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xxx INTRODUCTION Atomic Se= 1-07 Te- 1-37 Te= 1-27 Po- 1-70 Cr 1*25 Mo 1-36 W 1-37 U 1-49 F— 0*64 F= 0-54 Cl- 0-99 Cl= 0-89 Br— 1-14 Br= 1*04 I— 1-33 Te Te 4 + Cr 3 + Mo 4 + W 4 + U 4 + F- Cl- Br- I~ Ionic TABLE V (cont.) 211 0-89 0-65 0*68 0-68 1-05 1-33 1-81 1-96 2-20 I Atomic I I = Mn Re Fe" Fe'" Co" Co"' Ni" Ru" Rh'" Pd* Os* Ir w TABLE VI A 1*23 1*25 1*37 1*23 1-22 1*32 1*22 1-39 1*33 1*32 1-31 1*33 1*32 Ionic Fe++ Fe+++ Co++ Ni++ Ru 4 + Rh+++ Os 4 + Ir 4 + Heats of Atomization from St<strong>and</strong>ard States; h.cals per g.-atom H 51*7 Li 39*0 Na 25*9 K 19-8 Rb 18*9 Be Zn Cd Hg O S Se 75 27*4 14*6 591 66*3 61*0 B Al Tl 115 55 40 C 170*4« Si 85*0 Ge 85*0 Sn 78*0 Pb 47*5 Ti 100 Zr 110 F 16*7
H C N O S F Cl Br I Ag Be Zn Hg B Al Tl Si Ge Sn Pb" Ti Zr P As V Se Te Fe As H 103-4 98-8 92-9 110-2 87-5 132-4 102-7 87-3 71-4 751 77-3 56-7 730 62-3 INTRODUCTION TABLE VI B Heats of Formation of Links from Atoms (Ha) G 98-8 81-6 69-3 81-5 66-0 103-4 78-0 65-5 57-0 34-5 ca* 15 69-1 —C 70-7 =C 165-6 N 92-9 69-3 38-4 62*9 47-6 O 110-2 81-5 34-9 43-5 49-3 60-8 91-2 89-3 65-1 110-4 (OsO4) 8 87-5 66-0 63-8 71-4 66-1 57-2 60-9 F 132-4 103-4 62-9 43-5 71-4 33-3 71-3 140-6 127-9 89-9 67-1 78-3 Cl 102-7 78-0 47-6 49-3 66-1 71-3 57-8 52-7 51-0 70-4 107-9 52-9 96-7 91-6 85-3 85-8 104-1 78-0 77-4 97-0 116-9 77-1 69-7 88-7 66-8 Br 87-3 65-5 57-2 52-7 46-1 42-9 67-7 88-4 450 76*9 76-4 69-3 66-2 53-2 63-5 57-4 Si—Si 42-5 Ge-Ge 42-5 P-P 149-2 As—As 117-2 Se-Se 57-6 I 71-4 57-0 510 42-9 36-2 60-1 68-6 35-4 66-3 51*1 44-4 49-5 42-5
Page 1 and 2: THE CHEMICAL ELEMENTS AND THEIR COM
Page 3 and 4: PREFACE THIS book is an attempt to
Page 5 and 6: CONTENTS VOLUME I Abbreviations . .
Page 7 and 8: CONTENTS IX Phosphorus . . . . . .
Page 9 and 10: ABBREVIATIONS Journals Ann. Liebig'
Page 11: PHYSICAL CONSTANTS XHl Einstein's E
Page 14 and 15: xvi INTRODUCTION form a gas half as
Page 16 and 17: XVlJl INTRODUCTION conditions its a
Page 18 and 19: xx INTRODUCTION unshared electrons
Page 20 and 21: xxii INTRODUCTION other modifying i
Page 22 and 23: Group SvJbgp. 37Rb 38Sr 39 Y 40Zr 4
Page 24 and 25: xxvi INTRODUCTION Group Subgp, 73Ta
Page 26 and 27: H He Ne A Kr Xe Li Na K Rb Cs Cu Ag
Page 30 and 31: C-C C=C C=C N-N N=N N=E=N o—o 0=0
Page 32 and 33: 2 Group O. Helium . Helium is produ
Page 34 and 35: 4 Group O. Helium the carbon acting
Page 36 and 37: 6 Group O. Helium proportional to (
Page 38 and 39: 8 Oroup O. Inert Oases ceptible eve
Page 40 and 41: JO Group 0. Inert Gases gaseous pha
Page 42 and 43: 12 Group /. Hydrogen II. Elementary
Page 44 and 45: 14 Group I. Hydrogen The physical p
Page 46 and 47: 16 Group I. Hydrogen H2 and emittin
Page 48 and 49: 18 Group I. Hydrogen grpup untouche
Page 50 and 51: 20 Group I. Hydrogen present; in th
Page 52 and 53: 22 Group /• Hydrogen NaCl (6:1) l
Page 54 and 55: 24 Group I. Hydrogen work 69 showed
Page 56 and 57: 26 Group L Hydrogen The experimenta
Page 58 and 59: 28 Group I. Hydrogen The correspond
Page 60 and 61: 30 Group I. Hydrogen The N—H-"N i
Page 62 and 63: 32 Group / CHCl2F > CHClF2; thus wi
Page 64 and 65: 34 Group I. Deuterium difference wa
Page 66 and 67: 36 Group I. Deuterium It is probabl
Page 68 and 69: 38 Group I. Deuterium deuterium or
Page 70 and 71: 40 Group I. Deuterium at these temp
Page 72 and 73: 42 Group I. Deuterium importance, b
Page 74 and 75: 44 Group I. Deuterium Baits 2548 ha
Page 76 and 77: 46 Group J, Deuterium The mixed com
Page 78 and 79:
48 Group I. Deuterium CH3-COCH3 is
Page 80 and 81:
50 Group I. Deuterium sium chromium
Page 82 and 83:
62 Group L Deuterium ethane at 110
Page 84 and 85:
U Group L Deuterium paraffins, are
Page 86 and 87:
56 Group I. Deuterium Kharasch 351
Page 88 and 89:
58 Group L Tritium have shown that
Page 90 and 91:
60 Group 1(2). Alkali Metals GROUP
Page 92 and 93:
62 Group 1(2). Alkali Metals amalga
Page 94 and 95:
64 Group 1(2). Alkali Metals cent,
Page 96 and 97:
66 Group 1(2). Alkali Metals Compou
Page 98 and 99:
68 Group 1(2). Alkali Metals increa
Page 100 and 101:
70 Group 1(2). Alkali Metals Gilman
Page 102 and 103:
72 Group 1(2). Alkali Metals Caroth
Page 104 and 105:
74 Group 1(2). Alkali Metals Ziegle
Page 106 and 107:
76 Group 1(2). Alkali Metals Di-met
Page 108 and 109:
78 Group 1(2). Alkali Metals In all
Page 110 and 111:
80 Group 1(2). Alkali Metals are de
Page 112 and 113:
82 Group 1(2). Alkali Metals This l
Page 114 and 115:
84 Group I(2). Alkali-Metals of dou
Page 116 and 117:
86 Group 1(2). Alkali Metals of met
Page 118 and 119:
88 Group 1(2). Alkali Metals potass
Page 120 and 121:
90 Group 1(2). Alkali Metals They h
Page 122 and 123:
92 Group 1(2). Alkali Metals SULPHI
Page 125 and 126:
LiF 204 LiCl 2-57 LiBr 2-75 LiI 303
Page 127 and 128:
Complex Compounds 97 covalency are
Page 129 and 130:
Complex Compounds 99 The ammonia in
Page 131 and 132:
Peculiarities of Lithium 101 the de
Page 133 and 134:
GROUP 1(3) COPPER, SILVER, GOLD T H
Page 135 and 136:
The Elements 105 reaction with chlo
Page 137 and 138:
Limitations of Univalent State 107
Page 139 and 140:
Ionization of Compounds 109 silver
Page 141 and 142:
Copper Hydride 111 We can therefore
Page 143 and 144:
Acetylides 113 It regenerates acety
Page 145 and 146:
Alhyls and Aryls by treating silver
Page 147 and 148:
Nitrides, Phosphides, Oxides 117 wi
Page 149 and 150:
Sulphides, Halides 119 what amphote
Page 151 and 152:
Cuprous Halides: Argentous Halides
Page 153 and 154:
Argentous Halides 123 Solid silver
Page 155 and 156:
Derivatives of Oxy-acids 125 There
Page 157 and 158:
Oxalates, Nitrates 127 The crystal
Page 159 and 160:
Univalent Complexes / 129 Silver pe
Page 161 and 162:
Ethylene Complexes 131 (cy = cycloh
Page 163 and 164:
Cyanide Complexes 133 chloride at 9
Page 165 and 166:
Nitrile Complexes 135 The isonitril
Page 167 and 168:
Ammines 137 Other amino-derivatives
Page 169 and 170:
Phosphine and Arsine Complexes 139
Page 171 and 172:
Oxygen Complexes 141 The aurous com
Page 173 and 174:
Sulphur Complexes 143 2 mono-, 2 di
Page 175 and 176:
Chelate Complexes 145 ammonia, we m
Page 177 and 178:
Complex Halides 147 The correspondi
Page 179 and 180:
Cupric Compounds 149 They should al
Page 181 and 182:
Cupric Oxide and Sulphide 151 loss
Page 183 and 184:
Cupric Halides 153 the crystal stru
Page 185 and 186:
Cupric Salts of Oxy-acids 155 This
Page 187 and 188:
Cupric Ammines 157 cupric ion at 25
Page 189 and 190:
Complex Cupric Azides and Nitrites
Page 191 and 192:
Sulphur and Halide Complexes 161 a
Page 193 and 194:
Chelate Complexes 163 it is, howeve
Page 195 and 196:
Chelate Nitrogen-oxygen Complexes 1
Page 197 and 198:
Chelate Nitrogen-oxygen Complexes 1
Page 199 and 200:
Chelate Oxygen Complexes 169 Oxalat
Page 201 and 202:
Neutral Chelate Oxygen Complexes 17
Page 203 and 204:
Hexol Complexes 173 (c) .ff&roZ Com
Page 205 and 206:
Argentic Ions and Fluoride 175 Arge
Page 207 and 208:
Auric Compounds 177 It will be obse
Page 209 and 210:
Auric Oxide and Sulphide 179 owing
Page 211 and 212:
Auric Alkyls 181 auric chloride is
Page 213 and 214:
Auric Alky I Cyanides 183 cryoscopi
Page 215 and 216:
Dialkyhgold Compounds 185 Ewens and
Page 217 and 218:
Aryl Compounds 187 into potassium b
Page 219 and 220:
Phosphorus and Oxygen Complexes 189
Page 221 and 222:
Complex Halides 191 A curious serie
Page 223 and 224:
GROUP II THE difference in properti
Page 225 and 226:
GBOTJP II A BERYLLIUM, MAGNESIUM, C
Page 227 and 228:
BERYLLIUM THE chemistry of berylliu
Page 229 and 230:
Beryllium and Carbon 199 ntronger a
Page 231 and 232:
Beryllium and Oxygen 201 Beryllium
Page 233 and 234:
Beryllium Halides 203 fluoride, or
Page 235 and 236:
Salts of Oxy~acids 205 viscous solu
Page 237 and 238:
Salts of Oxy-acids indefinite basic
Page 239 and 240:
Ammines 209 lluoride only gives a m
Page 241 and 242:
Beryllated Beryllium Tons 211 There
Page 243 and 244:
Chelate Oxygen Complexes 213 dissol
Page 245 and 246:
Chelate Oxygen Complexes 215 become
Page 247 and 248:
Chelate Complexes 217 The existence
Page 249 and 250:
MAGNESIUM, CALCIUM, STRONTIUM, BARI
Page 251 and 252:
Alkaline Earth Salts 221 TABLE II,
Page 253 and 254:
Metal: Carbides 223 Magnesium is of
Page 255 and 256:
Grignard Reagents 225 In this solut
Page 257 and 258:
Grignard Reagents 227 The percentag
Page 259 and 260:
Grignard Reagents 229 The relative
Page 261 and 262:
Grignard Reagents 231 It is evident
Page 263 and 264:
Dialkyls and Diaryls 233 The questi
Page 265 and 266:
Oxygen Compounds 235 It reacts with
Page 267 and 268:
Halides Magnesium Chloride, MgCl2 T
Page 269 and 270:
Oxy-salts 239 dilution. This behavi
Page 271 and 272:
Complex Compounds 241 it decomposes
Page 273 and 274:
Alkaline Earth Metals 243 The Eleme
Page 275 and 276:
Hydrides radium chloride, with a me
Page 277 and 278:
Nitrides: Oxides 247 re-examined by
Page 279 and 280:
Peroxides 249 Peroxides MO2 and MO2
Page 281 and 282:
Halides 251 solution rapidly turns
Page 283 and 284:
Halides: Carbonates 253 Bromides Ca
Page 285 and 286:
Salts of Oxy-acids 255 Oxalates Cal
Page 287 and 288:
Oxy-halide Salts 257 A saturated so
Page 289 and 290:
Complexes 259 explosively at 300°
Page 291 and 292:
Complexes 261 given, and for compar
Page 293 and 294:
ZINC AND CADMIUM THESE elements giv
Page 295 and 296:
Zinc Alhyls and Aryls 265 Zinc Alhy
Page 297 and 298:
Cadmium Alhyls and Aryls 267 which
Page 299 and 300:
Oxides: Hydroxides 269 Cadmium amid
Page 301 and 302:
Halides 271 Cadmium sulphide, CdS,
Page 303 and 304:
Halides 273 Zinc Iodide This salt m
Page 305 and 306:
275 OXY-SALTS OF ZINC AND CADMIUM 0
Page 307 and 308:
Oxy~halogen Salts 277 The conductiv
Page 309 and 310:
Cyanides, Ammines 279 a lead anode
Page 311 and 312:
Oxygen-complexes 281 This is tetrah
Page 313 and 314:
Oxygen-complexes Acetylacetone Deri
Page 315 and 316:
Mercury 285 cadmium; this differenc
Page 317 and 318:
Metallic Mercury 287 and thus mercu
Page 319 and 320:
Mercurous Compounds 289 TABIIB Li 0
Page 321 and 322:
Mercurous Ion 291 (4) The X-ray ana
Page 323 and 324:
Mercurous Halides 293 to a mercurou
Page 325 and 326:
Mercurous Compounds 295 but there i
Page 327 and 328:
Mercuric Salts 297 The mercuric sal
Page 329 and 330:
Mercury-Carbon Compounds 299 format
Page 331 and 332:
Mercury-Carbon Compounds 301 (2) Bu
Page 333 and 334:
Mercury-Carbon Compounds 303 The on
Page 335 and 336:
Mercury-Carbon Compounds 305 the de
Page 337 and 338:
Mercury-Carbon Compounds 307 thiona
Page 339 and 340:
Mercury "Carbon Compounds 309 Physi
Page 341 and 342:
Mercury "Carbon Compounds 311 The w
Page 343 and 344:
Mercury-Carbon Compounds 313 into a
Page 345 and 346:
Mercury-Carbon Compounds 315 Acetyl
Page 347 and 348:
Mercury-Nitrogen Compounds 317 low
Page 349 and 350:
Mercury-Nitrogen Compounds 319 The
Page 351 and 352:
Sulphur Compounds 321 On heating th
Page 353 and 354:
Halides presence of potassium fluor
Page 355 and 356:
Oxy-Salts 325 nitric sulphuric and
Page 357 and 358:
Complexes 327 Oxy-salts of Sulphur
Page 359 and 360:
Complexes 329 p. 322) form covalent
Page 361 and 362:
Complexes 331 Complex Sulphides 8 *
Page 363 and 364:
Complexes These sulphonium salts (R
Page 365 and 366:
Group III 335 The change is most cl
Page 367 and 368:
Boron 337 which is thus reached by
Page 369 and 370:
Boron Hydrides 339 derivatives. A f
Page 371 and 372:
Boron Hydrides 341 determined. The
Page 373 and 374:
Boron Hydrides 343 Diborane melts a
Page 375 and 376:
Boron Hydrides 345 By electron diff
Page 377 and 378:
Boron Hydrides 347 It is insoluble
Page 379 and 380:
Alkyl Derivatives 349 450° leaves
Page 381 and 382:
Nitrogen Derivatives 351 is at 100
Page 383 and 384:
Ammonia Derivatives 353 - + - being
Page 385 and 386:
Ammonia Derivatives 355 can be heat
Page 387 and 388:
Triborine Triamine 357 conclusive,
Page 389 and 390:
Triborine Triamine 359 triborine tr
Page 391 and 392:
Oxygen Derivatives 361 L Addition C
Page 393 and 394:
Oxygen Derivatives 363 This has bee
Page 395 and 396:
Borohydrides 365 followed. Recently
Page 397 and 398:
Borohydrides 367 Na and BH4 ions. T
Page 399 and 400:
THalkyls and Triaryls 369 carbide c
Page 401 and 402:
Trialkyls and Triaryls 371 Oxygen*
Page 403 and 404:
Alkyl and Aryl Compounds 373 wein a
Page 405 and 406:
Alkyl and Aryl Compounds 375 Branch
Page 407 and 408:
Allcyl and Aryl Compounds 377 near
Page 409 and 410:
Alkyl and Aryl Compounds 379 The al
Page 411 and 412:
Ammonia Derivatives 381 by the acti
Page 413 and 414:
Oxygen Derivatives joined to three
Page 415 and 416:
Oxygen Derivatives 385 Borotungstat
Page 417 and 418:
Oxygen Derivatives 387 can be isola
Page 419 and 420:
Oxygen Derivatives 389 alcohols whi
Page 421 and 422:
Sulphur and Halogen Derivatives 391
Page 423 and 424:
Trihalides 393 As Meerwein has poin
Page 425 and 426:
Halides 395 the atomic weight of bo
Page 427 and 428:
Halide Derivatives 397 and the chlo
Page 429 and 430:
Nitrogen Complexes 399 upper (ether
Page 431 and 432:
Ammines 401 Boron tricyclohexyl and
Page 433 and 434:
Phosphorus Complexes 403 Methyl bor
Page 435 and 436:
Oxygen Complexes 405 The trihalides
Page 437 and 438:
Oxygen Complexes 407 Li[B(OCH3)J, 2
Page 439 and 440:
Complex Halides 409 by Boeseken and
Page 441 and 442:
Complex Halides 411 agree in not be
Page 443 and 444:
Aluminium Hydride and Carbide 413 c
Page 445 and 446:
Alkyls 415 Brockway and Davidson 39
Page 447 and 448:
Alhyl Compounds 417 ture, 405 while
Page 449 and 450:
Oxide and Hydroxide 419 A kind of i
Page 451 and 452:
Aluminates 421 them. The alkaline s
Page 453 and 454:
Halides 423 with aldehydes) by usin
Page 455 and 456:
Halides 425 The Al—X distance is
Page 457 and 458:
Salts of Oxy-acids 427 the acetate
Page 459 and 460:
Complexes 429 ALUMINIUM COMPLEXES A
Page 461 and 462:
Complexes 431 its benzene solution
Page 463 and 464:
Oxygen Complexes 433 points (especi
Page 465 and 466:
Halide Complexes 435 The 8-hydroxy-
Page 467 and 468:
Friedel-Crafts Reaction 437 tially
Page 469 and 470:
GROUP IIIA THIS subgroup consists o
Page 471 and 472:
Scandium 441 The metal is dimorphic
Page 473 and 474:
Lanthanides 443 ionic moments known
Page 475 and 476:
Lanthanides 445 Relative Abundance
Page 477 and 478:
Metals 447 order of basicities, fal
Page 479 and 480:
Lanihanide Salts 449 curves, the fi
Page 481 and 482:
Ceric Compounds 451 hydrochloric ac
Page 483 and 484:
Abnormal Valencies 453 Tetravalent
Page 485 and 486:
Divalent Compounds 455 Divalent Ytt
Page 487 and 488:
Actinium 457 reduction, samarium, y
Page 489 and 490:
Metals: Hydrides 459 The divalent c
Page 491 and 492:
Alkyls and Aryls 461 Oallium Trialk
Page 493 and 494:
Thallium Alkyls and Aryls Thallium
Page 495 and 496:
Alhyl Thallium Compounds 465 go ove
Page 497 and 498:
Oxides, Calcides 467 Gallium hydrox
Page 499 and 500:
Trihalides 469 (like aluminium and
Page 501 and 502:
Oxy-acid Salts 471 of crystallizati
Page 503 and 504:
Nitrogen and Oxygen Complexes 473 t
Page 505 and 506:
Oxygen Complexes 475 methoxide, m.p
Page 507 and 508:
Divalent Gallium 477 Divalent Galli
Page 509 and 510:
Divalent Indium 479 Aiken, Haley, a
Page 511 and 512:
Monovalent Indium 481 ride, for the
Page 513 and 514:
Thallous Compounds 483 following ta
Page 515 and 516:
Thallous Compounds 485 highly polym
Page 517 and 518:
Thallous Complexes 487 Several oxy-
Page 519 and 520:
Group IV 489 the normal group valen
Page 521 and 522:
Elementary Carbon 491 There are two
Page 523 and 524:
Graphite 493 The positions of the d
Page 525 and 526:
Graphite oxidized, especially by po
Page 527 and 528:
Hydrocarbons 497 established experi
Page 529 and 530:
Free and Restricted Rotation 499 wh
Page 531 and 532:
Ethane Barrier 501 seemed to be sup
Page 533 and 534:
Paraffins 503 It will be seen that
Page 535 and 536:
Olefines 505 Solid hydrates are for
Page 537 and 538:
Ethylene Derivatives 507 in oxygen
Page 539 and 540:
Aromatic Compotmds 509 hydrogenatio
Page 541 and 542:
'Mills-Nixon' Effect 511 5-ring pre
Page 543 and 544:
' Mills-Nixon' Effect 513 It is obv
Page 545 and 546:
Organic Reactivity 515 Bates of Rea
Page 547 and 548:
Organic Reactivity 517 the next. Su
Page 549 and 550:
Metallic Carbides 519 Metallic and
Page 551 and 552:
Binary Carbides 521 the carbon; and
Page 553 and 554:
Organic Oxygen Compounds 523 stable
Page 555 and 556:
Carboxylic Acids 525 The structure
Page 557 and 558:
Co-ordination Compounds 527 Esters.
Page 559 and 560:
Trivalent Carbon Compounds 529 the
Page 561 and 562:
Free Alkyl Radicals 531 which strik
Page 563 and 564:
Triaryl Methyls 533 explained by su
Page 565 and 566:
Triaryl Methyls 535 of a 0-03-molar
Page 567 and 568:
Triaryl Methyls 537 the compounds A
Page 569 and 570:
Triaryl Methyls 539 compound is hig
Page 571 and 572:
Triaryl Methyls 541 difference of e
Page 573 and 574:
Triaryl Methyls 543 The heat of con
Page 575 and 576:
Divalent Carbon 545 With lead the p
Page 577 and 578:
Metallic Garbonyls 547 with the neg
Page 579 and 580:
Metallic Carbonyls 549 Ammines. Car
Page 581 and 582:
GROUP IVB SILICON, GERMANIUM, TIN,
Page 583 and 584:
Hydrides 553 Lead This is more reac
Page 585 and 586:
Hydrides: Carbides 556 n an atmosph
Page 587 and 588:
Organic Compounds 557 increasing at
Page 589 and 590:
Organic Compounds 559 The tin and l
Page 591 and 592:
Silicon Tetra-aryls 561 is 19-3. 49
Page 593 and 594:
Silicon Allcyl Compounds 563 The di
Page 595 and 596:
Silicols acid—dissolves in cold c
Page 597 and 598:
Organic Si—Si Compounds 567 The a
Page 599 and 600:
Germanium Alkyls and Aryls 569 of 0
Page 601 and 602:
Germanium Alhyl Compounds 571 which
Page 603 and 604:
Germanium Alhyl Compounds 573 The a
Page 605 and 606:
Oe—Oe Aryls 575 properties, 597 o
Page 607 and 608:
Stannic Alkyls and Aryls 577 5. By
Page 609 and 610:
Stannic Alhyl Compounds Triphenyl t
Page 611 and 612:
Stannic Alhyl Compounds solvents. A
Page 613 and 614:
Stannic Allcyl Halides These halide
Page 615 and 616:
Distannanes 585 They all dissolve e
Page 617 and 618:
Lead Tetra-alkyls 587 Polystannanes
Page 619 and 620:
Lead aryls 589 ment of alkyls in th
Page 621 and 622:
Lead Alhyl Halides 591 diaryl with
Page 623 and 624:
Lead Aryl Halides 593 through co-or
Page 625 and 626:
Pb—Pb Compounds and PV" Radicals
Page 627 and 628:
Hexa-nryl Diplumbanes 597 get darke
Page 629 and 630:
Silicon Dioxide 599 Tin nitride, Sn
Page 631 and 632:
Silicates: Germanates 601 from Na2O
Page 633 and 634:
Hydroxides: Bisulphides 603 Plumbic
Page 635 and 636:
Tetrahalides Esters of thiostannic
Page 637 and 638:
Silicon Halides 607 compounds gener
Page 639 and 640:
Halides 609 GERMANIUM HYBBIBE-HALID
Page 641 and 642:
Derivatives of Oxy-acids 611 m.pt.
Page 643 and 644:
Oxygen Complexes 613 SnCl4, 2 py ca
Page 645 and 646:
Complex Halides 615 very stable flu
Page 647 and 648:
Divalent Compounds 617 COMPOUNDS OF
Page 649 and 650:
Stannous Compounds 619 would have a
Page 651 and 652:
Stannous Compounds 621 contain stan
Page 653 and 654:
Plumbous Compounds 623 Stannous flu
Page 655 and 656:
Plumbous Compounds 625 of lead. In
Page 657 and 658:
Plumbous Complexes 627 The crystal
Page 659 and 660:
Tetravalent Compounds 629 reflectio
Page 661 and 662:
Metals 631 With hafnium little is k
Page 663 and 664:
Carbides 633 and so it can be got i
Page 665 and 666:
Oxides, Hydroxides 635 Dioxides, AO
Page 667 and 668:
Tetrahalides 637 further proof of t
Page 669 and 670:
Salts of Oxy-acids 639 cent, low at
Page 671 and 672:
Oxygen Complexes 641 Oxygen Complex
Page 673 and 674:
Ato-complexes 643 /°\ Carbonato-co
Page 675 and 676:
Complex Halides 645 Dry hydrogen fl
Page 677 and 678:
Hafnium 647 covered until in 1923 t
Page 679 and 680:
Lower Valencies 649 TRIVALENT AND D
Page 681 and 682:
Divalent Titanium 651 precipitate t
Page 683 and 684:
Divalent Hafnium 053 non-volatile d
Page 685 and 686:
Group V 655 form trivalent cations.
Page 687 and 688:
Elementary Nitrogen 657 carbon-to-c
Page 689 and 690:
Ammonia 659 electrons, and are to a
Page 691 and 692:
Ammonium Halides 661 and —17-6°
Page 693 and 694:
Binary Nitrides 683 in water; they
Page 695 and 696:
Amines, Amides 665 The alkylamines
Page 697 and 698:
Cyanogen Compounds 667 are similarl
Page 699 and 700:
Hydrogen Cyanide 669 obscure. At th
Page 701 and 702:
Complex Cyanides 671 A—Ns=C. 101
Page 703 and 704:
Cyanic Acid 673 verted into nitrile
Page 705 and 706:
Thiocyanic Acid 675 gives the 'dihy
Page 707 and 708:
Cyanogen Halides 677 Cyanogen Halid
Page 709 and 710:
Cyanurates. Amine Oxides 679 known
Page 711 and 712:
Oxides of Nitrogen 681 like NH3, an
Page 713 and 714:
Nitrous and Nitric Oxides 683 solid
Page 715 and 716:
Metallic Nitrosyls 685 oxides of ni
Page 717 and 718:
Nitrosyls 687 than carbonyls; they
Page 719 and 720:
Nitrogen Peroxide 689 velocity of s
Page 721 and 722:
Nitrogen Pentoxide 691 that this wa
Page 723 and 724:
Oxy-acids of Nitrogen 693 /° struc
Page 725 and 726:
Organic Nitrites 695 these are very
Page 727 and 728:
Nitro-compou nds 697 The nitroparaf
Page 729 and 730:
Nitric Acid 699 spectrum in the nea
Page 731 and 732:
Nitrosyl Halides 701 and both of th
Page 733 and 734:
Fluorine Nitrate 703 have shown tha
Page 735 and 736:
Nitrogen Halides 705 occurs at the
Page 737 and 738:
Nitrogen Halides 707 Nitrogen Bromi
Page 739 and 740:
Hydrazine 709 nitrogen in the prese
Page 741 and 742:
A zo-compounds 711 Di-imide HN=NH,
Page 743 and 744:
Azo-compounds 713 melt at 71-4° (t
Page 745 and 746:
Nitramide 715 The first are strong
Page 747 and 748:
Azides 717 From the electron diffra
Page 749 and 750:
Diaryl Nitrogens B. 3-covalent: val
Page 751 and 752:
Aminium Salts 721 A, 2. Ar2N—N—
Page 753 and 754:
Diaryl Nitrogen Oxides 723 suppose
Page 755 and 756:
PHOSPHORUS THE most fundamental dif
Page 757 and 758:
Elementary Phosphorus 121 atmospher
Page 759 and 760:
Phosphine 729 PH8 is basic, but muc
Page 761 and 762:
Phosphines 731 alcohols, 461 or bet
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Phosphorus-Nitrogen Compounds 733 h
Page 765 and 766:
Phosphorus-Nitrogen Compounds 735 t
Page 767 and 768:
Phosphorus Oxides 737 phorus in air
Page 769 and 770:
Oxy-acids of Phosphorus 739 acid HP
Page 771 and 772:
Hypophosphoric Acid 743 of phosphor
Page 773 and 774:
Phosphates 745 much better (2 to 3
Page 775 and 776:
Organo-acids 747 Organo-acids of Ph
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Phosphorus Sulphides 749 The equili
Page 779 and 780:
Oxyhalides 751 Oxyhalides of Phosph
Page 781 and 782:
Halides 753 The trifluoride PF3 is
Page 783 and 784:
Complex Compounds this acid that do
Page 785 and 786:
Complex Halides 757 The P in [PF6],
Page 787 and 788:
Elementary Antimony ?59 Arsenic vap
Page 789 and 790:
Hydrides 761 highly poisonous. At a
Page 791 and 792:
Arsines oxidized by air, especially
Page 793 and 794:
Oxy-compounds 765 A. 2. Trivalent O
Page 795 and 796:
Oxy-compound$ 765 A. 2. Trivalent O
Page 797 and 798:
Halogen Derivatives 767 The phenyl
Page 799 and 800:
Halides 769 Dimethyl arsenic chlori
Page 801 and 802:
A rseno-Compounds 771 it has a norm
Page 803 and 804:
Stibines 773 still attached to the
Page 805 and 806:
Oxy-stibines 775 Oxy-derivatives of
Page 807 and 808:
Halogen Derivatives 777 halogen. (C
Page 809 and 810:
Bismuth, Organic Compounds 779 on a
Page 811 and 812:
Halide Derivatives 781 Bismuth aryl
Page 813 and 814:
Comparison of Carbon Compounds 783
Page 815 and 816:
Arsenic, Oxy-compounds 785 In the s
Page 817 and 818:
Pentoxides 787 Bismuth Trioxide Bis
Page 819 and 820:
Sulphur Compounds 789 The potassium
Page 821 and 822:
Sulphur Compounds 791 Thioantimonit
Page 823 and 824:
Antimony HaKdes 793 at low temperat
Page 825 and 826:
Sb+++ and Bi+++ Salts 795 shows tha
Page 827 and 828:
797 COMPLEX COMPOUNDS THESE are ver
Page 829 and 830:
Pentavalent Complexes 799 A series
Page 831 and 832:
Chelate Complexes 801 The complex b
Page 833 and 834:
Antimony Tetrachloride Derivatives
Page 835 and 836:
Vanadium 805 has no acidic properti
Page 837 and 838:
Vanadium Compounds 807 Vanadium is
Page 839 and 840:
Vanadium Pentoxide 809 Of the highe
Page 841 and 842:
Vcmadic Acid 811 In its properties
Page 843 and 844:
Vanadic Esters one form to another
Page 845 and 846:
Halides, Oxyhalides extra oxygen, e
Page 847 and 848:
Pentavalent Complexes 817 fades to
Page 849 and 850:
Tetrahalides 819 pentoxide with the
Page 851 and 852:
Tetravalent Vanadyl Salts 821 The p
Page 853 and 854:
Ghelate Complexes 823 a violet trih
Page 855 and 856:
Trivalent Compounds 825 Vanadium Se
Page 857 and 858:
Trivalent Oxyhalides A hexahydrate
Page 859 and 860:
Trivalent Complexes 829 number is n
Page 861 and 862:
Trivalent Chelate Complexes 831 pre
Page 863 and 864:
Vanadium Dihalides 833 in the brown
Page 865 and 866:
Niobium 835 The main characteristic
Page 867 and 868:
Peroxyniobates 837 tantalum pentoxi
Page 869 and 870:
Pentavalent Complexes 839 Niobium P
Page 871 and 872:
Pentavalent Complexes complexes is
Page 873 and 874:
Tantalum 843 MONOVALENT NIOBIFM Thi
Page 875 and 876:
Tantalum Compounds 845 Tantalum and
Page 877 and 878:
Pentahalides 847 It is less reactiv
Page 879 and 880:
Penta- and Tetravalent Tantalum 849
Page 881 and 882:
Protoactinium 851 If the aqueous so
Page 883:
Protoactinium 853 as the fourth doe
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