. Close the drum and dispose of properly. 

7. HANDLING AND STORAGE 

Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapor. Use appropriate personnel protective 

equipment. Wash hands, arms and face thoroughly with soap and water after handling and before eating or smoking. 

Routinely shower or bathe after work and wash all clothing with soap and hot water before reusing. In case of contact, 

immediately remove contaminated clothing and wash thoroughly with soap and water. Do not transport or store 

Guardsman Post & Pole Fumigant with any food or feed intended for human or animal consumption. Keep container tightly 

closed when not in use. Keep children and pets away from treated poles. 

Storage: Do not contaminate water, food or feed by storage or disposal. Store in a cool, dry, well ventilated area. Do not 

store below 0 °F. Product crystallizes at lower temperatures. 

NR00899 


Page 2 of 6

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

Engineering Controls: 

Use in a well ventilated area. Use of mechanical or local exhaust systems is recommended. 

Respiratory Protection: When using product in enclosed areas, use a NIOSH/MSHA approved pesticide respirator. 

Gloves: 

Rubber gloves. 

Skin Protection: Impervious clothing. Apron, coveralls and/or other resistant protective clothing. Launder contaminated 

clothing before reuse. 

Eyes: Chemical goggles; also wear a face shield if splashing hazard exists. 

Other Personal Protection Data: Long sleeves. Wear clean, body-covering clothing. Chemical resistant footwear. Ensure 

that eyewash stations and safety showers are proximal to the work-station location. 

Ingredients Exposure Limit - ACGIH Exposure Limit - OSHA Immediately Dangerous 

to Life or Health - IDLH 

Other inert ingredients Not available. Not available. Not Available. 

Metam-sodium Not available. Not available. Not Available. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Physical State: Liquid. 

Colour: Orange Light Yellow-green 

Odour: Essentially odourless to fairly strong odor of amine or sulfur. 

pH 9 - 10.5 

Specific Gravity: 1.158 

Boiling Point: 110°C /230°F 

Freezing/Melting Point: -17°C / 1°F 

Vapour Pressure: Not Available. 

Vapour Density: Not Available. 

% Volatile by Volume: 67% 

Evaporation Rate: Not Available. 

Solubility: Not Available. 

VOCs: Not Available. 

Viscosity: Not Available. 

Molecular Weight: Not Available. 

Other: Not Available. 

10. STABILITY AND REACTIVITY 

Chemical Stability: Stable. 

Hazardous Polymerization: Will not occur. 

Conditions to Avoid: Metam Sodium decomposes, when diluted with water, to methyl isothiocyanate (MITC, a 

lachrymator and moderate poison) and/or to hydrogen sulfide (a highly poisonous gas). It can also decompose to carbon 

disulfide and monomethylamine (both highly flammable) if contacted with strong acid. Use the solution promptly after 

mixing. Do not allow the sodium to stand. As originally packaged, it is stable under normal conditions for up to 2 years. 

Materials to Avoid: Additional water and strong aqueous acids. Corrosive to copper, brass, and zinc and may soften and 

or discolour iron. 

Hazardous Decomposition Products: Toxic fumes. Methyl isothiocyanate (MITC). Hydrogen sulfide. Oxides of nitrogen. 

Additional Information: 

If treated with strong acids, fumes of carbon disulfide and monomethylamine will be given off. 

11. TOXICOLOGICAL INFORMATION 

Principle Routes of Exposure 

Ingestion: Ingestion of this product would cause headache, dizziness, fatigue and central nervous system depression. 

Causes vomiting, nausea, and diarrhea. Harmful if swallowed. 

Skin Contact: Harmful if absorbed through the skin. Corrosive. May cause an allergic skin reaction. 

Inhalation: Harmful if inhaled. Causes irritation of the mouth, nose and throat. Causes irritation of the respiratory tract, 

experienced as nasal discomfort and discharge, with chest pain and coughing. Irritates mucous membranes. Headache, 

nausea, vomiting, dizziness, drowsiness and loss of consciousness may occur. 

NR00899 


Page 3 of 6

11. TOXICOLOGICAL INFORMATION 

Eye Contact: Causes moderate eye irritation. 

Additional Information: As a result of use of the product, applicators and other persons present in the area of the 

application can be exposed to MITC and/or hydrogen sulfide. These chemicals can be evolved as gases from the soil of 

an application. MITC has a horseradish like odor and can be very irritating to the eyes. Hydrogen sulfide has a rotten egg 

odor and can be very offensive. The nose becomes deadened to a hydrogen sulfide odor, so not being able to detect the 

odor any longer does not mean the exposure has ended. Over exposure to MITC may result in strong skin and eye 

irritation, running nose, dizziness, cramps, nausea, vomiting and mild to severe irritation to the mucous membranes. In 

addition, laboratoy studies hav eshown that exposure to the active ingredient, followed by ingestion of alcohol, may cause 

an adverse reaction, including low blood pressure, rapid hear beat, and flushing of the skin. Consumption of alcohol during 

and after exposure to this product should be avoided. 

Acute Test of Product: 

Acute Oral LD50: Not Available. 

Acute Dermal LD50: Not Available. 

Acute Inhalation LC50: Not Available. 

Carcinogenicity: 

Ingredients IARC - Carcinogens ACGIH - Carcinogens 

Other inert ingredients Not listed. Not listed. 

Metam-sodium Not listed. Not listed. 

Carcinogenicity Comment: Laboratory studies on a related Metam sodium product have shown some carcinogenic effect 

in laboratory animals. 

Reproductive Toxicity/ Teratogenicity/ Embryotoxicity/ Mutagenicity: Laboratory studies on a related Metal sodium 

product have shown some development effect in laboratory animals. Laboratory studies on a related Metam sodium 

product have shown some evidence of mutagenicity in vitro but no conclusive evidence in vivo. 

Ecotoxicological Information: 

12. ECOLOGICAL INFORMATION 

Ingredients Ecotoxicity - Fish Species Acute Crustaceans Toxicity: Ecotoxicity - Freshwater 

Data 

Algae Data 

Other inert ingredients Not Available. Not Available. Not Available. 

Metam-sodium LC50 96 h (Lepomis 

macrochirus) 0.175 - 0.82 

mg/L static 

Not Available. Not Available. 

Other Information: 

This material is expected to be toxic to aquatic life. 

13. DISPOSAL CONSIDERATIONS 

Disposal of Waste Method: Disposal of all wastes must be done in accordance with municipal, provincial and federal 

regulations. 

Contaminated Packaging: Empty containers should be recycled or disposed of through an approved waste management 

facility. 

14. TRANSPORT INFORMATION 

DOT (U.S.): 

DOT Shipping Name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (METAM SODIUM) 

DOT Hazardous Class 8 

DOT UN Number: UN3266 

DOT Packing Group: III 

DOT Reportable Quantity (lbs): Not Available. 

Note: No additional remark. 

NR00899 


Page 4 of 6

Marine Pollutant: Yes. 

14. TRANSPORT INFORMATION 

TDG (Canada): 

TDG Shipping Name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (METAM SODIUM) 

Hazard Class: 8 

UN Number: UN3266 

Packing Group: III 

Note: No additional remark. 

Marine Pollutant: Yes. 

15. REGULATORY INFORMATION 

U.S. TSCA Inventory Status: All components of this product are either on the Toxic Substances Control Act (TSCA) 

Inventory List or exempt. 

Canadian DSL Inventory Status: All components of this product are either on the Domestic Substances List (DSL), the 

Non-Domestic Substances List (NDSL) or exempt. 

Note: Not available. 

U.S. Regulatory Rules 

Ingredients CERCLA/SARA - Section SARA (311, 312) Hazard CERCLA/SARA - Section 

302: 

Class: 

313: 

Other inert ingredients Not Listed. Not Listed. Not Listed. 

Metam-sodium Not Listed. Not Listed. Listed 

California Proposition 65: Listed. 

MA Right to Know List: Not Listed. 

New Jersey Right-to-Know List: Listed. 

Pennsylvania Right to Know List: Not Listed. 

WHMIS Hazardous Class: 

WHMIS EXEMPT. 

Pest Control Products Act Registration No.19343 

NR00899 


Page 5 of 6

16. OTHER INFORMATION 

Additional Information: This product has been classified in accordance with the hazard criteria of the 

Canadian Controlled Products Regulations (CPR) and the MSDS contains all the 

information required by the CPR. 

Disclaimer: NOTICE TO READER: 

Univar, expressly disclaims all express or implied warranties of merchantability and 

fitness for a particular purpose, with respect to the product or information provided 

herein, and shall under no circumstances be liable for incidental or consequential 

damages. 

Do not use ingredient information and/or ingredient percentages in this MSDS as a 

product specification. For product specification information refer to a Product 

Specification Sheet and/or a Certificate of Analysis. These can be obtained from your 

local Univar Sales Office. 

All information appearing herein is based upon data obtained from the manufacturer 

and/or recognized technical sources. While the information is believed to be accurate, 

Univar makes no representations as to its accuracy or sufficiency. Conditions of use 

are beyond Univar's control and therefore users are responsible to verify this data 

under their own operating conditions to determine whether the product is suitable for 

their particular purposes and they assume all risks of their use, handling, and disposal 

of the product, or from the publication or use of, or reliance upon, information 

contained herein. This information relates only to the product designated herein, and 

does not relate to its use in combination with any other material or in any other 

process. 

***END OF MSDS*** 

NR00899 


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Wood Preservatives Labels - BC Hydro

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