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AP Chemistry “Things To Do” Summer Checklist

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<strong>AP</strong> <strong>Chemistry</strong> <strong>“Things</strong> <strong>To</strong> <strong>Do”</strong><br />

<strong>Summer</strong> <strong>Checklist</strong><br />

The following items must be completed and turned in by the<br />

first day of class. Take the time throughout the summer to<br />

complete these review assignments.<br />

Memorize “<strong>AP</strong> Chemical Naming” and “Stuff I Need to Memorize in <strong>AP</strong><br />

<strong>Chemistry</strong>” handout<br />

Complete the “<strong>AP</strong> Chemical Naming and Formula” worksheet.<br />

Read and understand Chapters 1, 2 and 3. The following<br />

assignments must be completed and checked with solutions:<br />

Ch. 1 Problems #<br />

22,25,29,30,33,36,37,52,57,59,67,75,76,81,82<br />

Ch. 2 Problems #<br />

11,12,16,17,22,26,31,33,36,38,41,44,45,54,56,58,59,64,69,82<br />

Ch. 3 Problems #<br />

13,15,20,24,25,43,47,49,57,60,64,66,72,77,78,80,84,88,100,124<br />

Study and prepare for Chapters 1,2 and 3 Test. You will have Ch. 1, 2<br />

and 3 Test on the second week of school.<br />

If you have any questions, please email at jrolader@walton.k12.ga.us<br />

I will be checking email on a weekly basis.<br />

I will have completed all of the above summer assignments for <strong>AP</strong> <strong>Chemistry</strong> by<br />

the first day of school.<br />

Signature ______________________________________________date_________<br />

Print Name_____________________________________________<br />

E-mail_________________________________________________


Common Ions<br />

CATIONS<br />

+1 +2 +3<br />

+<br />

ammonium NH4 2+<br />

cadmium(II) Cd<br />

3+<br />

cobalt(III) (blue) Co<br />

copper(I) (green) Cu + chromium(II) Cr 2+ chromium (III) Cr 3+<br />

hydronium H3O + copper(II) (blue) Cu 2+ iron(III) Fe 3+<br />

silver Ag + cobalt(II) (blue) Co 2+ lead(III) Pb 3+<br />

iron(II) Fe 2+ nickel(III) Ni 3+<br />

lead(II) Pb 2+ vanadium(III) V 3+<br />

2+<br />

mercury(I) Hg2 mercury(II) Hg 2+<br />

manganese(II) Mn 2+<br />

+4 nickel(II) (green) Ni 2+ +7<br />

tin(IV) Sn 4+ tin(II) Sn 2+ manganese(VII) Mn 7+<br />

lead(IV) Pb 4+ vanadium(II) V 2+<br />

vanadium(IV) V 4+ zinc Zn 2+<br />

ANIONS<br />

1- 2- 3-<br />

acetate CH3COO −<br />

2-<br />

carbonate CO3 3-<br />

phosphite PO3<br />

−<br />

C2H3O2 hypobromite BrO − chromate (yellow) CrO4 2- 3-<br />

phosphate PO4 −<br />

bromite BrO2 arsenate AsO4 3-<br />

−<br />

bromate BrO3 −<br />

perbromate BrO4 hypochlorite ClO − 2-<br />

dichromate (orange) Cr2O7 −<br />

chlorite ClO2 hydrogen phosphate HPO4 2-<br />

−<br />

chlorate ClO3 2-<br />

oxalate C2O4 −<br />

perchlorate ClO4 peroxide O2 2-<br />

cyanide CN − sulfite SO3 2-<br />

−<br />

dihydrogen phosphate H2PO4 sulfate SO4 2-<br />

formate HCOO − −<br />

hydrogen carbonate HCO3 (bicarbonate)<br />

−<br />

hydrogen sulfite HSO3 (bisulfite)<br />

−<br />

hydrogen sulfate HSO4 (bisulfate)<br />

bisulfide HS<br />

2-<br />

thiosulfate S2O3 −<br />

hydroxide OH −<br />

−<br />

nitrite NO2 −<br />

nitrate NO3 hypoiodite IO −<br />

iodite IO2 −<br />

−<br />

iodate IO3 −<br />

periodate IO4 −<br />

permanganate (purple) MnO4 thiocyanate SCN −<br />

STUFF I Need to Memorize in <strong>AP</strong> <strong>Chemistry</strong><br />

Solubility Rules of Common Ionic Compounds in Water at 25°C<br />

Soluble Compounds Exceptions<br />

alkali metals (H + , Li + , Na + , K + , Rb + , Cs + )<br />

ammonium ion (NH 4 + )<br />

nitrates (NO 3 ─ ), bicarbonates (HCO3 ─ ),<br />

chlorates (ClO3 ─ ), perchlorates (ClO 4 ─ ),<br />

acetates (CH 3COO ─ )<br />

halides (Cl ─ , Br ─ , I ─ )<br />

fluorine ion (F ─ )<br />

2─<br />

sulfates (SO4 )<br />

Polyatomic Elements<br />

(Diatomic)<br />

hydrogen H2<br />

nitrogen N2<br />

oxygen O2<br />

fluorine F2<br />

chlorine Cl2<br />

bromine Br2<br />

iodine I2<br />

astatine At2<br />

phosphorus P4<br />

sulfur S8<br />

oxone O<br />

Ag + 2+ 2+<br />

, Hg2 and Pb (<strong>AP</strong>H)<br />

Pb 2+ , Ca 2+ , Sr 2+ ,Ba 2+ and Mg 2+ (CBS/PM)<br />

Ag + 2+ 2+ 2+ 2+ 2+<br />

, Hg2 , Pb , Ca , Sr and Ba<br />

Insoluble Compounds Exceptions<br />

2─ 2─<br />

carbonates (CO3 ), chromates (CrO4 ),<br />

2─ 2─<br />

oxalate (C2O4 ),sulfides (S ),<br />

sulfites (SO3 2─ 3─<br />

), phosphates (PO4 ),<br />

alkali metal ions and NH4 +<br />

hydroxides (OH ─ ) and peroxides (O 2 2─ )<br />

8 Strong Acids (H + )<br />

(all other acids are weak)<br />

hydrochloric acid HCl<br />

hydrobromic acid HBr<br />

hydroiodic acid HI<br />

perchloric acid HClO4<br />

chloric acid HClO3<br />

nitric acid HNO3<br />

periodic acid HlO4<br />

sulfuric acid H2SO4<br />

alkali metal ions and NH 4 +<br />

*Ca 2+ , *Sr 2+ and Ba 2+ (CBS)<br />

Metric Prefixes<br />

kilo- k 10 3<br />

deci- d 10 −1<br />

centi- c 10 −2<br />

milli- m 10 −3<br />

micro- µ 10 −6<br />

nano- n 10 −9<br />

(CBS/<strong>AP</strong>H)<br />

8 Strong Bases (OH − )<br />

(all other bases are weak)<br />

lithium hydroxide LiOH<br />

sodium hydroxide NaOH<br />

potassium hydroxide KOH<br />

rubidium hydroxide RbOH<br />

cesium hydroxide CsOH<br />

calcium hydroxide *Ca(OH)2<br />

strontium hydroxide *Sr(OH)2<br />

barium hydroxide Ba(OH)2<br />

*Limited solubility


IONIC compound<br />

(metal + nonmetal)<br />

1) name the first element. Use roman<br />

numerals for d-block metals with<br />

more than 1 one oxidation number.<br />

2) name the second element with the<br />

–ide ending<br />

Ex: NaCl – sodium chloride<br />

CuCl2 – copper(II) chloride<br />

d-block metals:<br />

Cr 2+ , Cr 3+ , Cu 1+ , Cu 2+ , Co 2+ , Co 3+ , Fe 2+ , Fe 3+ ,<br />

Pb 2+ , Pb 3+ , Pb 4+ , Mn 2+ , Mn 7+ , Hg 2+ , Hg2 2+ ,<br />

Ni 1+ , Ni 2+ , Sn 2+ , Sn 4+ , V 2+ , V 3+ , V 4+<br />

ACID<br />

(compound beginning with hydrogen)<br />

1) hydrogen + halogen<br />

a) name hydro- for H atom<br />

b) replace the –ine ending of the<br />

halogen with –ic ending<br />

c) add the word acid<br />

Ex: HCl – hydrochloric acid<br />

2) hydrogen + polyatomic ion<br />

a) polyatomic ion has ending:<br />

replace –ate with –ic<br />

replace –ite with -ous<br />

b) add the word acid<br />

Ex: H2SO4 – sulfuric acid<br />

H2SO3 – sulfurous acid<br />

<strong>AP</strong> CHEMICAL NAMING<br />

COVALENT compound<br />

(nonmetal + nonmetal)<br />

1) name the first element using the<br />

proper prefix (never use mono-)<br />

2) name the second element using the<br />

proper prefix with the –ide ending<br />

Ex: NO – nitrogen monoxide<br />

N2O5 – dinitrogen pentoxide<br />

Prefixes:<br />

1 2 3 4 5 6 7 8 9 10<br />

mono di tri tetra penta hexa hepta octa nano deca<br />

ORGANIC compound including Hydrocarbons<br />

(compounds containing any of the following elements: C, O, H, N)<br />

1) identify compound as: Alkanes (all single bonds) = CnH2n+2 Ex: CH4 – methane<br />

Alkenes (at least 1 double bond)= CnH2n Ex: C3H6 – propene<br />

Alkynes (at least 1 triple bond)= CnH2n―2 Ex: C2H2 – ethyne<br />

(commonly known as acteylene)<br />

2) using the proper prefix to represent the number of CARBON atoms in the compound.<br />

3) if compound has an alcohol group (-OH), use the –ol ending. Ex: C4H9OH – butanol<br />

Prefixes according to the # of CARBON atoms:<br />

1 2 3 4 5 6 7 8 9 10 12 17<br />

meth eth prop but pent hex hept oct non dec dodec heptadec<br />

compound w/ POLYATOMIC ION<br />

(metal or nonmetal + polyatomic ion)<br />

1) use the rules for naming ionic<br />

compounds<br />

2) never modify the special name of<br />

the polyatomic ion<br />

Ex: NaHCO3 – sodium bicarbonate<br />

NH4Cl – ammonium chloride<br />

Fe(NO3)3 – iron (III) nitrate<br />

short-cuts:<br />

sulfate (SO4 2- ) – -ate ending for<br />

polyatomic ions with more oxygen atoms<br />

sulfite (SO3 2- ) – -ite ending for ions with<br />

less oxygen atoms<br />

Ex: nitrate (NO3 ― ) nitrite (NO2 ― )


<strong>AP</strong> CHEMICAL NAMING and FORMULA Worksheet<br />

IONIC Compound<br />

Chemical Name Chemical Formula<br />

iron(III) phosphide<br />

NiSe<br />

lithium oxide<br />

nickel(I) bromide<br />

aluminum sulfide<br />

K2O<br />

lithium arsenide<br />

copper(II) oxide<br />

vanadium(III) selenide<br />

beryllium oxide<br />

strontium sulfide<br />

Pb3N4<br />

CaBr2<br />

Zn3N2<br />

Co2S3<br />

FeO<br />

AgCl<br />

BaCl2<br />

Mn2O7<br />

Cu2S<br />

POLYATOMIC Compound<br />

Chemical Name Chemical Formula<br />

sodium hydroxide<br />

ammonium sulfate<br />

cobalt(III) nitrate<br />

zinc phosphate<br />

copper(II) cyanide<br />

magnesium chlorate<br />

aluminum carbonate<br />

nickel(II) hydroxide<br />

Cu(CH3COO)2<br />

SnCr2O7<br />

KMnO4<br />

K2SO3<br />

Sn(OH)2<br />

H2O2<br />

Cr(NO2)3<br />

CoCO3<br />

CuHCO3<br />

Mn(NO3)7<br />

Ga2(SO4)3<br />

AgNO3<br />

COVALENT Compound<br />

Chemical Name Chemical Formula<br />

chlorine dioxide<br />

dinitrogen trisulfide<br />

phosphorus triiodide<br />

selenium hexafluoride<br />

sulfur tetrachloride<br />

nitrogen trifluoride<br />

dinitrogen monoxide<br />

dinitrogen tetroxide<br />

SbBr3<br />

IF5<br />

N2O3<br />

NH3<br />

P4S5<br />

O2<br />

Si2Br6<br />

B2Si<br />

S2Cl2<br />

OF2<br />

Cl2O8<br />

SO3<br />

ACID<br />

Chemical Name Chemical Formula<br />

HBr<br />

CH3COOH<br />

nitric acid<br />

hypochlorous acid<br />

phosphoric acid<br />

hydrofluoric acid<br />

hydrochloric acid<br />

perchloric acid<br />

sulfurous acid<br />

bromic acid<br />

chlorous acid<br />

hydriodic acid<br />

HNO2<br />

HCN<br />

H2CO3<br />

HClO3<br />

H2SO4<br />

H2C2O4<br />

HF<br />

H2CrO4


ORGANIC Compound<br />

Chemical Name Chemical Formula<br />

butene<br />

pentane<br />

ethyne<br />

pentene<br />

hexyne<br />

octane<br />

propyne<br />

heptene<br />

heptadecyne<br />

methanol<br />

dodecanol<br />

<strong>AP</strong> CHEMICAL NAMING and FORMULA Worksheet<br />

C3H8<br />

C2H5OH<br />

C8H16<br />

C4H9OH<br />

C7H12<br />

C9H16<br />

C2H2<br />

C6H14<br />

C10H18<br />

CUMULATIVE<br />

Chemical Name Chemical Formula<br />

heptene<br />

phosphoric acid<br />

barium fluoride<br />

aluminum bicarbonate<br />

aluminum iodide<br />

iron(III) oxalate<br />

sulfuric acid<br />

nitrogen dioxide<br />

barium phosphate<br />

boron trichloride<br />

nitrogen gas<br />

copper(I) acetate<br />

propanol<br />

carbon monoxide<br />

ethyne<br />

diphosphorus pentoxide<br />

nitrous acid<br />

magnesium hydroxide<br />

NH4NO3<br />

Mg3P2<br />

MnO<br />

IO9<br />

PbCrO4<br />

ZnO<br />

CaH2<br />

SnO2<br />

C9C20<br />

N2H4<br />

HNO3<br />

C4H6<br />

CdF2<br />

Hg2Br2<br />

PI3<br />

Fe(CH3COO)3<br />

HCl<br />

CuCl<br />

KNO3<br />

Pb(SO3)2<br />

H2SO3<br />

NH4Cl<br />

K3PO4<br />

C5H12<br />

CH4

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