Ph. D. THESIS 2009

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and medicine: new sensing approaches, vision and perspectives», Current Oppinion in Chemical Biology 2005, 9, 538-544. 13. T. Baldacchini, A.-C. Pons, C. N. LaFratta, J. T. Fourkas, Y. Sun, M. J. Naughton, “Multiphoton laser direct writing of two-dimensional silver structures”, Optics Express, 2005, 13, 1275-1280. List of publications I. N. Tosa, L. Olenic, I. Bratu, R. Turdeanu, I. Turcu, “Infrared and UV-Vis Spectroscopic Study of 3,7,10-Substituted-Phenothiazine Derivatives Adsorbed on Gold Nanoparticles”, Journal of Physics: Conference Series 2009, 182, 012019, 1-5 II. N. Tosa, A. Bende, R. A. Varga, A. Terec, I. Bratu, I. Grosu, “H- Bond-Driven Supramolecular Architectures of the Syn and Anti Isomers of the Dioxime of Bicyclo[3.3.1]nonane-3,7-dione”, Journal of Organic Chemistry 2009, 74, 3944-3947. III. N. Tosa, G. Vitrant, P. L. Baldeck, O. Stephan, I. Grosu, “Fabrication of 3D Metallic Micro/nanostructures by Two-Photon Absorption”, Journal of Optoelectronics and Advanced Materials 2008, 10, 2199-2204. IV. N. Tosa, G. Vitrant, P. L. Baldeck, O. Stephan, S. Astilean, I. Grosu, “Two-photon laser deposition of gold nanowires”, Journal of Optoelectronics and Advanced Materials 2007, 9, 641-645. V. G. Vitrant, J. Bosson , N. Tosa , T. Rosenzveig, O. Stephan, S. Astilean, P.L. Baldeck, “Observation of optical dispersion effects in metallic nanostructures fabricated by laser illumination of an organic polymer doped with metallic salts”, Proceedings of SPIE 2007, 6470, 1-9. VI. N. Tosa, J. Bosson, G. Vitrant, P.L. Baldeck, O. Stephan, “Fabrication of metallic nanowires by two-photon absorption”, Scientific Study&Research-Chemistry&Chemical Engineering 2006, VII, 899-904. VII. N. Tosa, J. Bosson, M. Pierre, C. Rambaud, M. Bouriau, G. Vitrant, O. Stephan, S. Astilean, P. L. Baldeck, “Optical properties of metallic nanostructures fabricated by two-photon induced photoreduction”, Proceedings of SPIE 2006, 6195, 1-8. 21
VIII. J. Bosson-Ehoomann, A. Mihut, N. Tosa, S. Astilean, M. Pierre, C. Rambaud, L. Vurth, P. Baldeck, O. Stephan, „Two-Photon Fabrication of Metallic Nanowires for Plasmonics”, Nonlinear Optics and Quantum Optics 2006, 35, 195-200 . IX. A. Mihis, N. Tosa, L. Drule, „Synthesis of Some Compounds having 1,3-Dioxane Rings with Liquid-Cristalline Properties”, Scientific Bulletin of North University of Baia –Mare 2005, XIX, 185-192. X. N. Tosa, A. Bende. I. Bratu. I. Grosu, „Theoretical Modeling and Experimental Study of Intramolecular Hydrogen-bond in Tetramethyl 3,7-dihydroxybicyclo[3.3.1]nona-2,6-diene-2,4,6,8tetracarboxylate”, Studia Univ. Babes-Bolyai, Chemia 2005, L, 157-162. XI. N. Tosa, A. Bende, S. Pînzaru, I. Grosu, E. Surducan, „Structure and Vibrational Spectra of Tetramethyl 3,7- Dihydroxybicyclo[3.3.1.]nona-2,6-diene-2,4,6,8-tetracarboxylate and Bicyclo[3.3.1]nonane-3, 7-dione”, Studia Univ. Babes-Bolyai, Physica 2004, XLIV, 289-292. 22
Page 1 and 2:
“BABES-BOLYAI” UNIVERSITY CLUJ-
Page 3 and 4:
General Introduction OUTLINE Part A
Page 5 and 6:
3.6.1. Dots 188 3.6.2. 3D structure
Page 7 and 8:
Part A: Synthesis and Structural An
Page 9 and 10:
H 3C H 3C O O O C C O O 1a O O C C
Page 11 and 12:
The two forms are in equilibrium an
Page 13 and 14:
Figu re 4 . Th e 13 C-NMR APT (CDCl
Page 15 and 16:
set used , the anarmonicities that
Page 17 and 18:
Figure 9. ORTEP diagram for the bic
Page 19 and 20: 1.5.1. Tetramethyl 3,7-dihydroxybic
Page 21 and 22: Table 7. The selected molecular par
Page 23 and 24: a b Figure 14. 1 H NMR spectrum (CD
Page 25 and 26: Figure 16. 13 C NMR spectrum APT (C
Page 27 and 28: Absorbance (a. u.) Absorbance (a.u.
Page 29 and 30: icyclo[3.3.1]nonane-3,7-dione solut
Page 31 and 32: m u lt ip let a t a t δ ==1 .7 6 p
Page 33 and 34: Figure 22. 13 C NMR APT spectrum of
Page 35 and 36: Figure 24. NMR investigation of the
Page 37 and 38: (mol·l -1 ) syn 8.8 x10 -3 1.4373
Page 39 and 40: a b Figure 29. 3D FTIR spectra in s
Page 41 and 42: Figure 32. ORTEP diagram for the cy
Page 43 and 44: H2 … N3 = 1.839 Å H5 … N6 = 1.
Page 45 and 46: 2. Conclusions of the part A Differ
Page 47: 20. L. J. Bellamy, “Advanced in I
Page 50 and 51: 2. Experimental part: fabrication a
Page 52 and 53: 3 m 30 m a b Figure 4. Optical imag
Page 54 and 55: (NA 1.25) in phase-contrast (a) and
Page 56 and 57: was chosen instead of an aqueous on
Page 58 and 59: Our goal is to develope a lasser as
Page 60 and 61: Figure 15. a Optical image of gold
Page 62 and 63: the power as parameter exhibits a m
Page 64 and 65: a b Figure 21 a) Optical image of g
Page 66: 4.5.3. 3D structures The 3D structu
Page 69: Selected References 1. E. S. Wu, J.
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