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rare earth elements in Wyoming

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Wyo-DOG is a multi-tiered application us<strong>in</strong>g a<br />

structured, relational database. Data is entered via<br />

an application us<strong>in</strong>g the traditional client/server<br />

(two-tier) model. Data <strong>in</strong> the relational database<br />

can be queried directly by common model<strong>in</strong>g<br />

applications such as ESRI’s ArcDesktop or via<br />

custom, <strong>in</strong>clud<strong>in</strong>g Web-based, <strong>in</strong>terfaces. Where<br />

appropriate, data can also be made available to<br />

other model<strong>in</strong>g applications through common<br />

data exchange formats, such as CSV and XML, to<br />

facilitate a variety of uses.<br />

Wyo-DOG can be accessed from the WSGS website<br />

at www.wsgs.uwyo.edu/. Wyo-DOG was <strong>in</strong>itiated<br />

with this project to fulfill the goal of creat<strong>in</strong>g<br />

a statewide catalog of REE occurrences, as well as<br />

occurrences of other resources. It is our hope that<br />

adequate resources, <strong>in</strong>clud<strong>in</strong>g fund<strong>in</strong>g, personnel,<br />

and time, will cont<strong>in</strong>ue to be available to further<br />

expand Wyo-DOG to <strong>in</strong>clude new data types,<br />

<strong>in</strong>vestigations, and the many volumes of historical<br />

data that reside <strong>in</strong> paper files at the WSGS.<br />

samples and Analyses<br />

This <strong>in</strong>vestigation is a survey of various sites across<br />

Wyom<strong>in</strong>g based on grab samples (i.e., small, unmeasured<br />

samples, not necessarily representative of<br />

a larger volume of material). Analyses of these grab<br />

samples can neither confirm nor deny the presence<br />

or absence of economic concentrations of REE<br />

or other <strong>elements</strong>. A grab sample only represents<br />

one small piece of evidence for the occurrence of a<br />

m<strong>in</strong>eral concentration or deposit. The grab sample<br />

is not associated with, nor does it <strong>in</strong>dicate a volume<br />

of material greater than the size of the <strong>in</strong>dividual<br />

sample. The elemental concentrations associated<br />

with a grab sample may or may not extend <strong>in</strong>to the<br />

outcrop from which the sample was collected.<br />

A thorough evaluation of a deposit, as opposed to<br />

a survey of occurrences as presented <strong>in</strong> this report,<br />

requires multiple samples be evaluated across<br />

the range of geologic environments that occur at<br />

a specific location. Each of those samples must<br />

represent a specific volume of relatively uniform<br />

material such that elemental concentrations can be<br />

converted to tonnage estimates across the deposit.<br />

Only then can the economic tenor of the deposit<br />

3<br />

be estimated. No s<strong>in</strong>gle sample can def<strong>in</strong>e or elim<strong>in</strong>ate<br />

the possibility of an economic deposit.<br />

Not all samples are equal. The analysis of a panned<br />

concentrate from a placer sample is not equivalent<br />

to that of a grab sample. A panned concentrate results<br />

from wash<strong>in</strong>g disaggregated gra<strong>in</strong>s <strong>in</strong> the field<br />

with water to separate out the heavy ones from<br />

lighter ones. Analytical results may show relatively<br />

high values for some <strong>elements</strong> <strong>in</strong> the concentrate.<br />

However, to provide proper perspective, a panned<br />

concentrate analysis must be diluted to represent<br />

the orig<strong>in</strong>al larger volume of material from which<br />

the concentrate was derived. This dilution may<br />

reduce reported values by a factor of 10 to 100 or<br />

more, depend<strong>in</strong>g on techniques and equipment<br />

used <strong>in</strong> sampl<strong>in</strong>g. Placer samples are appropriately<br />

described <strong>in</strong> both the text of this report and <strong>in</strong><br />

Wyo-DOG.<br />

All sample analyses collected for this project were<br />

completed by ALS Chemex of Reno, Nevada.<br />

Analytical methods for historical samples <strong>in</strong>cluded<br />

with<strong>in</strong> Wyo-DOG or this report are referred to<br />

as generic if either the laboratory or the method<br />

of analysis is not known. Geochemical analyses<br />

on samples <strong>in</strong>cluded whole rock analyses (major<br />

element concentrations <strong>in</strong> the form of oxides) by<br />

<strong>in</strong>ductively coupled plasma (ICP), atomic emission<br />

spectrometry or mass spectrometry, and atomic<br />

adsorption. These methods, when preceded by effective<br />

preparation techniques, can generally detect<br />

most <strong>elements</strong> present <strong>in</strong> a sample from very low<br />

concentrations <strong>in</strong> the range of less than 0.1 to 5<br />

parts per million (ppm) up to ore-grade concentrations.<br />

To put this <strong>in</strong> perspective, 1.0 percent is<br />

equal to 10,000 ppm.<br />

<strong>rare</strong> Earth Elements def<strong>in</strong>ed<br />

Rare <strong>earth</strong> <strong>elements</strong> (a.k.a. <strong>rare</strong> <strong>earth</strong> metals) are<br />

a group of metallic <strong>elements</strong> with similar physical<br />

and chemical properties. Fifteen of these are<br />

listed <strong>in</strong> the periodic table (table 1) <strong>in</strong> a series<br />

from atomic numbers 57 through 71 known as the<br />

lanthanide series. However, one highly-unstable<br />

element, promethium, does not occur naturally on<br />

<strong>earth</strong>, has a half-life of 17.7 years, and decays <strong>in</strong>to

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