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toluene - National Park Service

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hydrocarbons; in exhaust of rotary gasoline engine: 16.3%<br />

of emitted hydrocarbons; in exhaust of gasoline engine:<br />

0.1-7.0 ppm (partly crotonaldehyde); in gasoline: 6-7 vol<br />

%. [Verschueren, K. Handbook of Environmental Data of<br />

Organic Chemicals. 2nd ed. New York, NY: Van Nostrand<br />

Reinhold Co., 1983. 1104<br />

Forms/Preparations/Formulations:<br />

Information from HSDB [609]:<br />

Research, reagent, nitration - all 99.8+%; Industrial:<br />

Contains 94+%, with 5% xylene and small amounts of<br />

benzene and nonaromatic hydrocarbons; 90/120: Less pure<br />

than industrial. [U.S. Coast Guard, Department of<br />

Transportation. CHRIS - Hazardous Chemical Data. Volume<br />

II. Washington, D.C.: U.S. Government] Printing Office,<br />

1984-5.<br />

Grades: Research 99.99%; Pure 99.98% [Flick, E.W.<br />

Industrial Solvents Handbook. 3rd ed. <strong>Park</strong> Ridge, NJ:<br />

Noyes Publications, 1985. 48].<br />

Grades: 1st degree nitration; 2nd degree commercial; 90%<br />

solvent [DCE/NCI; Monograph On Human Exposure To<br />

Chemicals In The Workplace: Toluene p.1-1 (1985)].<br />

Chem.Detail: Detailed Information on Chemical/Physical Properties:<br />

Solubilities:<br />

Water solubility ranges from 265 to 1581 mg/L at 25 degrees C<br />

(most values 515 to 580) [902].<br />

Toluene, with a water solubility of 535 mg/L at 25 deg C<br />

[866], is "moderately soluble" according to one source [866].<br />

SOL IN PETROLEUM ETHER. [Weast, R.C. (ed.) Handbook of<br />

Chemistry and Physics. 67th ed. Boca Raton, FL: CRC Press,<br />

Inc., 1986-87.,p. C-518] [609].<br />

Miscible with alcohol, chloroform, ether, acetone, glacial<br />

acetic acid, carbon disulfide [Budavari, S. (ed.). The Merck<br />

Index - Encyclopedia of Chemicals, Drugs and Biologicals.<br />

Rahway, NJ: Merck and Co., Inc., 1989. 1501] [609].<br />

Soluble in alcohol, ether, acetate, benzene, ligand [Lide,<br />

D.R. (ed). CRC Handbook of Chemistry and Physics. 72nd ed.<br />

Boca Raton, FL: CRC Press, 1991-1992.,p. 3-488] [609].<br />

Vapor Pressure:<br />

855 to 4000 Pa at 25 degrees C (most values near 3786) [902].

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