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They can also indicate the sign of optical rotation in the formula orname of an optically active compound. Example: IR-2.3.3 ‘Em’ dashes GRAMMAR IR-2.3 3 þ 5. ( þ ) 589-[Co(en)3 ] ( þ ) 589-tris(ethane-1,2-diamine)cobalt(3þ ) ‘Em’ dashes are used in formulae only when the formulae are structural. (The less precise term ‘long dashes’ was used in Ref. 4.) In names ,‘em’ dashes are used in two ways. (a) To indicate metal–metal bonds in polynuclear compounds. They separate the italicized symbols of the bond partners which are contained in parentheses at the end of the name. Example: 1. [Mn2(CO)10] bis(pentacarbonylmanganese)(Mn—Mn) (b) To separate the individual constituents in names of (formal) addition compounds. Examples: 2. 3CdSO 4 ·8H 2 O cadmium sulfate—water (3/8) 3. 2CHCl3 ·4H2 S·9H2 O chloroform—hydrogen sulfide—water (2/4/9) IR-2.3.4 Special bond indicators for line formulae The structural symbols | —— |and |——| may be used in line formulae to indicate bonds between non-adjacent atom symbols. Examples: 26 1. 2. Me P S Me Ni [Ni(S=PMe 2 )(η 5 -C 5 H 5 )] Ph 2 P (OC) 4 Mn Mo(CO) 3 [(CO) 4 MnMo(CO) 3 ( η 5 -C 5 H 4 PPh 2 )]
IR-2.5 3. 4. IR-2.4 SOLIDUS Me 2 N Cl Pt Et 3 P PEt 3 Pt Cl NMe 2 [(Et 3 P)ClPt(Me 2 NCH 2 CHCHCH 2 NMe 2 )PtCl(PEt 3 )] Ph 2 P H C PPh 2 (OC) 3 Fe FeH(CO) 3 [(OC) 3 Fe( μ -Ph 2 PCHPPh 2 )FeH(CO) 3 ] The solidus (/) is used in names of formal addition compounds to separate the arabic numerals which indicate the proportions of individual constituents in the compound. Examples: 1. BF3 ·2H2 O boron trifluoride—water (1/2) 2. BiCl 3 ·3PCl 5 bismuth trichloride—phosphorus pentachloride (1/3) IR-2.5 DOTS,COLONS, COMMASAND SEMICOLONS IR-2.5.1 Dots Dots are used in formulae in various positions. (a) As right superscripts they indicate unpaired electrons in radicals (see Section IR-4.6.2). Examples: 1. HO * 2 * 2. O 2 (b) As right superscripts in the Kröger–Vink notation of solid-state chemistry, they indicate the unit of positive effective charge (see Section IR-11.4.4). Example: 3. Li x Li; 1 2 x Mg * Li; x V 0 Li,x Cl x Cl GRAMMAR 27
Page 1 and 2: NOMENCLATURE OF INORGANIC CHEMISTRY
Page 3 and 4: International Union of Pure and App
Page 5 and 6: Preface Chemical nomenclature must
Page 7: chains and rings (adapted from Chap
Page 10 and 11: CONTENTS IR-3.3 Isotopes 48 IR-3.4
Page 12 and 13: CONTENTS TABLES Table I Names, symb
Page 14 and 15: GENERALAIMS,FUNCTIONS AND METHODS I
Page 28 and 29: GRAMMAR IR-2.1 IR-2.15 Ordering pri
Page 30 and 31: GRAMMAR IR-2.2 IR-2.2.2 Square brac
Page 32 and 33: (Compare with the use of parenthese
Page 34 and 35: GRAMMAR IR-2.2 (g) In the Kröger-V
Page 36 and 37: 11. ( þ ) 589-[Co(en) 3 ]Cl 3 ( þ
Page 40 and 41: (c) Centre dots in formulae of (for
Page 42 and 43: (b) To separate the subscripts that
Page 44 and 45: GRAMMAR IR-2.8 (d) To designate the
Page 46 and 47: GRAMMAR IR-2.9 Example: 20. IR-2.8.
Page 48 and 49: k as aligating atom designator in t
Page 50 and 51: IR-2.14 LOCANTS GRAMMAR IR-2.14 IR-
Page 52 and 53: GRAMMAR IR-2.15 (j) To indicate ste
Page 54 and 55: GRAMMAR IR-2.15 IR-2.15.3 Other ord
Page 56 and 57: GRAMMAR IR-2.16 Example: 5 1. [Cr2
Page 58 and 59: IR-3 Elements CONTENTS IR-3.1 Names
Page 60 and 61: ELEMENTS IR-3.4 The right lower pos
Page 62 and 63: ELEMENTS IR-3.4 atom. This symbol d
Page 64 and 65: ELEMENTS IR-3.6 The generic terms p
Page 66 and 67: FORMULAE IR-4.2 IR-4.1 INTRODUCTION
Page 68 and 69: FORMULAE IR-4.2 6. Ca 3 (PO 4 ) 2 7
Page 70 and 71: FORMULAE IR-4.4 14. ([CuCl 3 ] ) n
Page 72 and 73: FORMULAE IR-4.4 2 3. [Mo6 O 18] 5
Page 74 and 75: FORMULAE IR-4.4 3. FeO(OH) 4. NaTl(
Page 76 and 77: FORMULAE IR-4.5 IR-4.5 ISOTOPICALLY
Page 78 and 79: FORMULAE IR-4.6 Where it is not fea
Page 80 and 81: IR-5 Compositional Nomenclature, an
Page 82 and 83: 9. SiCl 4 10. Ca3 P 2 silicon tetra
Page 84 and 85: IR-5.3.3 Anions IR-5.3.3.1 Overview
Page 86 and 87: COMPOSITIONALNOMENCLATURE IR-5.3 8.
Page 88 and 89:
COMPOSITIONALNOMENCLATURE IR-5.4 4.
Page 90 and 91:
COMPOSITIONALNOMENCLATURE IR-5.4 Se
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COMPOSITIONALNOMENCLATURE IR-5.5 Ex
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COMPOSITIONALNOMENCLATURE IR-5.7 by
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SUBSTITUTIVE NOMENCLATURE IR-6.2 IR
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SUBSTITUTIVE NOMENCLATURE IR-6.2 Ex
Page 100 and 101:
SUBSTITUTIVE NOMENCLATURE IR-6.2 Ea
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SUBSTITUTIVE NOMENCLATURE IR-6.2 an
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SUBSTITUTIVE NOMENCLATURE IR-6.2 4.
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SUBSTITUTIVE NOMENCLATURE IR-6.2 Th
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SUBSTITUTIVE NOMENCLATURE IR-6.2 en
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Page 112 and 113:
SUBSTITUTIVE NOMENCLATURE IR-6.2 co
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Page 116 and 117:
SUBSTITUTIVE NOMENCLATURE IR-6.3 Ex
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SUBSTITUTIVE NOMENCLATURE IR-6.4 th
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Page 122 and 123:
Page 124 and 125:
ADDITIVE NOMENCLATURE IR-7.1 Note t
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ADDITIVE NOMENCLATURE IR-7.3 12. [T
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ADDITIVE NOMENCLATURE IR-7.3 13. (N
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For heterooligonuclear systems, mor
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ADDITIVE NOMENCLATURE IR-7.4 120 2.
Page 134 and 135:
ADDITIVE NOMENCLATURE IR-7.4 122 9.
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IR-8 Inorganic Acids and Derivative
Page 138 and 139:
INORGANIC ACIDSAND DERIVATIVES IR-8
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Page 142 and 143:
Page 144 and 145:
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Page 148 and 149:
Page 150 and 151:
Page 152 and 153:
Page 154 and 155:
IR-9 Coordination Compounds CONTENT
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IR-9.1 INTRODUCTION IR-9.1.1 Genera
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Examples: IR-9.1.2.6 Coordination n
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COORDINATION COMPOUNDS IR-9.1 Examp
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COORDINATION COMPOUNDS IR-9.2 The f
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COORDINATION COMPOUNDS IR-9.2 11. M
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Examples: 2 1. [PtCl6 ] 3 þ 2. [C
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COORDINATION COMPOUNDS IR-9.2 Donor
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COORDINATION COMPOUNDS IR-9.2 6. O
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COORDINATION COMPOUNDS IR-9.2 Note,
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COORDINATION COMPOUNDS IR-9.2 bridg
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COORDINATION COMPOUNDS IR-9.2 4. 1
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COORDINATION COMPOUNDS IR-9.2 6. OC
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COORDINATION COMPOUNDS IR-9.2 The t
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COORDINATION COMPOUNDS IR-9.3 3. [C
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COORDINATION COMPOUNDS IR-9.3 squar
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COORDINATION COMPOUNDS IR-9.3 Table
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COORDINATION COMPOUNDS IR-9.3 follo
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COORDINATION COMPOUNDS IR-9.3 IR-9.
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Page 198 and 199:
Page 200 and 201:
Page 202 and 203:
COORDINATION COMPOUNDS IR-9.3 The C
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COORDINATION COMPOUNDS IR-9.3 B B A
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COORDINATION COMPOUNDS IR-9.3 The f
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COORDINATION COMPOUNDS IR-9.3 Bis(t
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Page 212 and 213:
IR-10 Organometallic Compounds CONT
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IR-10.2.1.2 Chelation ORGANOMETALLI
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ORGANOMETALLICCOMPOUNDS IR-10.2 tra
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ORGANOMETALLICCOMPOUNDS IR-10.2 Tab
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Page 222 and 223:
ORGANOMETALLICCOMPOUNDS IR-10.2 Exa
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Page 226 and 227:
Page 228 and 229:
ORGANOMETALLICCOMPOUNDS IR-10.2 gro
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Page 232 and 233:
ORGANOMETALLICCOMPOUNDS IR-10.2 7.
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ORGANOMETALLICCOMPOUNDS IR-10.2 aft
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Page 238 and 239:
ORGANOMETALLICCOMPOUNDS IR-10.2 Sub
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ORGANOMETALLICCOMPOUNDS IR-10.3 ref
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Page 244 and 245:
ORGANOMETALLICCOMPOUNDS IR-10.4 nom
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Page 248 and 249:
IR-11.1 INTRODUCTION IR-11.1.1 Gene
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Examples: 3. (Li2 ,Mg)Cl2 denotes a
Page 252 and 253:
SOLIDS IR-11.4 subscripts such as a
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SOLIDS IR-11.6 systems. The use of
Page 256 and 257:
SOLIDS IR-11.6 IR-11.6.3 Crystallog
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SOLIDS IR-11.9 forms or modificatio
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TABLES Table I Names, symbols and a
Page 262 and 263:
TABLES TABLEII 250 Table II Tempora
Page 264 and 265:
TABLES TABLEIII Table III Continued
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Page 268 and 269:
Page 270 and 271:
TABLES TABLEIV 258 Table IV Multipl
Page 272 and 273:
Table VI Element sequence He Ne Ar
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TABLES TABLEVII Table VII Continued
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Page 278 and 279:
Page 280 and 281:
TABLES TABLEVII d The symbol ‘ (
Page 282 and 283:
TABLES TABLE VIII Table VIII Contin
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Page 286 and 287:
Page 288 and 289:
Page 290 and 291:
Page 292 and 293:
TABLES TABLE IX Table IX Names of h
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TABLES TABLE IX Table IX Continued
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Page 298 and 299:
Page 300 and 301:
Page 302 and 303:
Page 304 and 305:
Page 306 and 307:
Page 308 and 309:
Page 310 and 311:
Page 312 and 313:
Table IX Continued TABLES TABLE IX
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Page 316 and 317:
Page 318 and 319:
Page 320 and 321:
Page 322 and 323:
Page 324 and 325:
Page 326 and 327:
Page 328 and 329:
Table IX Continued TABLES TABLE IX
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Page 338 and 339:
Page 340 and 341:
Page 342 and 343:
Page 344 and 345:
Page 346 and 347:
Page 348 and 349:
TABLES TABLE IX b Where an element
Page 350 and 351:
TABLES TABLE X 338 Table X Continue
Page 352 and 353:
Subject Index Element names, parent
Page 354 and 355:
Subject Index stoichiometric names,
Page 356 and 357:
Subject Index Carbene, 109, 291 Car
Page 358 and 359:
Subject Index and diastereoisomers,
Page 360 and 361:
Subject Index isotopes, 48 names, 4
Page 362 and 363:
Subject Index order of constituents
Page 364 and 365:
Subject Index from parent hydrides,
Page 366 and 367:
Subject Index use of commas, 29 use
Page 368 and 369:
Subject Index element names, 46-47
Page 370 and 371:
Subject Index Orthoperiodate, 131,
Page 372 and 373:
Subject Index Phosphoric acid deriv
Page 374 and 375:
Subject Index homonuclear polycycli
Page 376 and 377:
Subject Index hydrogen substitution
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