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BAB V KESIMPULAN - Digilib ITS

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<strong>BAB</strong> V<br />

<strong>KESIMPULAN</strong><br />

5.1 Kesimpulan<br />

Berdasarkan pada penelitian yang telah dilakukan, dapat<br />

diambil kesimpulan bahwa suhu fusi mempengaruhi<br />

pembentukan zeolit A dari abu layang. Semakin meningkat suhu<br />

fusi maka kristalinitas padatan yang dihasilkan semakin menurun.<br />

Pada penelitian ini didapatkan bahwa suhu fusi yang terbaik<br />

untuk mensintesis zeolit A adalah 450 °C. Kelarutan Si, Al<br />

terbanyak, kristalinitas yang tertinggi, nilai kapasitas pengikatan<br />

kalsium (CBC) yang tertinggi serta produk yang dihasilkan<br />

merupakan zeolit A murni didapatkan pada suhu fusi 450 °C.<br />

Hasil sintesis zeolit A pada suhu fusi 450 °C yaitu: kapasitas<br />

pengikatan kalsium (CBC) sebesar 448,19 meq/100 g. Sedangkan<br />

pada suhu fusi 400, 500, 550 °C produk yang dihasilkan<br />

merupakan zeolit A bersama dengan faujasit dan pada suhu fusi<br />

600, 650 °C produk yang dihasilkan adalah amorf.<br />

5.2 Saran<br />

Perlu dilakukan studi lebih lanjut mengenai metode yang<br />

sesuai untuk mereduksi kandungan besi pada abu layang batubara<br />

awal serta pengaruh waktu aging terhadap sintesis zeolit A<br />

sehingga didapatkan kristalinitas yang lebih baik.<br />

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DAFTAR PUSTAKA<br />

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Materials.<br />

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and X from Fly Ashes and Their Ion-Exchange Behavior<br />

with Cobalt Ions”, Ind. Eng. Chem. Res., 39, 4185-4191.<br />

Charnell, J.F., (1971), “Gel Growth of Large Crystals of Sodium<br />

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Demortier, A., Gobeltz, N., Lelieur, J.P., Duhayon, C., (1999),<br />

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Compound During The Synthesis of Na-A from<br />

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Materials 1, 129-134.<br />

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Microstructure of Alkali Activated Fly Ash Binder :<br />

67


68<br />

Effect of The Activator”, Cement and Concrete Research<br />

35, 1984-1992.<br />

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Sons Inc., New York.<br />

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Conversion By-Products : Characterization, Utilization,<br />

and Disposal”, Materials Research Society, Mc Carthy,<br />

Massachusetts, Vol. IV, 3-38.<br />

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(1999), “A Two-Step Process for The Synthesis of<br />

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Hazardous Material B 137, 401-409.


69<br />

Inada, M., Eguchi, Y., Enomoyo, N., Hojo, J., (2004), “Synthesis<br />

of Zeolit from Coal Fly Ashes with Different Silica-<br />

Alumina Composition”, Departement of Chemistry and<br />

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Aspect 211, 49-66.<br />

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Materials from Coal Fly Ash”, Mesoporous and materials<br />

112, 170-177.<br />

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Two Method to Produce Zeolit from Fly Ash”, Mineral<br />

Engineering 17, 167-173.<br />

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Fly ash”, J. Env. Eng., hal. 994-1002.<br />

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of Zeolit Synthesis from Coal Fly ash by Alkali


70<br />

Hidrothermal Reaction.<br />

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Fly Ash: Synthesis and Characterization”, Bull. Mater.<br />

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1613-1622.<br />

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A.S., (2001), “Preparation and Catalyic Study of Metal<br />

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N2O”, Microporous and Mesoporous Materials 48, 345-<br />

353.<br />

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Zeolites from Coal Fly ash: An Overview” International<br />

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ash- Based Zeolit-A Using XRD and IR Spectroscopy”,<br />

National Env Eng Res Institut, Nagpur, India.<br />

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Crystalline Faujasite Zeolite from Fly Ash”, Journal of<br />

Hazardous Material B 77, 123-131.<br />

Rayalu, S.S., Udhoji, J.S., Munshi, K.N. dan Hasan, M.Z., (2001),<br />

“High Crystalline Zeolite A form Fly Ash of Bituminous<br />

and Lignite Coal Combustion”, Journal of Hazardous<br />

Materials B 88, 107-121.


71<br />

Rios, C. A., Williams, C. D., Fullen, M. A., (2008), “ Nucleation<br />

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72<br />

Somerset, V., Petrik, L. dan Iwuoha, E., (2007), “Alkaline<br />

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73<br />

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Ash”, Fuel 87, p. 1880–1886.<br />

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(Halaman ini sengaja dikosongkan)


RIWAYAT PENULIS<br />

Penulis bernama lengkap Tri Wahyuni,<br />

dilahirkan di Kediri tanggal 16 Maret<br />

1985. Penulis adalah anak pertama dari<br />

dua bersaudara pasangan Bpk. Ramidi dan<br />

Ibu Sumini. Penulis telah menempuh<br />

pendidikan formal di SDN Pelem II Kec.<br />

Pare (1992-1998), SLTP Negeri I Pare-<br />

Kediri (1998-2001), SMU Negeri II Pare-<br />

Kediri (2001-2004). Penulis selanjutnya<br />

melanjutkan jenjang pendidikan S1 di<br />

Jurusan Kimia FMIPA-<strong>ITS</strong> melalui SPMB<br />

pada tahun 2004 dengan NRP. 1404 100 055. Selama kuliah,<br />

penulis pernah aktif di organisasi kemahasiswaan sebagai staf di<br />

departemen kakak asuh (JMMI) <strong>ITS</strong> periode 2005-2006, sebagai<br />

staf KESMA Himpunan Mahasiswa Kimia (HIMKA) <strong>ITS</strong> periode<br />

2005-2006, staf di departemen keputrian kajian jurusan Kimia<br />

(CIS) periode 2005-2006, staf di departemen syiar Islam kajian<br />

jurusan Kimia (CIS) periode 2006-2007. Penulis mengambil<br />

Tugas Akhir di bidang Kimia Anorganik dalam menyelesaikan<br />

jenjang pendidikan S-1 di Jurusan Kimia FMIPA-<strong>ITS</strong>.

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